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At least 667 records · Page 37

Lidar observations of the stratospheric aerosol - California, October 1972 to March 1974

The paper describes the results of a series of 30 observations of stratospheric aerosol made with a ground-based lidar on the North Pacific Coast during a period relatively uninfluenced by major volcanic penetrations and displaying a relative temporal minimum in particulate content. The objectives were to provide a record of aerosol behavior during this intervolcanic period, to compare this behavior with that revealed by previous studies using a variety of techniques, and to provide comparative data on the stratospheric aerosol by conducting joint lidar and aircraft observations. Determination of scattering profile ratios from lidar signal profiles and analysis of experimental errors are described. Analysis of the data shows that significant temporal variability of the aerosol was observed, probably of nonvolcanic origin. Much of the variability was confined to the 23-30 km height region, above the major peak in scattering ratio. The evidence is that this is not due to influxes of extraterrestrial material. Vertical motions of the centroid of the scattering ratio peak were recorded during the 1973 stratospheric warming, and illustrate the value of lidar's ability to monitor temporal variations of vertical structure.

Russell, P. B.↗

The impact of stratospheric variability on measurement programs for minor constituents

The scales of temporal and spatial variations in stratospheric minor species concentrations and dynamical quantities are briefly reviewed. Despite the fact that the stratosphere is often considered to be a very quiescent region of the atmosphere, it exhibits transient and generally unpredictable episodes of intense activity. The resultant necessity for some degree of coordination between different observers in their choice of locations and times for measurements of minor constituents is emphasized. A specific suggestion is provided for one or more short 'International Stratospheric Periods' whose duration would depend upon the time of year. During these short periods, as many observers as possible would perform an integrated series of observations designed to optimize the usefulness of their data to atmospheric scientists.

Prinn, R. G.↗

The influence of the diabatic heating in the troposphere on the stratosphere

In order to simulate the seasonal variation of the stratospheric circulation in a zonal mean circulation model, a Newtonian heating function and a detailed heating function were applied to the troposphere and stratosphere, respectively. The purpose of this study was to investigate the response of stratospheric circulation to alterations of the radiative equilibrium temperature of the troposphere.

Turner, R. E.↗

A study of satellite observations of ozone and stratospheric temperatures during 1970-1971

A comparison is made between backscatter ultraviolet ozone data and the stratospheric radiance measurements made by the satellite infrared spectrometer on board Nimbus 4 for the period April 1970 to April 1971. These simultaneous measurements have been used to study the temporal and spatial behavior of ozone and the thermal structure of the stratosphere on a global basis. The most significant feature of the total ozone distribution observed is the strong increase in ozone values at the high latitudes of the Northern Hemisphere during the stratospheric warming of January 1971.

Ghazi, A.↗

The tropospheric-stratospheric polar vortex breakdown of January 1977

An extraordinary warming of the stratosphere in December-January 1976-77 was followed by tropospheric warming in the polar region and cooling in middle latitudes. During January 10-20, the associated polar anticyclone extended from the surface to 10 mb. Antecedents of the polar vortex breakdown are reviewed with the aid of results of zonal-harmonic analyses of planetary waves, for heights of the pressure surfaces (700-10 mb), temperature, and mean stratospheric temperature (the latter determined from satellite radiation measurements). Wave 1 in height and temperature played a dominant role in the stratosphere, attaining amplitudes of 1600 gpm and 25 C, respectively, at 10 mb. On the other hand, superposition of retrogressing wave 1 and quasi-stationary wave 2 in the height of the 300-mb surface, with individual amplitudes exceeding 300 gpm, is judged to have been an important factor in the overall development.

Quiroz, R. S.↗

A mechanism for inducing climatic variations through the stratosphere - Screening of cosmic rays by solar and terrestrial magnetic fields

The ability of heliomagnetic and geomagnetic fields to bring about climatic variations of long period is examined theoretically. A chemical relationship between low-energy cosmic rays and ozone balance in the stratosphere is sought as a crucial clue to historical changes in earth climate. A perturbation analysis is developed to arrive at zone depletion and reduction of stratospheric solar heating resulting from increased NOx concentration; temperature feedback and opacity feedback are allowed for. Modulation of galactic cosmic-radiation fluxes and ozone destruction in the stratosphere, colder surface temperatures associated with reduced magnetic shielding, and redistribution with height of total ozone decrease are explored.

Chamberlain, J. W.↗

On the origin of extraterrestrial stratospheric particles: Interplanetary dust or meteor ablation debris?

Meteor ablation debris was distinguished from unablated interplanetary dust in a collection of extraterrestrial particles collected in the stratosphere using NASA U-2 aircraft. A 62 g sample of the Murchison (C2) meteorite was artificially ablated to characterize ablation debris for comparison with the stratospheric particles. By using proper experimental conditions, artificial ablation debris can be produced that is similar to natural ablation debris. Analyses of natural fusion crusts, artificial fusion crust, and artificial ablation debris of the Murchison meteorite produced criteria for recognizing debris ablated by a primitive meteoroid. Ninety-five percent of the stratospheric particles can be described as either ablation debris from a primitive meteoroid, or as very primitive interplanetary dust.

