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At least 685 records · Page 38

Cosmic millicharge background and reheating probes

We demonstrate that the searches for dark sector particles can provide probes of reheating scenarios, focusing on the cosmic millicharge background produced in the early universe. We discuss two types of millicharge particles (mCPs): either with, or without, an accompanying dark photon. These two types of mCPs have distinct theoretical motivations and cosmological signatures. We discuss constraints from the overproduction and mCP-baryon interactions of the mCP without an accompanying dark photon, with different reheating temperatures. We also consider the ∆n eff constraints on the mCPs from kinetic mixing, varying the reheating temperature. The regions of interest in which the accelerator and other experiments can probe the reheating scenarios are identified in this paper for both scenarios. These probes can potentially allow us to set an upper bound on the reheating temperature down to ~ 10 MeV, much lower than the previously considered upper bound from inflationary cosmology at around ~ 10 16 GeV. In addition, we derive a new “distinguishability condition”, in which the two mCP scenarios may be differentiated by combining cosmological and theoretical considerations. Finally, we discuss the implications of dedicated mCP searches, future CMB-S4 observations, and the target for experiments when considering the minimally allowed reheating temperature.

79 ASTRONOMY AND ASTROPHYSICS↗

Ensemble cure kinetics network (ECK-Net): A method to derive cure kinetics of thermosetting resin

This paper introduces an Ensemble Cure Kinetics Network (ECK-Net), a neural network (NN)–based framework for modeling the cure kinetics of thermosetting resins within a phenomenological context. ECK-Net replaces traditional analytic models, which require extensive chemical insight and multiple isothermal/non-isothermal experiments, with a data-driven surrogate that maps nonlinear relationships between temperature, degree of cure, and reaction rate from differential scanning calorimetry data. The proposed approach predicts input-dependent kinetic coefficients of a generalized nth-order reaction equation rather than reaction rates directly, enabling a single unified model to represent various epoxy systems without relying on iso-conversional analysis or predefined functional forms. To ensure robustness, multiple independently trained networks under different random initializations are blended through an ensemble strategy, effectively mitigating the stochastic variability inherent to neural networks. The framework is validated using experimental datasets from multiple resin systems, including aerospace-grade materials (Toray 3900-2, Cycom 5320-1, and Hexcel 8552) and a windmill-grade resin (RIMR 035c). The model accurately reproduces the temporal evolution of the degree of cure under manufacturers’ recommended cure cycles across all tested resins systems, yielding Pearson’s correlation coefficients of 0.992, 0.994, 0.993, 0.997, respectively. To demonstrate process-level applicability, the trained network was implemented within the Abaqus environment to simulate out-of-autoclave (OOA) curing process of the CFRP panel composed of Toray T830H-6K/3900-2D prepreg. The simulation results showed excellent agreement with experimental temperature response (maximum peak temperature, simulation: 189.6 °C, experiment: 188.5 °C) and the final degree of cure (simulation: 0.948, experiment: 0.960 ± 0.013), confirming ECK-Net’s capability as a reliable alternative to conventional cure kinetics modeling methods.

Composite curing↗

Accuracy in Resolving the First Hydration Layer on a Transition-Metal Oxide Surface: Experiment (AP-XPS) and Theory

Understanding the equilibrium conditions at the metal oxide/aqueous interface is a key component toward visualizing the structure of water in confined environments and differentiating the catalytic activity of transition-metal oxides. While ambient pressure X-ray photoelectron spectroscopy (AP-XPS) has been the primary technique to investigate the formation of a hydration layer on many surfaces, results over the extended relative humidity (RH) range accessible experimentally have not been compared quantitatively to theoretical predictions. With the use of first-principles theoretical methods and accumulated knowledge of AP-XPS spectral analysis, we do so here for a model surface, TiO 2 -terminated undoped SrTiO 3 (100) (STO). The measured distribution of OH and H 2 O coverages from vacuum up to the first hydration layer is in good agreement with a static density functional theory (DFT) configuration involving partial dissociation of H 2 O per Ti-atom mediated by H-bonding. Furthermore, ab initio molecular dynamics (AIMD) simulations at 300 K for select coverages (1/4, 1/2, and 1 ML) test the role of fluctuations and entropy in the competition between adsorption and dissociation with coverage. This comparison between theory and experiment for OH and H 2 O coverages on STO provides a foundation for a more quantitative assessment of the first hydration layer and associated competition between adsorption, dissociation, and H-bonding on transition-metal oxide surfaces.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Cryogenic Equivalence Principle Experiment

