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At least 685 records · Page 38

A General Study of Counterflow Diffusion Flames for Supercritical CO2 Combustion

Abstract A counterflow diffusion flame for supercritical CO2 combustion is investigated at various CO2 dilution levels and pressures by accounting for real gas effects into both thermal and transport properties. The UCF 1.1 24-species mechanism is used to account the chemistry. The nature of important nonpremixed combustion characteristics such as Prandtl number, thermal diffusivity, Lewis number, stoichiometric scalar dissipation rate, flame thickness, and Damköhler number are investigated with respect to CO2 dilution and pressure. The results show that the aforementioned parameters are influenced by both dilution and pressure; the dilution effect is more dominant. Further, the result shows that Prandtl number increases with CO2 dilution and at 90% CO2 dilution, the difference between the Prandtl number of the inlet jets and the flame is minimal. Also, the common assumption of unity Lewis number in the theory and modeling of nonpremixed combustion does not hold reasonable for sCO2 applications due to large difference of Lewis number across the flame and the Lewis number on the flame drop significantly with an increase in the CO2 dilution. An interesting relation between Lewis number and CO2 dilution is observed. The Lewis number of species drops by 15% when increasing the CO2 dilution by 30%. Increasing the CO2 dilution increases both the flow and chemical timescales; however, chemical timescale increases faster than the flow timescales. The magnitudes of the Damköhler number signify the need to consider finite rate chemistry for sCO2 applications. Further, the Damköhler numbers at 90% sCO2 dilution are very small; hence, laminar flamelet assumptions in turbulent combustion simulations are not physically correct for this application. Also, it is observed that the Damköhler number drops nonlinearly with increasing CO2 dilution in the oxidizer stream. This is a very important observation for the operation of sCO2 combustors. Further, the flame thickness is found to increase with CO2 dilution and reduce with pressure.

Engineering↗

Modeling Premixed Flame Response to Transverse Acoustic Modes

During a thermoacoustic instability, the flame is disturbed by both the “direct” acoustic waves, as well as the “indirect” vortical structures excited by the acoustic disturbances. For lower frequency axial modes, there is significant evidence that the “indirect” vortical disturbances are much larger in magnitude and dominate the heat release excitation. This paper provides an analysis of the “direct” velocity coupled flame response to transverse modes; it was motivated by phenomenological arguments by prior researchers showing that these modes always have positive Rayleigh indices, because of the nature of the phasing between pressure, velocity, and unsteady heat release. This paper presents a modeling framework using the G-equation that captures the direct acoustic excitation of the flame with the effects of convective transport of wrinkles, flame displacement and flame propagation. Calculations for the Rayleigh index associated with direct excitation are shown for the first set of purely radial (0, m) and mixed radial-tangential (l, m) modes. Consistent with the results from prior phenomenological arguments, these results show that the Rayleigh index is always greater than zero for some modes – namely (0,1), (1,2) and (2,1), but others have zones of both positive and negative Rayleigh index, such as (1,1). The results also showed that the Rayleigh index decreases considerably much faster with increases in the azimuthal mode number than the radial mode number. This indicates a general tendency for flames to be relatively less unstable in higher azimuthal modes than in higher radial modes.

Acharya, Vishal S.↗

Flame inhibition by hydrogen halides - Some spectroscopic measurements

The far-ultraviolet absorption spectrum of an air-propane diffusion flame inhibited with hydrogen halides has been studied. Plots of the absorption of light by hydrogen halides as a function of position in the flame and also as a function of the amount of hydrogen halide added to the flame have been obtained. The hydrogen halides are shown to be more stable on the fuel side of the reaction zone than they are on the air side. Thermal diffusion is seen to be important in determining the concentration distribution of the heavier hydrogen halides in diffusion flames. The relationship between the concentration distribution of the hydrogen halides in the flame and the flame inhibition mechanism is discussed.