Kyte, F. T.↗

The reaction Cl + H2CO yields HCl + HCO: Decreased sensitivity of stratospheric ozone to chlorine perturbations

The absolute rate constant for the reaction Cl + H2CO yields HCl + HCO was determined by the flash-photolysis resonance fluorescence method to be 7.5 plus or minus 0.9 (2 sigma) times 10 to the minus 11th power cu cm/molecule sec at 298 K and to have a negligible temperature dependence. This rate which is more than 2000 times faster than the rate of Cl + CH4 indicates that formaldehyde (H2CO) will compete significantly with methane (CH4) for the conversion of active chlorine in the stratosphere to the inactive reservoir HCl. Chlorine will thus be a less efficient destroyer of stratosphere ozone than previously believed. Ambient stratospheric ozone will depend less on the ambient chlorine amount and the predicted response to chlorine perturbations will be lessened. One-dimensional eddy-diffusion photochemical model calculations indicate a factor of 1.1 less sensitivity to chlorine than recently reported. For a steady-state CFM release at 1975 rates (750,000 tons/year) the eventual ozone depletion is now calculated to be 14%.

Stief, L. J.↗

Atomic chlorine and the chlorine monoxide radical in the stratosphere - Three in situ observations

Three simultaneous observations of atomic chlorine (Cl) and the clorine monoxide radical (ClO) are reported which encompass the altitude interval between 25 and 45 kilometers. Together, Cl and ClO form a gas-phase catalytic cycle potentially capable of depleting stratospheric ozone. Observed Cl and ClO densities, although variable, imply that chlorine compounds constitute an important part of the stratospheric ozone budget. The results are compared with recent models of stratospheric photochemistry which have been used as a basis for predicting ozone depletion resulting from fluorocarbon release.

Anderson, J. G.↗

Airborne infrared interferometric observations and analysis of stratospheric trace constituents

Infrared interferometric observations of key trace constituents of the stratosphere have been obtained. The NASA Lear Airborne Observatory with the Grumman airborne interferometer system was flown in the lower stratosphere at an altitude of 13.7 km to obtain transmission spectra in the 2800-6000 per cm region at a resolution of 2.5 per cm using the moon as a source. An atmospheric modeling program and the AFGL line parameter atlas are used to identify H2O, CH4, O3 and other trace constituents and to derive stratospheric column densities (molecules/sq cm).

Smith, L. L.↗

Stratospheric ozone measurement with an infrared heterodyne spectrometer

Measurements of a stratospheric ozone concentration profile are made by detecting infrared absorption lines with a heterodyne spectrometer. The infrared spectrometer is based on a line-by-line tunable CO2 lasers, a liquid-nitrogen cooled HgCdTe photomixer, and a 64-channel spectral line receiver. The infrared radiation from the source is mixed with local-oscillator radiation. The difference frequency signal in a bandwidth above and below the local-oscillator frequency is detected. The intensity in each sideband is found by subtracting sideband contributions. It is found that absolute total column density is 0.32 plus or minus 0.02 cm-atm with a peak mixing ratio at about 24 km. The (7,1,6)-(7,1,7) O3 line center frequency is identified as 1043.1772/cm. Future work will involve a number of ozone absorption lines and measurements of diurnal variation. Completely resolved stratospheric lines may be inverted to yield concentration profiles of trace constituents and stratospheric gases.

Abbas, M. M.↗

A numerical simulation of seasonal stratospheric climate. II - Energetics

The paper analyzes the energetics involved in the two numerical experiments described in Part I, concerning a longwave radiative transfer model and a simple Newtonian cooling (or heating) model. A three-dimensional quasi-geostrophic model is developed and used over the entire annual cycle to test the climatic responses of the stratospheric circulation to the cited two different longwave radiative heating models. It is shown that the eddy energy parameters (eddy kinetic energy, eddy available potential energy, generation of the latter, and vertical propagation of eddy geopotential energy) undergo annual variations with maximum values in winter and minimum values in summer. The zonal energy parameters exhibit semiannual variations with major maximum values in winter, minor maxima in summer and minima in spring and fall. Analysis of the energy cycle reveals that the vertical propagation of eddy geopotential energy and the generation of eddy available potential energy are the energy sources for energetics in the upper stratosphere. Ways in which the longwave radiative processes may affect the stratospheric energetics are identified.

