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AmeriFlux US-SdH Nebraska SandHills Dry Valley

This is the AmeriFlux version of the carbon flux data for the site US-SdH Nebraska SandHills Dry Valley. Site Description - The Nebraska SandHills Dry Valley tower is located on public land owned by the University of Nebraska-Lincoln. The site is on a research cattle ranch where grazing primarily takes place.

Billesbach, Dave↗

AmeriFlux FLUXNET-1F MX-Tes Tesopaco, secondary tropical dry forest

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site MX-Tes Tesopaco, secondary tropical dry forest. This is the FLUXNET version of the carbon flux data for the site MX-Tes Tesopaco, secondary tropical dry forest produced by applying the standard ONEFlux (1F) software. Site Description - This tower was located in the "Ejido la Estrella" where the eddy covariance tower is located 7.5 km east of the town Rosario de Tesopaco, in southeastern Sonora, Mexico. The tower was positioned in the center of a homogeneous flat terrain at the foothills of the Madre Occidental. This ecosystem lies in a highly seasonal region under the influence of the North American Monsoon that brings about 70% of the rains from July to September. The site is dominated by leguminous trees. Some of the dominant species are Lysiloma divaricatum, Ipomoea arborescens, Acacia cochliacantha, Haematoxylum brasiletto, and Celtis reticulata. The mean basal area at the study site is 14.83 ± 3.3m2 ha-1, and the aboveground biomass is estimated to be 43.20±9.5Mgha-1. These values and the high counts of Acacia cochliacantha indicate that the area is a secondary forest with significant management activities in the past.

Yepez, Enrico A.↗

[LCA UP] Biomass Drying (2022)

This unit process quantifies the energy requirements and airborne emissions that are expected to result from the biomass drying process, where the biomass type being dried is woody crop biomass.

LCA Unit Process↗

Integrated Geologic Storage Prefeasibility Study Proximal to Dry Fork Power Station, Powder River Basin, Wyoming

The pre-feasibility study—funded by the Department of Energy CarbonSAFE program (DE-FE0029375)—is centred around Basin Electric’s Dry Fork Station (DFS) in Wyoming’s Powder River Basin. Dry Fork Station, completed in 2011, is a high efficient coal-fired power plant that emits 3.3 million tons of CO2 per annum. The DFS site also host’s the Wyoming Integrated Test Center (ITC) funded by a $15 million investment by the State of Wyoming. The ITC is a public-private partnership test bed for CCS technologies. Geologic storage sites are in immediate vicinity of the DFS providing significant opportunities for co-located source and saline storage. The Powder River Basin (PRB) of Wyoming and Montana, was identified by NETL (2010) as having a “high potential” for commercial-scale carbon sequestration. The basin contains as much as 17,000 feet of sedimentary rock and covers an area of approximately 24,000 square miles. The PRB has a long history of hydrocarbon production and remaining undiscovered reserves. Accumulations and production of hydrocarbons in the basin indicate the presence of reservoir formations with significant pore volumes and impermeable sealing formations. This attribute alone suggests the reservoir and seal characteristics of the formations provide significant opportunities for CO₂ storage in saline reservoirs. Four high quality potential reservoir and sealing complexes have been identified for geologic storage. These formations range in depth from 6,500-9,500 feet underneath DFS including: (1) the Pennsylvanian Minnelusa Formation reservoir and Permian Goose Egg Formation (Opeche Shale) seal; (2) the Jurassic Hulett and Canyon Springs Sandstones of the Sundance Formation sealed by the Late Jurassic Upper Sundance Member and Morrison Formation and (3) the Early Cretaceous Lakota and Dakota, and Muddy Formation reservoirs sealed by the Mowry Shale. The preliminary reservoir characterization results integrate data from petrophysical well logs, core measurements, faults/fractures analysis, artificial penetrations, and published literature to evaluate geologic storage capacity and potential risk, for the Powder River Basin. These reservoir and seal combinations reside within ideal depth constraints and show suitable reservoir and seal characteristics conducive to commercial-scale storage. Specifically, this paper presents 1) high level description of the geologic storage complex 2) a first order risk analysis associated with pre-existing oil and gas wells, and 3) preliminary storage capacity and Area of Review estimates.

