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All sources NASA NTRS DOE OSTI

DOE OSTI2016

Photocured epoxy/graphene nanocomposites with enhanced water vapor barrier properties

A transparent, water vapor barrier film made of an epoxy resin and graphene oxide (GO) was synthesized by photopolymerization process. The epoxy/GO film with just 0.05 wt% GO gives a 93% WVTR reduction with respect to the pristine polymer, reaching barrier properties better than other polymer composites containing higher amounts of graphene. The excellent water vapor barrier is attributed to the good dispersion of GO in the polymer matrix. Moreover, GO significantly enhances the toughness and the damping capacity of the epoxy resins. The hybrid film can have potential applications in anticorrosive coatings, electronic devices, pharmaceuticals and food packaging.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1985

The influence of dynamic inflow and torsional flexibility on rotor damping in forward flight from symbolically generated equations

The combined effects of blade torsion and dynamic inflow on the aeroelastic stability of an elastic rotor blade in forward flight are studied. The governing sets of equations of motion (fully nonlinear, linearized, and multiblade equations) used in this study are derived symbolically using a program written in FORTRAN. Stability results are presented for different structural models with and without dynamic inflow. A combination of symbolic and numerical programs at the proper stage in the derivation process makes the obtainment of final stability results an efficient and straightforward procedure.

Reddy, T. S. R.↗

DOE OSTI2026

Ligand Control of Ultrafast Hot-Carrier Cooling in CdSe Quantum Dots by a Coherent Nonadiabatic Mechanism

Using the results from global modeling of the broadband two-dimensional electronic spectrum and an analysis of the concurrent damping of excited-state vibronic coherences, we show herein that a coherent nonadiabatic mechanism converts the electronic excitation energy of the X3 (1P 3/2 –1P e ) exciton state to ligand vibrations on the <50 fs time scale in oleate- and hexadecylamine-capped CdSe quantum dots. A comparison of the rates for the two ligands suggests that this process is promoted by mid-frequency vibrations of the ligands due to modulation of their electron-donating tendency. An intramolecular vibrational redistribution process then follows on the ∼200 fs time scale with both ligands, which accompanies thermalization in the band-edge X1 (1S 3/2 –1S e ) state and dephasing of the spectator ligand vibrations. These findings suggest that charge-separated intermediates associated with photoinduced charge transfer or triplet–triplet excitation energy transfer will be produced with retention of phase coherence in the vibrations that modulate the charge-transfer character of surface-bound organic acceptors.

14 SOLAR ENERGY↗

DOE OSTI2021

Microbial production of megadalton titin yields fibers with advantageous mechanical properties

Manmade high-performance polymers are typically non-biodegradable and derived from petroleum feedstock through energy intensive processes involving toxic solvents and byproducts. While engineered microbes have been used for renewable production of many small molecules, direct microbial synthesis of high-performance polymeric materials remains a major challenge. Here we engineer microbial production of megadalton muscle titin polymers yielding high-performance fibers that not only recapture highly desirable properties of natural titin (i.e., high damping capacity and mechanical recovery) but also exhibit high strength, toughness, and damping energy — outperforming many synthetic and natural polymers. Structural analyses and molecular modeling suggest these properties derive from unique inter-chain crystallization of folded immunoglobulin-like domains that resists inter-chain slippage while permitting intra-chain unfolding. These fibers have potential applications in areas from biomedicine to textiles, and the developed approach, coupled with the structure-function insights, promises to accelerate further innovation in microbial production of high-performance materials.

36 MATERIALS SCIENCE↗

DOE OSTI2011

Transverse Instabilities in the Fermilab Recycler

Transverse instabilities of the antiproton beam have been observed in the Recycler ring soon after its commissioning. After installation of transverse dampers, the threshold for the instability limit increased significantly but the instability is still found to limit the brightness of the antiprotons extracted from the Recycler for Tevatron shots. In this paper, we describe observations of the instabilities during the extraction process as well as during dedicated studies. The measured instability threshold phase density agrees with the prediction of the rigid beam model within a factor of 2. Also, we conclude that the instability threshold can be significantly lowered for a bunch contained in a narrow and shallow potential well due to effective exclusion of the longitudinal tails from Landau damping.

