Tracking renewable carbon in bio-oil/crude co-processing with VGO through 13C/12C ratio analysis
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Li, Zheng-Hua (ORCID:000000030946500X)↗
SEARCH · Engineering Papers
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Technology and Economics, Inc. Technology Application Team
Technology + Economics, Inc. (T+E), under contract to the NASA Headquarters Technology Transfer Division, operates a Technology Applications Team (TATeam) to assist in the transfer of NASA-developed aerospace technology. T+E's specific areas of interest are selected urban needs at the local, county, and state levels. T+E contacts users and user agencies at the local, state, and county levels to assist in identifying significant urban needs amenable to potential applications of aerospace technology. Once viable urban needs have been identified in this manner, or through independent research, T+E searches the NASA technology database for technology and/or expertise applicable to the problem. Activities currently under way concerning potential aerospace applications are discussed.
Ballard, T.↗
Techno-economic analysis and life cycle assessment for the catalytic hydrogenolysis and hydrocracking of polyethylene
Catalytic hydrogenolysis and hydrocracking are promising technologies for the conversion of polyolefin waste into hydrocarbons. Here, to explore the economic and environmental viability of these approaches, we conducted techno-economic analysis and life cycle assessment of polyethylene hydrogenolysis and hydrocracking processes that produce fuel-range products or olefins, respectively. Relative to primary production, the minimum selling price (MSP) of alkanes for linear-chain naphtha was estimated to be 1.8-fold higher, whereas branched-chain naphtha and propylene were shown to be cost competitive. Environmental impacts showed similar trends across scenarios, with propylene production by hydrocracking exhibiting greenhouse gas emissions comparable with conventional propylene due to relatively low hydrogen demand and high yield. Together, these results suggest that innovations in catalysis and reaction engineering will be required to make viable products that are scale matched with today's plastics, such as light olefins for closed-loop recycling.
09 BIOMASS FUELS↗
Chapter 4 - Pretreatment Technologies for Lignocellulosic Biomass Refineries
Pretreatment is a critical step in processing lignocellulosic biomass into biofuel and bioproducts and is considered the energy and cost center of the biomass conversion process. Although a large number of pretreatment technologies have been developed, not all the techniques are viable on a commercial scale at this stage. Moreover, the technology choice and process conditions depend highly on the type of biomass and the overall biorefinery scheme. This chapter provides an overview of different pretreatment methods, including their mechanism, important process parameters, current status, and challenges. The opportunities associated with new technologies and approaches are presented. Emphasis is placed on low-severity thermal pretreatment technologies. The chapter also provides a brief discussion of the challenges to achieving the economic viability of the technologies on a commercial scale.
BIOMASS FUELS↗
An additively-manufactured molten salt-to-supercritical carbon di-oxide primary heat exchanger for solar thermal power generation – Design and techno-economic performance
The design and techno-economic performance of a compact additively manufactured (AM) molten salt (MS)-to-supercritical carbon di-oxide (sCO2) primary heat exchanger (PHE) for solar thermal application is described. The PHE design consists of sCO2 flow through an array of microscale pin fins while the MS flows through mm-scale rectangular channels. Constraints imposed by AM using laser powder bed fusion method are considered in the design. Structural and fluid flow simulations are performed to arrive at a viable design of the core and headers. A simplified one-dimensional steady state model for the PHE is developed including the impact of surface roughness from the AM process. A process-based cost model is used to determine the tradeoff between thermofluidic design and manufacturing cost. A parametric study is performed using the thermo-fluidic and cost models to determine the set of geometrical and flow variables that result in high power density and low cost, while restricting the pressure drop on the sCO2 side to less than 2% of line pressure. Flow rates of MS and sCO2 were varied over heat capacity rate ratios ranging from 0.2 to 1. Results indicate that it is possible to design a low-pressure drop AM PHE with an effectiveness of 90% and a power density in excess of 10 MW/m3 (including headers). Fabrication of representative nickel superalloy specimens are shown to demonstrate that low-porosity parts with the requisite dimensional tolerance of PHE core can be generated.
