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At least 685 records · Page 38

Redox Biochemistry of Energy Conservation in Methanogens and their Syntrophic Partners

The primary objective of this project was to uncover previously unknown modes by which living organisms harvested energy. Specifically, it queried microbial systems, which were once thought to not be able to utilize oxygen. Through the use of cutting-edge approaches, we were able to identify novel mechanistic processes that allow organisms to thrive under varying environmental conditions. This constitutes a paradigm shift in the field. Our work has opened new vistas for expanding the horizons of energy conservation in biological systems, as well as shed light on green energy innovations.

59 BASIC BIOLOGICAL SCIENCES↗

Post-Closure Report for Closed Resource Conservation and Recovery Act Corrective Action Units, Nevada National Security Site, Nevada, For Calendar Year 2019, Revision 0

This report serves as the combined annual report for post-closure activities in compliance with the requirements listed in Resource Conservation and Recovery Act Permit Number NEV HW0101 associated with the following closed corrective action units (CAUs): • CAU 90, Area 2 Bitcutter Containment • CAU 91, Area 3 U-3fi Injection Well • CAU 92, Area 6 Decon Pond Facility • CAU 110, Area 3 WMD U-3ax/bl Crater • CAU 111, Area 5 WMD Retired Mixed Waste Pits • CAU 112, Area 23 Hazardous Waste Trenches

54 ENVIRONMENTAL SCIENCES↗

Adaptive QM/MM for Molecular Dynamics Simulations: 5. On the Energy-Conserved Permuted Adaptive-Partitioning Schemes

In combined quantum-mechanical/molecular-mechanical (QM/MM) dynamics simulations, the adaptive-partitioning (AP) schemes reclassify atoms on-the-fly as QM or MM in a smooth manner. This yields a mobile QM subsystem with contents that are continuously updated as needed. Here, we tailor the Hamiltonian adaptive many-body correction (HAMBC) proposed by Boreboom et al. [J. Chem. Theory Comput. 2016, 12, 3441] to the permuted AP (PAP) scheme. The treatments lead to the HAMBC-PAP method (HPAP), which both conserves energy and produces accurate solvation structures in the test of “water-in-water” model system.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Conservation of Pax gene expression in ectodermal placodes of the lamprey

Ectodermal placodes contribute to the cranial ganglia and sense organs of the head and, together with neural crest cells, represent defining features of the vertebrate embryo. The identity of different placodes appears to be specified in part by the expression of different Pax genes, with Pax-3/7 class genes being expressed in the trigeminal placode of mice, chick, frogs and fish, and Pax-2/5/8 class genes expressed in the otic placode. Here, we present the cloning and expression pattern of lamprey Pax-7 and Pax-2, which mark the trigeminal and otic placodes, respectively, as well as other structures characteristic of vertebrate Pax genes. These results suggest conservation of Pax genes and placodal structures in basal and derived vertebrates.

NASA Discipline Evolutionary Biology↗

Direct Observation of Momentum Conservation at the Au/Si Interface Using BEEM (abstract)

The verification of parallel momentum conservation at a metal/semiconductor interface is a fundamental issue in interface transport. Ballistic-electron-microscopy (BEEM) is a recently developed method for probing interfaces with nanometer resolution. In this talk, BEEM spectroscopy on Au/Si(111) structures as a function of Au thickness and temperature will be described.

metal/semiconductor interface ballistic-electron-e↗

Assessing Ecosystem Service Provision Under Climate Change to Support Conservation and Development Planning in Myanmar

Inclusion of ecosystem services (ES) information into national-scale development and climate adaptation planning has yet to become common practice, despite demand from decision makers. Identifying where ES originate and to whom the benefits flowunder current and future climate conditionsis especially critical in rapidly developing countries, where the risk of ES loss is high. Here, using Myanmar as a case study, we assess where and how ecosystems provide key benefits to the countrys people and infrastructure. We model the supply of and demand for sediment retention, dry-season baseflows, flood risk reduction and coastal storm protection from multiple beneficiaries. We find that locations currently providing the greatest amount of services are likely to remain important under the range of climate conditions considered, demonstrating their importance in planning for climate resilience. Overlap between priority areas for ES provision and biodiversity conservation is higher than expected by chance overall, but the areas important for multiple ES are underrepresented in currently designated protected areas and Key Biodiversity Areas. Our results are contributing to development planning in Myanmar, and our approach could be extended to other contexts where there is demand for national-scale natural capital information to shape development plans and policies

