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At least 685 records · Page 38

Joint Assimilation of CO, O3, NO2, SO2, PM, AOD, NH4, PAN, and HNO3 in Support of the Tropospheric Regional Atmospheric Composition and Emissions Reanalysis (2005 - 2024) (TRACER-I)

NASA Ames Research Center is collaborating with the NOAA Chemical Systems Laboratory (NOAA/CSL), the NASA Jet Propulsion Laboratory (JPL), the NASA Goddard Modeling and Assimilation Office, and the National Center for Atmospheric Research to prepare a 20-year Tropospheric Regional Atmospheric Composition and Emissions Reanalysis (2005 – 2024) (TRACER-I) for the continental United States during the summer ozone (O3) and wildfire seasons (April to October). TRACER-I will be a regional complement to JPL’s global Tropospheric Chemistry Reanalyses II and III. We will use WRF-Chem/DART with NOAA/CSL’s WRF-Chem setup at 12 km x 12 km horizontal resolution, 51 vertical levels, and 30 ensemble members. We will assimilate: (i) conventional meteorological observations; (ii) EPA’s Air Quality System in situ measurements of carbon monoxide (CO), O3, nitrogen dioxide (NO2), sulfur dioxide (SO2), particulate matter (PM) with diameters less than 10 µm (PM10), and PM with diameters less than 2.5 µm (PM2.5); and (iii) MOPITT, MODIS, OMI, TROPOMI, GOME-2a, MLS, TES, SCIAMACHY, CrIS, and TEMPO total/partial column and/or profile retrievals of CO, O3, NO2, SO2, aerosol optical depth (AOD), formaldehyde (HCHO), ammonia (NH4), peroxyacetyl nitrate (PAN), and/or nitric acid (HNO3) with 3-hr cycling. We will present an overview of this project, its status, and available results (likely the analysis of sensitivity experiment results from the assimilation/emissions estimation system).

data assimilation↗

Development of an Improved Spatial Metadata Simplification Algorithm

The National Aeronautics and Space Administration's (NASA) Atmospheric Science Data Center (ASDC) at NASA Langley Research Center in Hampton, VA provides atmospheric science data products and services to the science community, including enhanced search and subsetting capabilities for numerous Earth Science datasets. The ASDC is the official Distributed Active Archive Center (DAAC) of record for the Tropospheric Emissions: Monitoring of Pollution (TEMPO) instrument. TEMPO is situated on a geostationary satellite positioned at a longitude near the center of the conterminous United States and focused on North America, making hourly swaths of its field of regard from east to west. Spatial metadata is an essential component for the discovery and distribution of Earth Science data. The simplified polygonal boundaries representing the archived data files ensure that any granule can be identified quickly and accurately by a geospatial query. Historically the Douglas-Peucker algorithm has been used for polygon simplification; however, due to the nature of the algorithm, a buffer must be added to the polygon before simplification to ensure pivotal points are not removed by the algorithm. This adds in additional error to the polygon simplification. ASDC’s goal is to test other methods of polyline simplification, such as Visvalingan-Whyatt and Opheim simplification alongside of Douglas-Peucker and different buffering methods, to produce less error during polygon simplification of TEMPO data swaths, and special spatial query geometries such as EPA non-attainment regions, and geopolitical boundaries.

Spatial Metadata↗

Use of Spatial Metadata Simplification for TEMPO

The National Aeronautics and Space Administration's (NASA) Atmospheric Science Data Center (ASDC) at NASA Langley Research Center in Hampton, VA provides atmospheric science data products and services to the science community, including enhanced search and subsetting capabilities for numerous Earth Science datasets. The ASDC is the official Distributed Active Archive Center (DAAC) of record for the Tropospheric Emissions: Monitoring of Pollution (TEMPO) instrument. TEMPO is situated on a geostationary satellite positioned at a longitude near the center of the conterminous United States and focused on North America, making hourly swaths of its field of regard from east to west. Spatial metadata is an essential component for the discovery and distribution of Earth Science data. The simplified polygonal boundaries representing the archived data files ensure that any granule can be identified quickly and accurately by a geospatial query. Historically the Douglas-Peucker algorithm has been used for polygon simplification; however, due to the nature of the algorithm, a buffer must be added to the polygon before simplification to ensure pivotal points are not removed by the algorithm. This adds in additional error to the polygon simplification. ASDC’s goal is to test other methods of polyline simplification, such as Visvalingan-Whyatt and Opheim simplification alongside of Douglas-Peucker and different buffering methods, to produce less error during polygon simplification of TEMPO data swaths, and special spatial query geometries such as EPA non-attainment regions, and geopolitical boundaries.

