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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 685 records · Page 38
All sourcesNASA NTRSDOE OSTI
NASA NTRS2004

A Novel Liquid-Liquid Transition in Undercooled Ti-Zr-Ni Liquids

If crystallization can be avoided, liquids enter a metastable (undercooled) state below their equilibrium liquidus temperatures, T(sub l), finally 'freezing' into a glass below a characteristic temperature called the glass transition temperature, T(sub g). In rare cases, the undercooled liquid may undergo a liquid-liquid phase transition (liquid polymorphism) before entering the glassy state. This has been suggested from experimental studies of H2O and Si. Such phase transitions have been predicted in some stable liquids, ie. above T(sub l) at atmospheric pressure, for SiO2 and BeF2, but these have not been verified experimentally. They have been observed in liquids of P, Si and C, but only under high pressure. In this letter we present the first experimental evidence for a phase transition in a low viscosity metallic liquid that is driven by an approach to a constant entropy configuration state and correlated with a growing icosahedral order in the liquid. A maximum in the specific heat at constant pressure, similar to what is normally observed near T(sub g), is reported for undercooled liquids of quasicrystal-forming Ti-Zr-Ni alloys. A two-state excitation model that includes cooperativity by incorporating a temperature-dependent excitation energy, fits the specific heat data well, signaling a phase transition. An inflection in the liquid density with decreasing temperature instead of a discontinuity indicates that this is not a typical first order phase transition; it could be a weakly first order or higher order transition. While showing many similarities to a glass transition, this liquid-liquid phase transition occurs in a mobile liquid, making it novel.

Lee, G. W.↗
NASA NTRSDate not supplied

Space-based UV Spectropolarimetry for Chromospheric Magnetic Field Measurements

High-resolution observations with space-and ground-based telescopes, along with advanced numerical modeling, have highlighted the intricate coupling between the chromosphere, transition region, and corona, and the critical role the chromosphere plays in the mass and energy balance of the outer solar atmosphere. Despite these recent advances, a major impediment to better understanding the solar atmosphere is our lack of empirical knowledge regarding the direction and strength of the magnetic field in the upper chromosphere (Decadal Survey, 2012). Such measurements are crucial to address several major unresolved issues in solar physics: for example, to constrain the energy flux carried by the Alfvén waves propagating through the chromosphere, and to determine the height at which the plasma β = 1 transition occurs, which has important consequences for the braiding of magnetic fields, for propagation and mode conversion of waves and for non-linear force-free extrapolation methods that are key to determining what drives instabilities such as flares or coronal mass ejections. Probing the magnetic nature of the Sun’s atmosphere requires measurement of the Stokes I, Q, U and V profiles of relevant spectral lines (of which Q, U and V encode the magnetic field information). Many of the magnetically sensitive lines formed in the chromosphere and transition region are in the ultraviolet spectrum, necessitating observations above the absorbing terrestrial atmosphere. The Chromospheric Layer Spectro-Polarimeter (“CLASP2”) sounding rocket was flown successfully in April 2019, as a follow-on to the successful flight in September 2015 of the Chromospheric Lyman-Alpha Spectro-Polarimeter (“CLASP1”). In October of 2021, we re-flew the CLASP2 experiment with a modified observing program to further demonstrate the maturity of the UV spectropolarimetry techniques, and readiness for development into a satellite observatory. During the reflight, called “CLASP2.1”, the spectrograph slit was scanned across an active region plage to acquire a two-dimensional map of Stokes V/I, to demonstrate the ability of UV spectropolarimetry to yield chromospheric magnetic fields over a large area.

David E McKenzie↗
NASA NTRS1975

Transition-radiation-Compton-scattering detector for very relativistic nuclei

The paper presents the design and predicted performance of a large acceptance (2 sq m sr) transition-radiation-Compton-scattering detector system which can be used to measure energy spectra up to several thousand Gev/nucleon for nuclei with Z between 6 and 28, as well as up to 40,000 GeV/nucleon for He. The following circumstances made such a detector system practicable: (1) transition radiation output is proportional to the square of particle charge; (2) output varies at least as rapidly as the square of Lorentz factor over the range from several hundred to several thousand.