The purpose of this project is to test the equivalence of inertial and passive gravitational mass in an Earth-orbiting satellite. A ground-based experiment is now well developed. It consists of comparing the motions of two cylindrical test masses suspended in precision superconducting magnetic bearings and free to move along the horizontal (axis) direction. The masses are made of niobium and lead-plated aluminum. A position detector based on a SQUID magnetometer measures the differential motion between the masses. The periods of the masses are matched by adjustment of the position detector until the system is insensitive to common mode signals, and so that the experiment is less sensitive to seismic vibration. The apparatus is contained in a twelve inch helium dewar suspended in a vibration isolation stand. The stand achieves 30 db isolation from horizontal motions between 0.1 and 60 Hz, by simulating the motion of a 200 meter long pendulum with an air bearing. With this attenuation of seismic noise and a common mode rejection ratio of 10 to the 5th power in the differential mode, the ground based apparatus should have a sensitivity to equivalence principle violations of one part in 10 to the 13th power; the satellite version might have a sensitivity of one part in 10 to the 17th power.

Everitt, C. W. F.↗

Experiments on the Capillary Condensation/Evaporation Hysteresis of Pure Fluids and Binary Mixtures in Cylindrical Nanopores

Here, a new experimental method, i.e., isochoric cooling/heating cycle measurement using differential scanning calorimeter (DSC), is applied to investigate the hysteretic phenomenon of pure components and mixtures confined in two different types of cylindrical nanopores (SBA-15 and KIT-6). The capillary condensation/evaporation hysteresis end point (T he ) for a specific system is determined by performing a series of measurements with different densities by increasing initial temperature and pressure. We confirm that for a pure component, T he is lower when confined in smaller nanopores, whereas T he for CH 4 /CO 2 and CH 4 /C 2 H 6 mixtures at the specific composition investigated are higher than that of pure CO 2 and C 2 H 6 , respectively, when confined in the same nanopores. To the best of our knowledge, this is the first time that T he of fluid mixture is experimentally studied, which further demonstrates that binary mixtures behave similarly to pure fluids when confined in nanoporous media. At low temperatures where hysteresis is observed, the shape as well as the duration of the exothermic peak (due to capillary condensation) and endothermic peak (due to capillary evaporation) indicate that capillary condensation, rather than capillary evaporation, takes place at/near a thermodynamic equilibrium. Within the accuracy of the measurements, we find that the total heat of capillary condensation is identical to that of capillary evaporation for all systems examined, regardless of the presence of hysteresis. By comparing the heat per unit volume among different systems, we also find that the heat per unit volume of the phase transition of confined pure fluid is lower than that of bulk, which further demonstrates that the molar density of confined pure liquid is less than that of bulk pure liquid at saturation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Measurements of the production cross-section for a Z boson in association with b -jets in proton-proton collisions at √s = 13 TeV with the ATLAS detector

This paper presents a measurement of the production cross-section of a Z boson in association with b-jets, in proton-proton collisions at √s = 13 TeV with the ATLAS experiment at the Large Hadron Collider using data corresponding to an integrated luminosity of 35.6 fb -1 . Inclusive and differential cross-sections are measured for events containing a Z boson decaying into electrons or muons and produced in association with at least one or at least two b-jets with transverse momentum p T > 20 GeV and rapidity |y| < 2.5. Predictions from several Monte Carlo generators based on leading-order (LO) or next-to-leading-order (NLO) matrix elements interfaced with a parton-shower simulation and testing different flavour schemes for the choice of initial-state partons are compared with measured cross-sections. We find that the 5-flavour number scheme predictions at NLO accuracy agree better with data than 4-flavour number scheme ones. This is because the 4-flavour number scheme predictions underestimate data in events with at least one b-jet.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Steady Secondary Momentum and Enthalpy Streaming in the Pulse Tube Refrigerator