Spatial Metadata↗

June 2023 Canadian Wildfire Effects on Hampton Roads VA using ASDC Data

In June of 2023 thousands of acres of wildfires spread across northwestern Canada. This event emitted huge amounts of smoke, and pollutants that travelled east across the North America, the Atlantic ocean and eventually all the way to Continental Europe. This smoke created a dangerous air quality event throughout the Atlantic Coast. As climate change increases the prevalence of wildfires more cities and states will be affected by the dangerous smoke and pollutants produced by these events. In this poster we documented and investigated the June 06th Air Quality Event over Hampton Roads, VA. To perform a comparative analysis, we utilized two data sources: NASA’s Atmospheric Science Data Center we used the Cloud Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO), the Deep Space Climate ObserVatoRy (DSCOVR) Enhanced Polychromatic Imaging Camera (EPIC), data product, and the EPA’s ground-based Air Quality System (AQS).

Air Quality↗

Hydrocarbon Burn Facility, SWMU 007 Per- and Polyfluoroalkyl Substances (PFAS) Assessment Report Addendum

This document discusses the Per-and Polyfluoroalkyl Substances (PFAS) assessment activities performed from May through August 2023 at the Hydrocarbon Burn Facility (HBF) located at Kennedy Space Center (KSC), Florida. HBF was used for firefighting training between 1966 and 1994. Aqueous film-forming foams (AFFFs) that contained PFAS were used as suppressants for fighting petroleum fuel fires during training. PFAS sampling was first completed at HBF in 2015. This PFAS Assessment Report Addendum (ARA) is a continuation of sampling efforts, with an overall objective to further delineate PFAS concentrations in groundwater to the pGCTLs and the United States Environmental Protection Agency (EPA) Tapwater Regional Screening Levels (RSLs) dated November 2023 and better understand groundwater to surface water interaction at the Site. The field activities presented in this PFAS ARA were conducted between May and August 2023 and included the collection of 132 direct push groundwater samples and the collection of five colocated surface water, sediment, and pore water samples from locations south/southeast of HBF in August 2023. Exceedances of the pGCTLs and Tapwater RSLs were observed in the direct push groundwater results; however, groundwater has been delineated to the pGCTLs. Exceedances of the Florida provisional Surface Water Screening Levels (pSWSLs) were observed in surface water and porewater, and concentrations of PFAS in these media confirm PFAS migration within surface channels to the south of the HBF site area. Maximum sediment concentrations, which correlate with the maximum surface water and porewater concentrations, demonstrate that PFAS impacted surface water is the source of sediment impacts. Overall, elevated concentrations of PFAS are centered on the HBF site area that trend north and south along the surface water filled swales and along the edge of Banana River. Based on analytical results, not all surface water features in this area exhibit evidence of transport. PFAS migration/transport appears to be more dominant in surface water features during the wet season. Discharges to the Banana River primarily occur where surface water facilitates transport. In contrast, groundwater transport is more effective during the dry season. During precipitation events in either the dry season or the wet season, there appears to be migration from the intermediate groundwater zone to the shallow zone into the surface water features. Additional sampling and data collection is recommended to support further refinement of PFAS groundwater delineation, a remedial alternative evaluation, and the fate and transport model.

Jennifer Buel↗

PM 2.5 Concentrations over Major Metropolitan Regions Inferred from Airborne High Spectral Resolution Lidar Measurements Using Machine Learning Regression

We use measurements of near-surface aerosol backscatter, extinction, and depolarization acquired by four NASA Langley Research Center airborne High Spectral Resolution Lidars (HSRLs) to develop a machine learning regression methodology to infer PM2.5 concentrations at the surface and aloft. These airborne HSRL measurements were acquired over major metropolitan regions in the United States and Asia during more than 170 flights since 2010. Hourly surface PM2.5 measurements from the EPA air quality system and similar networks in other countries acquired within 10 km and 15 minutes of these near-surface HSRL measurements are used to train models that compute PM2.5 concentrations from the HSRL measurements. We examine several regression methods and find that exponential Gaussian Process algorithms consistently give the best performance in terms of the lowest root-mean-square (RMS) errors and the highest correlations. Model performance varies significantly depending on various combinations of HSRL aerosol measurements (e.g., aerosol backscatter, extinction, depolarization, backscatter color ratios, lidar ratios, aerosol optical thickness) and retrievals (e.g., mixed layer height, aerosol type) used in the regressions. Models that use near-surface measurements of aerosol backscatter and aerosol intensive properties such as depolarization, backscatter color ratio, and lidar ratio typically give the best performance with RMS errors around 4 mg/m3 and correlation coefficients above 0.9. HSRL measurements were often acquired when the aircraft flew systematic “raster-scan” patterns for several hours over these cities. These flight patterns enabled measurements of the spatial, temporal, and vertical variabilities in the distributions of aerosol backscatter and aerosol intensive properties and allowed us to derive the corresponding variabilities in PM2.5 concentrations. We present examples of such variabilities over urban areas in the United States as well as Asia. We describe also how the distribution of surface PM2.5 varies with aerosol type and use these retrievals to examine model simulations of surface PM2.5 in these metropolitan regions. We also discuss how this methodology may be applied to measurements from satellite lidars such as CALIOP on CALIPSO and ATLID on EarthCARE.