Chen, T.-C.↗

Photochemical-radiative damping and instability in the stratosphere. II Numerical results

In a paper by Strobel (1977), opacity effects on the joint photochemical-radiative relaxation in the stratosphere were evaluated by a linear perturbation analysis. Significant reductions in the photochemical acceleration of the thermal relaxation rate and the ozone photochemical relaxation rate were obtained in the upper stratosphere as a result of opacity changes. For very large vertical scale height ozone density perturbations, amplifying solutions were generated by large opacity changes in the O3 dissociation and heating rates. Such solutions could indicate that the stratosphere does not possess an equilibrium ozone concentration. In the present paper, some illustrative numerical calculations are presented to demonstrate the properties of the amplifying solutions. The results indicate that ungeophysically large disturbances are required and that they cease growth before attainment of geophysically interesting amplitudes, and decay to the unperturbed state.

Strobel, D. F.↗

Post-volcanic stratospheric aerosol decay as measured by lidar

The paper summarizes and discusses results of lidar observations, at Hampton (Virginia), of the stratospheric aerosol vertical distribution for a period of 22 months (October 1974 to July 1976) after the volcanic eruption of the Volcan de Fuego in Guatemala. Data are presented in terms of lidar scattering ratio, vertically integrated aerosol backscattering, layer structure and location, and rawinsonde temperature profiles as a function of time. The results reveal a sudden increase in the stratospheric aerosol content after the volcanic eruption as well as its subsequent decline. There exists a high degree of correlation between the integrated aerosol backscattering and the tropopause height such that as one decreases the other increases and vice versa. Rapid decay of the stratospheric aerosol is found to occur over the late winter to early spring period.

Mccormick, M. P.↗

Asymmetries in ozone depressions between the polar stratospheres following a solar proton event

Ozone depletions in the polar stratosphere during the energetic solar proton event on 4 August 1972 were observed by the backscattered ultraviolet (BUV) experiments on the Nimbus 4 satellite. The observed ozone contents, the ozone depressions and their temporal variations above the 4 mb level exhibited distinct asymmetries between the northern and southern hemispheres. Since the ozone destroying solar particles precipitate rather symmetrically into the two polar atmospheres, due to the geomagnetic dipole field, it is suggested that these asymmetries may be explained in terms of the differences in dynamics between the summer and the winter polar atmospheres. In the summer (northern) hemisphere, the stratospheric and mesospheric ozone depletion and recovery are smooth functions of time due to the preponderance of undistributed orderly flow in this region. On the other hand, the temporal variation of the upper stratospheric ozone in the winter polar atmosphere (southern hemisphere) exhibits large amplitude irregularities. These characteristic differences between the two polar atmospheres are also evident in the vertical distributions of temperatures and winds observed by balloons and rocket soundings.

Maeda, K.↗

Seasonal variation of the vertical distribution of stratospheric ozone as observed with the Umkehr and BUV methods

Month-to-month variations evidenced by ozone profiles inferred from the classical Umkehr observations and from the back-scattered ultraviolet (BUV) satellite observations made from the Nimbus 4 satellite are examined. Upper stratospheric ozone profiles derived from BUV and Umkehr data display similar seasonal variations of about the same phase and magnitude for the 38 km to 50 km region. Between 28 km and 38 km, the seasonal variations are less marked, but the same rough picture emerges for both data sets. If both data sets indicate an increasing (or decreasing) trend over a period of years, it is not possible to conclude that a trend exists unless separate means exists for monitoring stratospheric dust. Because of the stratosphere well above the Junge layer seems less likely to be affected by volcanic debris, BUV data should be superior to Umkehr data for monitoring trends in the 38 km to 50 km range, provided that the calibration problems of flying such a monitoring instrument in space can be overcome.

Mateer, C. L.↗

Stratospheric Aerosol Measurement (SAM 2) experiment

The Stratospheric Aerosol Measurement 2 (SAM 2) is used to map the concentration and optical properties of stratospheric aerosols as a function of altitude, latitude, and longitude. The vertical distribution of the stratospheric aerosols in the polar regions of both hemispheres is provided.

Mccormick, M. P.↗

SAGE ground truth plan: Correlative measurements for the Stratospheric Aerosol and Gas Experiment (SAGE) on the AEM-B satellite

The ground truth plan is outlined for correlative measurements to validate the Stratospheric Aerosol and Gas Experiment (SAGE) sensor data. SAGE will fly aboard the Applications Explorer Mission-B satellite scheduled for launch in early 1979 and measure stratospheric vertical profiles of aerosol, ozone, nitrogen dioxide, and molecular extinction between 79 N and 79 S. latitude. The plan gives details of the location and times for the simultaneous satellite/correlative measurements for the nominal launch time, the rationale and choice of the correlative sensors, their characteristics and expected accuracies, and the conversion of their data to extinction profiles. In addition, an overview of the SAGE expected instrument performance and data inversion results are presented. Various atmospheric models representative of stratospheric aerosols and ozone are used in the SAGE and correlative sensor analyses.

Russell, P. B.↗