Our study investigates the steady secondary streaming that occurs in the pulse tube refrigerator through application of the conservation laws and support by flow visualization experiments. A series expansion of the mass, momentum and energy conservation laws for an axisymmetric system yields a set of linear differential equations. The series solution is expanded in the small parameter epsilon = 1/Str where Str is the Strouhal number. The O(1) basic flow problem is solved for the case of a compressible ideal gas oscillating within a cylindrical tube. The phase and amplitude of the boundary conditions on axial velocity are treated as independent parameters. The basic solution for the gas domain is solved for the case of temperature and heat flux coupling to the tube wall. The temperature coupled solution shows how the Fourier number of the tube wall affects the gas temperature, phase angle, and time-averaged enthalpy flow. The basic solution is also examined for the time-averaged Reynolds stresses which are shown to be the driving force that produces steady secondary momentum streaming. Calculated solutions to the steady momentum streaming are shown to be in qualitative agreement with flow visualization experiments.

Lee, J. M.↗

Inhibition of root elongation in microgravity by an applied electric field

Roots grown in an applied electric field demonstrate a bidirectional curvature. To further understand the nature of this response and its implications for the regulation of differential growth, we applied an electric field to roots growing in microgravity. We found that growth rates of roots in microgravity were higher than growth rates of ground controls. Immediately upon application of the electric field, root elongation was inhibited. We interpret this result as an indication that, in the absence of a gravity stimulus, the sensitivity of the root to an applied electric stimulus is increased. Further space experiments are required to determine the extent to which this sensitivity is shifted. The implications of this result are discussed in relation to gravitropic signaling and the regulation of differential cell elongation in the root.

short duration↗

Constraining the destruction rate of K 40 in stellar nucleosynthesis through the study of the Ar 40 ( p , n ) K 40 reaction

Background: We present that K 40 plays a significant role in the radiogenic heating of Earth-like exoplanets, which can affect the development of a habitable environment on their surfaces. The initial amount of K 40 in the interior of these planets depends on the composition of the interstellar clouds from which they formed. Within this context, nuclear reactions that regulate the production of K 40 during stellar evolution can play a critical role. Purpose: In this study, we constrain for the first time the astrophysical reaction rate of K 40 ( n , p ) Ar 40 , which is responsible for the destruction of K 40 during stellar nucleosynthesis. We provide to the nuclear physics community high-resolution data on the cross section and angular distribution of the Ar 40 ( p , n ) K 40 reaction. These are important to various applications involving Ar 40 . The associated reaction rate of the Ar 40 ( p , n ) K 40 process addresses a reaction rate gap in the Joint Institute for Nuclear Astrophysics REACLIB database in the region of intermediate-mass isotopes. Methods: We performed differential cross-section measurements on the Ar 40 ( p , n ) K 40 reaction, for six energies in the center-of-mass system between 3.2 and 4.0 MeV and various angles between 0 ° and 135 ° . The experiment took place at the Edwards Accelerator Laboratory at Ohio University using the beam swinger target location and a standard neutron time-of-flight technique. We extracted total and partial cross sections by integrating the double differential cross sections we measured. Results: The total and partial cross sections varied with energy due to the contribution from isobaric analog states and Ericson type fluctuations. The energy-averaged neutron angular distributions were symmetrical relative to 90 ° . Based on the experimental data, local transmission coefficients were extracted and were used to calculate the astrophysical reaction rates of Ar 40 ( p , n ) K 40 and K 40 ( n , p ) Ar 40 reactions. The new rates were found to vary significantly from the theoretical rates in the REACLIB library. We implemented the new rates in network calculations to study nucleosynthesis via the slow neutron capture process, and we found that the produced abundance of K 40 is reduced by up to 10% compared to calculations with the library rates. At the same time, the above result removes a significant portion of the previous theoretical uncertainty on the K 40 yields from stellar evolution calculations. Conclusions: Our results support a destruction rate of K 40 in massive stars via the K 40 ( n , p ) Ar 40 reaction that is larger compared to previous estimates. The rate of K 40 destruction via the K 40 ( n , p ) Ar 40 reaction now has a dramatically reduced uncertainty based on our measurement. Lastly, this result directly affects the predicted stellar yields of K 40 from nucleosynthesis, which is a critical input parameter for the galactic chemical evolution models that are currently employed for the study of significant properties of exoplanets.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Punzi-loss: a non-differentiable metric approximation for sensitivity optimisation in the search for new particles