lidar↗

Spaceborne Lidar Retrievals of PM2.5 for Air Quality Studies and Applications

Fine particulate matter (PM2.5) substantially contributes to air pollution and negatively affects human health. While many studies have investigated the use of passive column-integrated aerosol optical depth to infer surface PM2.5, the use of lidar observations for air quality characterization is not nearly as extensive. Lidar measurements are critical, however, due to the vertical aerosol information they provide, including near the surface. In this presentation, we first provide an overview of various lidar-based approaches for estimating PM2.5 concentrations and then discuss how lidar measurements can assist other air quality applications. For example, estimates of PM2.5 have been obtained in a physics-based approach through CALIOP near-surface aerosol extinction retrievals, assumptions on the mass extinction efficiency, and incorporating other parameters (an aerosol hygroscopic growth factor and PM2.5/PM10 ratio). Application of this algorithm over the contiguous United States (CONUS) from 2006 to 2018 yielded larger PM2.5 values over the eastern and western CONUS (~10-15 μg/m³) and lower PM2.5 levels in the central CONUS (~5 μg/m³). These spatial patterns were similar to those from gridded PM2.5 concentrations obtained through in situ measurements at ground stations operated by the US Environmental Protection Agency. In another approach, the Cloud Aerosol Transport System (CATS) lidar was used with the Goddard Earth Observing System (GEOS) model in a 1D ensemble-based variational technique to obtain PM2.5 over the US and Europe, and the spatial patterns of the CATS/GEOS based PM2.5 concentrations generally captured those from surface stations (with corresponding hourly EPA PM2.5 vs CATS PM2.5 statistics of R=0.4 and bias=1.5 μg/m³). In our recent work, as part of the Models, In situ, and Remote sensing of Aerosols (MIRA) Working Group, we have applied both the CALIOP and CATS/GEOS based approaches over the highly polluted country of India during the post-monsoon season (September-October 2016). We derived elevated levels of two-month mean PM2.5 (~100 μg/m³) in northern India, especially near New Delhi. These high PM2.5 concentrations in the Indo-Gangetic plain are driven in large part from the seasonal burning of crop residue and meteorological conditions typical at this time of the year, such as low wind speeds and a shallow boundary layer. While the satellite-derived PM2.5 moderately replicates (R = ~0.7-0.9) the spatial variability in the two-month mean of surface in situ PM2.5 from monitoring sites operated by the Central and State Pollution Control Boards, we show results from specific scenes for which there are large deviations between the satellite-derived PM2.5 and in situ measurements. Other current work on this topic focuses on developing PM2.5 estimates using airborne high spectral resolution lidar measurements through machine learning regression algorithms and involves several parameters (e.g., aerosol extinction, color ratio, lidar ratio). Application of this method over major metropolitan areas in the US and Asia have resulted in high correlations (R = 0.93) with surface measurements. This airborne lidar approach can be adapted to spaceborne lidar measurements, and all three of these approaches can be applied to ESA’s EarthCARE Atmospheric Lidar instrument, setting the stage for the future Cloud Aerosol Lidar for Global Scale Observations of the Ocean-Land Atmosphere System (CALIGOLA) mission. Ultimately, beyond estimates of PM2.5, the aerosol vertical distribution from lidars can benefit studies involving passive sensor approaches for PM2.5 proxies (including from geostationary satellites), wildfire smoke plume injection heights, volcanic emissions (e.g., ash height retrievals), and aerosol/air quality model assimilation, evaluation, and forecasts.

