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At least 667 records · Page 37

Chemical reaction path modeling of hydrothermal processes on Mars: Preliminary results

Hydrothermal processes are thought to have had significant roles in the development of surficial mineralogies and morphological features on Mars. For example, a significant proportion of the Martian soil could consist of the erosional products of hydrothermally altered impact melt sheets. In this model, impact-driven, vapor-dominated hydrothermal systems hydrothermally altered the surrounding rocks and transported volatiles such as S and Cl to the surface. Further support for impact-driven hydrothermal alteration on Mars was provided by studies of the Ries crater, Germany, where suevite deposits were extensively altered to montmorillonite clays by inferred low-temperature (100-130 C) hydrothermal fluids. It was also suggested that surface outflow from both impact-driven and volcano-driven hydrothermal systems could generate the valley networks, thereby eliminating the need for an early warm wet climate. We use computer-driven chemical reaction path calculation to model chemical processes which were likely associated with postulated Martian hydrothermal systems.

Plumlee, Geoffrey S.↗

Considerations on Terrestrial Iron Depositing Analogs to Earliest Mars

Iron oxide and hydroxide minerals, including hematite, can mineralize and preservemicrofossils and physical biomarkers (Allen at al., 2004). Preserved remnants of phototrophic microorganisms are recognized as biosignatures of past life on Earth (Schopf, 2006). To date, two types of surface iron depositing environments have been studied as analogs to possible habitable environments on earliest Mars: the highly acidified Rio Tinto River (Iberian Belt, Spain) [Gomez Ortis et al., 2007], and the nearneutral iron depositing Chocolate Pots Hot Spring (Yellowstone National Park, US) [Parenteau at al., 2005]. While phototrophs in the Rio Tinto are only represented by eukaryotic algae (Amaral Zettler et all., 2002), Chocolate Pots is mainly populated with cyanobacteria (Pierson et all., 2000; Brown et all., 2007). Which of these environments is the closer analog to a potentially habitable early Mars? Paleobiological data, combined with recent "tree of life" interpretations, suggest that phototrophic eukaryotes evolved not earlier than 2.5 - 2.8 b.y. after Earth s accretion (4.6 b.y.), while cyanobacteria and /or their iron-tolerant predecessors evolved between 1 - 1.5 b.y. after accretion (Brown et al., 2007). Lindsay and Brasier (2002) postulated that microbial life on Mars surface could have lasted no more than 1-1.5 b.y. after Mars accretion (also 4.6 b.y.). Recent multispectral mapping of Mars suggests that near-neutral wet environments prevailed at approximately this time (Bibring, et al., 2006). Thus, near-neutral iron depositing hot springs such as Chocolate Pots Hot Spring seem to be the more likely habitable analogs for earliest Mars.

Brown, Igor I.↗

Supersonic Retropulsion Surface Preparation of Carbon Fiber Reinforced Epoxy Composites for Adhesive Bonding

Surface preparation is widely recognized as a key step to producing robust and predictable bonds in a precise and reproducible manner. Standard surface preparation techniques, including grit blasting, manual abrasion, and peel ply, can lack precision and reproducibility, which can lead to variation in surface properties and subsequent bonding performance. The use of a laser to ablate composite surface resin can provide an efficient, precise, and reproducible means of preparing composite surfaces for adhesive bonding. Advantages include elimination of physical waste (i.e., grit media and sacrificial peel ply layers that ultimately require disposal), reduction in process variability due to increased precision (e.g. increased reproducibility), and automation of surface preparation, all of which improve reliability and process control. This paper describes a Nd:YAG laser surface preparation technique for composite substrates and the mechanical performance and failure modes of bonded laminates thus prepared. Additionally, bonded specimens were aged in a hot, wet environment for approximately one year and subsequently mechanically tested. The results of a one year hygrothermal aging study will be presented.

Palmieri, Frank L.↗

Spectral Study of Water Tracks as an Analog for Recurring Slope Lineae

Liquid water is a key requirement for life on Earth, and serves as an important constraint on present day habitability on Mars. Recurring Slope Lineae (RSL) are a unique phenomenon on Mars that may be formed by brine seeps. Their morphological, seasonal and temporal characteristics support this hypothesis; however, spectral evidence has been lacking. Ojha et al., 2013 recently analyzed CRISM images from all confirmed RSL in the southern mid-latitudes and equatorial regions and found no spectro-scopic evidence for water. Instead, enhanced abun-dances or distinct grain sizes of both ferric and ferrous minerals are observed at most sites. The strength of these spectral signatures changes as a function of sea-son, possibly indicating removal of a fine-grained sur-face component during RSL flow, precipitation of fer-ric oxides, and/or wetting of the substrate. Water tracks (WT) have been suggested as a terrestrial analog for RSL by Levy et al., 2011. WT are defined as dark surface features that extend downslope in a linear or branching fashion, usually oriented along the steepest local gradient, in the Dry Valleys of Antarctica. They can be 1-3 m in width and can have lengths up to 2 km. They share many morphological and seasonal characteristics with RSL including active growth during summer seasons and fading during winter. Snowmelt, ground ice melt and deliquescence by hygroscopic salts have been suggested as possible formation mechanisms for water tracks. No spectral work to date has been reported for water tracks.

