Results for “dynamic simulation” — Page 37

NASA NTRS2015

Computational Simulations of the 10-MW TP3 Arc-Jet Facility Flow

This paper reports computational simulations and analysis in support of calibration tests in a high enthalpy arc-jet facility at NASA Ames Research Center. These tests were conducted using stagnation calorimeters and two different blunted wedge models with calibration plates at a wide range of conditions in the NASA Ames 10-megawatt TP3 (Test Position 3) facility. Data were obtained using four different conical nozzles with the same test configuration in which the models were placed in a free jet downstream of the nozzle. Experimental surveys of arc-jet test flow with pitot and null-point heat flux probes were also performed at several arc-heater conditions, providing assessment of the flow uniformity and valuable data for the flow characterization. The present analysis comprises computational fluid dynamics simulations of the nonequilibrium flowfield in the facility nozzle and test box, including the models tested, and comparisons with the experimental measurements. These computational simulations provide estimates of the arc-jet test environment parameters that are not measured but are needed to evaluate the performance of thermal protection system materials, along with further valuable insights into the arc-jet testing environment. Simulation results are used to estimate centerline total enthalpy, surface shear, boundary layer thickness, and boundary layer edge Mach number and to verify that specific test requirements from the Orion program are met.

CFD↗

NASA NTRSDate not supplied

A Strategic Approach for Dense, Integrated, Vehicle Navigation

Drone usage has been on the rise in recent years with applications that include parcel delivery, wildlife protection, precision farming, law enforcement, and industrial inspection, just to name a few. Once regulations and safety policies are put in place to allow for the widespread use of unmanned drones, the number of aircraft in the National Airspace System (NAS) is expected to skyrocket to millions, potentially congesting the airspace which increases the likelihood of separation violations and possibly incidents. Currently, flight infrastructure can only support a few thousand aircraft flying over the United States National Airspace System (NAS) at any given time. A delay at one airport can send ripple effects throughout the system, causing more delays and missed connections. In air traffic control, separation is the concept of keeping an “ownship” aircraft outside a minimum distance from “intruder” aircraft to reduce the risk of the aircraft colliding, as well as preventing accidents due to secondary factors, such as wake turbulence. Maintaining proper separation is often a safety critical property for fixed-wing drones in the airspace. This paper addresses drone separation in time and distance for high volume corridors (en route) and lanes (on ground), merging as well as crossing intersections of multiple corridors/lanes. In this paper, the term drone is applied to both Unmanned Aerial Vehicle (UAV) and small Unmanned Aircraft System (UAS) vehicles operating autonomously. There exists a gamut of approaches to the merging and crossing problems. At one end of the extreme are the conservative yet low cost and verifiable solutions of today that deal with two drones at a time. At the other end are complex Machine Learning-based solutions with high computing requirements for fully autonomous drones of the future that are expected to handle all contentions. This paper presents a feasible and verifiable strategic approach to these problems that is based on distributed cooperation between the drones and the infrastructure. Three phases of the strategic approach (Prepare, Adjust, Commit) are presented. Simulation results are presented that show the proposed approach is stable and resilient to induced perturbations and guarantees a set of fixed-wing drones to merge and cross intersections by adjusting their speed based on their distance to the aircraft in front of them while remaining in the equilibrium state. The equilibrium state is defined as the state when a set of n aircraft move at a relatively constant speed and uniform spacing from each other in a congested system. A congested system is defined as the state when at least one aircraft cannot move at its maximum allowed speed. Unlike existing centralized and pre-planned approaches, the proposed solution is fully distributed and enables autonomous aircraft to decide to adjust their speed and distance with respect to the preceding aircraft, dynamically. Simulation results are presented that assess the feasibility of the approach.