Travis D Toth↗

DOE Investments in Environmentally Acceptable Lubricants for Hydropower Applications Fact Sheet

Environmentally acceptable lubricants (EALs) are defined as lubricants that meet U.S. Environmental Protection Agency (EPA) standards for “biodegradability, toxicity, and bioaccumulation potential that minimize their likely adverse consequences in the aquatic environment, compared to conventional lubricants.” Restrictions from state, local, and federal agencies, as well as a growing awareness of the environmental risks associated with petroleumbased lubricants, have shifted government and industry to seek out high-performing EALs. The U.S. Department of Energy (DOE) is working to reduce the environmental impacts of hydropower development and operation by investing in tools and methods to develop, demonstrate, and validate EAL materials.

water, environment, hydropower, EALs↗

BETO 2021 Peer Review - Analytical Development & Support WBS 2.5.1.101

The objective of the Analytical Development and Support (ADS) Project is to produce and maintain the critical analytical methods and tools that enable evaluation of emerging biofuels R&D at NREL and in the broader biofuels research community. Our project is divided into two tasks: one task to develop novel analytical techniques and improve existing methods and one task to maintain existing analytical capabilities at NREL and provide outreach to the wider community. The ADS Project is world-recognized for our Laboratory Analytical Procedures (LAPS) which provide detailed procedures for compositional analysis of biomass and have been adopted as the de facto standards within the biofuels community largely due to the transparency of the methods and the high reputation of NREL's research. Our dialog with stakeholders allows us to provide robust, precise, accurate, and publicly available analytical procedures for better valuation of scientific tools such as our recent accomplishment in developing a cellulose assay to support the EPA and industry in calculation of converted cellulose during starch ethanol production. We continue to develop analytical capabilities to support BETO's directives to research cost advantaged fuels such as animal wastes and novel bioproducts like 2,3-Butane-diol.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Modular High Temperature Gas-Cooled Reactor: Safety Design Approach

Deployment Objectives Flexibly co-locate with new industry users of nuclear energy Steam and electric cogeneration applications Direct process heat with temperature ranges from 700°C to 950°C Enabling Requirements Meet regulatory dose limits at the Exclusion Area Boundary (EAB) 25 rem Total Effective Dose Equivalent (TEDE) for duration of the release from 10 CFR 50.34 (10 CFR 52.79) at Exclusion Area Boundary (EAB) for design basis accidents EAB is estimated approximately 400 meters from the modular HTGR plant (to support co-location with industrial facilities) Meet safety goals for cumulative individual risk for normal and off-normal operation Design goal: meet EPA Protective Action Guides (PAGs) at EAB 1 rem TEDE for sheltering Design basis and beyond design basis events are considered Realistically evaluated at the EAB Emergency planning and protection

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Nuclear Energy Model Intercomparison Project

This document summarizes the current status and future plans of the Nuclear Model Intercomparison Project. The objectives of this project are to understand how issues central to nuclear energy are modeled in long-term capacity expansion models, to investigate how model structures and input assumptions impact projections for nuclear’s role, to refine model representations of nuclear energy, and to communicate findings to the research community and decision-makers. High-level goals are discussed for each of the four participating model groups: the U.S. Energy Information Administration (EIA), U.S. Environmental Protection Agency (EPA), Electric Power Research Institute (EPRI), and National Renewable Energy Laboratory (NREL). This document summarizes scenarios and assumptions for the model comparison, outcomes from the first workshop, and next steps.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

SO3/H2SO4 continuous real-time sensor demonstration at a power plant

We present results from field testing of a new, innovative sensor developed to measure SO3/H2SO4 continuously and in real time at a coal-fired power plant. The system utilizes the sensitivity, specificity, and real-time capabilities of mid-infrared (Mid-IR) laser-based sensor technology, along with a heated, close-coupled cell mounted directly to a power plant duct. Measurements were made by the laser sensor over a 2-day period and compared to results from the accepted method, EPA 8A, which requires a 30-minute collection, labor intensive processing, and off-site analysis at a lab. In contrast to the condensation method, the laser sensor continuously samples flue gas and reports measurements of the concentration of SO3/H2SO4, SO2 ever second with unattended operation. This initial demonstration proved the sensor concept and paves the way for its use for optimizing sorbent injection used to neutralize SO3/H2SO4. Optimized sorbent injection will enable significant cost savings associated with efforts to mitigate the presence and effects of SO3/H2SO4 such as “Blue Plume”, air heater fouling, and duct corrosion. In particular, the real-time, actionable information will enable better control of additive injection in flex conditions and variable fuels.

