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At least 685 records · Page 38

The rotation-inversion spectra and vibration-rotation interaction in NH2D

An additional 86 lines of the NH2D rotation-inversion spectrum were measured between 7.5 and 850 GHz. These data and the existing NH2D and ND2H data are fitted to a Hamiltonian in which the vibration-rotation interaction is included in the form of an off-diagonal inertial tensor term. For comparison with the symmetric ammonias an oblate basis and a Watson-type reduced 'S' set of distortion constants are used. A theory for the interaction term is given which is in excellent agreement with experiment. Structural parameters are derived. The magnitude and relative sign of the two dipole moment components of NH2D are determined and previously measured nitrogen hyperfine structure for both species is reexamined using improved rotational wavefunctions.

Cohen, E. A.↗

Application of the regular associated solution model to the Cd-Te and Hg-Te binary systems

The regular associated solution model is used to treat the phase diagrams of the binary II-VI semiconductor alloy systems Hg-Te and Cd-Te. The equations for the species activity coefficients are used without approximations regarding the magnitudes of the various binary interchange energies or the functional dependence on component mol fraction. The values of the four-adjustable parameters required for description of each system are fixed by fitting liquidus data, and the resulting activity coefficients are used to calculate component partial pressures, which are compared with experimental values as an indpendent check of the validity of the model. The results show that the regular associated solution model provides a usefully accurate, but not complete, description for both the Hg-Te and Cd-Te systems. The relationship of this work to previous investigations is discussed.

Kelley, J. D.↗

Adsorption of humic acids and trace metals in natural waters

Studies concerning the interactions between suspended hydrous iron oxide and dissolved humic acids and trace metals are reported. As a major component of dissolved organic matters and its readiness for adsorption at the solid/water interface, humic acids may play a very important role in the organometallic geochemistry of suspended sediments and in determining the fate and distribution of trace metals, pesticides and anions in natural water systems. Most of the solid phases in natural waters contain oxides and hydroxides. The most simple promising theory to describe the interactions of hydrous iron oxide interface is the surface complex formation model. In this model, the adsorptions of humic acids on hydrous iron oxide may be interpreted as complex formation of the organic bases (humic acid oxyanions) with surface Fe ions. Measurements on adsorptions were made in both fresh water and seawater. Attempts have been made to fit our data to Langmuir adsorption isotherm. Adsorption equilibrium constants were determined.

Leung, W. H.↗

The Spectral Properties of Gamma-ray Bursts: a Review of Recent Development

Developments in the spectroscopy of gamma ray bursts (GRB) are reviewed. The general question of the validity of the spectral results, particularly with regard to features in the spectrum, is discussed. Confirmations of these spectral features are summarized. Results from the KONUS experiments on Venera 13 and 14 are reviewed. The status of models of the continuum spectrum is summarized. A number of different radiation mechanisms appear capable of fitting the data. These include thermal bremsstrahlung, thermal synchrotron and inverse Compton. Rapid variability of the spectra shape on time scales 76] 0.25 sec. was reported. The characteristic energy of the spectrum was observed to vary over nearly an order of magnitude during individual events. A strong correlation between spectral hardness and luminosity was found. Low-energy (50 keV) absorption features and high-energy (400 keV) emission features continue to appear in GRB spectra. Understanding the origin of these lines in the context of the existing continuum models remains a difficult problem.

Teegarden, B. J.↗

Corrosion fatigue of high strength fastener materials in seawater

Environmental effects which significantly reduce the fatigue life of metals are discussed. Corrosion fatigue is a major concern in the engineering application of high strength fasteners in marine environments. The corrosion fatigue failure of an AISI 41L4O high strength steel blade to hub attachment bolt at the MOD-OA 200 kW wind turbine generator was investigated. The reduction of fatigue strength of AISI 41L4O in marine environments and to obtain similar corrosion fatigue data for candidate replacement materials was studied. The AISI 4140, PH 13-8Mo stainless steel, alloy 718 and alloy MP-35N were tested in axial fatigue at a frequency of 20 Hz in dry air and natural seawater. The fatigue data are fitted by regression equations to allow determination of fatigue strength for a given number of cycles to failure.

Tipton, D. G.↗

A numerical scheme for the identification of hybrid systems describing the vibration of flexible beams with tip bodies

A cubic spline based Galerkin-like method is developed for the identification of a class of hybrid systems which describe the transverse vibration to flexible beams with attached tip bodies. The identification problem is formulated as a least squares fit to data subject to the system dynamics given by a coupled system of ordnary and partial differential equations recast as an abstract evolution equation (AEE) in an appropriate infinite dimensional Hilbert space. Projecting the AEE into spline-based subspaces leads naturally to a sequence of approximating finite dimensional identification problems. The solutions to these problems are shown to exist, are relatively easily computed, and are shown to, in some sense, converge to solutions to the original identification problem. Numerical results for a variety of examples are discussed.