Distributed↗

NASA NTRSDate not supplied

A Strategic Approach for Dense, Integrated, Vehicle Navigation

Drone usage has been on the rise in recent years with applications that include parcel delivery, wildlife protection, precision farming, law enforcement, and industrial inspection, just to name a few. Once regulations and safety policies are put in place to allow for the widespread use of unmanned drones, the number of aircraft in the National Airspace System (NAS) is expected to skyrocket to millions, potentially congesting the airspace which increases the likelihood of separation violations and possibly incidents. Currently, flight infrastructure can only support a few thousand aircraft flying over the United States National Airspace System (NAS) at any given time. A delay at one airport can send ripple effects throughout the system, causing more delays and missed connections. In air traffic control, separation is the concept of keeping an “ownship” aircraft outside a minimum distance from “intruder” aircraft to reduce the risk of the aircraft colliding, as well as preventing accidents due to secondary factors, such as wake turbulence. Maintaining proper separation is often a safety critical property for fixed-wing drones in the airspace. This paper addresses drone separation in time and distance for high volume corridors (en route) and lanes (on ground), merging as well as crossing intersections of multiple corridors/lanes. In this paper, the term drone is applied to both Unmanned Aerial Vehicle (UAV) and small Unmanned Aircraft System (UAS) vehicles operating autonomously. There exists a gamut of approaches to the merging and crossing problems. At one end of the extreme are the conservative yet low cost and verifiable solutions of today that deal with two drones at a time. At the other end are complex Machine Learning-based solutions with high computing requirements for fully autonomous drones of the future that are expected to handle all contentions. This paper presents a feasible and verifiable strategic approach to these problems that is based on distributed cooperation between the drones and the infrastructure. Three phases of the strategic approach (Prepare, Adjust, Commit) are presented. Simulation results are presented that show the proposed approach is stable and resilient to induced perturbations and guarantees a set of fixed-wing drones to merge and cross intersections by adjusting their speed based on their distance to the aircraft in front of them while remaining in the equilibrium state. The equilibrium state is defined as the state when a set of n aircraft move at a relatively constant speed and uniform spacing from each other in a congested system. A congested system is defined as the state when at least one aircraft cannot move at its maximum allowed speed. Unlike existing centralized and pre-planned approaches, the proposed solution is fully distributed and enables autonomous aircraft to decide to adjust their speed and distance with respect to the preceding aircraft, dynamically. Simulation results are presented that assess the feasibility of the approach.

Distributed↗

NASA NTRSDate not supplied

ICME for NASA Aerospace Applications: Batteries for Electric Aviation

NASA’s approach to computational materials modeling is detailed in the NASA Vision 2040 Roadmap for Multiscale Modeling and Simulation of Materials and Systems. This report is in the spirit of national initiatives such as the Material Genome Initiative (MGI), Integrated Computational Materials Engineering (ICME), and others. We utilize a combination of fundamental modeling, computational high-throughput screening, and data science methods, e.g., machine learning, are used to find innovative solutions to NASA or national technology challenges. Applications of interest are wide ranging from advanced alloys to batteries to coatings, among others. In this talk, we present three examples for recent work related to NASA applications. First, doping advanced sulfur battery cathodes with selenium boosts electrical conductivity important for electric aircraft applications. First principles calculations will be discussed that result in compositional design maps for these materials. Second, development of icephobic coatings is important to mitigate safety hazards associated with icing for aircraft. Molecular dynamics simulations are reported for ice-surface interfaces to understand adhesion mechanisms and help screen optimal ice-phobic coatings. Third, shape memory alloys have numerous applications as actuators, superelastic materials, etc. for aerospace. We report machine learning models that predict martensitic transition temperatures across a broad swath of compositional space.

John Lawson↗

NASA NTRSDate not supplied

On Characterization of Flow Disturbances in Arc-Jet Testing

This paper reports computational simulations and analysis of flow characterization tests in high enthalpy arc-jet facilities at NASA Ames Research Center. Flow disturbances and their characterization are presented through case studies, and their implications for testing are discussed. The case studies include free-jet test configurations from three different arc heaters and nozzles: the 60-MW IHF 30-inch conical nozzle, the 10-MW TP3 15-inch conical nozzle, and the 20-MW AHF 12-inch conical nozzle. For all cases, test articles are placed in the jet exiting the conical nozzle, and the existence of a flow disturbance is confirmed through flow survey data using pitot pressure and heat flux probes and accompanying analysis. The paper focuses on cases where the effects of the disturbances on test article surface quantities are important. The present analysis comprises computational fluid dynamics simulations of the nonequilibrium flowfield in the facility nozzles and test box, including the models tested. Comparisons of computations with the experimental measurements are presented. The computations that reproduce the probe sweep data approximately are essential to interpret the arc-jet test data accurately, while providing insights into several observed calorimeter anomalies caused by flow disturbances.