volumet-ric water content (VWC)↗

Modifying Matrix Materials to Increase Wetting and Adhesion

In an alternative approach to increasing the degrees of wetting and adhesion between the fiber and matrix components of organic-fiber/polymer matrix composite materials, the matrix resins are modified. Heretofore, it has been common practice to modify the fibers rather than the matrices: The fibers are modified by chemical and/or physical surface treatments prior to combining the fibers with matrix resins - an approach that entails considerable expense and usually results in degradation (typically, weakening) of fibers. The alternative approach of modifying the matrix resins does not entail degradation of fibers, and affords opportunities for improving the mechanical properties of the fiber composites. The alternative approach is more cost-effective, not only because it eliminates expensive fiber-surface treatments but also because it does not entail changes in procedures for manufacturing conventional composite-material structures. The alternative approach is best described by citing an example of its application to a composite of ultra-high-molecular- weight polyethylene (UHMWPE) fibers in an epoxy matrix. The epoxy matrix was modified to a chemically reactive, polarized epoxy nano-matrix to increase the degrees of wetting and adhesion between the fibers and the matrix. The modification was effected by incorporating a small proportion (0.3 weight percent) of reactive graphitic nanofibers produced from functionalized nanofibers into the epoxy matrix resin prior to combining the resin with the UHMWPE fibers. The resulting increase in fiber/matrix adhesion manifested itself in several test results, notably including an increase of 25 percent in the maximum fiber pullout force and an increase of 60-65 percent in fiber pullout energy. In addition, it was conjectured that the functionalized nanofibers became involved in the cross linking reaction of the epoxy resin, with resultant enhancement of the mechanical properties and lower viscosity of the matrix.

Zhong, Katie↗

Kinetic Friction of Non-Coalescing and Non- Wetting Drops

This project has focused on the experimental determination of the frictional forces associated with noncoalescing and nonwetting systems. In particular, the focus has been on friction associated with an isothermal nonwetting droplet sliding on a solid surface. The nonwetting phenomenon is driven by the establishment of a thin (of order microns in thickness) layer of lubricating gas that is swept by viscous action into the space between the liquid and solid, preventing them from coming into contact. The mechanism has been described in the review article by Neitzel & Dell'Aversana (2002). The work performed under this NASA GSRP sponsorship extends work done by Dell'Aversana & Neitzel (2004) on the load-carrying capacities of thermocapillary nonwetting droplets for a given relative displacement of the two surfaces in question.

Neitzel, G. paul↗

Estimates of Ground Temperature and Atmospheric Moisture from CERES Observations

A method is developed to retrieve surface ground temperature (Tg) and atmospheric moisture using clear sky fluxes (CSF) from CERES-TRMM observations. In general, the clear sky outgoing long-wave radiation (CLR) is sensitive to upper level moisture (q(sub h)) over wet regions and Tg over dry regions The clear sky window flux from 800 to 1200 /cm (RadWn) is sensitive to low level moisture (q(sub j)) and Tg. Combining these two measurements (CLR and RadWn), Tg and q(sub h) can be estimated over land, while q(sub h) and q(sub t) can be estimated over the oceans. The approach capitalizes on the availability of satellite estimates of CLR and RadWn and other auxiliary satellite data. The basic methodology employs off-line forward radiative transfer calculations to generate synthetic CSF data from two different global 4-dimensional data assimilation products. Simple linear regression is used to relate discrepancies in CSF to discrepancies in Tg, q(sub h) and q(sub t). The slopes of the regression lines define sensitivity parameters that can be exploited to help interpret mismatches between satellite observations and model-based estimates of CSF. For illustration, we analyze the discrepancies in the CSF between an early implementation of the Goddard Earth Observing System Data Assimilation System (GEOS-DAS) and a recent operational version of the European Center for Medium-Range Weather Prediction data assimilation system. In particular, our analysis of synthetic total and window region SCF differences (computed from two different assimilated data sets) shows that simple linear regression employing (Delta)Tg and broad layer (Delta)q(sub l) from 500 hPa to surface and (Delta)q(sub h) from 200 to 500 hPa provides a good approximation to the full radiative transfer calculations, typically explaining more than 90% of the 6-hourly variance in the flux differences. These simple regression relations can be inverted to "retrieve" the errors in the geophysical parameters. Uncertainties (normalized by standard deviation) in the monthly mean retrieved parameters range from 7% for (Delta)T to about 20% for (Delta)q(sub t). Our initial application of the methodology employed an early CERES-TRMM data set (CLR and Radwn) to assess the quality of the GEOS2 data. The results showed that over the tropical and subtropical oceans GEOS2 is, in general, too wet in the upper troposphere (mean bias of 0.99 mm) and too dry in the lower troposphere (mean bias of -4.7 mm). We note that these errors, as well as a cold bias in the Tg, have largely been corrected in the current version of GEOS-2 with the introduction of a land surface model, a moist turbulence scheme and the assimilation of SSTM/I total precipitable water.