14 SOLAR ENERGY↗
Convergent Manufacturing of Large-Scale Components for Nuclear Applications, via Additive Manufacturing and Powder Metallurgy Hot Isostatic Pressing
Powder metallurgy (PM)–hot isostatic pressing (PM-HIP) has long been recognized as a powerful route for producing fully dense, near net shape metallic components. By consolidating powders under high temperature and pressure, HIP provides isotropic properties, uniform microstructures, and scalability to complex geometries that are vital for sectors such as aerospace, energy, and nuclear power. Yet despite these advantages, the technology has remained constrained by costly trial and error canister fabrication, limitations of conventional forging, and incomplete knowledge about how the canister design influences final part properties. Additive manufacturing (AM), by contrast, thrives on design freedom and geometric flexibility but struggles with speed, scalability, and cost when applied to very large structures. The research presented in this report investigated how a convergent manufacturing approach, combining AM with PM-HIP, can merge the strengths of both technologies, leveraging AM’s flexibility for canister design and HIP’s consolidation capability to deliver reliable, large, and complex parts. The work progressed through three case studies that built on one another in scale and complexity. Small cylindrical canisters fabricated by conventional methods, laser powder bed fusion, and directed energy deposition were filled with stainless steel powders and subjected to HIP. The resulting parts demonstrated near-full density and mechanical properties on par with wrought stainless steel, showing for the first time that AM canisters can be a direct substitute for conventional ones without sacrificing quality. The next step involved a medium-scale, noncentrosymmetric T-valve, which is an enclosed, multibranch geometry that tested the limits of AM + PM-HIP integration. The T-valve achieved predictable shrinkage and uniform densification, confirming feasibility for enclosed designs. However, this study also revealed oxide inclusions and interfacial challenges at the AM + HIP boundary, underscoring the critical importance of controlling interface chemistry and employing robust, in situ strategies, such as melt pool monitoring and thermal monitoring, coupled with nondestructive evaluation techniques such as x-ray computed tomography. Finally, the effort culminated in fabricating a large-scale impeller weighing nearly 2000 lb and spanning 5 ft in diameter. Produced via multirobot wire arc AM and hot isostatic pressed to near-full density, the impeller validated industrial-scale feasibility. Predictive models closely matched experimental shrinkage, tensile properties were spatially uniform across the component, and the AM + PM-HIP interface proved mechanically sound despite the presence of oxide-decorated prior particle boundaries. This large-scale demonstration is a major milestone, showing that hybrid AM + PM‑HIP can reliably deliver components at reactor-relevant scales. Collectively, these studies charted a logical pathway: small-scale work built scientific confidence, medium-scale work highlighted opportunities and challenges, and large-scale work proved industrial impact. The overarching conclusion of this report is that AM + PM-HIP should not be seen as a replacement for forging but as a complementary pathway that provides the US with flexibility, resilience, and new options for manufacturing nuclear-grade components. Looking ahead, several directions emerge as critical to sustaining progress. Predictive modeling must become faster, more accessible, and more accurate, with digital twins and machine learning reducing reliance on trial and error. Powders and alloys must be optimized for HIP, with improved cleanliness, reduced oxides, and tailored chemistries that enhance creep, fatigue, and irradiation resistance. Interfaces between AM and HIP regions must be better engineered through coatings, machining strategies, and surface treatments to mitigate oxide formation and ensure reliable bonding to explore opportunities for HIP of targeted compositional parts, as well as multimaterial HIP cladding applications. Monitoring and nondestructive evaluation need to expand, incorporating multimodal sensors, x-ray computed tomography, and real-time data integration through platforms such as Pelican. At the same time, the pathway to industrial adoption requires techno-economic analysis, machinability studies, and qualification frameworks aligned with industry and regulatory standards. Finally, workforce and academic engagement must be strengthened. Programs that train technicians and engineers for US Navy and US Department of Energy manufacturing challenges should be paired with academic partnerships to support fundamental research, with open sharing of non-export-controlled data to accelerate innovation and build the next generation of experts. In conclusion, this report demonstrates that hybrid AM + PM-HIP is scientifically viable and strategically important. By combining the design agility of AM with the consolidation strength of HIP and embedding modeling, monitoring, and workforce development, this approach provided a transformative new capability for US manufacturing. The path forward is clear: hybrid AM + PM-HIP is not just a promising research direction but is also potentially an industrially relevant pathway that can reshape how nuclear-grade components are designed, qualified, and deployed.
