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It is established that the nucleonic intensity recorded at the polar stations Thule and McMurdo decreases as the streams associated with co-rotating interaction regions (CIR) overtake the earth. The modulation, however, is limited to only those CIR-streams in which a neutral sheet is imbedded. In contrast to this, all CIR-streams produce geomagnetic storms.
The MAPS experiment was designed to remotely measure the mixing ratio of carbon monoxide in the middle and upper troposphere using a gas filter radiometer as the sensing instrument. The asymmetrical worldwide distribution of CO is discussed as background, and the experimental scientific and technical objectives are briefly stated. The gas filter radiometer is described in detail, and the second Shuttle mission is summarized. Auxiliary and correlative data were obtained in order to evaluate the performance of the measurement system, to assess the effect of stratospheric ozone on the radiometer signals, and to determine the effect of the underlying surface. The experiment acquired about 32 hours of data between 38 deg N and 38 deg S, signal-to-noise ratios were as predicted and the instrument achieved satisfactory stability in spite of large temperature variations. Data reduction is in progress.
A series of four instrument test flights was conducted during July 1981 in preparation for the NASA Global Tropospheric Experiment. The purpose of the flights was to demonstrate the feasibility and value of simultaneously measuring several specific atmospheric pollutants over a 25 deg latitudinal range. Carbon monoxide and methane grab samples were obtained simultaneously with nearly continuous in situ ozone and remote ozone and aerosol optical radar measurements. The sampling platform was a NASA Electra, a four engine turboprop aircraft. Attention is given to CO and CH4 sample collection and analysis, ozone measurement methods, the aerosol measurement method, an interpretation of the optical radar display, and a synergistic consideration of results.
Ab initio infrared intensities and dipole moment derivatives expressed in atomic polar tensor form are calculated using the 4-31 and 6-31G(double asterisk) basis sets for the isoelectronic HCN, HNC, CO, HCO(+), and HOC(+) series of molecules. The calculated atomic polar tensors are analyzed in terms of the charge-charge flux-overlap model, which is found to be useful in explaining some of the trends observed in the dipole moment derivatives for this series of molecules. A detailed examination of the dipole moment derivatives for the structural isomers indicates some of the ways in which experimental atomic polar tensors for one isomer should be modified to predict infrared intensities for the other isomer. The absolute intensities calculated for the HCO(+) and HOC(+) ions are believed to be accurate to within a factor of 2 and thus should be useful in astrophysical applications.
The motions of co-orbiting satellites is examined with reference to a free flying satellite requiring periodic servicing and an orbiting service base. The problems of differential orbit decay and nodal regression are emphasized.
The first observations of the J = 16 to J = 15, 162.8 microns transition of CO from an astronomical source are reported. Measurements were carried out on the Kleinmann-Low Nebula. The intensity observed is in good agreement with predictions from previous spectroscopic work carried out in the far infrared. The observation strengthens the previous claim that approximately 1.5 solar mass of molecular hydrogen is heated to a temperature above 750 K within the shocked region in the Nebula. Upper limits to he OH intensity in the F2 (2Pi 1/2) transitions J = 3/2 to J = 1/2 which fall into two groups centered respectively at 163.12 and 163.40 are presented.
An examination of animal response to CO is studied along with potential models for extrapolating animal test data to humans. The best models for extrapolating data were found to be the Probit and Weibull models.
CO Lacertae is one of the very few known binaries with both a short period of apsidal motion and good M, L, R data. The new U, B, V light curves presented here provide two times of minima and a check on Semeniuk's value for P(aps). This is the first published example of an eclipsing binary analyzed in terms of a physical model (as opposed to a model based on spherical or ellipsoidal star figures) which allows for eccentric orbit effects. The light curves show some peculiarities - particularly a large, probably intrinsic, scatter.
Clean surfaces of (111)-type Pd layers, grown from the vapor phase on Mo(110) at room temperature, were used to study the adsorption of CO and H2 by temperature-programmed desorption, Auger electron spectroscopy, and low-energy electron diffraction. Mild annealing of the as-grown layers during a single desorption cycle (to about 600 K) drastically reduces the adsorption for both adsorbates. Low-dose argon-ion bombardment introduces surface imperfections which restore a high adsorption probability. The results are interpreted in terms of particular (111)-type surface structures that persist tp layer thicknesses of about four monolayers; the results raise questions with respect to the surface structure of supported thin epitaxial islands and particles of Pd and possibly also with respect to conventional methods of preparing bulk surfaces of Pd for adsorption studies.
The largest fraction of the matter returned by stars to the interstellar medium is probably provided by red giants. The carbon star IRC +10216 is an example of an evolved giant with a large mass loss rate. One plausible mechanism for the acceleration of the gas in stars like IRC +10216 is radiation pressure on dust grains which then collide with and transfer their momentum to the gas. However, at the present time neither infrared nor microwave observations provide a clear picture of the distribution of matter near cool red giant stars. There exists one method which may be used to obtain more information about the distribution of matter very close to the star. This method involves the measurement of the spatial extent of near-infrared lines by employing a combination of very high spatial and high spectral resolution. The present investigation is concerned with an application of this method. Speckle interferometry is used to measure the radial distribution of CO molecules on angular scales of 1 sec near IRC +10216.
