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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Spectroscopy and Dynamics of Phosphonate-Derivatized Ruthenium Complexes on TiO2
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Spin-state effects on the thermal dihydrogen release from solid-state [MH(η2-H2)dppe2]+ (M = Fe, Ru, Os) organometallic complexes for hydrogen storage applications
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Structure and Electronic Spectra of Purine–Methyl Viologen Charge Transfer Complexes
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Rigid Medium Effects on Photophysical Properties of MLCT Excited States of Polypyridyl Os(II) Complexes in Polymerized Poly(ethyleneglycol) dimethacrylate Monoliths
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DFT Study of the Reaction of a Two-Coordinate Iron(II) Dialkyl Complex with Molecular Oxygen
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Hapticity-Dependent Charge Transport through Carbodithioate-Terminated [5,15-Bis(phenylethynyl)porphinato]zinc(II) Complexes in Metal–Molecule–Metal Junctions
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Electromagnetic study of the chlorosome antenna complex of Chlorobium-Tepidum
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Contrasting Protonation Behavior of Diphosphido vs Dithiolato Diiron(I) Carbonyl Complexes
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Distortional Effects of Noncovalent Interactions in the Crystal Lattice of a Cp*Ir(III) Acylhydroxamic Acid Complex: A Joint Experimental–Computational Study
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Structural insight into the regulation of MOF in the male-specific lethal complex and the non-specific lethal complex
Abstract not provided
The MHF complex senses branched DNA by binding a pair of crossover DNA duplexes
Abstract not provided
Spatial Control Of Functional Properties Via Octahedral Modulations In Complex Oxide Superlattices
The design of distortions and rotations of the corner-connected BO6 octahedra across interfaces has emerged as an exciting platform to control electronic or ferroic behavior in ABO3 perovskite heterostructures. Here, we investigate isovalent manganite superlattices, [(La0.7Sr0.3MnO3)n/(Eu0.7Sr0.3MnO3)n]×m, as a route to spatial control over electronic bandwidth and ferromagnetism through the creation of octahedral superstructures. Electron energy loss spectroscopy confirms a uniform Mn valence state throughout the superlattices. In contrast, the presence of modulations of the MnO6 octahedral rotations along the growth direction commensurate with the superlattice period is revealed by scanning transmission electron microscopy and x-ray diffraction. We show that the Curie temperatures of the constituent materials can be systematically engineered via the octahedral superstructures leading to a modulated magnetization in samples where the superlattice period is larger than the interfacial octahedral coupling length scale, while a single magnetic transition is observed in the short period superlattices.
Design and validation of non-metal oxo complexes for C–H activation
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