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At least 685 records · Page 38

A prototype cooling blanket for mitigating occupant overheating risk in a hot indoor environment: Modeling and assessments

Conventional ways of cooling a room or an entire house for occupant thermal comfort during summer consume a significant amount of energy and are vulnerable to overheating risk during power outages that lead to loss of cooling system operations. This study investigates a low-power cooling blanket, as a Personal Cooling System (PCS), that covers the upper human body for direct cooling during a five-day heat wave in a single-family house. A modeling framework is developed for evaluating the thermal and energy performance of the cooling blanket, which builds upon the co-simulation of three models: a house energy model, a personal thermal comfort model, and a cooling blanket model. Simulation results show that under the power outage scenario, the cooling blanket can greatly reduce the occupant heat stress with a reduction of daily hours of exceedance (discomfort hours defined as TSV>2) by up to 17.2 h (a 95.3 % improvement from the baseline power outage without the blanket). The cooling blanket, equipped with an innovative electrocaloric heat pump (COP as high as 10.1) consumes 6.31 W and can be operated by a portable battery for several days. The cooling blanket consumes only 0.28 % of the electricity of a central air-conditioning system running to provide cooling for the whole house during the five-day heatwave period. The findings justify further research of electrocaloric wearable PCS as low-power effective cooling to ensure thermal survivability of occupants during extreme indoor environments.

Electrocaloric heat pump↗

Achieving SEI preformed graphite in flow cell to mitigate initial lithium loss

The irreversible lithium loss due to the formation of solid electrolyte interphase (SEI) in the initial cycle on the graphite anode greatly reduces the overall cell energy density of lithium ion batteries, that is, the lost Li ions from forming SEI lead to the decrease of Li ions for the intercalation. The method of cathode prelithiation has been widely explored to compensate this lithium loss. However, these cathode additives with high lithium contents inevitably lower the loading of the cathode active materials. In this work, we report a novel approach to solve this challenge, a facile graphite prelithiation method by preforming SEI layers on the surface of graphite powders (Pre-SEI graphite) utilizing a specially designed flow cell. The Li accommodation in the graphite anode can be controlled by the operating time and current density in the flow cell for the electrochemical SEI formation. As a result, we demonstrate a 10% initial Columbic efficiency increase of the LiFePO 4 electrode in a full cell configuration using the Pre-SEI graphite, compared with the pristine graphite anode. The electrochemical preformation of SEI on the graphite powders offers a complete solution to offset initial lithium loss without a sacrifice of active cathode material loading.

25 ENERGY STORAGE↗

Win-win transportation strategies for India: Linking air pollution and climate mitigation

Here, this article analyzes road transport in India to explore linkages between air pollution and climate change policies in the transportation sector. Five teams modeled five policy scenarios – fuel efficiency, electrification, alternative fuels, modal shifts, and moderation in transport demand – to explore which policy brings the largest synergetic effects in reducing carbon dioxide (CO 2 ) and particulate matter (PM 2.5 ) emissions. The teams also modeled the comprehensive scenario which included policy measures from individual scenarios. The paper concludes that all of the measures provide strong co-benefits in reducing air pollutant and CO 2 emissions. The modeling results show that increased energy efficiency of passenger and freight vehicles has the largest protentional for reducing both CO 2 and PM 2.5 emissions. It is possible to reach even a larger reduction of air pollutants and CO 2 emissions by combining several policy measures in the comprehensive scenario.

54 ENVIRONMENTAL SCIENCES↗

Ionic Interdiffusion at Cathode|Solid-Electrolyte Interface: A Machine Learning–Assisted Multiscale Investigation and Mitigation Strategies

Future lithium batteries are expected to use solid electrolytes to achieve higher energy density and fast charge capabilities. However, most solid electrolytes are thermodynamically unstable against layered oxide cathodes. In this study, the stability of LiCoO2 (LCO) cathode with Li10GeP2S12 (LGPS) solid electrolyte is investigated using ab initio molecular dynamics (AIMD) and machine learning molecular dynamics (MLMD). The propensity of ionic interdiffusion, formation of a passivating interphase layer, and corresponding decay in cell performance is addressed using a continuum model. Large-scale MLMD simulations confirm that the LCO|LGPS interface permits interdiffusion of cobalt (Co) and other ionic species, leading to the formation and growth of a resistive interphase and to dramatic capacity fade even in the first cycle. We examine the literature evidence that incorporating a thin layer of LiNb0.5Ta0.5O3 (LNTO) between LCO and LGPS prevents the interdiffusion of ions. Atomistic simulations suggest that substituting lithium (Li) in LNTO with Co is thermodynamically unfavorable, thereby inhibiting ionic interdiffusion. The stable Nb5+/Ta5+ states form a rigid metal-oxide framework, which consequently also prevents the substitution of niobium (Nb) or tantalum (Ta). However, continuum-level analysis suggests that the higher mechanical stiffness of LNTO can lead to interfacial delamination between the LCO and LNTO. This phenomenon reduces the effectiveness of the protective layer. This paper, therefore, highlights the need to develop novel interlayers that balance low ionic interdiffusion with low mechanical stiffness.

Ncube, Musawenkosi K.↗

Mitigating the soil carbon deficit of annual agriculture with perennial bioenergy crops in the U.S. Midwest

Maize ( Zea mays L.) is the dominant bioenergy feedstock in the US Midwest but its cultivation since the early 1800s has incurred substantial losses in soil organic carbon (SOC). We quantified differences in SOC stocks under perennial bioenergy crops of Panicum virgatum L. (switchgrass) and Miscanthus x giganteus Greef et Deuter (miscanthus) planted on former maize and soybean fields relative to maize-based annual cropping and native prairie. Comparisons were made at seven locations across Illinois, USA, spanning a range of climate and soil types. Across sites, SOC stocks to 1-m depth on an equivalent soil mass basis were 146 Mg C ha −1 under prairie, 107 Mg C ha −1 under miscanthus, 97.9 Mg C ha −1 under switchgrass, and 87.7 Mg C ha −1 under maize. Higher SOC demonstrates the potential of perennial bioenergy crops to rebuild the SOC deficit accrued under nearly two centuries of maize-based annual cropping. SOC stock increased in the first 5 years under mature bioenergy crops at four out of seven sites. Carbon isotope (δ 13 C) analyses of surface depths confirmed short-term increases in SOC to be derived from miscanthus and switchgrass. Stocks of SOC could be increased over time under miscanthus or switchgrass cultivation even with annual harvesting, though our measured rates of SOC accumulation were lower than previous estimates for Illinois and varied by site.

bioenergy↗