Osborne, W. Z.↗
NASA NTRS2002

Microwave, Millimeter, Submillimeter, and Far Infrared Spectral Databases

The spectrum of most known astrophysical molecules is derived from transitions between a few hundred to a few hundred thousand energy levels populated at room temperature. In the microwave and millimeter wave regions. spectroscopy is almost always performed with traditional microwave techniques. In the submillimeter and far infrared microwave technique becomes progressively more technologically challenging and infrared techniques become more widely employed as the wavelength gets shorter. Infrared techniques are typically one to two orders of magnitude less precise but they do generate all the strong features in the spectrum. With microwave technique, it is generally impossible and rarely necessary to measure every single transition of a molecular species, so careful fitting of quantum mechanical Hamiltonians to the transitions measured are required to produce the complete spectral picture of the molecule required by astronomers. The fitting process produces the most precise data possible and is required in the interpret heterodyne observations. The drawback of traditional microwave technique is that precise knowledge of the band origins of low lying excited states is rarely gained. The fitting of data interpolates well for the range of quantum numbers where there is laboratory data, but extrapolation is almost never precise. The majority of high resolution spectroscopic data is millimeter or longer in wavelength and a very limited number of molecules have ever been studied with microwave techniques at wavelengths shorter than 0.3 millimeters. The situation with infrared technique is similarly dire in the submillimeter and far infrared because the black body sources used are competing with a very significant thermal background making the signal to noise poor. Regardless of the technique used the data must be archived in a way useful for the interpretation of observations.

Pearson, J. C.↗
NASA NTRS1974

Theory of photoelectron production, transport and energy loss

Current understanding of the theory of ionospheric photoelectron production, transport and energy loss is summarized. The various approaches used in the theoretical calculations of photoelectron fluxes appear to be self consistent and sound; improved values for a number of input parameters are needed now in order to achieve significant improvements and more confidence in the results. The major remaining problem in the present day theory of photoelectron transport and energy loss is centered around the calculations of photoelectron transit through the protonosphere.

Nagy, A. F.↗
NASA NTRS1977

Statistical equilibrium in cometary C2. I

Swan-band emission from the C2 molecule provides important information for a study of the physical processes occurring in comets. It is, therefore, a disturbing factor that many quantitative Swan-band observations are in clear contradiction of predictions of resonance fluorescence excitation of the Swan bands. A description is presented of an investigation involving an application of resonance fluorescence theory to C2. The investigation takes into account all important electronic transitions which determine the population distribution of the lowest energy states. It is found that the previous discrepancy for the brighter band sequences disappears.

Swamy, K. S. K.↗
NASA NTRS1979

X-ray spectrum of Cassiopeia A measured with the Einstein SSS

The solid state spectrometer (SSS) on the Einstein Observatory observed the X-ray spectrum of Cas A between 0.8 and 4.5 keV with a FWHM energy resolution of 160 eV. Line emission consistent with transitions of helium-like ions of Si, S, and Ar was well defined. Comparison between the data and the emission expected from a gas containing two distinct thermal components requires additional line emission from Mg, Al, Ca, and Fe. These results are discussed in the context of both equilibrium and nonequilibrium situations.

Becker, R. H.↗
NASA NTRS1982

Three dimensional flow field inside compressor rotor, including blade boundary layers

The flow in a turbomachinery blade passage has a predominant flow direction. The viscous diffusion in the streamwise direction is usually small and the elliptic influence is transmitted upstream through the pressure field. Starting with a guessed pressure field, it is possible to converge on the full elliptic solution by iterating between a parabolic solution and an iteration of the pressure field. The main steps of the calculation are given. The blade boundary layers which are three dimensional with laminar, transitional, turbulent, and separation zones are investigated. The kinetic energy is analyzed, and the dissipation equation is presented. Measurements were made of the three dimensional flow inside an axial flow compressor passage.

Pouagare, M.↗
NASA NTRS1982

Ultrasonic determination of thermodynamic threshold parameters for irreversible cutaneous burns

In vivo ultrasonic measurements of the depth of conductive cutaneous burns experimentally induced in anesthetized Yorkshire pigs are reported as a function of burn time for the case in which the skin surface temperature is maintained at 100 C. The data are used in the solution of the one-dimensional heat diffusion equation with time-dependent boundary conditions to obtain the threshold temperature and the energy of transformation per unit mass associated with the transition of the tissue from the state of viability to the state of necrosis. The simplicity of the mathematical model and the expediency of the ultrasonic measurements in studies of thermal injury are emphasized.

Cantrell, J. H., Jr.↗
NASA NTRS1982

Diffraction studies of the high pressure phases of GaAs and GaP

High pressure structural phase transitions of GaAs and GaP have been studied by energy dispersive X-ray diffraction with the radiation from the Cornell High Energy Synchrotron Source. GaAs began to transform at 172 + or - 7 kbar to an orthorhombic structure possibly belonging to space group Fmmm. GaP transformed to a tetragonal beta-Sn type phase at 215 + or - 8 kbar. Although pressure transmitting media were used to minimize shear stresses in the specimens, the high pressure diffraction results were interpreted as showing evidence for planar defects in the specimens.

