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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 685 records · Page 38

Seasonal investigation of ultrafine-particle organic composition in an eastern Amazonian rainforest

Abstract. Reports on the composition of ultrafine particles (<100 nm in diameter) in the Amazon are scarce, due in part to the fact that new-particle formation has rarely been observed near ground level. Ultrafine particles near the surface have nevertheless been observed, leaving open questions regarding the sources and chemistry of their formation and growth, particularly as these vary across seasons. Here, we present measurements of the composition of ultrafine particles collected in the Tapajós National Forest (2.857° S, 54.959° W) during three different seasonal periods: 10–30 September 2016 (SEP), 18 November–23 December 2016 (DEC), and 22 May–21 June 2017 (JUN). Size-selected (5–70 nm) particles were collected daily (for 22 h each day) using an offline sampler. Samples collected during the three time periods were compiled and analyzed using liquid chromatography coupled with Orbitrap high-resolution mass spectrometry. Our findings suggest a sustained influence of isoprene organosulfate chemistry on ultrafine particles from the different periods. We present chemical evidence that indicates that biological-spore fragmentation impacted ultrafine-particle composition during the late wet season (JUN), while chemical markers for biomass burning and secondary chemistry peaked during the dry season (SEP and DEC). Higher oxidation states and degrees of unsaturation were observed for organics in the dry season (SEP and DEC), suggesting greater extents of aerosol aging. Finally, applying a volatility parameterization to the observed compounds suggests that organic sulfur species are likely key drivers of new-particle growth in the region due to their low volatility compared to other species.

54 ENVIRONMENTAL SCIENCES↗

The role of föhn winds in eastern Antarctic Peninsula rapid ice shelf collapse

Ice shelf collapse reduces buttressing and enables grounded glaciers to contribute more rapidly to sea-level rise in a warming climate. The abrupt collapses of the Larsen A (1995) and B (2002) ice shelves on the Antarctic Peninsula (AP) occurred, at least for Larsen B, when long-period ocean swells damaged the calving front and the ice shelf was inundated with melt lakes that led to large-scale hydrofracture cascades. During collapse, field and satellite observations indicate föhn winds were present on both ice shelves. Here we use a regional climate model and machine learning analyses to evaluate the contributory roles of föhn winds and associated melt events prior to and during the collapses for ice shelves on the AP. Föhn winds caused about 25 % ± 3 % of the total annual melt in just 9 d on Larsen A prior to and during collapse and were present during the Larsen B collapse, which helped form extensive melt lakes. At the same time, the off-coast wind direction created by föhn winds helped melt and physically push sea ice away from the ice shelf calving fronts that allowed long-period ocean swells to reach and damage the front, which has been theorized to have ultimately triggered collapse. Collapsed ice shelves experienced enhanced surface melt driven by föhn winds over a large spatial extent and near the calving front, whereas SCAR inlet and the Larsen C ice shelves are affected less by föhn-wind-induced melt and do not experience large-scale melt ponds. These results suggest SCAR inlet and the Larsen C ice shelves may be less likely to experience rapid collapse due to föhn-driven melt so long as surface temperatures and föhn occurrence remain within historical bounds.

58 GEOSCIENCES↗

Quantitative comparison of power production and power quality onshore and offshore: a case study from the eastern United States

Abstract. A major issue in quantifying potential power generation from prospective wind energy sites is the lack of observations from heights relevant to modern wind turbines, particularly for offshore where blade tip heights are projected to increase beyond 250 m. We present analyses of uniquely detailed data sets from lidar (light detection and ranging) deployments in New York State and on two buoys in the adjacent New York Bight to examine the relative power generation potential and power quality at these on- and offshore locations. Time series of 10 min wind power production are computed from these wind speeds using the power curve from the International Energy Agency 15 MW reference wind turbine. Given the relatively close proximity of these lidar deployments, they share a common synoptic-scale meteorology and seasonal variability with lowest wind speeds in July and August. Time series of power production from the on- and offshore location are highly spatially correlated with the Spearman rank correlation coefficient dropping below 0.4 for separation distances of approximately 350 km. Hence careful planning of on- and offshore wind farms (i.e., separation of major plants by > 350 km) can be used reduce the system-wide probability of low wind energy power production. Energy density at 150 m height at the offshore buoys is more than 40 % higher, and the Weibull scale parameter is 2 m s−1 higher than at all but one of the land sites. Analyses of power production time series indicate annual energy production is almost twice as high for the two offshore locations. Further, electrical power production quality is higher from the offshore sites that exhibit a lower amplitude of diurnal variability, plus a lower probability of wind speeds below the cut-in and of ramp events of any magnitude. Despite this and the higher resource, the estimated levelized cost of energy (LCoE) is higher from the offshore sites mainly due to the higher infrastructure costs. Nonetheless, the projected LCoE is highly competitive from all sites considered.

Foody, Rebecca↗