Another self-similar blast wave - Early time asymptote with shock-heated electrons and high thermal conductivity
(Previously announced in STAR as N82-19962)
Cox, D. P.↗
SEARCH · Engineering Papers
Results for “electronic conduction”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Electron Energy Interplay in the Geomagnetic Trap Below the Auroral Acceleration Region
This publication addresses the collisional superthermal electron dynamics below the auroral acceleration region (AAR). This region is the portion of an auroral field line with a field-aligned electric field that leads to the formation of precipitating monoenergetic keV electron fluxes that produce the discrete auroral displays observable from the ground. It is assumed that these precipitating electron fluxes are monoenergetic and accelerated through a potential drop, V, such that these electrons are peaked at an energy E0 = eV, where e is the electron charge. Monoenergetic electrons precipitating into the upper atmosphere degrade to lower energies via many different collisional processes and produce the secondary electron population with energies of 10–100s eV which escapes back to magnetospheric altitudes and becomes geomagnetically trapped between the AAR and the upper ionosphere. The secondary electrons in this geomagnetic trap transfer energy via elastic Coulomb collisions to the thermal electrons. That energy is then returned to the topside ionosphere as heat flux carried by the electron thermal conduction which is essential to maintaining the topside electron temperature.
George V Khazanov↗
Conductive Liquid Metal Vitrimer Composites for Reconfigurable and Recyclable Flexible Electronics
Liquid metal (LM) elastomer composites exhibit excellent functionality for stretchable electronics and wearables, but limited recycling and reuse pathways constrain their sustainable use. Here, to address these challenges amid growing concerns over electronic waste, a conductive LM–vitrimer composite is presented that enables recyclable and reconfigurable electronics. This soft and stretchable composite features uniformly distributed LM inclusions that enhance thermal conductivity by 6.53× and enable the formation of conductive traces with electrical self-healing, while the vitrimer provides structural restoration. The dynamic covalent bonds of the vitrimer matrix are leveraged for both reprocessing the composite and chemically recovering 94% of the LM. This liquid-state filler slightly reduces the vitrimer's stiffness to 2.63 MPa (≈20% lower), while maintaining its high stretchability (>135% strain) and thermal stability. It is further examined how ultrasonicated LM inclusions interact with the vitrimer matrix and demonstrate the composite's self-healing and recyclability through two distinct approaches: 1) thermomechanical reprocessing, which restores fragmented composites under heat and compression for circuit reconfiguration; and 2) chemical recycling, which recovers the embedded LM for reuse in fabricating new composites and redesigned circuitry. With the integration of recyclability and diverse functional capabilities, LM–vitrimer composites emerge as a promising material platform for sustainable, flexible electronics.
Han, Youngshang [Univ. of Washington, Seattle, WA ↗
Investigation of electrical conductivity in amorphous semiconductors Semiannual report
Electric conductivity and electron transport mechanisms in amorphous semiconductors
ELECTRIC CONDUCTIVITY↗
The Key Role of Grain Boundary Dynamics in Revolutionizing the Potential of Solid Electrolytes
Solid electrolytes (SEs) have the potential to enhance the safety and performance of Li-metal batteries. However, the existence of grain boundaries in polycrystalline SEs presents a significant challenge for both ionic and electronic migration, promoting the propagation of detrimental lithium dendrites. This study compares the roles of grain boundaries in electrical properties of three distinct SEs including garnet-type Li 6.5 La 3 Zr 1.5 Ta 0.5 O 12 (LLZO), argyrodite-type Li 6 PS 5 Cl (LPSC), and NASICON-type Li 1+x+y Al x (Ti,Ge) 2-x Si y P 3-y O 12 (LATP). Results demonstrate that the electronic and ionic conductivities of solid-state electrolytes are affected differently by grain boundaries, depending on the specific type of electrolyte. For instance, LLZO and LATP experience dielectric breakdown at 3.7 and 5.3 V, respectively, while LPSC does not exhibit such behavior. Here, a new chemical modification is proposed that simultaneously alters the composition of both the surface and grain boundaries of SEs, ultimately reducing electronic conductivity for the LLZO SEs. Consequently, the proposed LLZO exhibits unprecedented dendrite-free cycling stability, achieving a remarkable 12 000-h lifetime at room temperature, surpassing conventional strategies such as surface coatings in dendrite mitigation. This study highlights the significance of modifying grain boundaries to design safe and durable Li-metal batteries. It provides new insights for developing SEs that are highly resistant to dendrite formation.