Quillinan, Scott↗

Dry Cask Storage Inspection and Monitoring. Interim Report.

Recently, the U.S. Nuclear Regulatory Commission (NRC) issued the guidance on the aging management of dry storage facilities that indicates the necessity to monitor the conditions of dry cask storage systems (DCSSs) over extended periods of time.1 Part of the justification of the aging management plans is the requirement for inspection and monitoring to verify whether continued monitoring, inspection or mitigation are necessary. To meet this challenge Argonne National Laboratory (ANL) in collaboration with Idaho National Laboratory (INL) is conducting scoping studies on current and emerging nondestructive evaluation/examination (NDE) and online monitoring (OLM) technologies for DCSS integrity assessments. The scope of work plan includes identification and verification of technologies for long-term online monitoring of DCSSs’ crucial physical parameters such as temperature, pressure, leakage and structural integrity in general. Modifications have been made to the current technologies to accommodate field inspections and monitoring. A summary of the scoping studies and experimental efforts conducted to date as well as plans for future activities is provided below.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Incidental Reflector Comparison of Containerized Dry Fire Extinguishing Agents

This document addresses the incidental reflector reactivity worth of containerized fire extinguishing agents authorized for use in PF-4 at Los Alamos National Laboratory (LANL). The intent of the document is to analyze dry fire extinguishing agent that remains in a container and is not actively being used in a fire emergency. The incidental reflector reactivity worth is determined by comparison to various thicknesses of close fitting water reflection which is commonly used to bound incidental reflectors in criticality safety evaluations. The conclusion is that even in unlimited quantities, when containerized the authorized dry fire extinguishing agents are bound by 0.4 inches of close fitting water.

36 MATERIALS SCIENCE↗

Final Technical Report: Imaging a Dry Storage Cask with Cosmic Ray Muons

The goal of this project is to build a scaled prototype system for monitoring used nuclear fuel (UNF) dry storage casks (DSCs) through cosmic ray muon imaging. Such a system will have the capability of verifying the content inside a DSC without opening it. Because of the growth of the nuclear power industry in the U.S. and the policy decision to ban reprocessing of commercial UNF, the used fuel inventory at commercial reactor sites has been increasing. Currently, UNF needs to be moved to independent spent fuel storage installations (ISFSIs), as its inventory approaches the limit on capacity of on-site wet storage. Thereafter, the fuel will be placed in shipping containers to be transferred to a final disposal site. The ISFSIs were initially licensed as temporary facilities for ~20-yr periods. Given the cancellation of the Yucca mountain project and no clear path forward, extended dry-cask storage (~100 yr.) at ISFSIs is very likely. From the point of view of nuclear material protection, accountability and control technologies (MPACT) campaign, it is important to ensure that special nuclear material (SNM) in UNF is not stolen or diverted from civilian facilities for other use during the extended storage.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Quarterly Report for Dry Storage Safeguards -Q3-2018-LLNL

The objective of this study is to develop a novel methodology for verification of spent fuel inside dry storage casks by analyzing fast/epi-thermal neutrons coming from the top surface of the dry storage casks. In FY2018, data required for MCNP modeling will be gathered, prepared and used to perform MCNP simulations of the system to validate the effectiveness of the verification methodology. Once the methodology is demonstrated to be effective and valid, parameters that affect the detector system sensitivity will be studied as well as the study of diversion scenarios and partial detect.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Aluminum Clad Spent Nuclear Fuel Long Term Dry Storage Technical Issues Action Plan - Technical and Engineering Activities

The DOE Spent Nuclear Fuel Working Group (SNFWG)’s report on technical considerations and challenges for extended dry storage of aluminum-clad spent nuclear fuel (ASNF) entitled, Aluminum-Clad Spent Nuclear Fuel: Technical Consideration and Challenges for Extended (>50 Years) Dry Storage, DOE/ID RPT-1575, June 2017 identified five knowledge gaps and technical data needs. This DOE SNFWG report also made several recommendations including one to develop an action plan to identify needed technical and engineering activities and analyses to address the identified knowledge gaps and technical data needs. A team composed of twenty SNF management experts and appropriate subject matter experts from the Idaho National Laboratory and Savannah River National Laboratory was assembled to develop this action plan. The action plan identifies and recommends six technical and engineering tasks and estimated cost and schedule for task completion. It is estimated that $5M and 18 months will be required to execute the recommended tasks.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Effects of Lower Drying-Storage Temperatures on the DBTT of High-Burnup PWR Cladding