43 PARTICLE ACCELERATORS↗

NASA NTRS1988

Wavenumber transition and wavenumber vacillation in Eady-type baroclinic flows

Wavenumber transition and wavenumber vacillation are studied numerically in a maximum simplification Eady-type model with uneven Ekman dissipation. The spectral wave solution for the model contains three waves with adjacent zonal wavenumbers and the gravest meridional mode. The model only allows for wave-mean-flow interaction. The model is used to obtain the main characteristics of the process of wavenumber transition at various stratifications and the flow regime of wave-number vacillation at specific parameter settings. It is found that wavenumber vacillation is a flow regime observed at some parameter settings when the flow has at least two spatial and three temporal degrees of freedom. It is suggested that the balance between baroclinic forcing and damping adjusted by wave-mean-flow interaction is a basic mechanism for wavenumber transition and wavenumber vacillation.

Weng, H.-Y.↗

NASA NTRS1987

Active vibration control in microgravity environment

The low gravity environment of the space station is suitable for experiments or manufacturing processes which require near zero gravity. An experiment was fabricated to test the validity of the active control process and to verify the flow and control parameters identified in a theoretical model. Zero gravity is approximated in the horizontal plane using a low friction air bearing table. An analog control system was designed to activate calibrated air jets when displacement of the test mass is sensed. The experiment demonstrates that an air jet control system introduces an effective damping factor to control oscillatory response. The amount of damping as well as the flow parameters, such as pressure drop across the valve and flow rate of air, are verified by the analytical model.

Gerhold, Carl H.↗

NASA NTRS1994

The evolution of convective storms from their footprints on the sea as viewed by synthetic aperture radar from space

SEASAT synthetic aperture radar (SAR) echoes from the sea have previously been shown to be the result of rain and winds produced by convective stroms; rain damps the surface waves and causes ech-free holes, while the diverging winds associated with downdraft generate waves and associated echoes surrounding the holes. Gust fronts are also evident. Such a snapshot from 8 July 1978 has been examined in conjunction with ground-based radar. This leads to the conclusion that the SAR storm footprints resulted from storm processes that occurred up to an hour or more prior to the snapshot. A sequence of events is discerned from the SAR imagery in which new cell growth is triggered in between the converging outflows of two preexisting cells. In turn, the new cell generates a mini-squall line along its expanding gust front. While such phenomena are well known over land, the spaceborne SAR now allows important inferences to be made about the nature and frequency of convective storms over the oceans. The storm effects on the sea have significant implications for spaceborne wind scatterometry and rainfall measurements. Some of the findings herein remain speculative because of the great distance to the Miami weather radar-the only source of corroborative data.

Atlas, David↗

DOE OSTI2016

Non-modal theory of the kinetic ion temperature gradient driven instability of plasma shear flows across the magnetic field

The temporal evolution of the kinetic ion temperature gradient driven instability and of the related anomalous transport of the ion thermal energy of plasma shear flow across the magnetic field is investigated analytically. This instability develops in a steady plasma due to the inverse ion Landau damping and has the growth rate of the order of the frequency when the ion temperature is equal to or above the electron temperature. The investigation is performed employing the non-modal methodology of the shearing modes which are the waves that have a static spatial structure in the frame of the background flow. The solution of the governing linear integral equation for the perturbed potential displays that the instability experiences the non-modal temporal evolution in the shearing flow during which the unstable perturbation becomes very different from a canonical modal form. It transforms into the non-modal structure with vanishing frequency and growth rate with time. The obtained solution of the nonlinear integral equation, which accounts for the random scattering of the angle of the ion gyro-motion due to the interaction of ions with ensemble of shearing waves, reveals similar but accelerated process of the transformations of the perturbations into the zero frequency structures. It was obtained that in the shear flow the anomalous ion thermal conductivity decays with time. It is a strictly non-modal effect, which originates from the temporal evolution of the shearing modes turbulence.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DOE OSTI2012

First results from EBW emission diagnostics on COMPASS

COMPASS tokamak shots at low magnetic field feature overdense plasmas during the extended current flat-top phase. The first harmonic of the electron cyclotron emission is completely cutoff for O and X modes and so the emission caused by electron Bernstein waves (EBWs) propagating obliquely with respect to the magnetic field and undergoing so called EBW-X-O conversion process can be observed. We perform an angular scan of the EBW emission during a set of comparable shots in order to determine the optimum antenna direction. A weak dependence of the radiative temperature on the antenna angles indicates an influence of multiple reflections from the vessel wall. The low temperature at the mode conversion region is responsible for the collisional damping of EBW, which can explain several times lower measured radiative temperature than the electron temperature measured by the Thomson scattering system.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

DOE OSTI2022

Predicted performance of a tangential viewing hard x-ray camera for the DIII-D high field side lower hybrid current drive experiment