36 MATERIALS SCIENCE↗
Collective Energy Transport of Excitons in Two-dimensional Materials
Electronic thermal transport and thermoelectric measurements are pursued in this project to obtain unique insights into the unusual collective energy transport behaviors in two-dimensional (2D) heterostructures. Electronic thermal transport and thermoelectric measurements are essential techniques for characterizing bulk superconductors by probing the heat-carrying quasi-particles. Thermoelectric and electronic thermal transport measurements are expanded in this work beyond bulk systems to probe interactions among electrons, holes, and phonons in 2D heterostructures. In one experiment, a microbridge platform is advanced to demonstrate field-effect resistive-thermometry measurements of the electronic thermal conductivity of graphene heterostructures. Together with first principles theoretical calculations and analytical models, the experimental results suggest that tunable electron coupling with flexural phonons provides a knob to control quantum matters in graphene heterostructures with broken reflection symmetry. In another experiment, the Seebeck coefficient (S) is measured to probe interlayer interactions in electron-hole bilayers that are predicted to give rise to the emergence of a variety of correlated states. As a measure of the entropy, the measured S reveals the signature of electric injection of interlayer excitons in transition metal dichalcogenide (TMD) structures.
36 MATERIALS SCIENCE↗
Dayside auroral-oval plasma density and conductivity enhancements due to magnetosheath electron precipitation.
Demonstration that magnetosheath electrons precipitating into the dayside auroral oval are a significant source of ionization and consequently will lead to electrical conductivity enhancements within the oval. By assuming that the electrons are maintained isotropic by strong pitch-angle diffusion as they precipitate into the ionosphere, the precipitation heat flux can be simply related to solar-wind energy density and consequently to the level of magnetic activity. For quiet solar-wind conditions, the heat fluxes of 1 to 10 ergs/sq cm/sec expected and observed lead to height-integrated Pedersen conductivity enhancements of 4 to 15 mhos. During magnetic storms the conductivity enhancements could increase by a factor of 3 to 5. Since the precipitating electrons are soft, the Hall conductivity enhancements are smaller than the Pedersen conductivity enhancements. For typical electric fields the computed conductivity enhancements lead to field-aligned currents bounding the enhancements in order-of-magnitude agreement with observation. The topside ionosphere should also have a density enhancement over the auroral oval on the dayside.
Kennel, C. F.↗
Thermodynamic and electron transport properties of Ca 3 Ru 2 O 7 from first-principles phonon calculations and Boltzmann transport theory
Here, this work demonstrates a first-principles-based approach to obtaining finite temperature thermal and electronic transport properties which can be employed to model and understand mesoscale structural evolution during electronic, magnetic, and structural phase transitions. A computationally tractable model was introduced to estimate electron relaxation time and its temperature dependence. The model is applied to Ca 3 Ru 2 O 7 with a focus on understanding its electrical resistivity across the electronic phase transition at 48 K. A quasiharmonic phonon approach to the lattice vibrations was employed to account for thermal expansion while the Boltzmann transport theory including spin-orbit coupling was used to calculate the electron-transport properties, including the temperature dependence of electrical conductivity.
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
Deciphering the Conflict Between Ion and Electron Percolating Networks in Solid-State Battery Cathodes
High-energy- and power-density solid state batteries require an optimal cathode composition and microstructural arrangement of cathode active material, solid-state electrolyte, conductive carbon, and binder to simultaneously support lithium-ion transport, electron conduction, and storage capacity. The ion and electron conducting phases in solid-state cathodes counteract each other's percolating networks as their mass ratios increase or decrease relative to each other. Here, we investigate targeted mass ratio variations of argyrodite solid electrolyte and two different types of conductive carbon (particles and fibers) in composite LiNi0.8Mn0.1Co0.1O2 (NMC811) solid-state cathodes to ascertain the ionic-electronic tradeoffs in cathode performance. Through ionic and electronic conductivity measurements on composite cathodes, as well as rate-testing and cycling performance in full cells, it is shown that the conductive carbon fibers form a percolative electronic network within the composite at a lower mass ratio (3-5 wt%) than particulate carbon (>5 wt%). The threshold to achieve electronic percolation coincides with higher accessible capacity in the cathode as the active material particles become electronically connected. However, carbon loadings beyond this percolation threshold lead to increased ion transport resistance, arising from disruptions to ionic conduction pathways and degraded contact at the interface between the electrolyte and active materials. Imaging, spectroscopy, and physics-based models quantitatively describe the relationship between carbon and electrolyte compositions and the cell's capacity and rate performance through percolation theory. This work demonstrates the importance of quantitatively understanding percolating networks in solid-state cells and that strategic engineering of conductive carbon morphologies can further increase the energy- and power-density of solid-state cells.
