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Natural fracture mapping and discrete fracture network modeling of Wolfcamp formation in hydraulic fracturing test site phase 1 area, Midland Basin: Fractures from 3D seismic data, image log, and core
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Hydraulic and thermal controls on gas production from methane hydrate reservoirs
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Hydraulic permeation-induced water concentration gradients in ion exchange membranes
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Non-equilibrium simulations of hydraulic permeation: Role of mechanical boundary conditions in dense membranes
Understanding the mechanisms of water transport in reverse osmosis membranes is critical for improving membrane performance and guiding material design. While classical models describe transport as either solution-diffusion (SD)—involving concentration-driven diffusion through a homogeneous medium—or pore-flow (PF)—involving pressure-driven convection through percolated water channels—their applicability to crosslinked polyamide membranes remains debated. Here, using non-equilibrium molecular dynamics simulations, we investigate the impact of mechanical support conditions on pressure-driven water transport in polyamide membranes across varying crosslink densities and pressure differentials (1000–5000 bar). Two support conditions are considered: graphene-restrained, representing experimentally relevant supported membranes, and freeze-restrained, mimicking a self-supported structure. In graphene-restrained systems, water concentration gradients and constant pressure profiles emerge, consistent with SD theory and incompatible with PF assumptions due to the absence of percolated pores and sub-nanometer voids. In contrast, freeze-restrained systems display uniform water concentration and linearly decreasing pressure at 1000 bar, and exhibit compressibility-induced water gradients and partial percolation at 5000 bar, resembling PF-like behavior. However, the underlying assumptions of PF theory—continuous solvent pathways and pressure transmission through water-filled pores—are not met under most conditions. Our results demonstrate that accurate modeling of reverse osmosis membranes must incorporate realistic mechanical boundary conditions to distinguish between transport mechanisms. For dense polyamide membranes supported by porous substrates, graphene-restrained simulations best reflect experimental setups and support the SD model as the dominant mechanism of water permeation.
Extension of the NEAMS workbench to parallel sensitivity and uncertainty analysis of thermal hydraulic parameters using Dakota and Nek5000
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Thermal dehydration tests of FLiNaK salt for thermal-hydraulic experiments
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Implications of accident tolerant fuels on thermal-hydraulic research
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Neutronics and thermal-hydraulics coupling analysis using the FLUENT code and the RELAP5-3D code for a molten salt fast reactor
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Thermal-hydraulic transient analysis of the FFTF LOFWOS Test #13
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