Rosen, I. G.↗

Approximation methods for inverse problems involving the vibration of beams with tip bodies

Two cubic spline based approximation schemes for the estimation of structural parameters associated with the transverse vibration of flexible beams with tip appendages are outlined. The identification problem is formulated as a least squares fit to data subject to the system dynamics which are given by a hybrid system of coupled ordinary and partial differential equations. The first approximation scheme is based upon an abstract semigroup formulation of the state equation while a weak/variational form is the basis for the second. Cubic spline based subspaces together with a Rayleigh-Ritz-Galerkin approach were used to construct sequences of easily solved finite dimensional approximating identification problems. Convergence results are briefly discussed and a numerical example demonstrating the feasibility of the schemes and exhibiting their relative performance for purposes of comparison is provided.

Rosen, I. G.↗

A Galerkin method for the estimation of parameters in hybrid systems governing the vibration of flexible beams with tip bodies

An approximation scheme is developed for the identification of hybrid systems describing the transverse vibrations of flexible beams with attached tip bodies. In particular, problems involving the estimation of functional parameters are considered. The identification problem is formulated as a least squares fit to data subject to the coupled system of partial and ordinary differential equations describing the transverse displacement of the beam and the motion of the tip bodies respectively. A cubic spline-based Galerkin method applied to the state equations in weak form and the discretization of the admissible parameter space yield a sequence of approximating finite dimensional identification problems. It is shown that each of the approximating problems admits a solution and that from the resulting sequence of optimal solutions a convergent subsequence can be extracted, the limit of which is a solution to the original identification problem. The approximating identification problems can be solved using standard techniques and readily available software.

Banks, H. T.↗

The Structure and Composition of Uranus and Neptune

Uranus and Neptune form a special class of planetary objects; intermediate in mass and composition between the giant Hydrogen-rich planets, Jupiter and Saturn, and the small, rocky terrestrial planets. Their structure and composition are not only of intrinsic importance, but also should provide information as to the nature of the protoplanetary nebula and the processes of planetary formation. A detailed set of theoretical models of these planets within the framework of two and three shell models was constructed. The ratio of ice to rock (1/r) is varied. The three shell model fits the data on the two planets best.

Reynolds, R. T.↗

Accurate Albedos of the Brightest Regions on Io

The brightest, coldest areas on Io, the white regions, may act as cold traps for SO2 gas, and thus have an important role in governing the pressure, diurnal variation, and flow of the satellite's tenuous SO2 atmosphere. Therefore, it is essential to derive accurate albedos for the brightest regions, where the necessary albedos are those in the energy balance equation of the surface used to compute temperatures. Forty-one of the brightest of the white areas, each 60 to 120 km on a side were studied. The simplest way to estimate the required energy balance albedo for each region is to determine the Bond slbedo of a planet covered with that type of material. This process is outlined and resulting albedos are given. with the exception of several darker regions on the poorly-resolved post eclipse face of Io, typical albedos are 0.6 to 0.7. The brightest areas studied are located in the cluster of white regions east of Prometheus (longitudes 90 to 40 deg W). It is possible using Voyager data and fits to Hapke's equation to derive albedos for the bright regions without making any assumptions about the phase integrals.

Simonelli, D. P.↗

Generation of Surface Coordinates by Elliptic Partial Differential Equations

The problem of generating spatial coordinates by numerical methods through carefully selected mathematical models is of current interest both in mechanics and physics. The problem of generation of a desired system of coordinates in a given surface was considered, which essentially is an effort directed to the problem of grid generation in a two-dimensional non-Euclidean space. The mathematical model selected for this purpose is based on the formulae of Gauss for a surface. The proposed equations can be used to generate a new coordinate system from the data of an already given coordinate system in a surface. If the coefficients of the first and second fundamental forms have been given, then the proposed equations can be used to generate a surface satisfying the given data (surface fitting). The proposed equations can also be used to generate surfaces in the space between two arbitrary given surfaces, thus providing 3D grids in an Euclidean space.

Warsi, Z. U. A.↗

Absolute rigidity spectrum of protons and helium nuclei above 10 GV/c

Proton and helium nuclei differential spectra were gathered with a balloon borne magnet spectrometer. The data were fitted to the assumption that the differential flux can be represented by a power law in rigidity. In the rigidity range 10 to 25 GV/c the spectral indices were found to be -(2.74 plus or minus 0.04) for protons and -(2.71 plus or minus 0.05) for helium nuclei. A brief discussion is given by systematic errors.