20 FOSSIL-FUELED POWER PLANTS↗

Per- and Polyfluoroalkyl Substances: A Preliminary Evaluation of Groundwater Contamination in the Western States

Per- and Polyfluoroalkyl Substances (PFAS) are a manufactured group of chemicals that have been used since the 1940s. PFAS break down very slowly and studies show that exposure to these chemicals may cause negative reproductive effects, developmental delays in children, increased risk of some cancers, and interference with the body’s natural hormones. On June 15, 2022, EPA issued interim updated drinking water health advisories for the two most widely studied PFAS, perfluorooctanoic acid (PFOA) and perfluorooctane sulfonic acid (PFOS). The concentrations for the health advisory limits are 0.004 parts per trillion (ppt) and 0.02 ppt respectively. Because data is often reported in combined PFOA and PFOS concentrations, and for ease of data visualization, concentrations of the two chemicals will be discussed as a single, summed value and will be compared to the combined health advisory limits of 0.024 ppt. Due to the recently published near-zero health advisory limits and the known negative health effects, a map of estimated PFAS groundwater contamination was created using ArcGIS Pro and geostatistical tools to inform the public and determine which regions are most at-risk.

54 ENVIRONMENTAL SCIENCES↗

Utilizing the Inflation Reduction Act to Remediate and Redevelop Energy Assets and Sites

There are thousands of retired and operating energy sites located in communities throughout the country waiting to be cleaned up and modernized. Together with other existing federal grants and tax credits, the newly created Energy Infrastructure Reinvestment (EIR) loan guarantees from the Department of Energy can catalyze capital investment in these sites, empowering local communities and reducing carbon pollution. The IRA makes available up to $250 billion in EIR loan guarantees and up to $5 billion in EIR credit subsidy to support remediating, repurposing, and redeveloping eligible sites. EIR provides opportunities for reinvestment in America’s energy communities amid the energy industry’s ongoing transformation to reduce carbon pollution. This resource guide describes four possible redevelopment models that align EIR resources with EPA Brownfield Grants and the energy community tax credit program.

Eisdorfer, Jason G↗

Key Strategies in Industry for Circular Economy : Analysis of Remanufacturing and Beneficial Reuse

Manufacturing, in the effort to be more sustainable, is increasingly focusing on energy efficiency and waste reduction. DOE’s Better Buildings Better Plants Program has a Waste Reduction Network that works with 32 industrial partners to achieve higher material efficiency and reduce waste. United States generates 7.6 Billion Tons of industrial solid waste as estimated by EPA. In a linear economy as the economy grows, so does the waste – increasing strain on resources and the environment. The Circular Economy (CE) model keeps the available resources in circulation for longer period of time easing the burden on the environment. Remanufacturing and (Beneficial) re-use are widely accepted channels in 9R methodology and established pillars of CE. This paper reviews the two key strategies and their adoption in different industrial sectors. It reviews the key barriers faced by manufacturers in implementing these methodologies and discusses the possible solutions to those barriers. The paper also reviews impact of these CE strategies on sustainability, material efficiency and the economic and social benefits. Finally, this paper presents two case studies from DOE’s Better Plants partners – one on remanufacturing of components in heavy vehicles industry and one on beneficial reuse of spent foundry sand, a non-hazardous solid waste, and discusses the project impacts.

Chaudhari, Subodh↗

Technical Assistance 101 - How Can the Joint Office Support You?

The Joint Office of Energy and Transportation (Joint Office), in partnership with the Federal Highway Administration (FHWA), National Renewable Energy Laboratory (NREL), the Federal Transit Administration (FTA), and the Environmental Protection Agency (EPA), provides free technical assistance on the planning, deployment, operation, and maintenance of a national network of electric vehicle chargers, zero-emission fueling infrastructure, and zero-emission transit and school buses. This help sheet shares how technical assistance can support stakeholders.

ADVANCED PROPULSION SYSTEMS,ENERGY PLANNING, POLIC↗

Sodium Components Maintenance Shop (SCMS) Carbonation Vessel – Partial HWMA/RCRA Closure Certification Report

This report documents the Hazardous Waste Management Act (HWMA)/ Resource Conservation and Recovery Act (RCRA) Partial Closure Certification of the Sodium Components Maintenance Shop (SCMS) Carbonation Vessel. The HWMA/RCRA Closure followed the multi step review and evaluation closure process identified in the Idaho National Laboratory (INL) Materials and Fuels Complex (MFC) HWMA/RCRA Partial Permit Closure Plan, October 1, 2015. This closure certification report documents that the SCMS Carbonation Vessel was removed from the SCMS, packaged as hazardous waste and stored for future treatment and disposal, and therefore has met the closure performance standards in accordance with the Department of Energy Idaho National Laboratory Materials and Fuels Complex HWMA/RCRA Partial Permit Closure Plan (EPA No. ID4890008952, October 1, 2015).

99 GENERAL AND MISCELLANEOUS↗