36 MATERIALS SCIENCE↗
Summary of the recent short-haul systems studies
The results of several NASA sponsored high density short haul air transportation systems studies are reported as well as analyzed. Included are the total STOL systems analysis approach, a companion STOL composites study conducted in conjunction with STOL systems studies, a STOL economic assessment study, an evaluation of STOL aircraft with and without externally blown flaps, an alternative STOL systems for the San Francisco Bay Area, and the quiet, clean experimental engine studies. Assumptions and results of these studies are summarized, their differences, analyzed, and the results compared with those in-house analyses performed by the Systems Studies Division of the NASA-Ames Research Center. Pertinent conclusions are developed and the more significant technology needs for the evaluation of a viable short haul transportation system are identified.
Savin, R. C.↗
On ( g – 2) μ from gauged $\mathrm{U(1)_X}$
We investigate an economical explanation for the (g – 2) μ anomaly with a neutral vector boson from a spontaneously broken U(1) X gauge symmetry. The Standard Model fermion content is minimally extended by 3 right-handed neutrinos. Using a battery of complementary constraints, we perform a thorough investigation of the renormalizable, quark flavor-universal, vector-like U(1) X models, allowing for arbitrary kinetic mixing. Out of 419 models with integer charges not greater than ten, only 7 models are viable solutions, describing a narrow region in model space. These are either L μ – L τ or models with a ratio of electron to baryon number close to –2. The key complementary constraints are from the searches for nonstandard neutrino interactions. Furthermore, we comment on the severe challenges to chiral U(1) X solutions and show the severe constraints on a particularly promising such candidate.
71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
Advanced Physics-Based Fluid System Performance Monitoring to Support Nuclear Power Plant Operations. Final CRADA report
This project targeted performance monitoring requirements for nuclear power plants with the goal of improving plant economics. We introduced a new and innovative technology to the industry that can reduce operations staffing levels by automating surveillance and can reduce maintenance staffing levels by providing early detection of degrading equipment. A beta-stage release of the PRO-AID power plant equipment fault diagnostic software ready for deployment in nuclear power plants will be delivered and demonstrated in a utility pilot project. To provide for efficient use of DOE funds the aim is to generate a minimum viable product for which we can prove the value of the product. The end state product will be serviceable for use in either a simulator environment or plant environment. The former provides a means for demonstration of the diagnostic capability for faults unlikely to be encountered in day-to-day operations.