Differential thermal analysis (DTA) and Thermogravimetric analysis (TGA) were used to study the chlorination of alpha-Al2O3, gamma-Al2O3 and amorphous SiO2 in a Cl + CO stream, for the preparation of AlCl3 and SiCl4. The chlorination starting temperatures were 235 deg for Al2O3 and 680 deg for SiO2. The chlorination of alpha- and gamma-Al2O3 takes place via the formation of AlOCl as an intermediate product, and its subsequent dissociation at 480 to 560 deg, according to 3AlOCl yields AlCl3 + Al2O3. The chlorination activation energies are given for the three oxides.
An ongoing research program aims to characterize the solidification of several Ni- and Co-based commercial wrought type alloys. The techniques used and the data items sought are: (1) thermal analysis, liquidus, nonequilibrium solidus as a function of cooling rate, secondary reactions temperatures, incipient melting, progress of solidification as a function of temperature; (2) optical metallography, characteristic structures and secondary dendrite arm spacing as a function of cooling rate; (3) X-ray diffraction, identification of precipitates; and (4) SEM/EDAX, measure of microsegregation.
Measurements for Washington, DC and Boulder, CO are combined to provide a time series of midlatitude stratospheric water vapor data for the period 1964-82. The mean concentration for the data period is shown to be nearly constant with altitude for the low stratospheric layer between 16-22 km with a mass mixing ratio for the layer of 2.5-2.6 ppmm. Above 22 km the mixing ratio increases slightly with altitude. Evident in the 60 mb level time series is an annual cycle, a quasi-biennial cycle and a long-term nonlinear trend. The quasi-biennial cycle in water vapor at midlatitudes is consistent with variations in tropical stratosphere zonal winds and temperature and total ozone and suggests a modulation of the Hadley cell circulation. The long-term trend shows mixing ratio increasing during the 1960s and decreasing in the 1970s after 1972.
Observations of the 691-GHz (J = 6-5) transition of CO in the BN/KL region of Orion obtained in February 1981, at the IR Telescope Facility at Mauna Kea are reported. The system employs a heterodyne receiver with an overall noise temperature of 3900 K DSB at 432 microns, 64 5-MHz IF-filter-bank channels, and a chopping secondary with 120-arcsec excursion, and has 35-arcsec resolution. Sample data are presented graphically and analyzed using a rate equation and a kinetic model. A 35 x 45-arcsec core with hot broad plateau emission (antenna temperature 180 + or - 36 K) surrounded by an area of strong narrow-line 120-K emission is found. It is suggested that the plateau emission originates in a wide thin sheet after a shock wave, with H2 density at least 10 to the 6th/cu cm and gas kinetic temperature greater than 500 K.
A description is presented of coherent Raman spectroscopic studies of N2, CO, and NO molecules. It is pointed out that the Q-branch Raman spectra of these simple diatomics are characterized by lines which overlap with increasing pressure as a result of collisional line broadening. Attention is given to Q-branch vibrational spectra and their determination, the spectral line shape of isolated lines, the line overlap regime, fitting laws, and the isotropic Raman spectrum of NO. It is found that the room temperature spectra of the considered molecules at low pressure (approximately 0.2 atm) may be treated as a sum of isolated lines. It is possible to extract J-dependent pressure-broadening coefficients. With increasing pressure, collisional narrowing occurs and the description of the spectrum must include the effects of interference among neighboring lines.
The giant H II region W33 is a strong radio continuum source. However, it has received little attention compared to the nearby M17 region. The present investigation is concerned with the results of 1 min resolution far-infrared (far-IR) and CO observations of the W33 region. The complex has been resolved into several components at the far-IR wavelengths, and information has been obtained regarding spectral characteristics in the range from 20 to 250 microns. An examination is conducted of the nature of the individual W33 sources and their relationship to the radio sources and the molecular clouds. Particular attention is given to the nature of the unusual source W33 A which has a very high ratio of far-IR to radio luminosity.
It is now well established that molecular clouds are an important part of the interstellar medium, containing much or most of the dense, cold component of the gas, and producing the massive stars and supernovae responsible for the diffuse, hot component. It would therefore appear essential in formulating a complete picture of the local interstellar medium to have some knowledge of the distribution and properties of nearly molecular clouds. The Goddard-Columbia 1.2 meter telescope was used to carry out a wide latitude, low angular resolution survey of CO along most of the first galactic quadrant and a small part of the second. A plane-of-the-sky map, which resulted from numerically integrating the survey over radial velocity, is presented. The Great Rift and the Aquila Rift molecular clouds of the Milky Way are discussed.
A sample of 14 low-mass premain-sequence stars were studied in the far-infrared. There is evidence for outflowing material around twelve of these stars; in most cases the evidence includes broad wings on the profiles of the CO J=2 to 1 line. Ten of the objects were detected ( 5 sigma) at 100 micro, and seven were mapped at 50 and 100 micro. The far-infrared emission makes a significant contribution to the total luminosity of the objects. It is found that the force available from radiation pressure is not sufficient to drive the outflows. Any process which taps the same energy source as does the present stellar luminosity must have high efficiency.