High field side launch of lower hybrid current drive (LHCD) has improved accessibility and penetration over low field side launch on DIII-D. Simulations predict single pass absorption under a wide range of plasma conditions. Hard x-ray (HXR) measurement of LHCD generated fast electron bremsstrahlung (50–250 keV) will validate wave propagation and absorption. Emissivity profiles are recovered from one-dimensional inversion of HXR brightness to determine LH damping location, fast electron slowing down time, and some indication of the fast electron energy. The camera will be implemented by populating 32 tangential sightlines of the existing Gamma Ray Imager with Kromek SPEARTM Cadmium Zinc Telluride (CZT) detectors sensitive to 10–1000 keV photons with 10 keV energy resolution. Expected count rates allow for <0.5 ms time resolution. Pulses are processed using 50 ns shaping time Cremat CR-200 Gaussian shaping modules and are digitized by 25 MHz D-TACQ ACQ216 digitizers. The performance of the HXR camera is evaluated by comparing predicted fast electron density profiles and inverted synthetic brightnesses obtained from the ray-tracing/Fokker–Planck codes GENRAY/CQL3D. Inversions closely matched predicted fast electron profiles for a range of experimental parameters.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DOE OSTI2025

SPECTER: an instrument concept for CMB spectral distortion measurements with enhanced sensitivity

Deviations of the cosmic microwave background (CMB) energy spectrum from a perfect blackbody uniquely probe a wide range of physics, ranging from fundamental physics in the primordial Universe (μ-distortion) to late-time baryonic feedback processes (y-distortion). While the y-distortion can be detected with a moderate increase in sensitivity over that of COBE/FIRAS, the ΛCDM-predicted μ-distortion is roughly two orders of magnitude smaller and requires substantial improvements, with foregrounds presenting a serious obstacle. Within the standard model, the dominant contribution to μ arises from energy injected via Silk damping, yielding sensitivity to the primordial power spectrum at wavenumbers k ≈ 1-10 4 Mpc -1 . Here, we present a new instrument concept, SPECTER, with the goal of robustly detecting μ. The instrument technology is similar to that of LiteBIRD, but with an absolute temperature calibration system. Using a Fisher approach, we optimize the instrument's configuration to target μ while marginalizing over foreground contaminants. Unlike Fourier-transform-spectrometer-based designs, the specific bands and their individual sensitivities can be independently set in this instrument, allowing significant flexibility. We forecast SPECTER to observe the ΛCDM-predicted μ-distortion at ≈ 5σ (10σ) assuming an observation time of 1 (4) year(s) (corresponding to mission duration of 2 (8) years), after foreground marginalization. Our optimized configuration includes 16 bands spanning 1–2000 GHz with ∼degree-scale angular resolution at ∼ 150 GHz and 1100 total detectors. SPECTER will additionally measure the y-distortion at sub-percent precision and its relativistic correction at percent-level precision, yielding tight constraints on the total thermal energy and mean temperature of ionized gas.

CMBR experiments↗

DOE OSTI2013

Higher Order Modes Damping and Multipacting Analysis for the SPX Deflecting Cavity in APS Upgrade

A single-cell superconducting deflecting cavity operating at 2.815 GHz has been proposed and designed for the Short Pulse X-ray (SPX) project for the Advanced Photon Source (APS) upgrade. Each deflecting cavity is equipped with one fundamental power coupler (FPC), one lower order mode (LOM) coupler, and two higher order mode (HOM) couplers to achieve the stringent damping requirements for the unwanted modes. Using the electromagnetic simulation suite ACE3P, HOM damping will be calculated for the cavity including the full engineering design waveguide configurations and rf windows. Trapped modes in the bellows located in the beampipes connecting the cavities in a cryomodule will be computed and their effects on heating evaluated. Furthermore, multipacting activities at the end groups of the cavity will be identified to assess possible problems during high power processing.

Li, Z.↗

DOE OSTI2019

Damping of density oscillations in neutrino-transparent nuclear matter

We calculate the bulk-viscous dissipation time for adiabatic density oscillations in nuclear matter at densities of one to seven times the nuclear saturation density and at temperatures ranging from 1 MeV, where corrections to previous low-temperature calculations become important, up to 10 MeV, where the assumption of neutrino transparency is no longer valid. Under these conditions, which are expected to occur in neutron star mergers, damping of density oscillations arises from β equilibration via weak interactions. Here, we find that for 1-kHz oscillations the shortest dissipation times are in the 5- to 20-ms range, depending on the equation of state, which means that bulk viscous damping could affect the dynamics of a neutron star merger. For higher frequencies, the dissipation time can be even shorter.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