We present the novel implementation of a non-differentiable metric approximation and a corresponding loss-scheduling aimed at the search for new particles of unknown mass in high energy physics experiments. We call the loss-scheduling, based on the minimisation of a figure-of-merit related function typical of particle physics, a Punzi-loss function, and the neural network that utilises this loss function a Punzi-net. We show that the Punzi-net outperforms standard multivariate analysis techniques and generalises well to mass hypotheses for which it was not trained. This is achieved by training a single classifier that provides a coherent and optimal classification of all signal hypotheses over the whole search space. Our result constitutes a complementary approach to fully differentiable analyses in particle physics. We implemented this work using PyTorch and provide users full access to a public repository containing all the codes and a training example.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

On the effects of quadrupolar relaxation in Earth’s field NMR spectra

There is growing interest in using low-field magnetic resonance experiments for routine chemical characterization. Earth’s field NMR is one such technique that can garner structural information and enable sample differentiation with low cost and highly portable designs. The resulting NMR spectra are primarily influenced by $J$-couplings, resulting in so-called $J$-coupled spectra (JCS). Many small molecules include atoms with NMR-active nuclei that are quadrupolar either at natural abundance or are often isotopically enriched (e.g., 2 H, 6 Li, 11 B, 14 N, 17 O, etc.) where the effects of quadrupolar J-couplings and relaxation on JCS of strongly- and weakly-coupled spin systems have not been explored to date. Herein, using a set of seven fluoropyridine samples with unique substitution and $J$-couplings, we demonstrate that the 14 N relaxation rates can induce drastic line-broadening in the JCS. This includes a previously unexplored unique line broadening mechanism enabled by strongly coupled spins at low-field. In conclusion, numerical simulations are used to model and refine the magnitudes and signs of $J$-couplings, as well as indirectly determine the 14 N relaxation rates in a single 1D experiment that has a higher fidelity than observed in high-field NMR experiments.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Experimental Constraints on the Chemical Differentiation of Mercurys Mantle

Mercury is known as being the most reduced terrestrial planet with the highest core/mantle ratio. Results from MESSENGER spacecraft have shown that its surface is FeO-poor (2-4 wt%) and S-rich (up to 6-7 wt%), which confirms the reducing nature of its silicate mantle. In addition several features suggest important melting stages of the Mercurian mantle: widespread volcanic deposits on its surface, a high crustal thickness (approximately 10% of the planet's volume) and chemical compositions of its surface suggesting several stages of differentiation and remelting processes. Therefore it is likely that igneous processes like magma ocean crystallization and continuous melting have induced chemical and mineralogical heterogeneities in the Mercurian mantle. The extent and nature of compositional variations produced by partial melting remains poorly constrained for the particular compositions of Mercury (very reducing conditions, low FeO-contents and high sulfur-contents). Melting experiments with bulk Mercury-analogue compositions are scarce and with poorly con-trolled starting compositions. Therefore additional experimental data are needed to better understand the differentiation processes that lead to the observed chemical compositions of Mercury's surface.

Boujibar, A.↗

State elimination for mixed‐integer optimal control of partial differential equations by semigroup theory

Abstract Mixed‐integer optimal control problems governed by partial differential equations (MIPDECOs) are powerful modeling tools but also challenging in terms of theory and computation. We propose a highly efficient state elimination approach for MIPDECOs that are governed by partial differential equations that have the structure of an abstract ordinary differential equation in function space. This allows us to avoid repeated calculations of the states for all time steps, and our approach is applied only once before starting the optimization. The presentation of theoretical results is complemented by numerical experiments.

97 MATHEMATICS AND COMPUTING↗

Current limiting mechanisms in electron and ion beam experiments

The emission and collection of current from satellites or rockets in the ionosphere is a process which, at equilibrium, requires a balance between inward and outward currents. In most active experiments in the ionosphere and magnetosphere, the emitted current exceeds the integrated thermal current by one or more orders of magnitude. The system response is typically for the emitted current to be limited by processes such as differential charging of insulating surfaces, interactions between an emitted beam and the local plasma, and interactions between the beam and local neutral gas. These current limiting mechanisms have been illustrated for 20 years in sounding rocket and satellite experiments, which are reviewed here. Detailed presentations of the Spacecraft Charging at High Altitude (SCATHA) electron and ion gun experiments are used to demonstrate the general range of observed phenomena.