25 ENERGY STORAGE↗
An experimental investigation of mesospheric ionization
Mesospheric ionization and its variability are examined. Data were obtained primarily by the parachute-borne blunt probe technique conducted in coordinated rocket experiments at White Sands Missile Range, New Mexico and Wallops Island, Virginia. Electrical conductivity measurements and deduced charge density values from ten rocket launches are presented and discussed. Positive ion conductivity and electron density were found to be relatively invariant with height between 45 and 60 km. Variations in positive conductivity of a factor of two and enhancements in negative conductivity by as much as a factor of four were measured by the blunt probe. A simple lumped parameter ion chemistry model is shown to satisfactorily explain the charge density values for the undisturbed lower D-region. Implications of the data in terms of this model are considered. The principal loss mechanism for positive ions in the 45 to 60 km. region is concluded to be dissociative recombination. Electron densities deduced from the conductivity data are explained by detachment involving a minor neutral constituent which is mixed between 65 and 45 km. and then cuts off sharply below 45 km. A correlation study involving blunt probe measurements shows relatively good agreement between variations in positive conductivity and temperature.
Mitchell, J. D.↗
Deep Dielectric Charging of Spacecraft Polymers by Energetic Protons
The majority of research in the field of spacecraft charging concentrates on electron charging effects with little discussion of charging by protons. For spacecraft orbiting in the traditional LEO and GEO environments this emphasis on electrons is appropriate since energetic electrons are the dominant species in those orbits. But for spacecraft in orbits within the inner radiation belts or for interplanetary and lunar space probes, proton charging (center dot) effects may also be of concern. To examine bulk spacecraft charging effects in these environments several typical highly insulating spacecraft polymers were exposed to energetic protons (center dot) with energies from 1 Me V to lO Me V to simulate protons from the solar wind and from solar energetic proton events. Results indicate that effects in proton charged dielectrics are distinctly different than those observed due to electron charging. In most cases, the positive surface potential continued to increase for periods on the order of minutes to a day, followed by long time scale decay at rates similar to those observed for electron charging. All samples charged to positive potentials with substantially lower magnitudes than for equivalent electron doses. Possible explanations for the different behavior of the measured surface potentials from proton irradiation are discussed; these are related to the evolving internal charge distribution from energy dependent electron and proton transport, electron emission, charge migration due to dark current and radiation induced conductivity, and electron capture by embedded protons.
radiation induced conductivity↗
Many-body Effects in a Laterally Inhomogeneous Semiconductor Quantum Well
Many body effects on conduction and diffusion of electrons and holes in a semiconductor quantum well are studied using a microscopic theory. The roles played by the screened Hartree-Fock (SHE) terms and the scattering terms are examined. It is found that the electron and hole conductivities depend only on the scattering terms, while the two-component electron-hole diffusion coefficients depend on both the SHE part and the scattering part. We show that, in the limit of the ambipolax diffusion approximation, however, the diffusion coefficients for carrier density and temperature are independent of electron-hole scattering. In particular, we found that the SHE terms lead to a reduction of density-diffusion coefficients and an increase in temperature-diffusion coefficients. Such a reduction or increase is explained in terms of a density-and temperature dependent energy landscape created by the bandgap renormalization.
Ning, Cun-Zheng↗
Widely Tunable Optical and Thermal Properties of Dirac Semimetal Cd 3 As 2
In this paper, a detailed analysis of the temperature-dependent optical properties of epitaxially grown cadmium arsenide (Cd 3 As 2 ), a newly discovered 3D Dirac semimetal is reported. Fermi level tuning—instigated from Pauli-blocking in the linear Dirac cone—and varying Drude response, generate large variations in the mid- and far-infrared optical properties. Thermo-optic shifts larger than those of traditional III–V semiconductors are demonstrated. Electron scattering rate, plasma frequency edge, Fermi level shift, optical conductivity, and electron effective mass analysis of Cd 3 As 2 thin-films are quantified and discussed in detail. The ab initio density functional study and experimental analysis of epitaxially grown Cd 3 As 2 promise applications for nanophotonic and nanoelectronic devices, such as reconfigurable metamaterials and metasurfaces, nanoscale thermal emitters, and on-chip directional antennas.