21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
Coal-based Bricks & Blocks (CBBs): Process Development to Prototype Fabrication Coupled with Techno-Economic Analysis and Market Survey
The decline of coal use for energy production provides an abundance of local feedstock for new innovative uses and value-added products. Expanding the U.S. coal-value chain to manufacture high-value carbon products can strengthen the nation’s energy and mineral security, enhance the U.S. national defense security, increase the United States’ economic prosperity, while achieving U.S. environmental objectives. The primary project goal is a relatively light-weight composite product with superior (or comparable) compressive strength. Both virgin and, where available, post-consumer recycled thermoplastic versions are tested for each thermoplastic species. A useful attribute of thermoplastics as binders is that they can be heated to their melting point, cooled, and reheated again without significant degradation. A key advantage of thermoset CBBs is that they require only mixing and molding. CBB advantages include low cost, availability, binding ability and processability. Coal-based bricks and blocks (CBBs) weigh about 50% less than clay bricks and can be manufactured with an interlocking design to promote ease of use for the novice builder. CBB formulation is evaluated according to a design-of-experiments (DoE) approach. DoE variables are a) relative weight fractions of binder, b) relative proportions of large versus small (milled) anthracite size fractions, and c) additive percentage. Fabrication methods include hot-press molding and extrusion, the later being the most commercially viable. CBBs are tested for compressive strength, modulus of rupture (by flexure test) and water absorption per ASTM C67, with density determined by the Archimedes drainage method. Fractured interfaces are examined by SEM (Scanning Electron Microscopy) to resolve fracture dynamics and interior microstructure uniformity. Differential scanning calorimetry (DSC) is used to compare plastic transition temperatures i.e., glass and melting temperatures to contrast virgin with post-consumer recycled thermoplastics and optimize their usage. These results are used in the DoE analysis to identify the binder and relative weight percentages for optimum strength, density, and porosity. Overall, CBBs possess strength comparable to clay-based bricks but are non-permeable and hydrophobic, and hence resistant to degradation by freeze-fracturing, corrosion, and efflorescence. The strongest composites have been made with the following thermoplastic binders (in order of strength): thermoset, high-density polyethylene crosslink resin, high-density polyethylene, nylon 6/6, and polypropylene. Results from a techno-economic analysis TEA show economy of scale for CBBs by modularization and reveal the binder as the cost driver for material costs. Ideally, the incorporation of post-consumer recycled thermoplastic will decrease material acquisition costs and increase product sustainability. Notably, CBBs do not require the high temperature calcination needed to produce cement, nor do they require firing in the 1600-2400 °F range for three days using natural gas, as do clay brick equivalents. Instead, CBBs are heated to a modest <600 °F according to the melt flow index of the thermoplastic binder. Existing anthracite mines can be expanded to produce CBBs to reduce aggregate transportation costs and emissions that exist for clay bricks. TEA reflects this reduced energy cost while a comparative CO2 emission analysis quantifies the reduced environmental footprint. The market survey identifies several commercialization opportunities, dependent upon the brick classification.
01 COAL, LIGNITE, AND PEAT↗
Renewable linear alpha-olefins by base-catalyzed dehydration of biologically-derived fatty alcohols
In this work, base catalysts were studied for the dehydration of fatty alcohols to linear alpha olefins (LAOs). For the dehydration of 1-octanol to 1-octene, 15%Cs/SiO 2 catalyst was 56% selective at 10% conversion. Diluting a feed of C 8 , C 10 , and C 14 fatty alcohols to 50% in undecane increased the selectivity to alpha olefins to 77-99%. 15%Cs/SiO 2 was further investigated for the dehydration of a 4.2 g/L mixed C 8 -C 14 fatty alcohol in tridecane feed and showed linear alpha olefin selectivities of 78-100% at initial conversions of 51-91% with the conversion lowering to 32-77% over 30 h. Catalytic activity was totally regenerated through calcination. A feed of biologically derived alcohols was produced with E. coli strain CM24 transformed with three plasmids (pBTRCk – pVHb – maACR, pACYC – pVHb – seFadBA, pTRC99A – pVHb – tdTER – fdh) which yielded a 5.5 g/L of C 8 -C 14 fatty alcohol in tridecane. This biologically-derived feed was successfully dehydrated to linear alpha olefins over 15%Cs/SiO 2 at selectivities of 60-100% with initial conversions of 35-75% which decreased to 22-55% over 30 h. Techno-economic analysis (TEA) of the integrated process for fatty alcohol production and subsequent dehydration to alpha olefins was conducted across the potential fermentation TRY (titer, rate, yield) landscape. Baseline fermentation performance resulted in a minimum product selling price (MPSP) double the market price for LAOs due to low titers and high costs associated with managing water and tridecane solvent flows through the system. However, targeted improvements in fermentation performance (e.g., achieving 40 g/L titer, 0.5 g/L/h productivity, 80% theoretical yield) can enable financially viable production of biologically derived LAOs.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Biogas Utilization in Refuse Power Plants (BURP 2 )
