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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 685 records · Page 38
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

CO2 Sorption in Aminopolymer-Based Direct Air Capture Composites Through Fluorescent Detection

Aminopolymer-mesoporous oxide composites are becoming widely recognized for their ability to adsorb CO2 directly from the air. However, a better fundamental understanding of the nature of these materials under different environmental operating conditions will be necessary before they become ubiquitous in industrial direct air capture (DAC) systems. For example, gas diffusion in general is coupled with polymer segmental mobility in these composites; diffusion is therefore affected by interactions of the polymer with the pore wall of the mesoporous oxide, by the relative humidity of the air, and by electrostatic crosslinks that develop as a function of CO2 sorption. Disentangling these and additional complicated effects in order to better optimize operating conditions is a major challenge for the field. Here, we present a method for quantifying the adsorption of CO2 and moisture in a polyethylenimine (PEI) - Al2O3 composite using infrared sensing while we simultaneously monitor polymer mobility with a fluorescent probe molecule doped into the composite. Both the fluorescence intensity and shape of the emission spectra are strongly dependent on the mobility of the supporting medium. We monitor the polymer mobility and CO2 adsorption kinetics across a series of different relative humidities (RH) with this technique, and we observed that the relative difference between polymer mobility and sorption kinetics from one RH to the next are quite dramatic. We interpret these results and discuss how they can be used to inform the design of more efficient DAC systems for real-world operating conditions.

carbon capture↗
DOE OSTI2023

Optical tags comprising rare earth metal-organic frameworks

Optical tags provide a way to identify assets quickly and unambiguously, an application relevant to anti-counterfeiting and protection of valuable resources or information. The present invention is directed to a tag fluorophore that encodes multilayer complexity in a family of heterometallic rare-earth metal-organic frameworks (RE-MOFs) based on highly connected polynuclear clusters and carboxylic acid-based linkers. Both overt (visible) and covert (near infrared, NIR) properties with concomitant multi-emissive spectra and tunable luminescence lifetimes impart both intricacy and security. Tag authentication can be validated with a variety of orthogonal detection methodologies. The relationships between structure, composition, and optical properties of the family of RE-MOFs can be used to create a large library of rationally designed, highly complex, difficult to counterfeit optical tags.

Sava Gallis, Dorina F.↗
NASA NTRS1981

Observations of neutral iron emission in twilight spectra

A method is presented for the analysis of twilight airglow spectra that may be contaminated by atmospheric continuum emission of unknown brightness. The necessity of correcting for this continuum emission when measuring weak airglow features in twilight is illustrated by application of the method to the neutral iron line at 3860 A.

Tepley, C. A.↗
NASA NTRS1974

Measurements of trace constituents from atmospheric infrared emission and absorption spectra, a feasibility study

The feasibility of detecting eight trace constituents (CH4, HCl, HF, HNO3, NH3, NO, NO2 and SO2) against the rest of the atmospheric background at various altitudes from infrared emission and absorption atmospheric spectra was studied. Line-by-line calculations and observational data were used to establish features that can be observed in the atmospheric spectrum due to each trace constituent. Model calculations were made for experimental conditions which approximately represent state of the art emission and absorption spectrometers.

Goldman, A.↗
NASA NTRS1984

Emission lines in the spectra of the RV Tauri stars U Monocerotis and AC Herculis

Strong metallic emission lines have been observed in the spectra of the RV Tauri stars U Mon and AC Her near recent light minima. While these two variables differ in a number of significant respects, the metallic emission spectra are quite similar, resembling the emission that was previously reported as present in the spectrum of R Sct at a deep minimum. The data appear to support Baird's shock-wave model for the spectral behavior of RV Tauri stars.

Bopp, B. W.↗
NASA NTRS1995

Diffuse emission and pathological Seyfert spectra

In this annual ROSAT status report, the diffuse emission and spectra from Seyfert galaxies are examined. Three papers are presented and their contents include the soft x-ray properties and spectra of a binary millisecond pulsar, the PSPC and HRI observations of a Starburst/Seyfert 2 Galaxy, and an analysis of the possibility of x-ray luminous starbursts in the Einstein Medium Sensitivity Survey.

Halpern, Jules P.↗
NASA NTRS1988

The effects of thermal accretion disk spectra on the emission lines from active galactic nuclei

Although most ratios of AGN emission lines depend primarily on global averages over the ionizing spectrum of the thermal accretion disk, there are some which behave quite differently for different spectra. Using these, it may be possible to infer the shape of the spectrum in the unobservable ultraviolet. Two classes of methods for making this inference are discussed, one based upon as many line ratios as can be observed, the other singling out those best at distinguishing different spectral shapes. Because of a variety of technical difficulties, only the first class, which uses global measures of goodness-of-fit, is practical. Application of this method to a compilation of quasar line ratios yields a weak conclusion, however, with the best fit favoring the presence of a thermal accretion disk with T(b) of roughly 20 eV.