The purpose of this research effort is to determine the effects of canister and /or cask drying and storage on radial hydride precipitation in, and potential embrittlement of, high-burnup (HBU) pressurized water reactor (PWR) cladding alloys during cooling for a range of peak drying-storage temperatures and hoop stresses. Extensive precipitation of radial hydrides could lower the failure hoop stresses and strains, relative to limits established for as-irradiated cladding from discharged fuel rods stored in pools, at temperatures below the ductile- to-brittle transition temperature (DBTT).

36 MATERIALS SCIENCE↗

FINAL SCIENTIFIC/TECHNICAL REPORT: Dry Solids Pump - Coal Feed Technologies

Gas Technology Institute (GTI) has concluded the Dry Solids Pump Coal - Feed Technologies (DSP-CFT) program that was initiated on October 1, 2013. The project’s primary objectives have been to gather data to increase the fidelity of the economic benefits of the Dry Solids Pump (DSP) technology for Integrated Gasification Combined Cycle (IGCC) plants, mature the technology to a Technology Readiness Level (TRL) of TRL 6 by continued testing and upgrades to the existing DSP, advance pump configuration knowledge to the point that a commercial pump can be confidently designed for low rank coal feed stocks and develop the next generation design configuration of a 1000 ton per day (tpd) DSP. After initial efforts with the existing DSP, a subscale pump was built to reduce the cost and time required to develop upgrades. The subscale development program evaluated three exit configurations and a host of geometric variations in each configuration concluding a side exit upward discharge configuration offered the greatest improvements. Both configuration and operation focused improvements were implemented on the full scale existing DSP and demonstrated 500 psi operation. An initial Techno-economic Analysis (TEA) and later update that was undertaken by Mr. Chris Higman and associates. The TEA quantifies the dramatic savings in capital and operational expenses achieved by reducing plant height and nitrogen consumption/compression, respectively in a commercial gasifier application. Drawings of the suggested design configuration for a commercial DSP feeder reflect the side exit design and incorporate lighter weight and lower cost fabrication methods. Features used for development testing are removed. A follow-on optimization program to allow the DSP technology to achieve TRL 7 is outlined.