The BURP 2 project investigated the technical and financial viability of co firing biogas with waste coal for power generation while using carbon capture and sequestration to achieve net negative emissions. A comparative assessment integrating geospatial mapping, technoeconomic analysis, and life cycle analysis was carried out to evaluate retrofitting an existing coal fired facility in West Virginia, versus developing a new greenfield power plant in Kentucky located near a low quality coal resource. The study found that CO 2 capture rates of 90% or higher, in combination with biogas feedstocks such as animal manure, could significantly reduce global warming potential compared to plants using neither biogas nor CO 2 capture systems. Economic feasibility depended heavily on federal tax credits and proximity to fuel sources. In both greenfield and retrofit scenarios, access to biogas played a key role. Because the retrofit site was located close to existing biogas resources, it represented a feasible option, whereas the greenfield site, being far from pipelines or biogas sources, would require prohibitively expensive biogas transport infrastructure. Overall, the research showed that repurposing waste or low-quality coal with renewable biogas and CO 2 capture systems could provide a viable approach for reducing carbon emissions in power production, if biogas resources are easily accessible and available in sufficient quantities.
01 COAL, LIGNITE, AND PEAT↗
Study of aircraft in intraurban transportation systems
A systems analysis was conducted to define the technical economic and operational characteristics of an aircraft transportation system for short-range intracity commutor operations. The analysis was for 1975 and 1985 in the seven county, Detroit, Michigan area. STOL and VTOL aircraft were studied in sizes from 40 to 120 passengers. The preferred vehicle for the Detroit area was the deflected slipstream STOL. Since the study was parametric in nature, it is applicable to generalization, and it was concluded that a feasible intraurban air transportation system could be developed in many viable situations.
Stout, E. G.↗
Analysis of hydrogen infrastructure for the feasibility, economics, and sustainability of a fuel cell powered data center
Data centers used for internet data services, cloud computing, and/or data storage consume vast amounts of electricity and are increasing rapidly in capacity. Consequently, their power consumption has raised concerns about energy sustainability and environmental impacts. Large-scale, on-site renewable energy could help reduce data centers’ carbon footprint; however, wind and solar power alone cannot provide an uninterrupted power supply to computer servers due to their natural variability. Instead, reliable power integration can be achieved by using fuel cells powered by hydrogen from sustainable resources (e.g., wind and solar energy). Establishing a hydrogen infrastructure will be critical for realizing these benefits and establishing fuel cells as a viable power source for data centers. Here, to facilitate the development of novel carbon-free fuel cell data enters, this paper presents renewable power integrated with hydrogen infrastructures in four scenarios to provide reliable hydrogen supply from production to storage. Various paths were analyzed toward a hydrogen supply infrastructure by determining the proper component sizes and calculating the cost of meeting the server load. We used a microgrid modeling software, Hybrid Optimization of Multiple Energy Resources (HOMER), and studied the feasibility of fuel cell powered data centers employing renewable hydrogen. The modeling results show various renewable integration configurations to meet reliable and sustainable power requirement under four scenarios for a carbon-free data center.
08 HYDROGEN↗
Propulsion technology challenges for turn-of-the-century commercial aircraft
This paper highlights the efforts being performed or sponsored by NASA, in cooperation with the U.S. civil aviation industry, to address the propulsion system technological challenges that must be met in order to ensure a viable future for the industry. Both the subsonic and supersonic aeropropulsion programs are considered. Subsonic transport propulsion program elements, including ultra-high-bypass-ratio turbofans with attendant noise reduction efforts, high-efficiency cores, and combustor emissions reductions are discussed in terms of goals, technical issues, and problem solutions. Similarly, the high-speed research propulsion efforts addressing a high-speed commercial transport are reviewed in terms of environmental barrier issues, such as oxides of nitrogen and noise reduction, and the related economic issues.
