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At least 685 records · Page 38

Scattering by nonspherical particles of size comparable to wavelength - A new semi-empirical theory and its application to tropospheric aerosols

A semiempirical theory is developed which is based on simple physical principles and comparisons with laboratory measurements. The ultimate utility of this approach rests on its ability to successfully reproduce the observed single-scattering phase function for a wide variety of particle shapes, sizes and refractive indices. This approximate theory is developed for evaluating the interaction of randomly oriented, nonspherical particles with the total intensity component of electromagnetic radiation. Mie theory is used when the particle size parameter x (ratio of particle circumference to wavelength) is less than some upper bound x sub zero (about 5). For x greater than x sub zero, the interaction is divided into three components: diffraction, external reflection and transmission. The application of the theory is illustrated by considering the influence of the shape of tropospheric aerosols on their contribution to the earth's global albedo.

Pollack, J. B.↗

NASA's Space Launch System: Systems Engineering Approach for Affordability and Mission Success

NASA is working toward the first launch of a new, unmatched capability for deep space exploration, with launch readiness planned for 2018. The initial Block 1 configuration of the Space Launch System will more than double the mass and volume to Low Earth Orbit (LEO) of any launch vehicle currently in operation - with a path to evolve to the greatest capability ever developed. The program formally began in 2011. The vehicle successfully passed Preliminary Design Review (PDR) in 2013, Key Decision Point C (KDPC) in 2014 and Critical Design Review (CDR) in October 2015 - nearly 40 years since the last CDR of a NASA human-rated rocket. Every major SLS element has completed components of test and flight hardware. Flight software has completed several development cycles. RS-25 hotfire testing at NASA Stennis Space Center (SSC) has successfully demonstrated the space shuttle-heritage engine can perform to SLS requirements and environments. The five-segment solid rocket booster design has successfully completed two full-size motor firing tests in Utah. Stage and component test facilities at Stennis and NASA Marshall Space Flight Center are nearing completion. Launch and test facilities, as well as transportation and other ground support equipment are largely complete at NASA's Kennedy, Stennis and Marshall field centers. Work is also underway on the more powerful Block 1 B variant with successful completion of the Exploration Upper Stage (EUS) PDR in January 2017. NASA's approach is to develop this heavy lift launch vehicle with limited resources by building on existing subsystem designs and existing hardware where available. The systems engineering and integration (SE&I) of existing and new designs introduces unique challenges and opportunities. The SLS approach was designed with three objectives in mind: 1) Design the vehicle around the capability of existing systems; 2) Reduce work hours for nonhardware/ software activities; 3) Increase the probability of mission success by focusing effort on more critical activities.

Hutt, John J.↗

Magnetic beneficiation of highland and hi-Ti mare soils - Rock, mineral, and glassy components

The exploitation of lunar soil can provide valuable raw materials for in situ resource utilization at a lunar base. A study of magnetic characterization was undertaken of three mare and two highland soils obtained from NASA. Beneficiation of mare and highland soils by sizing and magnetic separation can effectively concentrate the important components of the soils (e.g., ilmenite, native Fe, plagioclase, and aggluminates). As a soil matures and the impact melts consume additional minerals and rocks, the modal percentage of the minerals will decrease. The 'normative' percentage will become much greater than the modal percentage. Therefore, greater efficiency of separation can be realized with the proper selection of maturity of the soil, as well as by secondary grinding to further liberate specific minerals from lithic fragments (e.g., ilmenite and plagioclase).

Taylor, Lawrence A.↗

Agent-based modeling for multimodal transportation of CO 2 for carbon capture, utilization, and storage: CCUS-agent

Here, to understand the system-level interactions between the entities in Carbon Capture, Utilization, and Storage (CCUS), an agent-based foundational modeling tool, CCUS-Agent, is developed for a large-scale study of transportation flows and infrastructure in the United States. Key features of the tool include (i) modular design, (ii) multiple transportation modes, (iii) capabilities for extension, and (iv) testing against various system components and networks of small and large sizes. Five matching algorithms for CO 2 supply agents (e.g., powerplants and industrial facilities) and demand agents (e.g., storage and utilization sites) are explored: Most Profitable First Year (MPFY), Most Profitable All Years (MPAY), Shortest Total Distance First Year (SDFY), Shortest Total Distance All Years (SDAY), and Shortest distance to long-haul transport All Years (ACAY). Before matching, the supply agent, demand agent, and route must be available, and the connection must be profitable. A profitable connection means the supply agent portion of revenue from the 45Q tax credit must cover the supply agent costs and all transportation costs, while the demand agent revenue portion must cover all demand agent costs. A case study employing over 5500 supply and demand agents and multimodal CCUS transportation infrastructure in the contiguous United States is conducted. The results suggest that it is possible to capture over 9 billion tonnes (GT) of CO 2 from 2025 to 2043, which will increase significantly to 22 GT if the capture costs are reduced by 40 %. The MPFY and SDFY algorithms capture more CO 2 earlier in the time horizon, while the MPAY and SDAY algorithms capture more later in the time horizon.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Design and optimization of flexible decoupled high-temperature gas-cooled reactor plants with thermal energy storage