36 MATERIALS SCIENCE↗
Ultrafast vertical photoconductive intrinsic diamond switch with high current (17.1 A at 1 kV)
Here, this Letter reports on a vertical, bulk-conducting photoconductive semiconductor switch (PCSS) fabricated on an intrinsic Type IIa single-crystal diamond substrate. Under near-bandgap excitation at 225 nm with a 20 μ J pulse, a strong photocurrent response of 17.1 A at 1 kV DC bias magnitude is obtained by (i) tuning the optical trigger wavelength to the “matched-absorption” window (224–235 nm) near the band edge, where the optical penetration depth becomes comparable to the 500 μ m substrate thickness, and (ii) choosing the bias polarity ensuring electron-dominant conduction, given that electrons have a higher mobility than holes in diamond. The PCSS has an area-normalized responsivity of 54.2 mA W −1 cm −2 and an effective on-resistance of 8.48 Ω, with a fast 90%–10% transient fall time of 25 ns, attributed to carrier sweep-out. These results support vertical, bulk-conducting intrinsic diamond PCSS as a promising platform for high-power optical switching and provide new insight into intrinsic photoconductivity in diamond.
24 POWER TRANSMISSION AND DISTRIBUTION↗
Progress on the normal conducting magnets for the Electron-Ion Collider
The electron-ion collider (EIC) at Brookhaven National Laboratory (BNL) is designed to deliver a peak luminosity of 1e+34 1/cm2 1/sec. The EIC will take advantage of the existing Relativistic Heavy Ion Collider (RHIC) facility. Two additional rings will be installed: an electron storage ring (ESR) and a rapid cycling electron synchrotron ring (RCS).This paper presents an update on the normal conducting magnet designs required for both the ESR and RCS rings. The ESR will store polarized electron beams up to 18 GeV and utilizes a triplet of dipole magnets to increase the emittance at 5 GeV and generate excess bending to create additional radiation damping to allow a larger beam-beam tune shift. The RCS will accelerate single bunches of spin-polarized electrons at various energies from 5 GeV to 18 GeV, with a ramp rate of 100 ms and 1 Hz repetition rate. Both rings require dipole, quadrupole and sextupole magnets with different specifications.
43 PARTICLE ACCELERATORS↗
Rational Designed Mixed-Conductive Sulfur Cathodes for All-Solid-State Lithium Batteries
All-solid-state lithium–sulfur batteries (ASSLSBs) hold great promise for safe and high-energy-density energy storage. However, developing high-performance sulfur cathodes has been proven difficult due to low electronic and ionic conductivities and large volume change of sulfur during charge and discharge. Here, we reported an approach to synthesize sulfur cathodes with a mixed electronic and ionic conductivity by infiltrating a solution consisting of Li 3 PS 4 (LPS) solid electrolyte and S active material into a mesoporous carbon (CMK-3). This approach leads to a uniform dispersion of amorphous Li 3 PS 7 (L 3 PS) catholyte in an electronically conductive carbon matrix, enabling high and balanced electronic/ionic conductivities in the cathode composite. The inherent porous structure of CMK-3 also helps to accommodate the strain/stress generated during the expansion and shrinkage of the active material. In sulfide-based all-solid-state batteries with Li metal as the anode, this cathode composite delivered a high capacity of 1025 mAh g –1 after 50 cycles at 60 °C at 1/8C. This work highlights the important role of high and balanced electronic and ionic conductivities in developing high-performance sulfur cathodes for ASSLSBs.
25 ENERGY STORAGE↗
Thermal conduction and heating by nonthermal electrons in the X-ray halo of M87
A hydrostatic model for the X-ray halo around the giant elliptical galaxy M87 is presented. It is shown that by taking into account the processes of thermal conduction, and nonthermal heating by relativistic electrons in the radio lobes, a self-consistent hydrostatic model can be constructed. There is no need to invoke radiative accretion or the suppression of thermal conductivity.
Tucker, W. H.↗
Redox active polymer devices and methods of using and manufacturing the same
The disclosed technology relates generally to apparatus comprising conductive polymers and more particularly to tag and tag devices comprising a redox-active polymer film, and method of using and manufacturing the same. In one aspect, an apparatus includes a substrate and a conductive structure formed on the substrate which includes a layer of redox-active polymer film having mobile ions and electrons. The conductive structure further includes a first terminal and a second terminal configured to receive an electrical signal therebetween, where the layer of redox-active polymer is configured to conduct an electrical current generated by the mobile ions and the electrons in response to the electrical signal. The apparatus additionally includes a detection circuit operatively coupled to the conductive structure and configured to detect the electrical current flowing through the conductive structure.
Johnson, Paul B.↗