Krolik, Julian H.↗
NASA NTRS2001

The Annual Cycle of Water Vapor on Mars as Observed by the Thermal Emission Spectrometer

Spectra taken by the Mars Global Surveyor Thermal Emission Spectrometer (TES) have been used to monitor the latitude, longitude, and seasonal dependence of water vapor for over one full Martian year (March 1999-March 2001). A maximum in water vapor abundance is observed at high latitudes during mid-summer in both hemispheres, reaching a maximum value of approximately 100 pr-micrometer in the north and approximately 50 pr-micrometer in the south. Low water vapor abundance (<5 pr-micrometer) is observed at middle and high latitudes in the fall and winter of both hemispheres. There are large differences in the hemispheric (north versus south) and seasonal (perihelion versus aphelion) behavior of water vapor. The latitudinal and seasonal dependence of the decay of the northern summer water vapor maximum implies cross-equatorial transport of water to the southern hemisphere, while there is little or no corresponding transport during the decay of the southern hemisphere summer maximum. The latitude-longitude dependence of annually-averaged water vapor (corrected for topography) has a significant positive correlation with albedo and significant negative correlations with thermal inertia and surface pressure. Comparison of TES results with those retrieved from the Viking Orbiter Mars Atmospheric Water Detectors (MAWD) experiments shows some similar features, but also many significant differences. The southern hemisphere maximum observed by TES was not observed by MAWD and the large latitudinal gradient in annually-averaged water vapor observed by MAWD does not appear in the TES results.

Smith, Michael D.↗
NASA NTRS1991

Weighted slit extraction of low-dispersion IUE spectral data

The weighted slit extraction has been chosen by the IUE project as the standard extraction for low-dispersion spectra in the final IUE archives. In order to properly weight the data within the extraction slit and obtain the optimal evaluation of the true spectrum, a noise model is derived for IUE data. The exclusion of cosmic rays is demonstrated and the improvement in signal-to-noise ratio is quantified for spectra taken with a wide range of flux level. Problematic spectra, such as trailed spectra, multiple spectra, discontinuous spectra, and emission-line spectra, are extracted to demonstrate the robust nature of the method. Comparisons are made between the standard IUE Standard Image Processing System (IUESIPS) extraction, nonstandard narrow slit extraction, trailed IUESIPS extraction, and weighted extraction for these data. Other weighted slit extractions are briefly discussed. The advantages of the weighted slit extraction are: (1) the extraction improves the signal-to-noise ratio of the spectrum while conserving total flux; (2) most of the cosmic rays are automatically removed; (3) the output includes an error estimate for each point in the flux spectrum; and (4) the algorithm can be run in a batch mode that requires no special input parameters.

Kinney, A. L.↗
NASA NTRS2003

Palagonitic (Not Andesitic) Mars: Evidence from Thermal Emission and VNIR Spectra of Palgonitic Alteration Rinds on Basaltic Rock

Visible and near-IR (VNIR) spectra of both Martian bright and dark regions are characterized by a ferric absorption edge extending from approx. 400 to 750 nm, with bright regions having about twice the reflectivity at 750 nm as dark regions. Between 750 nm to beyond 2000 nm, bright and dark regions have nearly constant and slightly negative spectral slopes, respectively. Depending on location, bright regions have shallow reflectivity minima in the range 850-910 nm that are attributed to ferric oxides. Similarly, dark regions have shallow reflectivity minima near approx. 950 and 1700-2000 nm that are attributed to ferrous silicate minerals (pyroxene). Among terrestrial geologic materials, the best spectral analogues for Martian bright regions are certain palagonitic tephras from Mauna Kea Volcano (Hawaii). By definition, palagonite is a "yellow or orange isotropic mineraloid formed by hydration and devitrification of basaltic glass". The ferric pigment in palagonite is nanometer-sized ferric oxide particles (np-Ox) dispersed throughout the hydrated basaltic glass matrix. The hydration state of the np-Ox particles is not known, but the best Martian spectral analogues contain allophane-like materials and not crystalline phyllosilicates.