Olsen, R. C.↗

Experimental investigation of flow distribution in enhanced geothermal systems with deep eutectic solvent

Geothermal energy has been recognized as a valuable alternative to fossil fuels and nuclear power, as it is renewable and reliable. Enhanced Geothermal Systems (EGSs) have the potential to expand geothermal energy production by enabling access to previously untapped geothermal resources. Geothermal short-circuiting poses a significant challenge to EGS development, leading to reduced heat extraction. Deep Eutectic Solvent (DES) exhibits favorable thermal and rheological properties, making it a candidate for geothermal applications. Here, this paper examines Choline Chloride-Based Deep Eutectic Solvent (DES) as a working fluid in geothermal applications and its potential to mitigate geothermal short-circuiting. Hydraulic experiments using a dual fracture flow loop were conducted at high temperatures. The results showed that DES exhibited higher differential pressure behavior compared to water. Flow distribution results revealed that DES enhances flow allocation within the small fracture, particularly when a temperature difference exists between fractures. Specifically, DES increased flow distribution by an average of 11% when the temperature difference was 85°C, and by 13% when the difference was 45°C, relative to water. These findings suggest that DES responds to thermal fracture differences, making it a potential remedy to address geothermal short-circuiting.

15 GEOTHERMAL ENERGY↗

Functional Design of Peptide Materials Based on Supramolecular Cohesion

Peptide materials offer a broad platform to design biomimetic soft matter, and filamentous networks that emulate those in extracellular matrices and the cytoskeleton are among the important targets. Given the vast sequence space, a combination of computational approaches and readily accessible experimental techniques is required to design peptide materials efficiently. Here, we report here on a strategy that utilizes this combination to predict supramolecular cohesion within filaments of peptide amphiphiles, a property recently linked to supramolecular dynamics and consequently bioactivity. Using established coarse-grained simulations on 10,000 randomly generated peptide sequences, we identified 3500 likely to self-assemble in water into nanoscale filaments. Atomistic simulations of small clusters were used to further analyze this subset of sequences and identify mathematical descriptors that are predictive of intermolecular cohesion, which was the main purpose of this work. We arbitrarily selected a small cohort of these sequences for chemical synthesis and verified their fiber morphology. With further characterization, we were able to link the latent heat associated with fiber to micelle transitions, an indicator of cohesion and potential supramolecular dynamicity within the filaments, to calculated hydrogen bond densities in the simulation clusters. Based on validation from in situ synchrotron X-ray scattering and differential scanning calorimetry, we conclude that the phase transitions can be easily observed by very simple polarized light microscopy experiments. We are encouraged by the methodology explored here as a relatively low-cost and fast way to design potential functions of peptide materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Insights from multinucleon transfer reactions in 206 Pb+ 118 Sn

Multinucleon transfer reactions for the 206 Pb + 118 Sn system were measured at E lab = 1200 MeV using the PRISMA large solid-angle magnetic spectrometer. The experiment was conducted at laboratory angles around the grazing angle, covering an angular range of approximately 20°. The resulting differential and total cross sections, along with Q-value distributions for various neutron and proton pick-up and stripping channels, are presented. The Q-value distributions suggest a transition from quasi-elastic to deep inelastic collision processes, particularly in channels involving nucleon transfers. The experimental results have been compared with GRAZING code calculations, showing good agreement for few-nucleon transfer channels, while channels with large nucleon transfers are underestimated, indicating the involvement of more complex processes.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Machine Learning Pattern Recognition Algorithm With Applications to Coherent Laser Combination

Herein we analyze a new kind of machine learning algorithm designed to feedback stabilize coherently combined lasers. This algorithm learns differential, rather than absolute, values of action in phase space, in order to facilitate learning on initially unstable systems. Experiments have shown that this approach can control small-scale spatial beam combination with high stability. In this paper we analyze the algorithm's performance and limitations in depth, showing that it can continuously learn during operation in order to track changes. Using simulation, we extend the application to temporal combination, and show that it scales to more complex instances by combining 81 beams.

97 MATHEMATICS AND COMPUTING↗