Wu, Man Li C.↗

Estimates of Ground Temperature and Atmospheric Moisture from CERES Observations

A method is developed to retrieve surface ground temperature (T(sub g)) and atmospheric moisture using clear sky fluxes (CSF) from CERES-TRMM observations. In general, the clear sky outgoing longwave radiation (CLR) is sensitive to upper level moisture (q(sub l)) over wet regions and (T(sub g)) over dry regions The clear sky window flux from 800 to 1200/cm (RadWn) is sensitive to low level moisture (q(sub t)) and T(sub g). Combining these two measurements (CLR and RadWn), Tg and q(sub h) can be estimated over land, while q(sub h) and q(sub l) can be estimated over the oceans. The approach capitalizes on the availability of satellite estimates of CLR and RadWn and other auxiliary satellite data. The basic methodology employs off-line forward radiative transfer calculations to generate synthetic CSF data from two different global 4-dimensional data assimilation products. Simple linear regression is used to relate discrepancies in CSF to discrepancies in T(sub g), q(sub h) and q(sub l). The slopes of the regression lines define sensitivity parameters that can be exploited to help interpret mismatches between satellite observations and model-based estimates of CSF. For illustration, we analyze the discrepancies in the CSF between an early implementation of the Goddard Earth Observing System Data Assimilation System (GEOS-DAS) and a recent operational version of the European Center for Medium-Range Weather Prediction data assimilation system. In particular, our analysis of synthetic total and window region SCF differences (computed from two different assimilated data sets) shows that simple linear regression employing Delta(T(sub g)) and broad layer Delta(q(sub l) from .500 hPa to surface and Delta(q(sub h)) from 200 to .300 hPa provides a good approximation to the full radiative transfer calculations. typically explaining more than 90% of the 6-hourly variance in the flux differences. These simple regression relations can be inverted to "retrieve" the errors in the geophysical parameters. Uncertainties (normalized by standard deviation) in the monthly mean retrieved parameters range from 7% for Delta(T(sub g)) to about 20% for Delta(q(sub l)). Our initial application of the methodology employed an early CERES-TRMM data set (CLR and Radwn) to assess the quality of the GEOS2 data. The results showed that over the tropical and subtropical oceans GEOS2 is, in general, too wet in the upper troposphere (mean bias of 0.99 mm) and too dry in the lower troposphere (mean bias of -4.7 min). We note that these errors, as well as a cold bias in the T(sub g). have largely been corrected in the current version of GEOS-2 with the introduction of a land surface model, a moist turbulence scheme and the assimilation of SSM/I total precipitable water.

Wu, Man Li C.↗

Bubble Departure from Metal-Graphite Composite Surfaces and Its Effects on Pool Boiling Heat Transfer

The formation and growth processes of a bubble in the vicinity of graphite micro-fiber tips on metal-graphite composite boiling surfaces and their effects on boiling behavior are investigated. It is discovered that a large number of micro bubbles are formed first at the micro scratches and cavities on the metal matrix in pool boiling. By virtue of the non-wetting property of graphite, once the growing micro bubbles touch the graphite tips, the micro bubbles are sucked by the tips and merged into larger micro bubbles sitting on the end of the tips. The micro bubbles grow rapidly and coalesce to form macro bubbles, each spanning several tips. The necking process of a detaching macro bubble is analyzed. It is revealed that a liquid jet is produced by sudden break-off of the bubble throat. The composite surfaces not only have higher temperatures in micro- and macrolayers but also make higher frequency of the bubble departure, which increase the average heat fluxes in both the bubble growth stage and in the bubble departure period. Based on these analyses, the enhancement mechanism of pool boiling heat transfer on composite surfaces is clearly revealed.