Climate change↗

Perceptions of Climate Risk and Use of Climate Risk Information by Natural Resource Conservation Stakeholders Participating in ADVANCE Projects in Asia and Latin America

Integrating climate risk information into resilience-building activities in the field is important to ensure that adaptation is based on the best available science. Despite this, many challenges exist when developing, communicating, and incorporating climate risk information. There are limited resources on how stakeholders perceive risks, use risk information, and what barriers exist to limit knowledge integration. This paper seeks to define the following: 1) What do conservation stakeholders consider to be the most significant climate risks they face now and possibly in the future? 2) What have been the most significant barriers to their using climate risk information? 3) What sources and types of knowledge would be most useful for these managers to overcome these barriers? A survey was conducted among stakeholders (n = 224) associated with World Wildlife Fund projects in tropical and subtropical countries. A very high proportion of stakeholders used climate risk information and yet faced integration-related challenges, which included too much uncertainty and the lack of a relevant scale for planning. The main factors preventing the use of climate risk information in decision-making were unavailability of climate risk information, no or limited financial or human resources available to respond, lack of organizational mandate or support, and no or limited institutional incentives. Comparing perceived current and future risks revealed a decline in concern for some future climate hazards. Survey respondents identified scientific reports, climate scientists, and online sources as the most useful information sources of climate risk information, while (i) maps and illustrations; (ii) scenarios format; and (iii) data tables, graphs, and charts were identified as user-friendly formats.

Climate risk↗

Predicting Patterns of Solar Energy Buildout to Identify Opportunities for Biodiversity Conservation

The construction of solar energy facilities can have positive or negative impacts on biodiversity depending on siting and associated land use transitions. We identified drivers of solar siting and quantified patterns of buildout in states surrounding the Chesapeake Bay watershed – a biodiversity hotspot with numerous ecosystem services. Using a convolutional neural network, we mapped the footprints of ground-mounted solar arrays present in satellite imagery annually from 2017 to 2021 in Delaware, Maryland, Pennsylvania, New York, Virginia, and West Virginia. As of 2021, we identified 958 solar arrays covering 52.3 km2 built primarily on previously cultivated land, while avoiding natural landcover. We fit a binomial-Weibull model to these solar timeseries data in a hierarchical, Bayesian framework to quantify the relationship between geospatial covariates and rate of solar development. Solar array construction rate increased in cultivated areas, areas of lower agricultural suitability, lower slope, lower forest cover, lower biodiversity protection, and greater distances from roads. We also estimated changes in the rate of solar construction over time and found differences among states: acceleration in Virginia and deceleration in New York. We used parameter estimates to map the relative likelihood of future solar development across the study area. This methodology can be used to anticipate where solar is likely to be built in different landscapes and how these patterns align with conservation goals. Around the Chesapeake Bay watershed, the selection of lower quality agricultural areas for solar energy minimizes removal of important habitat and provides opportunities for native plant and pollinator restoration.

Artificial Intelligence↗

Conservation Voltage Reduction with Distributed Energy Resource Management System, Grid-Edge, and Legacy Devices

Distribution utilities use conservation voltage reduction (CVR) to obtain energy savings and lower peak demand by reducing bus voltages. Traditionally, the CVR is accomplished by controlling the legacy assets such as load tap changers, voltage regulators, and capacitor banks. The deployment of the advanced distribution management system (ADMS) and distributed energy resource management system (DERMS) enables the integration of distributed energy resources into the distribution networks and provide the grid services including CVR. This paper studies the coordinated operation of an ADMS and a DERMS in achieving CVR and voltage regulation. A commercial ADMS uses legacy devices and Edge-of-Network Grid Optimization (ENGO) devices to obtain energy savings through CVR. A prototype DERMS dispatches the photovoltaic smart inverters based on real-time optimal power low to ensure voltage regulation across the feeder. The results show that the coordinated operation of ADMS and DERMS is effective in achieving CVR and voltage regulation. Specifically, energy savings of up to 4.7% are observed in the real utility distribution system used in this study.