Advanced nuclear power plants are well-positioned for future zero-carbon grids, however, the need for flexible power generation will be required over the traditional emphasis on baseload generation for meeting historical demands. To achieve such flexibility, this work examines viable configurations for coupling nuclear energy production with thermal energy storage. Previous designs on nuclear-thermal energy storage configurations for advanced reactor designs, which utilized reactor steam as the heat source for charging the thermal energy storage, are restricted by the heat diversion ratio and efficiency losses, thus their impacts can be limited. In this context, this study proposes configurations for fully decoupling the nuclear reactor from the power cycle and positioning the storage as an intermediate loop, thereby achieving an unconstrained heat diversion ratio and improved efficiency. Compared with a standard high-temperature gas-cooled reactor’s power cycle, steady-state thermodynamic modeling and dispatch optimizations quantify the benefits of a steam reheat cycle within the fully decoupled thermal energy system to separate the plant cycle from the high-pressure primary side. These benefits are further detailed, compatible with required high-temperature and high-pressure conditions, through (1) open-source dynamic transient models that examine the impact of off-design operation on the systems, (2) the investigation of components design and costing and finally (3) sizing and dispatch optimization. The fully-decoupled design achieves a cycle efficiency of 43.1%, an enhancement over the vendor’s standard efficiency of 42.2% (Xe-100 design). Here, the proposed design offers strengthened physical barriers from the nuclear island as well as superior operational flexibility and power boosting. Dispatch optimization and market analysis reveal that thermal energy storage size is highly dependent on the peak patterns of electricity prices and the minimum generation level constraint imposed on the balance of plant. Evaluation of off-design operation demonstrates that the full decoupling design with the suggested fail-safe control mechanisms ensures a minimal impact on reactor parameters, even during rapid power ramping.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Interface-modulated kinetic differentials in electron and hole transfer rates as a key design principle for redox photocatalysis by Sb2VO5/QD heterostructures

The efficient conversion of solar energy to chemical energy represents a critical bottleneck to the energy transition. Photocatalytic splitting of water to generate solar fuels is a promising solution. Semiconductor quantum dots (QDs) are prime candidates for light-harvesting components of photocatalytic heterostructures, given their size-dependent photophysical properties and band-edge energies. A promising series of heterostructured photocatalysts interface QDs with transition-metal oxides which embed midgap electronic states derived from the stereochemically active electron lone pairs of p-block cations. Here, we examine the thermodynamic driving forces and dynamics of charge separation in Sb2VO5/CdSe QD heterostructures, wherein a high density of Sb 5s2-derived midgap states are prospective acceptors for photogenerated holes. Hard-x-ray valence band photoemission spectroscopy measurements of Sb2VO5/CdSe QD heterostructures were used to deduce thermodynamic driving forces for charge separation. Interfacial charge transfer dynamics in the heterostructures were examined as a function of the mode of interfacial connectivity, contrasting heterostructures with direct interfaces assembled by successive ion layer adsorption and reaction (SILAR) and interfaces comprising molecular bridges assembled by linker-assisted assembly (LAA). Transient absorption spectroscopy measurements indicate ultrafast (<2 ps) electron and hole transfer in SILAR-derived heterostructures, whereas LAA-derived heterostructures show orders of magnitude differentials in the kinetics of hole (<100 ps) and electron (∼1 ns) transfer. The interface-modulated kinetic differentials in electron and hole transfer rates underpin the more effective charge separation, reduced charge recombination, and greater photocatalytic efficiency observed for the LAA-derived Sb2VO5/CdSe QD heterostructures.