Chao, David F.↗

Ecology and thermal inactivation of microbes in and on interplanetary space vehicle components

The uses of scanning electron microscopy in assessing changes that occur in spores exposed to wet and dry heat cycles at elevated temperatures were examined. Several species of Bacillus and other nonspore-forming species of organisms were used for the experiment. Surface morphology of viable and nonviable organisms was clearly detectable by this method, making it a potentially useful technique for investigating microbial inactivation on space vehicle surfaces and components. Micrographs of the spores and bacterial cells are provided.

Campbell, J. E.↗

Uniform Etching For Polycrystalline Photoconductor Films

Prewetting surface overcomes problem of nonuniformity of etching often occuring in polycrystalline films at PbS and PbSe. Believed prewetting causes etchant to attack film uniformly. Because process involves wet chemistry, inexpensive and easy to use.

Barrett, John↗

Supercritical droplet gasification experiments with forced convection

Preliminary results of a comprehensive experimental program are presented which offer the first direct observations of suspended n-heptane droplet gasifications in pure nitrogen with forced convection without the interference to optical probing associated with a flame. Measurements show attainment of a wet-bulb temperature until reduced pressures exceed about 1.0 under supercritical gas temperatures. Thereafter, temperature measurements indicate fully transient heat-up through the critical temperature. The surface is found to regress in a continuous manner with the measured temperature approaching the critical value at the end of the droplet lifetime under supercritical conditions with very mild level of convection. At increased level of convection for the same ambient conditions, similar sized droplets will undergo significant deformation during the gasification process until partially convected away as a dense vapor cloud as the critical temperature is approached.

Litchford, Ron↗

Composition of near-Earth asteroids

The continuing goal is to determine whether any of the near-Earth asteroids or the satellites of Mars contain hydrated phyllosilicate (clay) minerals. If these minerals are present, they would provide a ready source of water for propellant generation and use in life support systems. Many of the dark main belt asteroids have been shown to contain hydrated phyllosilicate minerals. Some of the near-Earth asteroids are also dark, but telescopic detection of water on these near-Earth asteroids is complicated because of the faintness of these small asteroids and because thermal emission masks the diagnostic spectral features beyond 3 microns due to water of hydration for objects within 2 AU of the Sun. New techniques for asteroid classification based on spectral reflectance and mineralogy will be necessary to determine whether the water absorption features are present on any of the near-Earth asteroids. This past year, better ways to classify 'wet' vs. 'dry' asteroids in the main belt were looked at. This new classification may allow us to determine the presence of water of hydration in the surface minerals of near-Earth asteroids even when we can only observe them at wavelengths that are not affected by thermal emission.

Lebofsky, Larry A.↗

Microbial Characterization Space Solid Wastes Treated with a Heat Melt Compactor

The on going purpose of the project efforts was to characterize and determine the fate of microorganisms in space-generated solid wastes before and after processing by candidate solid waste processing. For FY 11, the candidate technology that was assessed was the Heat Melt Compactor (HMC). The scope included five HMC. product disks produced at ARC from either simulated space-generated trash or from actual space trash, Volume F compartment wet waste, returned on STS 130. This project used conventional microbiological methods to detect and enumerate microorganisms in heat melt compaction (HMC) product disks as well as surface swab samples of the HMC hardware before and after operation. In addition, biological indicators were added to the STS trash prior to compaction in order to determine if these spore-forming bacteria could survive the HMC processing conditions, i.e., high temperature (160 C) over a long duration (3 hrs). To ensure that surface dwelling microbes did not contaminate HMC product disk interiors, the disk surfaces were sanitized with 70% alcohol. Microbiological assays were run before and after sanitization and found that sanitization greatly reduced the number of identified isolates but did not totally eliminate them. To characterize the interior of the disks, ten 1.25 cm diameter core samples were aseptically obtained for each disk. These were run through the microbial characterization analyses. Low counts of bacteria, on the order of 5 to 50 per core, were found, indicating that the HMC operating conditions might not be sufficient for waste sterilization. However, the direct counts were 6 to 8 orders of magnitude greater, indicating that the vast majority of microbes present in the wastes were dead or non-cultivable. An additional indication that the HMC was sterilizing the wastes was the results from the added commercial spore test strips to the wastes prior to HMC operation. Nearly all could be recovered from the HMC disks post-operation and all were showed negative growth when run through the manufacturer's protocol, meaning that the 106 or so spores impregnated into the strips were dead. Control test strips, i.e., not exposed to the HMC conditions were all strongly positive. One area of concern is that the identities of isolates from the cultivable counts included several human pathogens, namely Staphylococcus aureus. The project reported here provides microbial characterization support to the Waste Management Systems element of the Life Support and Habitation Systems program.