Ziemianski, Joseph A.↗
Propulsion technology challenges for turn-of-the-century commercial aircraft
This paper highlights the efforts being performed or sponsored by NASA, in cooperation with the U.S. civil aviation industry, to address the propulsion system technological challenges that must be met in order to ensure a viable future for the industry. Both the subsonic and supersonic aeropropulsion programs are considered. Subsonic transport propulsion program elements, including ultra-high-bypass-ratio turbofans with attendant noise reduction efforts, high-efficiency cores, and combustor emissions reductions are discussed in terms of goals, technical issues, and problem solutions. Similarly, the high-speed research propulsion efforts addressing a high-speed commercial transport are reviewed in terms of environmental barrier issues, such as oxides of nitrogen and noise reduction, and the related economic issues.
Ziemianski, Joseph A.↗
Capillary-Driven Heat Transfer Experiment: Keeping It Cool in Space
Capillary-pumped loops (CPL's) are devices that are used to transport heat from one location to another--specifically to transfer heat away from something. In low-gravity applications, such as satellites (and possibly the International Space Station), CPL's are used to transfer heat from electrical devices to space radiators. This is accomplished by evaporating one liquid surface on the hot side of the CPL and condensing the vapor produced onto another liquid surface on the cold side. Capillary action, the phenomenon that causes paper towels to absorb spilled liquids, is used to "pump" the liquid back to the evaporating liquid surface (hot side) to complete the "loop." CPL's require no power to operate and can transfer heat over distances as large as 30 ft or more. Their reliance upon evaporation and condensation to transfer heat makes them much more economical in terms of weight than conventional heat transfer systems. Unfortunately, they have proven to be unreliable in space operations, and the explanation for this unreliability has been elusive. The Capillary-Driven Heat Transfer (CHT) experiment is investigating the fundamental fluid physics phenomena thought to be responsible for the failure of CPL's in low-gravity operations. If the failure mechanism can be identified, then appropriate design modifications can be developed to make capillary phase-change heat-transport devices a more viable option in space applications. CHT was conducted onboard the Space Shuttle Columbia during the first Microgravity Science Laboratory (MSL-1) mission, STS-94, which flew from July 1 to 17, 1997. The CHT glovebox investigation, which was conceived by Dr. Kevin Hallinan and Jeffrey Allen of the University of Dayton, focused on studying the dynamics associated with the heating and cooling at the evaporating meniscus within a capillary phase-change device in a low-gravity environment. The CHT experimental hardware was designed by a small team of engineers from Aerospace Design & Fabrication (ADF), the NASA Lewis Research Center, and the University of Dayton. The hardware consisted of two experiment modules that each contained an instrumented test loop (idealized capillary-pumped loop), a base unit for power conversion and backlighting, a display unit with 15 LED's (light-emitting diodes) to display temperatures, pressure, heater power, and time, a control unit to select heaters and heater settings, a cooling fan, and associated cables.
Lekan, Jack F.↗
Community Solar and Community Solar+Storage: A Roadmap of Barriers and Solutions for Commercial Systems in NYC
Sustainable CUNY worked with decision makers and subject matter experts (SME's) to identify the barriers to and solutions for advancing commercial Community Solar (CS) and CS+Storage (CS+S) in urban areas. This roadmap captures the key challenges and solutions identified by New York City (NYC) stakeholders, including the Real Estate Board of New York (REBNY), through a collaborative process. Solar, as well as storage, are among the fastest growing energy segments in the United States, with CS, also known as Community Distributed Generation (CDG), gaining popularity with those who may not own or have access to a viable roof. Urban areas like NYC, which have a large population of renters, are particularly well suited for CS projects where credits from the power produced by a large remote installation are offered on a subscription basis to residents or businesses in the community. However, CS and CS+S projects have stalled at the doorstep of many cities. Host site owners, particularly those with large rooftops, have been slow to commit to installing CS due to competing rooftop usage and programs, limited knowledge about incentives, lack of economic data, and a complicated implementation process.
14 SOLAR ENERGY↗