Lerner, N. R.↗

Statistical model for premixed turbulent flames

Statistical concepts and physical arguments are used to develop closure models for the mean energy equation governing one-dimensional, premixed, intense turbulent flames. It is proposed that the turbulent transport terms can be modeled by a turbulent conductivity based on turbulence kinetic energy (k) and energy dissipation rate (epsilon). The models obtained are used to derive correlations for the turbulent flame speed. Results show that there are three different flame regimes: a low-intensity turbulence, wrinkled flame; a high-intensity, fast-chemistry flame; and a high-intensity, finite-rate-chemistry flame.

Gouldin, F. C.↗

Premixed flame propagation characteristics in a supersonic airstream

Measured values of flame angles are presented to aid the design of premixed combustion chambers and prediction of flame propagation. Flame spread, velocity, and dependence of burning rate on the properties of unburned flow and on turbulence levels are compared with the measured values. The premixed flame angle is found proportional to the amount of heat released, and correlates readily with the fuel mixture ratio through the rate of heat release or rate of water formation. Finite rate combustion affects flame angle mostly at off-stoichiometric conditions. The pilot affects the flame angle if abundant unburnt fuel is present in the pilot hot gases. Viscosity runs several times over the rated level.

Agnone, A. M.↗

Characteristics of laminar gas jet diffusion flames under the influence of elevated gravity

Laminar gas jet diffusion flames of hydrogen, methane, ethane, and propane, stabilized on small cylindrical burners, were studied at elevated gravity in a centrifuge to investigate the role of buoyancy in such flames. Photographic observation of the hydrocarbon flames indicated that length and carbon luminosity decreased with increasing buoyancy. These flames eventually separated from the burner rim and finally extinguished as gravity increased. Hydrogen flames, however, did not separate or extinguish up to about 31 times earth normal gravity. Length data are reported and interpreted with the aid of a simplified model which describes the flame as a heated vertical cylindrical sheet to which oxygen is supplied by a free convection boundary layer.

Altenkirch, R. A.↗

A high-pressure premixed flat-flame burner for chemical process studies

A premixed flat-flame burner was designed and tested with methane-air mixtures at pressures from 1.1 to 20 atm and equivalence ratios from 0.7 to 1.1. Reactant velocity in the burner mixing chamber was used to characterize the range of stable flames at each pressure-equivalence-ratio condition. Color photographs of the flames were used to determine flame zone thickness and flame height. The results show that this burner can be used for chemical process studies in premixed high pressure methane-air flames up to 20 atm.

Miller, I. M.↗

Coherent Anti-stokes Raman Spectroscopy (CARS) of gun propellant flames

Temperature measurements were made in a slightly fuel rich, premixed propane/air reference flame and nitrate ester propellant flames burning in air at atmospheric pressure using coherent anti-stokes raman scattering (CARS). Both single and multiple pulse VARS spectra of nitrogen in the reference flame were in good agreement with calculated and reported values. Single pulse CARS nitrogen spectra obtained in the propellant flames were analyzed to give temperatures consistent with values calculated using the NASA-Lewis thermochemical calculation. Comparison of a 0.1 second separated sequence of single pulse CARS spectra indicate turbulent air mixing in these propellant flames. The CARS spectral results demonstrate that temporal and spatially resolved temperature measurements could be determined in transient, turbulent flames.

Mcilwain, M. E.↗

Temperature and velocity measurements in premixed turbulent flames

Turbulent flame speed data for premixed flames of methane-air, propane-air and ethylene-air mixtures stabilized in grid turbulence are reported and discussed. It is shown that turbulence effects on flame speed cannot be fully correlated by the turbulence length scale and r.m.s. velocity in the cold flow. Rather there appear to be significant flame-flow-turbulence interactions affecting both turbulence level in the reaction zone and measured flame speeds. Results of detailed velocity measurements, including autocorrelations, by laser velocimetry are used to elucidate the nature of these interactions. It is concluded that flame speed experiments must be designed and conducted to provide sufficient information (e.g., boundary conditions) to allow for reconstruction of the flow field and these interactions by modelers if the data are to be of value in turbulent combustion model development and evaluation.