advanced distribution management system↗

Conservation Voltage Reduction with Distributed Energy Resource Management System, Grid-Edge, and Legacy Devices

Distribution utilities use conservation voltage reduction (CVR) to obtain energy savings and lower peak demand by reducing bus voltages. Traditionally, the CVR is accomplished by controlling the legacy assets such as load tap changers, voltage regulators, and capacitor banks. The deployment of the advanced distribution management system (ADMS) and distributed energy resource management system (DERMS) enables the integration of distributed energy resources into the distribution networks and provide the grid services including CVR. This paper studies the coordinated operation of an ADMS and a DERMS in achieving CVR and voltage regulation. A commercial ADMS uses legacy devices and Edge-of-Network Grid Optimization (ENGO) devices to obtain energy savings through CVR. A prototype DERMS dispatches the photovoltaic smart inverters based on real-time optimal power low to ensure voltage regulation across the feeder. The results show that the coordinated operation of ADMS and DERMS is effective in achieving CVR and voltage regulation. Specifically, energy savings of up to 4.7% are observed in the real utility distribution system used in this study.

advanced distribution management system↗

Conservation planning for freshwater–marine carryover effects on Chinook salmon survival

Experiences of migratory species in one habitat may affect their survival in the next habitat, in what is known as carryover effects. These effects are especially relevant for understanding how freshwater experience affects survival in anadromous fishes. Here, we study the carryover effects of juvenile salmon passage through a hydropower system (Snake and Columbia rivers, northwestern United States). To reduce the direct effect of hydrosystem passage on juveniles, some fishes are transported through the hydrosystem in barges, while the others are allowed to migrate in-river. Although hydrosystem survival of transported fishes is greater than that of their run-of-river counterparts, their relative juvenile-to-adult survival (hereafter survival) can be less. We tested for carryover effects using generalized linear mixed effects models of survival with over 1 million tagged Chinook salmon, Oncorhynchus tshawytscha (Walbaum) (Salmonidae), migrating in 1999–2013. Carryover effects were identified with rear-type (wild vs. hatchery), passage-type (run-of-river vs. transported), and freshwater and marine covariates. Importantly, the Pacific Decadal Oscillation (PDO) index characterizing cool/warm (i.e., productive/nonproductive) ocean phases had a strong influence on the relative survival of rear- and passage-types. Specifically, transportation benefited wild Chinook salmon more in cool PDO years, while hatchery counterparts benefited more in warm PDO years. Transportation was detrimental for wild Chinook salmon migrating early in the season, but beneficial for later season migrants. Hatchery counterparts benefited from transportation throughout the season. Altogether, wild fish could benefit from transportation approximately 2 weeks earlier during cool PDO years, with still a benefit to hatchery counterparts. Furthermore, we found some support for hypotheses related to higher survival with increased river flow, high predation in the estuary and plume areas, and faster migration and development-related increased survival with temperature. Thus, pre- and within-season information on local- and broad-scale conditions across habitats can be useful for planning and implementing real-time conservation programs.

54 ENVIRONMENTAL SCIENCES↗

A mass conservative well-balanced reconstruction at wet/dry interfaces for the Godunov-type shallow water model

This paper presents a novel mass conservative, positivity preserving wetting and drying treatment for Godunov-type shallow water models with second-order bed elevation discretization. The novel method allows to compute water depths equal to machine accuracy without any restrictions on the time step or any threshold that defines whether the finite volume cell is considered to be wet or dry. The resulting scheme is second-order accurate in space and keeps the C-property condition at fully flooded area and also at the wet/dry interface. For the time integration, a second-order accurate Runge–Kutta method is used. The method is tested in two well-known computational benchmarks for which an analytical solution can be derived, a C-property benchmark and in an additional example where the experimental results are reproduced. Overall, the presented scheme shows very good agreement with the reference solutions. The method can also be used in the discontinuous Galerkin method.