01 COAL, LIGNITE, AND PEAT↗

Multimodal Nondestructive Dry Cask Basket Structure and Spent Fuel Evaluation

This NEUP-IRP assembled a team from diverse institutions and a diverse set of expertise to examine the problem of assessing the structural health of dry nuclear fuel storage casks, specifically the TN-32 design. With no physical access designed into these storage casks and the high cost and risk associated with opening casks for direct inspection, the technical difficulty of structural assessment of the basket structure and fuel assemblies is high. In response to this challenge, this IRP brought together experts in both traditional and novel NDE methodologies: active acoustics (University of Mississippi), emissions tomography (University of Florida), muon tomography (Oregon State University), and passive-active ultrasonics (University of South Carolina). Further, our industry partners in the Electric Power Research Institute (EPRI) and AREVA provided invaluable insight into technical design details for the cask, practical knowledge of operating parameters at a storage facility, and key relationships that enabled activities unforeseen at the time of the proposed work but were critical in guiding the path of the research. The team decided early in the project that we had a collective goal of laying the technical ground work for practical solutions that could be implemented in the field with reasonable cost, time, and reliability. A fortunate opportunity arose early in this IRP project to obtain access to a new TN-32 cask at Columbiana High Tech. Both acoustics teams were given access for testing concepts in the first year of the project. This ended up providing critical guidance in the design of subsequent laboratory experiments. Specifically, it became clear that the only reliable acoustic pathways to the interior were through the trunnions, base plate, and top ring of the cask. Based on these field tests and discussions about what would be of practical interest, the team as a whole decided a realistic goal was to detect catastrophic failure of a single fuel assembly, or one that was missing. It is clear from this work that the active acoustics / resonance and muon tomography methodologies would be capable of detecting interior structural integrity problems at this level. The other two areas of investigation (emissions tomography and passive/active ultrasonics) would need more testing to determine a successful implementation, but each may also have other applications such as long term monitoring and monitoring during transportation. This IRP project resulted in technical advances with applications that extend beyond the problem at hand, supported the training of 10 graduate students + 1 post doc, 21 publications, and 13 conference presentations. The remainder of this summary highlights significant activities and achievements in each of the methodologies and a brief discussion on how they can be combined to leverage strengths. Active Acoustics The active acoustics team at UM used both linear and non-linear structural resonance methods to infer information about the internal structure of a cask. Significant activities were a set of four field test measurements on a full scale TN-32 cask at the Columbiana Hi Tech facility in Greensboro, NC and the design and fabrication of a 1/6th scale model TN-32 cask for laboratory measurements. A significant set of acoustic data has been acquired on both the full scale and laboratory scale casks. It was determined early in the project that mechanical resonance techniques were not going to be sensitive to small scale (centimeter) cracks and structural defects in the basket structure or fuel assemblies. We were able to ascertain that both the energy and complexity of the resonance spectra were sensitive to “bulk state” of the fuel assemblies – an intact assembly versus a severely degraded assembly. By developing a novel combination of metrics, we are able to measure a statistically significant shift due to one out of the 32 fuel assemblies being either missing or degraded to a point of complete loss of structural coherence (i.e. “rubble”). We believe this combination of resonance metrics is new to the field and will have applications beyond the fuel storage problem. Emissions Tomography The Emissions Tomography team at the University of Florida explored the concept of using scattering of radiation emissions from the stored fuel as method of evaluating the internal structural health of the cask. Due to the need for emissive fuel assemblies and the difficulties of gaining access to storage facilities, this team primarily relied on simulations to inform feasibility. A key question was the flux estimates of neutrons with a small enough number of scattering events to retain spatial information. Some key conclusions from the transmission component of this work are that the number of scattering events falls rapidly with energy – setting a 11MeV threshold, the average number of scattering events is 8∓4. Rough estimates of scanning times using an ideal detector array would be 1 week. The team also explored the case of significant structural failure resulting in a shift of the source material (fuel). The result is that a +/- 2% mass shift results in a detectable (5.13%) shift in the correlated 2 neutron emission counts and thus may be a candidate as an initial survey. Finally, simulations for predicting the azimuthal dependence of the flux based on specific loading patterns were conducted. Due to self-shielding effects of the assemblies, a periodic pattern results and could potentially be used to identify missing or severely degraded assemblies. This work forms a basis for proper detector placement with the goal of optimizing sensitivity. Muon Tomography Muon tomography (MT) is a relatively novel method of interrogating interior structure on a large scale. One of the advantages of this technique is that the exciting energy source (cosmic muons) is ubiquitous and relatively stable in time. Challenging aspects are relatively low flux rates and appropriate detector technologies. The efforts of the muon group at Oregon State University focused on two areas: (1) simulation of various combinations of muon scattering events and detection schemes to assess sensitivities and time scales for image construction and (2) building a prototype muon detection system applicable to the dry storage cask problem as well as many other similar systems. Significant accomplishments in this area are: (1) demonstration that MT is a viable method for detecting missing or severely degraded rod assemblies, (2) a scintillation based detector with 4 panels and 32 channels of position data each were constructed, tested, and calibrated. Testing of the panels using natural muon background and no scattering objects yielded largely expected results – a straight line path for the muon through the four panels. However some anomalies (paths deviating from a line) were also detected. A redesign of the board improved the signal which greatly improved the muon tracking through the panels. Testing with lead bricks as scattering bodies showed a reduction in the coincidence rate with increasing bricks indicating increased scattering events. A refinement of the scintillator detector design resulted in a spatial image resolution of around 2 cm based on lead brick spacing tests lasting 24 hours. Passive/Active Ultrasonics This team at the University of South Carolina investigated the feasibility of combining passive ultrasonics, in which an elastic pulse is generated by a degradation process (such as a crack extending), and active ultrasonics, in which a known excitation is introduced into the structure and detected by an array of transducers. Significant accomplishments in this area include the development of elastic wave propagation simulation in relevant materials, development of diagnostic algorithms, and laboratory testing and validation using laser doppler vibrometry. This group demonstrated the applicability of various non-contact vibration detection methodologies such as air-coupled ultrasonic transducers and scanning laser doppler vibrometry. While passive acoustic emissions monitoring will likely have a role during the transportation of a fuel storage cask, the level of detailed information about the defect generating the event which can be ascertained from the detections in a complex structure remains for future work. Thermography The EPRI team contributed early in the project a series of thermography measurements in which various levels of water pooled in a mock-up canister were analyzed using commercially available infrared imaging technologies. While large levels of water (100 L, ~10 cm deep) were observable in the thermograms, more realistic levels of pooled water (1 L) were not detectable whether localized or distributed.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Evaluation of Hydrogen Generation in High Burnup Demonstration Dry Storage Cask