DOE OSTI2021

Shielded and Low-Damping SPM Probes for Quantitative Electrical and Electrochemical Characterization (Phase IIA)

The purpose of this DOE SBIR award was to develop new scanning probe microscopy tools for the elucidation of electrical and electrochemical properties at the nanoscale. High performance probes are important for energy materials research. In both solar cells and batteries, the essential physics and chemistry occur at the nanoscale and nanoscale characterization tools are required for their elucidation. Two products were developed: an electrically shielded probe and an electrically conductive probe with low leakage currents. Our processes were based on post processing of existing probes and fabrication methods were tested, leading to a laser micromachining based approach that led to the first minimal viable product. We invented a method to make a reliable electrical contact that attaches a flexible printed circuit board to the chip. enable leak-free operation crucial when used in conductive liquids and electrolytes. This proprietary solution improves chip handling, reduces contamination, and maintains effective electrical contact. The probes fabricated in this Phase IIa are a minimal viable product which attracted attention from various tip manufacturers and instrument manufacturers alike.

36 MATERIALS SCIENCE↗

DOE OSTI2013

A 2.5D boundary element formulation for modeling damped waves in arbitrary cross-section waveguides and cavities

Highlights: •Dispersive properties of viscoelastic waveguides and cavities are computed using a regularized 2.5D BEM. •Linear viscoelasticity is introduced at the constitutive level by means of frequency dependent complex moduli. •A contour integral algorithm is used to solve the nonlinear eigenvalue problem. •The Sommerfeld radiation condition is used to select the permissible Riemann sheets. •Attenuation of surface waves in cavities approaches the attenuation of Rayleigh waves. -- Abstract: A regularized 2.5D boundary element method (BEM) is proposed to predict the dispersion properties of damped stress guided waves in waveguides and cavities of arbitrary cross-section. The wave attenuation, induced by material damping, is introduced using linear viscoelastic constitutive relations and described in a spatial manner by the imaginary component of the axial wavenumber. The discretized dispersive wave equation results in a nonlinear eigenvalue problem, which is solved obtaining complex axial wavenumbers for a fixed frequency using a contour integral algorithm. Due to the singular characteristics and the multivalued feature of the wave equation, the requirement of holomorphicity inside the contour region over the complex wavenumber plane is fulfilled by the introduction of the Sommerfeld branch cuts and by the choice of the permissible Riemann sheets. A post processing analysis is developed for the extraction of the energy velocity of propagative guided waves. The reliability of the method is demonstrated by comparing the results obtained for a rail and a bar with square cross-section with those obtained from a 2.5D Finite Element formulation also known in literature as Semi Analytical Finite Element (SAFE) method. Next, to show the potential of the proposed numerical framework, dispersion properties are predicted for surface waves propagating along cylindrical cavities of arbitrary cross-section. It is demonstrated that the attenuation of surface waves approaches asymptotically the attenuation of Rayleigh waves.

97 MATHEMATICS AND COMPUTING↗

NASA NTRS1980

Strongly turbulent stabilization of electron beam-plasma interactions

The stabilization of electron beam interactions due to strongly turbulent nonlinearities is studied analytically and numerically for a wide range of plasma parameters. A fluid mode coupling code is described in which the effects of electron and ion Landau damping and linear growth due to the energetic electron beam are included in a phenomenological manner. Stabilization of the instability is found to occur when the amplitudes of the unstable modes exceed the threshold of the oscillating two-stream instability. The coordinate space structure of the turbulent spectrum which results clearly shows that soliton-like structures are formed by this process. Phenomenological models of both the initial stabilization and the asymptotic states are developed. Scaling laws between the beam-plasma growth rate and the fluctuations in the fields and plasma density are found in both cases, and shown to be in good agreement with the results of the simulation.

Freund, H. P.↗

NASA NTRS1988

Time domain identification of element matrices

Accurate mathematical models are clearly an important part of the design, modification, control, and damage assessment of large space structures. A critical part of model determination of any type of structure is the use of system identification (SI), a process for using measured excitation and response data to improve the form of a mathematical model or the values of the parameters in it. The reasons for using SI are manifold, but most of them involve uncertainties in either the form of or the parameters in the mathematical model. Some of the more common uncertainties are the following: the nature of the damping, the characteristics of sloppy or sticky joints, inelastic material properties, and parameters in a reduced Degree-of-Freedom (DOF) model. This paper contains a description of the SI algorithm followed by two illustrations: one in which all parameters in a shear building model are determined using pull back and quick release data, and another in which an equivalent reduced DOF model is obtained for a two story frame.

Matzen, Vernon C.↗