Dandekar, K. V.↗

The premixed flame in uniform straining flow

Characteristics of the premixed flame in uniform straining flow are investigated by the technique of activation-energy asymptotics. An inverse method is used, which avoids some of the restrictions of previous analyses. It is shown that this method recovers known results for adiabatic flames. New results for flames with heat loss are obtained, and it is shown that, in the presence of finite heat loss, straining can extinguish flames. A stability analysis shows that straining can suppress the cellular instability of flames with Lewis number less than unity. Strain can produce instability of flames with Lewis number greater than unity. A comparison shows quite good agreement between theoretical deductions and experimental observations of Ishizuka, Miyasaka & Law (1981).

Durbin, P. A.↗

The detailed chemistry and thermodynamics of sodium in oxygen-rich flames

Measurement of sodium and OH concentrations in ten oxygen-rich H2/O2/N2 flames by respective saturated and low-power laser induced fluorescence techniques have permitted a detailed examination of the pronounced flame chemistry of sodium in such oxygen rich media. Previous interpretations have been shown to be largely incomplete or in error. The flame downstream profiles indicate that the amount of free sodium tracks the decay of H-atom and as the flame radicals decay sodium becomes increasingly bound in a molecular form. A detailed kinetic model indicates that the sodium is distributed between NaOH and NaO2 species. Concentrations of NaO are very small and NaH negligible. The actual distribution is controlled by the state of equilibrium of the flames' basic free radicals. Na, NaO2 and NaOH are all coupled to one another by fast reactions which can rapidly interconvert one to another as flame conditions vary. Above about 2000K, NaOH becomes dominant whereas NaO2 plays an increasingly important contribution at lower temperatures.

Hynes, A. J.↗

An invariant derivation of flame stretch

The flame stretch factor is derived using an invariant formulation in a consistent manner. The derived generalized expression has two terms and completely describes the flame area evolution with its movement. One term represents the stretch due to the nonuniform tangential velocity field and the other represents the effect of the curvature of the propagating flame. The effect of curvature for stationary flames is implicitly included in the former term through variations of the tangential velocity. The flame sheet assumption, and thereby the stretch factor, are uniquely defined. Another expression is derived under the assumption that the tangential velocity of the flame equals the tangential component of the fluid velocity.

Chung, S. H.↗

Diffusion flame extinction in slow convenctive flow under microgravity environment

A theoretical analysis is presented to study the extinction characteristics of a diffusion flame near the leading edge of a thin fuel plate in slow, forced convective flows in a microgravity environment. The mathematical model includes two-dimensional Navier-Stokes momentum, energy and species equations with one-step overall chemical reaction using second-order finite rate Arrhenius kinetics. Radiant heat loss on the fuel plate is applied in the model as it is the dominant mechanism for flame extinguishment in the small convective flow regime. A parametric study based on the variation of convective flow velocity, which varies the Damkohler number (Da), and the surface radiant heat loss parameter (S) simultaneously, is given. An extinction limit is found in the regime of slow convective flow when the rate of radiant heat loss from fuel surface outweighs the rate of heat generation due to combustion. The transition from existent envelope flame to extinguishment consists of gradual flame contraction in the opposed flow direction together with flame temperature reduction as the convective flow velocity decreases continuously until the extinction limit is reached. A case of flame structure subjected to surface radiant heat loss is also presented and discussed.