Chemistry↗

Controlling the size of non-axisymmetric magnetic footprints using resonant magnetic perturbations

The structure of the non-axisymmetric heat load distribution at the divertor plates is determined not only by the toroidal but also from the poloidal spectrum of non-axisymmetric field perturbations. Whether they are intrinsic, like error fields, or they are applied through 3D coils, the non-axisymmetric fields produce complex 3D edge magnetic topologies (footprints) that alter the properties of the heat and particle flux distributions on the divertor target plates. In this manuscript, a study of the impact of applied 3D field poloidal spectrum on the footprint size and structure is done for the DIII-D tokamak using the resistive MHD code M3D-C1 coupled with the field line tracing code TRIP3D. To resolve the impact of the poloidal spectrum of the magnetic perturbation, the relative phase of the two rows of in-vessel 3D coils used to produce both a n = 2 and a n = 3 perturbation is varied, where n is the toroidal harmonic of the magnetic perturbation. This shows that the largest footprint is predicted when the relative phase of the two rows is close to zero, which is also where the resonant coupling with the plasma is maximized. These results suggest that it will be challenging to decouple the footprint size from the requisite resonant coupling for RMP–ELM control. The correlation between the measured heat load and particle flux distributions at the outer divertor plates in DIII-D and the magnetic measurements is in good agreement with the predicted dependence of the magnetic footprint size on the amplitude of the resonant component of the plasma response.

3D fields↗

Impact of Additive Manufacturing on Internal Cooling Channels With Varying Diameters and Build Directions

Abstract The use of additive manufacturing (AM) processes, such as direct metal laser sintering, provides the design freedom required to incorporate complex cooling schemes in gas turbine components. Additively manufactured turbine components have a range of cooling feature sizes and, because of the inherent three-dimensionality, a wide range of build angles. Previous studies have shown that AM built directions influence internal channel surface roughness that, in turn, augment heat transfer and pressure loss. This study investigates the impact of AM on channel feature size and builds direction relative to tolerance, surface roughness, pressure losses, and convective cooling. Multiple AM coupons were built from Inconel 718 consisting of channels with different diameters and a variety of build directions. An experimental rig was used to measure pressure drop to calculate friction factor and was used to impose a constant surface temperature boundary condition to collect Nusselt number over a range of Reynolds numbers. Significant variations in surface roughness and geometric deviations from the design intent were observed for distinct build directions and channel sizes. These differences led to notable impacts in friction factor and Nusselt number augmentations, which were a strong function of build angle.

Engineering↗

Optimal dimensionality selection for independent component analysis of transcriptomic data

Independent component analysis is an unsupervised machine learning algorithm that separates a set of mixed signals into a set of statistically independent source signals. Applied to high-quality gene expression datasets, independent component analysis effectively reveals both the source signals of the transcriptome as co-regulated gene sets, and the activity levels of the underlying regulators across diverse experimental conditions. Two major variables that affect the final gene sets are the diversity of the expression profiles contained in the underlying data, and the user-defined number of independent components, or dimensionality, to compute. Availability of high-quality transcriptomic datasets has grown exponentially as high-throughput technologies have advanced; however, optimal dimensionality selection remains an open question. We computed independent components across a range of dimensionalities for four gene expression datasets with varying dimensions (both in terms of number of genes and number of samples). We computed the correlation between independent components across different dimensionalities to understand how the overall structure evolves as the number of user-defined components increases. We then measured how well the resulting gene clusters reflected known regulatory mechanisms, and developed a set of metrics to assess the accuracy of the decomposition at a given dimension. We found that over-decomposition results in many independent components dominated by a single gene, whereas under-decomposition results in independent components that poorly capture the known regulatory structure. From these results, we developed a new method, called OptICA, for finding the optimal dimensionality that controls for both over- and under-decomposition. Specifically, OptICA selects the highest dimension that produces a low number of components that are dominated by a single gene. We show that OptICA outperforms two previously proposed methods for selecting the number of independent components across four transcriptomic databases of varying sizes. OptICA avoids both over-decomposition and under-decomposition of transcriptomic datasets resulting in the best representation of the organism’s underlying transcriptional regulatory network.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Investigating the contribution of grown new particles to cloud condensation nuclei with largely varying preexisting particles – Part 1: Observational data analysis

This study employed multiple techniques to investigate the contribution of grown new particles to the number concentration of cloud condensation nuclei (CCN) at various supersaturation (SS) levels at a rural mountain site in the North China Plain from 29 June to 14 July 2019. On 8 new particle formation (NPF) days, the total particle number concentrations (N cn ) were 8.4 ± 6.1×10 3 cm -3 , which was substantially higher compared to 4.7 ± 2.6×10 3 cm -3 on non-NPF days. However, the CCN concentration (Nccn) at 0.2 % SS and 0.4 % SS on the NPF days was significantly lower than those observed on non-NPF days (p<0.05). This was due to the lower cloud activation efficiency of preexisting particles resulting from organic vapor condensation and smaller number concentrations of preexisting particles on NPF days. A case-by-case examination showed that the grown new particles only yielded a detectable contribution to N ccn at 0.4 % SS and 1.0 % SS during the NPF event on 1 July 2019, accounting for 12 % ± 11 % and 23 % ± 12 % of N ccn , respectively. The increased N ccn during two other NPF events and at 0.2 % SS on 1 July 2019 were detectable but determined mainly by varying preexisting particles rather than grown new particles. In addition, the hygroscopicity parameter values, concentrations of inorganic and organic particulate components, and surface chemical composition of different sized particles were analyzed in terms of chemical drivers to grow new particles. The results showed that the grown new particles via organic vapor condensation generally had no detectable contribution to N ccn but incidentally did. However, this conclusion was drawn from a small size of observational data, leaving more observations, particularly long-term observations and the growth of preexisting particles to the CCN required size, needed for further investigation.