R V Morris↗
NASA NTRS1978

Spectrophotometry of Seyfert 2 galaxies and narrow-line radio galaxies

Results are reported for a spectrophotometric survey of several Seyfert 2 galaxies, intermediate Seyferts, and narrow-line radio galaxies. The emission-line spectra of the galaxies are analyzed, emphasizing line intensities, reddening, temperatures, densities, line strength correlations, line widths, and redshift differences. The continuous spectra are examined, and possible ionization sources are considered. It is found that: (1) there are no distinguishing differences between the spectra of Seyfert 2 galaxies and narrow-line radio galaxies; (2) the emission spectra are rich in lines from a wide range of ionization levels; (3) the continuum is starlight diluted by an underlying continuous spectrum; (4) the line widths of both classes of galaxies have the same distribution; (5) there appear to be regions of high and low ionization in the Seyfert 2 and narrow-line radio galaxies; (6) photoionization seems quite likely as the energy input to the gas; and (7) all the galaxies show a UV excess in their spectra.

Koski, A. T.↗
NASA NTRS1984

Fluorescent excitation of Fe 2, Mn 2, Ti 2, N 1 lines by V 4, N 5, O 6: Emission lines in the spectra of symbiotic stars and Seyfert galaxies

Analysis of the published IUE and ground based high resolution spectra of symbiotic stars, particularly RR Tel, shows that the dominant excitation mechanism of Fe II, Mn II, Ti II, and N I lines is the selective fluorescent excitation of some levels by the strong C IV, N V, and O VI emission lines. The same mechanism should work for the excitation of Fe II lines in the spectra of Seyfert galaxies and Q60's whose emission spectra are quite similar to those of symbiotic stars. The similarities and differences between the fluroescent excitation mechanism reported herein and the Bowen's mechanism is analyzed.

Gilra, D. P.↗
NASA NTRS1989

IUE observations of the Jovian dayglow emission

IUE spectra of Jupiter are examined in light of recent models put forward to explain the anomalously bright ultraviolet emissions seen from the upper atmospheres of the outer planets. Chi-squared fits of the IUE spectra with model spectra produced by two proposed excitation mechanisms, electron impact and fluorescence of solar radiation, result in consistently higher chi-squared values for the solar fluorescence model. No conclusive evidence is found in the IUE data for the dominance of solar fluorescence over electron excitation in producing the Jovian dayglow emission.

Mcgrath, M. A.↗
NASA NTRS1993

Faint Object Spectrograph Spectra of the UV Emission Lines in NGC 5558: Detection of Strong Narrow Components

Ultraviolet spectra of the Seyfert 1 galaxy NGC 5548 were obtained with the Faint Object Spectrograph (FOS) on the Hubble Space Telescope on 1992 July 5, when the UV continuum and broad emission lines were at their lowest ever observed level. The high resolution of the spectra, relative to previous UV observations, and the low state of NGC 5548 allow the detection and accurate measurement of strong narrow components of the emission lines of Ly alpha, C IV 1549, and C III 1909. Isolation of the UV narrow components enables a detailed comparison of narrow-line region (NLR) properties in Seyfert 1 and 2 galaxies, and removal of their contribution is important for studies of the broad-line region (BLR). Relative to the other narrow lines, C IV 1549 is much stronger in NGC 5548 than in Seyfert 2 galaxies, and Mg II 2798 is very weak or absent.

Crenshaw, D. Michael↗
NASA NTRS1995

The Hubble Space Telescope Quasar Absorption Line Key Project. 10: Galactic H I 21 centimeter emission toward 143 quasars and active Galactic nuclei

Sensitive H I 21 cm emission line spectra have been measured for the directions to 143 quasars and active galactic nuclei (AGNs) chosen from the observing lists for the Hubble Space Telescope (HST) Quasar Absorption Line Key Project. Narrow-band and wide-band data were obtained with the National Radio Astronomy Observatory (NRAO) 43 m radio telescope for each object. The narrow-band data have a velocity resolution of 1 km/s, extend from -220 to +170 km/s, and are corrected for stray 21 cm radiation. The wide-band data have a resolution of 4 km/s and extend from -1000 to +1000 km/s. The data are important for the interpretation of ultraviolet absorption lines near zero redshift in Key Project spectra. Twenty-two percent of the quasars lie behind Galactic high-velocity H I clouds with absolute value of V(sub LSR) greater than 100 km/s whose presence can increase the equivalent width of interstellar absorption lines significantly. This paper contains the emission spectra and measures of the H I velocities and column densities along the sight line to each quasar. We discuss how the measurements can be used to estimate the visual and ultraviolet extinction toward each quasar and to predict the approximate strength of the strong ultraviolet resonance lines of neutral gas species in the HST Key Project spectra.

Lockman, Felix J.↗