Chen, C. H.↗

Propagation of a premixed flame in a divided-chamber combustor

The propagation of premixed ethylene-air mixtures (of 0.5, 0.525, 0.55, and 0.65 equivalence ratios) in a divided-chamber combustor was investigated. The vessel, divided by a small cylindrical prechamber, had optical access (for laser-schlieren videography) and was instrumented by a pressure transducer. For the Reynolds numbers of 1870, 2300, and 2830, the observed spatial development of the laminar flames showed that the flame position and shape could be scaled by a characteristic time, based on the burned gas flame speed and the length of the prechamber. Above a Reynolds number of 4330, this scaling breaks down the appearance of Kelvin-Helmholtz instabilities. The observed flame propagation was compared with predictions obtained with a numerical model of flame propagation. The calculated spatial and temporal development of the flame in the main combustion chamber agreed with the experimental observations only for the lowest Reynolds number (1870).

Cattolica, R. J.↗

Heat and mass transfer in flames

Heat- and mass-transfer processes in turbulent diffusion flames are discussed, considering turbulent mixing and the structure of single-phase flames, drop processes in spray flames, and nonluminous and luminous flame radiation. Interactions between turbulence and other phenomena are emphasized, concentrating on past work of the author and his associates. The conserved-scalar formalism, along with the laminar-flamelet approximation, is shown to provide reasonable estimates of the structure of gas flames, with modest levels of empiricism. Extending this approach to spray flames has highlighted the importance of drop/turbulence interactions; e.g., turbulent dispersion of drops, modification of turbulence by drops, etc. Stochastic methods being developed to treat these phenomena are yielding encouraging results.

Faeth, G. M.↗

Diffusion flame extinction in slow convection flow under microgravity environment

A theoretical analysis is presented to study the extinction characteristics of a diffusion flame near the leading edge of a thin fuel plate in slow, forced convective flows in a microgravity environment. The mathematical model includes two-dimensional Navier-Stokes momentum, energy and species equations with one-step overall chemical reaction using second-order finite rate Arrhenius kinetics. Radiant heat loss on the fuel plate is applied in the model as it is the dominant mechanism for flame extinguishment in the small convective flow regime. A parametric study based on the variation of convective flow velocity, which varies the Damkchler number (Da), and the surface radiant heat loss parameter (S) simultaneously, is given. An extinction limit is found in the regime of slow convective flow when the rate of radiant heat loss from fuel surface outweighs the rate of heat generation due to combustion. The transition from existent envelope flame to extinguishment consists of gradual flame contraction in the opposed flow direction together with flame temperature reduction as the convective flow velocity decreases continuously until the extinction limit is reached. A case of flame structure subjected to surface radiant heat loss is also presented and discussed.

Chen, Chiun-Hsun↗

Nongradient diffusion in premixed turbulent flames

Recent theoretical and experimental results demonstrating the interaction between force fields and density inhomogeneities as they arise in premixed turbulent flames are discussed. In such flames, the density fluctuates between two levels, the high density in reactants rho sub r and the low density in products rho sub p, with the ratio rho sub r/rho sub p on the order of five to ten in flows of applied interest. The force fields in such flames arise from the mean pressure drop across the flame or from the Reynolds shear stresses in tangential flames with constrained streamlines. The consequence of the interaction is nongradient turbulent transport, countergradient in the direction normal to the flame and nongradient in the tangential direction. The theoretical basis for these results, the presently available experimental support therefore and the implications for other variable density turbulent flows are discussed.

Libby, Paul A.↗

An experimental study of opposed flow diffusion flame extinction over a thin fuel in microgravity

The flame spread and flame extinction characteristics of a thin fuel burning in a low-speed forced convective environment in microgravity were examined. The flame spread rate was observed to decrease both with decreasing ambient oxygen concentration as well as decreasing free stream velocity. A new mode of flame extinction was observed, caused by either of two means: keeping the free stream velocity constant and decreasing the oxygen concentration, or keeping the oxygen concentration constant and decreasing the free stream velocity. This extinction is called quenching extinction. By combining this data together with a previous microgravity quiescent flame study and normal-gravity blowoff extinction data, a flammability map was constructed with molar percentage oxygen and characteristic relative velocity as coordinates. The Damkohler number is not sufficient to predict flame spread and extinction in the near quench limit region.

Ferkul, Paul V.↗