54 ENVIRONMENTAL SCIENCES↗

Experimental Observations for Anode Optimization of Oxide Reduction Equipment

The electrochemical behavior of several components has been investigated during the electrolysis of nickel oxide in LiCl-Li 2 O salt mixture at 650°C. The focus of this work is to improve anode design and shroud to increase current densities. The tested components were ceramic anode shroud porosity, porosity size, anode geometry, anode material, and metallic porous anode shroud. The goal of these experiments was to optimize and improve the reduction process. The highest contributors to higher current densities were anode shroud porosity and anode geometry.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Rapid scanning with the Fabry-Perot etalon.

Rapid scanning Fabry-Perot spectrometers, considering time resolution, wavelength resolution, wavelength interval size, aperture diameter and limitations of mechanical components

Cooper, J.↗

Jupiter's Red Spot in 1967-68

Jupiter Red Spot observed photographically in 1967-1968, correlating activity in southern component of South Equatorial Belt to spot size

Solberg, H. G., Jr.↗

Brayton heat exchange unit development program

A Brayton Heat Exchanger Unit (BHXU), consisting of a recuperator, a heat sink heat exchanger and a gas ducting system, was designed, fabricated, and tested. The design was formulated to provide a high performance unit suitable for use in a long-life Brayton-cycle powerplant. A parametric analysis and design study was performed to establish the optimum component configurations to achieve low weight and size and high reliability, while meeting the requirements of high effectiveness and low pressure drop. Layout studies and detailed mechanical and structural design were performed to obtain a flight-type packaging arrangement. Evaluation testing was conducted from which it is estimated that near-design performance can be expected with the use of He-Xe as the working fluid.

Morse, C. J.↗

Brayton heat exchanger unit development program (alternate design)

A Brayton Heat Exchanger Unit Alternate Design (BHXU-Alternate) consisting of a recuperator, a heat sink heat exchanger, and a gas ducting system, was designed and fabricated. The design was formulated to provide a high performance unit suitable for use in a long-life Brayton-cycle powerplant. Emphasis was on double containment against external leakage and leakage of the organic coolant into the gas stream. A parametric analysis and design study was performed to establish the optimum component configurations to achieve low weight and size and high reliability, while meeting the requirements of high effectiveness and low pressure drop. Layout studies and detailed mechanical and structural design were performed to obtain a flight-type packaging arrangement, including the close-coupled integration of the BHXU-Alternate with the Brayton Rotating Unit (BRU).

Duncan, J. D.↗

Numerical simulation of turbulence in the presence of shear

The numerical calculations are presented of the large eddy structure of turbulent flows, by use of the averaged Navier-Stokes equations, where averages are taken over spatial regions small compared to the size of the computational grid. The subgrid components of motion are modeled by a local eddy-viscosity model. A new finite-difference scheme is proposed to represent the nonlinear average advective term which has fourth-order accuracy. This scheme exhibits several advantages over existing schemes with regard to the following: (1) the scheme is compact as it extends only one point away in each direction from the point to which it is applied; (2) it gives better resolution for high wave-number waves in the solution of Poisson equation, and (3) it reduces programming complexity and computation time. Examples worked out in detail are the decay of isotropic turbulence, homogeneous turbulent shear flow, and homogeneous turbulent shear flow with system rotation.

Shaanan, S.↗

Liquid drop technique for generation of organic glass and metal shells

It was found that liquid drop techniques are very useful in several diverse areas. For producing very uniform metallic, organic, inorganic and, on particular, glassy shells, the liquid jet method is the most reproducible and exceptionally useful of all the techniques studied. The technique of capillary wave synchronization of the break-up of single and multiple component jets was utilized to produce uniform sized liquid drops and solid particles, and hollow liquid and solid shells. The technique was also used to encapsulate a number of liquids in impermeable spherical shells. Highly uniform glass shells were made by generating uniform drops of glass forming materials in an aqueous solution, subsequently evaporating the water, and then fusing and blowing the remaining solids in a high temperature vertical tube furnace. Experimental results are presented and the critical problems in further research in this field are discussed.

Hendricks, C. D.↗