Baublitz, M., Jr.↗
NASA NTRS1982

Polymeric metallic electrodes for rechargeable battery applications

A review is presented on the status of plastic metal electrodes, emphasizing the use of polyacetylene as a prototype polymeric material. The electrochemical characteristics of polyacetylene are examined; and the potential use of this material, as well as other types of plastic metal electrodes, in batteries is evaluated. Several problem areas which must be solved before polyacetylene can be widely used in battery applications are discussed, including the problem of electrolyte stability, the problem that the depth of discharge and the energy density is limited by the metal-semiconductor transition, and also the poor electrochemical performance of impure material.

Somoano, R.↗
NASA NTRS1981

The sunspot chromosphere-corona transition region

Data from simultaneous readings of the line intensities, Doppler shifts, and line widths of a sunspot ion emission lines between 1170-1700 A are reported. Subsonic and supersonic flows were observed in the same line of sight above the umbra. A reduction of coronal plasma over sunspots with an electron temperature exceeding 1,000,000 K was confirmed, concurrent with enhanced emission from the transition region plasma in the temperature range 200,000-1,000,000 K. The differential emission measure is noted to have been caused to shift because of the enhancement of the transition region plasma emission, where radiative losses dominated the energy balance. Calculations of the energy balance also indicated that a detected divergence in the enthalpy flux for the umbral downflows could balance the radiative losses in the electron temperature range 30,000-200,000 K.

Nicolas, K. R.↗
NASA NTRS1984

Turbulent compressible convection in a deep atmosphere. II - Two-dimensional results for main-sequence A5 and F0 type envelopes

In the present two-dimensional numerical study of turbulent compressible convection in the A5 and F0 main-sequence envelope types, ionization effects are included in the equation of state of the gas, and radiative transfer is modeled in a diffusive process with tabulated gas opacities. It is noted that the thermal effects of ionization significantly affect the dynamics of the flows and that an inversion of the mean density can be created and sustained in a dynamical situation. The substantial differences in the flows of A5 and F0 indicate development trends in the transition from the radiative to the convective mode of energy transport. As convection becomes more effective, the flow becomes more turbulent and the scaling effects of local scale heights become more significant.

Sofia, S.↗
NASA NTRS1985

Nonlinear shock acceleration. III - Finite wave velocity, wave pressure, and entropy generation via wave damping

The nonlinear theory of shock acceleration developed in earlier papers, which treated the waves as being completely frozen into the fluid, is generalized to include wave dynamics. In the limit where damping keeps the wave amplitude small, it is found that a finite phase velocity (V sub ph) of the scattering waves through the background fluid, tempers the acceleration generated by high Mach number shocks. Asymptotic spectra proportional to 1/E sq are possible only when the ratio of wave velocity to shock velocity is less than 0.13. For a given asymptotic spectrum, the efficiency of relativistic particle production is found to be practically independent of the value of V sub ph, so that earlier results concerning its value remain valid for finite V sub ph. In the limit where there is no wave damping, it is shown that for modest Alfven Mach numbers, approximately greater than 4 and less than 6, the magnetic field is amplified by the energetic particles to the point of being in rough equipartition with them, as models of synchrotron emission frequently take the field to be. In this case, the disordering and amplification of field energy may play a major role in the shock transition.

Eichler, D.↗
NASA NTRS1986

The quiet solar transition region

The results of recent studies (in the UV) of the structure and dynamics of the quiet solar transition region and its role in the mass and energy balance of the outer layers of the solar atmosphere are summarized. The region is one in which temperature increases from 25,000 K to about 1 million K and the matter density, fed by the outward flowing wind and the inward streaming plasma, increases by a factor of 40. The morphology of the region is described, along with the theoretical models being applied to the observed nonthermal line broadening, Doppler wavelength shifts, temporal fluctuations, and fine structure. Deficiencies in existing simple models of the region are discussed.

Mariska, John T.↗
NASA NTRS1988

Extreme ultraviolet quantum efficiency of opaque alkali halide photocathodes on microchannel plates

Comprehensive measurements are presented for the quantum detection efficiency (QDE) of the microchannel plate materials CsI, KBr, KCl, and MgF2, over the 44-1800 A wavelength range. QDEs in excess of 40 percent are achieved by several materials in specific wavelength regions of the EUV. Structure is noted in the wavelength dependence of the QDE that is directly related to the valence-band/conduction-band gap energy and the onset of atomic-like resonant transitions. A simple photocathode model allows interpretation of these features, together with the QDE efficiency variation, as a function of illumination angle.

Siegmund, O. H. W.↗