This report provides a best-estimate evaluation of residual water content (post-dry out) in the High Burnup (HBU) LWR Spent Fuel Demonstration project TN-32 cask, and evaluates the radiolysis of the residual free water, and the physisorbed and chemisorbed waters on the surfaces of the fuel and cask internal contents. The evaluation of radiolytic breakdown of those waters with gamma radiation causing the generation of hydrogen gas (H 2 ) is made using available literature data and models. This evaluation is part of the overall materials performance evaluation of the SNF-in-canister system, and is part of the technical bases for their continued safe dry storage. The TN-32 cask contents included 32 HBU LWR spent fuel assemblies each with 264 fuel rods clad in zirconium alloys, aluminum neutron absorber components, and aluminum and stainless steel structural components. The residual free and surface (physisorbed/chemisorbed) waters are ascribed to water vapor in the free volume and to components’ surfaces, respectively. The total potential radiolytic hydrogen inventory from the water vapor and from waters ascribed to surfaces has been calculated assuming all the water produced molecular H 2 . The residual water that is chemically incorporated into the bulk of a hydrated oxide, i.e., chemisorbed water, and its total potential hydrogen inventory has been calculated. These calculations are at the physical limit of material available and are used for a bounding assessment purpose only.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Quantitative form and fit of N95 filtering facepiece respirators are retained after dry and humid heat treatments for coronavirus deactivation

Re-use of filtering facepiece respirators (FFRs, commonly referred to as N95s) normally meant for single use only is becoming common in healthcare facilities due to shortages caused by the COVID19 pandemic. Here we report that mouse hepatitis virus (MHV) initially seeded on FFR filter material is inactivated (6 log reduction as measured by 50% tissue culture infective dose (TCID50)) after dry heating at 75 °C for 30 minutes. We also find that the quantitative fit of FFRs after heat treatment at this temperature, under dry conditions or at 90% relative humidity, is not affected by single or ten heating cycles. Previous studies have reported that the filtration efficiency of FFR filters is not negatively impacted by these heating conditions. These results suggest that thermal inactivation of coronaviruses is a potentially rapid and widely deployable method to re-use N95 FFRs in emergency situations where reusing FFRs is a necessity and broad-spectrum sterilization is unavailable. However, we also found that a heat source that emits radiation (e.g., an exposed heating element) results in rapid qualitative degradation of the FFR. Finally, we discuss differences in the results reported here and other recent studies investing heat as a means to recycle FFRs and suggest that overall wear time and donning/doffing cycles are important factors that need to be considered.