Arc-jet testing↗

NASA NTRSDate not supplied

On Characterization of Flow Disturbances in Arc-Jet Testing

This paper reports computational simulations and analysis of flow characterization tests in high enthalpy arc-jet facilities at NASA Ames Research Center. Flow disturbances and their characterization are presented through case studies, and their implications for testing are discussed. The case studies include free-jet test configurations from three different arc heaters and nozzles: the 60-MW IHF 30-inch conical nozzle, the 10-MW TP3 15-inch conical nozzle, and the 20-MW AHF 12-inch conical nozzle. For all cases, test articles are placed in the jet exiting the conical nozzle, and the existence of a flow disturbance is confirmed through flow survey data using pitot pressure and heat flux probes and accompanying analysis. The paper focuses on cases where the effects of the disturbances on test article surface quantities are important. The present analysis comprises computational fluid dynamics simulations of the nonequilibrium flowfield in the facility nozzles and test box, including the models tested. Comparisons of computations with the experimental measurements are presented. The computations that reproduce the probe sweep data approximately are essential to interpret the arc-jet test data accurately, while providing insights into several observed calorimeter anomalies caused by flow disturbances.

Arc-jet testing↗

NASA NTRS1993

Preliminary analysis and design optimization of the short spacer truss of Space Station Freedom

The analysis, dynamic simulation, and design optimization of the short spacer truss of the Space Station Freedom are presented in this report. The short spacer truss will be positioned between the integrated equipment assembly (IEA) and another truss, called the long spacer truss, in the Space Station Freedom. During its launch in the Space Shuttle, the truss will be subjected to considerable in-span distributed inertia loads due to shuttle accelerations. The short spacer truss, therefore, has been modeled as a space frame to account for flexural response. Several parameters have been assumed, since the design specifications are in the process of development; hence the results presented should be considered preliminary. However, the automated analysis and design capabilities that have been developed can readily be used to generate an optimum design of the short spacer truss once the actual specifications have been determined. This report includes static and dynamic analyses of the short spacer truss, which have been obtained with the linear elastic code LE-HOST (in these analyses, LE-HOST data files have been automated to facilitate their future use for different design specifications of the short spacer truss); the dynamic animation of the short spacer truss, which has been carried out by using the results of the dynamic analysis and a post-processing feature of the modeling code PATRAN; and the optimum-weight design of the spacer truss, which was obtained under prescribed stress, displacement, and frequency constraints by using the design code COMETBOARDS. Examination of the analysis and design results revealed that the design could be improved if the configuration of the short spacer truss were modified to a certain extent. A modified configuration, which may simplify fabrication, has been suggested. The performance of this configuration has been evaluated and was found to be satisfactory under both static and dynamic conditions.

Gendy, A. S.↗

NASA NTRS2000

Efficient Use of Distributed Systems for Scientific Applications

Distributed computing has been regarded as the future of high performance computing. Nationwide high speed networks such as vBNS are becoming widely available to interconnect high-speed computers, virtual environments, scientific instruments and large data sets. One of the major issues to be addressed with distributed systems is the development of computational tools that facilitate the efficient execution of parallel applications on such systems. These tools must exploit the heterogeneous resources (networks and compute nodes) in distributed systems. This paper presents a tool, called PART, which addresses this issue for mesh partitioning. PART takes advantage of the following heterogeneous system features: (1) processor speed; (2) number of processors; (3) local network performance; and (4) wide area network performance. Further, different finite element applications under consideration may have different computational complexities, different communication patterns, and different element types, which also must be taken into consideration when partitioning. PART uses parallel simulated annealing to partition the domain, taking into consideration network and processor heterogeneity. The results of using PART for an explicit finite element application executing on two IBM SPs (located at Argonne National Laboratory and the San Diego Supercomputer Center) indicate an increase in efficiency by up to 36% as compared to METIS, a widely used mesh partitioning tool. The input to METIS was modified to take into consideration heterogeneous processor performance; METIS does not take into consideration heterogeneous networks. The execution times for these applications were reduced by up to 30% as compared to METIS. These results are given in Figure 1 for four irregular meshes with number of elements ranging from 30,269 elements for the Barth5 mesh to 11,451 elements for the Barth4 mesh. Future work with PART entails using the tool with an integrated application requiring distributed systems. In particular this application, illustrated in the document entails an integration of finite element and fluid dynamic simulations to address the cooling of turbine blades of a gas turbine engine design. It is not uncommon to encounter high-temperature, film-cooled turbine airfoils with 1,000,000s of degrees of freedom. This results because of the complexity of the various components of the airfoils, requiring fine-grain meshing for accuracy. Additional information is contained in the original.