47 OTHER INSTRUMENTATION↗

Conservative solute transport processes and associated transient storage mechanisms: Comparing streams with contrasting channel morphologies, land use and land cover

Abstract Land use within a watershed impacts stream channel morphology and hydrology and, therefore, in‐stream solute transport processes and associated transient storage mechanisms. This study evaluated transport processes in two contrasting stream sites where channel morphology was influenced by the surrounding land use, land cover, climate and geologic controls: Como Creek, CO, a relatively undisturbed, high gradient, forested stream with a gravel bed and complex channel morphology, and Clear Creek, IA, an incised, low‐gradient stream with low‐permeability substrate draining an agricultural landscape. We performed conservative stream tracer injections at these sites to address the following questions: (1) How does solute transport vary between streams with differing morphologies? and (2) How does solute transport at each stream site change as a function of discharge? We analysed in‐stream tracer time series data and compared results quantifying solute attenuation in surface and subsurface transient storage zones. Significant trends were observed in these metrics with varying discharge conditions at the forested site but not at the agricultural site. There was a broad range of transport mechanisms and evidence of substantial exchange with both surface and hyporheic transient storage in the relatively undisturbed, forested stream. Changing discharge conditions activated or deactivated different solute transport mechanisms in the forested site and greatly impacted advective travel time. Conversely in the simplified agricultural stream, there was a narrow range of solute transport behaviour across flows and predominantly surface transient storage at all measured discharge conditions. These results demonstrate how channel simplification inhibits available solute transport mechanisms across varying discharge conditions.

54 ENVIRONMENTAL SCIENCES↗

An evolutionarily conserved tryptophan cage promotes folding of the extended RNA recognition motif in the hnRNPR ‐like protein family

Abstract The heterogeneous nuclear ribonucleoprotein (hnRNP) R‐like family is a class of RNA binding proteins in the hnRNP superfamily with diverse functions in RNA processing. Here, we present the 1.90 Å X‐ray crystal structure and solution NMR studies of the first RNA recognition motif (RRM) of human hnRNPR. We find that this domain adopts an extended RRM (eRRM1) featuring a canonical RRM with a structured N‐terminal extension (N ext ) motif that docks against the RRM and extends the β‐sheet surface. The adjoining loop is structured and forms a tryptophan cage motif to position the N ext motif for docking to the RRM. Combining mutagenesis, solution NMR spectroscopy, and thermal denaturation studies, we evaluate the importance of residues in the N ext –RRM interface and adjoining loop on eRRM folding and conformational dynamics. We find that these sites are essential for protein solubility, conformational ordering, and thermal stability. Consistent with their importance, mutations in the N ext –RRM interface and loop are associated with several cancers in a survey of somatic mutations in cancer studies. Sequence and structure comparison of the human hnRNPR eRRM1 to experimentally verified and predicted hnRNPR‐like proteins reveals conserved features in the eRRM.

Biochemistry & Molecular Biology↗

Cross-Correlators of Conserved Charges in QCD

We present cross-correlators of QCD conserved charges at µ B = 0 from lattice simulations and perform a Hadron Resonance Gas (HRG) model analysis to break down the hadronic contributions to these correlators. We construct a suitable hadronic proxy for the ratio –χ$^{BS}_{11}$ /χ$^{S}_{2}$ and discuss the dependence on the chemical potential and experimental cuts. Furthermore, we then perform a comparison to preliminary STAR results and comment on a possible direct comparison of lattice and experiment

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Momentum conservation and unitarity in parton showers and NLL resummation

We present a systematic study of differences between NLL resummation and parton showers. We first construct a Markovian Monte-Carlo algorithm for resummation of additive observables in electron-positron annihilation. Approximations intrinsic to the pure NLL result are then removed, in order to obtain a traditional, momentum and probability conserving parton shower based on the coherent branching formalism. The impact of each approximation is studied, and an overall comparison is made between the parton shower and pure NLL resummation. Differences compared to modern parton-shower algorithms formulated in terms of color dipoles are analyzed.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Energy conservation and axion back-reaction in a magnetic field

Axion clumps in an external magnetic field can emit electromagnetic radiation which causes them to decay. In the presence of a plasma, such radiation can become resonant if the clump frequency matches the plasma frequency. Typically, the decay or back-reaction of the clump is ignored in the literature when analyzing such radiation. In this paper we present a self consistent, semi-analytic approach which captures axion backreaction using energy conservation. We find that inclusion of back-reaction changes the clump frequency over time enabling clumps with a range of different initial frequencies to become resonant at some point in their time evolution.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