Golden, R. L.↗

The ultraviolet dayglow at solar maximum. III - Photoelectron-excited emissions of N2 and O

Rocket observations of the far ultraviolet dayglow spectrum near solar cycle maximum are analyzed using laboratory cross sections, atmospheric composition models, and photoelectron production models. Photoelectron-excited emissions of N2 and O are used to derive a self-consistent description of the atmosphere at solar maximum. Spectral synthesis of the N2 Lyman-Birge-Hopfield bands shows a departure of a 1Pi(q) state vibrational populations from the direct excitation theory. Observations of the N2 second positive (0, 0) 3371-A band and O I 1356-A emission indicate an exospheric temperature of 1600 K, 200 K higher than predicted by empirical models. The empirical models are also found to overestimate the O and O2 densities required to fit the data by a factor of 2 and 1.4, respectively. These results are compared to the results of an analysis of similar observations made in 1978 near solar minimum.

Meier, R. R.↗

Evidence for ion heat flux in the light ion polar wind

Cold flowing hydrogen and helium ions have been observed using the retarding ion mass spectrometer on board the Dynamics Explorer 1 spacecraft in the dayside magnetosphere at subauroral latitudes. The ions show a marked flux asymmetry with respect to the relative wind direction. The observed data are fitted by a model of drifting Maxwellian distributions perturbed by a first order-Spritzer-Haerm heat flux distribution function. It is shown that both ion species are supersonic just equatorward of the auroral zone at L = 14, and the shape of asymmetry and direction of the asymmetry are consistent with the presence of an upward heat flux. At L = 6, both species evolve smoothly into warmer subsonic upward flows with downward heat fluxes. In the case of subsonic flows the downward heat flux implies a significant heat source at higher altitudes. Spin curves of the spectrometer count rate versus the spin phase angle are provided.

Biddle, A. P.↗

Meteor Wind Results at Durham (43 Deg N, 71 Deg W) During the ATMAP November 1981 and May 1982 Campaigns

Winds modeled from data measured with the University of New Hampshire Meteor Wind Radar System at Durham, New Hampshire, over the two 4-day periods November 20 to 23, 1981 and May 8 to 11, 1982 are presented. The raw meteor wind data was fit in a least square sense to a three dimensional model containing mean, 12-, 24-, and 48-h periods. The means winds for both periods are very close to the three year average values at Durham during May and November, respectively. The semidiurnal component for the November period had a normal amplitude and phase, and an estimated veritcal wavelength of 60 km. The May period results were essentially typical except that the Northward amplitude was 3 to 4 times smaller than normal. The diurnal amplitudes measured for both periods are typical for Durham and the diurnal phase is normally not very consistent. The 48-hour component amplitude is typical for these months. The intrinsic errors fo the radar are approximately + or - 2 km in position and + or - 4 m/s in radial velocity including quantization errors. These errors are random with zero mean and should not bias the wind results.

Clark, R. R.↗

Characterization of Io's volcanic activity by infrared polarimetry

The thermal emission from Io's volcanic hot spots is linearly polarized. Infrared measurements at 4.76 micrometers show disk-integrated polarization as large as 1.6 percent. The degree and position angle of linear polarization vary with Io's rotation in a manner characteristic of emission from a small number of hot spots. A model incorporating three hot spots best fits the data. The largest of these hot spots lies to the northeast of Loki Patera, as mapped from Voyager, and the other spot on the trailing hemisphere is near Ra Patera. The hot spot on the leading hemisphere corresponds to no named feature on the Voyager maps. The value determined for the index of refraction of the emitting surface is a lower bound; it is similar to that of terrestrial basalts and is somewhat less than that of sulfur.

Goguen, J. D.↗

The origin of CS in comet IRAS-Araki-Alcock 1983d

It is shown that the IUE observations of CS in the atmosphere of comet IRAS-Araki-Alcock 1983d are consistent with its formation by the photodissociation of CS2 released from the nucleus. The observed scale length can be matched by a calculated scale length, which is based on the photochemical lifetime of CS2 at 1 AU and hydrodynamic models of the velocity field in the coma. A flow velocity of about 0.6 km/s is required to fit the data, which is in excellent agreement with recent calculations of the flow regime in the inner coma.

Jackson, W. M.↗

Durability predictions of adhesively bonded composite structures using accelerated characterization methods

The utilization of adhesive bonding for composite structures is briefly assessed. The need for a method to determine damage initiation and propagation for such joints is outlined. Methods currently in use to analyze both adhesive joints and fiber reinforced plastics is mentioned and it is indicated that all methods require the input of the mechanical properties of the polymeric adhesive and composite matrix material. The mechanical properties of polymers are indicated to be viscoelastic and sensitive to environmental effects. A method to analytically characterize environmentally dependent linear and nonlinear viscoelastic properties is given. It is indicated that the methodology can be used to extrapolate short term data to long term design lifetimes. That is, the method can be used for long term durability predictions. Experimental results for near adhesive resins, polymers used as composite matrices and unidirectional composite laminates is given. The data is fitted well with the analytical durability methodology. Finally, suggestions are outlined for the development of an analytical methodology for the durability predictions of adhesively bonded composite structures.

Brinson, H. F.↗