Strayer, Richard F.↗

The Ancient Martian Climate System

Today Mars is a cold, dry, desert planet. The atmosphere is thin and liquid water is not stable at the surface. But there is evidence that very early in its history, some 3.7-4.1 billion years ago, the climate system supported much warmer conditions including an active hydrological cycle with rainfall and runoff. Given the importance of liquid water to astrobiology and NASA’s Mars Exploration Program, researchers have been trying to understand the ancient martian climate system since the early 1970s when the Mariner 9 spacecraft first detected fluvial features on its oldest terrains. Though the evidence for warm wet conditions is compelling, the problem is not yet solved. The main issue is coping with the faint young sun. During the period when warmer conditions prevailed the sun’s luminosity was ~25% less than it is today. How can we explain the presence of liquid water on the surface of ancient Mars under such conditions? A similar problem exists for Earth, which would have frozen over under a faint sun even though the evidence suggests otherwise. Attempts to solve the “Faint Young Sun Paradox”, as it is commonly known, rely on greenhouse warming from an atmosphere with a different mass and composition than we see today. This is true for both Mars and Earth. However, for Mars there is no solution in sight. Long-lived continuously warm and wet atmospheres are difficult to produce and sustain. And a new and emerging idea - that ancient Mars was fundamentally a cold planet with transient episodes of warm wet conditions brought about by external forcings such as impacts, volcanism, and/or orbital changes – also has issues. In this seminar I will review this fascinating topic and discuss some of the recent ideas on how to solve it, the issues they raise, and what I believe are some promising avenues for future research.

Haberle, Robert M.↗

Effects of Leading-Edge Camber on Low-Speed Characteristics of Slender Delta Wings: Techniques and Tabulated Data

Special tests to determine the importance of transition fixing and Reynolds number variation on forces produced by thin delta wings are discussed. Transition fixing was achieved by applying cement to models and sprinkling grit on wet adhesive. Strips were applied along lines emanating from the apex located along sixty-five percent semi-span rays. Tests were made with grit on both surfaces, upper surface only, lower surface only, and on clean surfaces. Reynolds number varied by testing at three dynamic pressures. Correspondence between dynamic pressure and Reynolds number based on the mean aerodynamic chord are shown. No significant changes are noted due to either Reynolds number variation or transition fixing, within the range of Reynolds numbers used for the test.

Wentz, W. H., Jr.↗

Soil moisture variation patterns observed in Hand County, South Dakota

Soil moisture data were taken during 1976 (April, June, October), 1977 (April, May, June), and 1978 (May, June, July) Hand County, South Dakota as part of the ground truth used in NASA's aircraft experiments to study the use of microwave radiometers for the remote sensing of soil moisture. The spatial variability observed on the ground during each of the sampling events was studied. The data reported are the mean gravimetric soil moisture contained in three surface horizon depths: 0 to 2.5, 0 to 5 and 0 to 10 cm. The overall moisture levels ranged from extremely dry conditions in June 1976 to very wet in May 1978, with a relatively even distribution of values within that range. It is indicated that well drained sites have to be partitioned from imperfectly drained areas when attempting to characterize the general moisture profile throughout an area of varying soil and cover type conditions. It is also found that the variability in moisture content is greatest in the 0 to 2.5 cm measurements and decreases as the measurements are integrated over a greater depth. It is also determined that the sampling intensity of 10 measurements per km is adequate to estimate the mean moisture with an uncertainty of + or - 3 percent under average moisture conditions in areas of moderate to good drainage.

Jones, E. B.↗

Antarctic field tests of SARSAT personal locater beacons

Field tests of SARSAT personal locater beacons were conducted in the Antarctic to assess the viability of using these beacons to increase the safety of Antarctic field parties. Data were collected on the extent to which dry or wet snow, melting conditions, crevasse walls and snow bridges affected the ability of the SARSAT satellite to calculate an accurate position of the beacon. Average response time between beacon turn on and alert reception in McMurdo was between 4 and 5 hours for these tests. It is concluded that the SARSAT system is viable for Antarctic operations and it is recommended that it be implemented for future field operations. Because of obstruction of line-of-sight between beacon and satellite degrades the accuracy of the location calculation (particularly in wet snow), it is further recommended that field parties have sufficient numbers of beacons to insure that in an emergency, one will be able to operate from the surface.

Bindschadler, Robert↗