36 MATERIALS SCIENCE↗

Verification of Spent Fuel Inside Dry Storage Casks by Fast/Epi-thermal Neutron Mapping: FY2020 Annual Report to NA241 (Annual Report)

Lawrence Livermore National Laboratory has embarked upon development of a novel methodology for verification of spent fuel inside dry storage casks. The issue of verification of the integrity of spent fuel inside dry storage has been one of the most challenging technical problems facing IAEA for many decades. The difficulty arises because of the massive amount of shielding between the inner spent fuel and the outer surface where measurements can be performed. Despite many efforts, detection of useful gamma rays or neutrons from the outer surface has so far proven unsuccessful.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Taxonomic and Functional Diversity of Soil and Hypolithic Microbial Communities in Miers Valley, McMurdo Dry Valleys, Antarctica

The McMurdo Dry Valleys of Antarctica are an extreme polar desert. Mineral soils support subsurface microbial communities and translucent rocks support development of hypolithic communities on ventral surfaces in soil contact. Despite significant research attention, relatively little is known about taxonomic and functional diversity or their inter-relationships. Here we report a combined diversity and functional interrogation for soil and hypoliths of the Miers Valley in the McMurdo Dry Valleys of Antarctica. The study employed 16S rRNA fingerprinting and high throughput sequencing combined with the GeoChip functional microarray. The soil community was revealed as a highly diverse reservoir of bacterial diversity dominated by actinobacteria. Hypolithic communities were less diverse and dominated by cyanobacteria. Major differences in putative functionality were that soil communities displayed greater diversity in stress tolerance and recalcitrant substrate utilization pathways, whilst hypolithic communities supported greater diversity of nutrient limitation adaptation pathways. A relatively high level of functional redundancy in both soil and hypoliths may indicate adaptation of these communities to fluctuating environmental conditions.

54 ENVIRONMENTAL SCIENCES↗

Evaluation of PBL Parameterization Schemes in WRF Model Predictions during the Dry Season of the Central Amazon Basin

Planetary Boundary Layer (PBL) parameterization schemes are employed to handle subgrid-scale processes on atmospheric models, playing a key role in accurately representing the atmosphere. Recent studies have shown that PBL schemes are particularly fundamental to the depiction of PBL height (PBLH), especially over the Amazon. In the present study, we investigated the performance of PBL schemes on the representation of meteorological variables, turbulent fluxes, PBL vertical structures, and PBLH over the central Amazon basin under dry conditions, taking advantage of observations from the Observations and Modeling of the Green Ocean Amazon campaign (GoAmazon2014/5) for validation and evaluation. Numerical experiments were carried out within the WRF model using eight PBL schemes for two dry periods from 2014 (typical year) and 2015 (El-Niño year), and results from the 1-km resolution domain were directly compared to hourly in situ observations. In general, all PBL schemes present good performance to reproduce meteorological variables, with nonlocal (local) PBL schemes producing better performance in the 2014 (2015) study period. All PBL schemes in general overestimate (>100%) daytime turbulent fluxes. Thermodynamic (daytime) vertical structures are better predicted than mechanical (nocturnal) ones. The local MYNN2.5 scheme showed the overall best performance for PBLH prediction, mainly at night.

54 ENVIRONMENTAL SCIENCES↗

Effect of Deep Drying and Torrefaction Temperature on Proximate, Ultimate Composition, and Heating Value of 2-mm Lodgepole Pine (Pinus contorta) Grind

Deep drying and torrefaction is a thermal pretreatment method, where biomass is heated in the temperature range of 150–300°C in an inert or reduced environment. The process parameters like temperature and residence time has a significant impact on proximate, ultimate, and energy properties of the biomass. In the present study, torrrefaction experiments were conducted on 2 mm lodgepole pine grind using a thermogravimetric analyzer. Both deep drying and torrefaction temperature (160–270°C) and time (15–120 min) were selected. Torrefied samples were analyzed for proximate, ultimate and energy properties. Results indicated that moisture content decreased with increases in torrefaction temperature and time, where at 270°C and 120 min, the moisture content was found to be 1.15% (w.b.). Volatile content in the biomass decreased from about 80% to about 45%, and ash content increased from 0.77 to about 1.91% at 270°C and 120 min. The hydrogen, oxygen and sulfur content decreased to 3%, 28.24%, and 0.01 whereas carbon content and higher heating value increased to 68.86% and 23.67 MJ/kg at 270°C and 120 min. H/C and O/C ratio calculated at 270°C and 120 min residence time were about 0.56 and 0.47. This study indicated that higher torrefaction temperatures >230°C and residence time >15 min influenced the proximate, ultimate, and energy properties.

09 BIOMASS FUELS↗