Taylor, Valerie↗

NASA NTRSDate not supplied

Analysis of Probe Surveys Conducted in the 10-MW TP3 Arc-Jet Facility 15-Inch Nozzle Flow

Computational simulations and analysis of flow characterization tests in a high enthalpy arc-jet facility at NASA Ames Research Center are reported. These tests were conducted in the 10-MW TP3 facility 15-inch conical nozzle, and pitot pressure and heat flux probes are used to survey test flow downstream of the nozzle exit. Two 1.59-cm (0.625 in) diameter hemisphere probes were used: one with a stagnation-point pressure port, the other with a Gardon heat flux gage. Calibration data were also obtained using 20.32-cm flat-faced slug calorimeters. Experimental surveys of arc-jet test flow with pitot pressure and heat flux probes were obtained at eight arc-heater conditions, covering wide ranges in arc current (316–1756 A) and mass flow rate (32–500 g/s, without any cold-gas injection at the arc-heater plenum) and providing assessment of the flow uniformity in the facility. The present analysis comprises computational fluid dynamics simulations of the nonequilibrium flowfield in the facility nozzle and test box, including the models tested. These simulations take into account non-uniform total enthalpy and mass flux profiles at the nozzle inlet as well as the expansion waves emanating from the nozzle exit and their effects on the model flowfields. Comparisons of computations with the experimental measurements are presented, showing reasonably good agreement. The probe survey data and accompanying analysis show that the test flow in the TP3 15-inch nozzle is highly non-uniform at most conditions, and the extent of flow non-uniformity depends on arc current and mass flow rate.

Arc-jets↗

NASA NTRS1989

DYSCO: A software system for modeling general dynamic systems

The DYSCO program has been under development since 1979. It has been funded by Army and Air Force laboratories and by the Kaman Aerospace Corporation. It is presently available at a number of government and nongovernment installations. It has been used to analyze a very broad range of dynamics problems. A principle feature of the software design of DYSCO is the separation of the executive from the technology. The executive, which controls all the operations, is intelligent in the sense that it knows that its function is to assemble differential equations and to prepare them for solution. The technology library contains FORTRAN routines which perform standard functions, such as, computing the equation coefficients of an element (or component) given the local state at any time. The technology library also contains algorithms and procedures for solving the coupled system equations. The system was designed to allow easy additional of technology to the library. Any linear or nonlinear structural entity, control system, or set of ordinary differential equations may be simply coded and added to the library, as well as algorithms for time or frequency domain solution. The program is described with emphasis on its usefulness in easily modeling unusual concepts and configurations, performing analysis of damage, evaluating new algorithms, and simulating dynamic tests.

Berman, Alex↗

NASA NTRS2024

Multiscale Modeling of Thermoplastics Using Atomistic-informed Micromechanics

A multiscale repeating unit cell model of a single spherulite containing four disparate length scales was developed to predict the thermoelastic behavior of semicrystalline thermoplastic materials for composite aerospace applications. The continuum level scales were fully coupled and modeled using the generalized method of cells and the high fidelity generalized method of cells micromechanics theories. Data from molecular dynamics simulations were used as inputs for the amorphous and crystalline constituents in the multiscale continuum models. Effective Young’s modulus, shear modulus, Poisson’s ratio, coefficient of thermal expansion, and thermal conductivity were predicted for polyether ether ketone and polyether ketone ketone, showing good agreement with the available experimental data from the open literature. Moreover, it is shown that predicted properties are fairly insensitive to the fidelity of the micromechanics model used at the highest continuum scale or the assumed shape of the spherulite.

thermoplastics↗

NASA NTRSDate not supplied

Analysis of Probe Surveys Conducted in the 10-MW TP3 Arc-Jet Facility 15-Inch Nozzle Flow

Computational simulations and analysis of flow characterization tests in a high enthalpy arc-jet facility at NASA Ames Research Center are reported. These tests were conducted in the 10-MW TP3 facility 15-inch conical nozzle, and pitot pressure and heat flux probes are used to survey test flow downstream of the nozzle exit. Two 1.59-cm (0.625 in) diameter hemisphere probes were used: one with a stagnation-point pressure port, the other with a Gardon heat flux gage. Calibration data were also obtained using 10.16-cm iso-q and 20.32-cm flat-faced slug calorimeters. Experimental surveys of arc-jet test flow with pitot pressure and heat flux probes were obtained at eight arc-heater conditions, covering wide ranges in arc current (316–1756 A) and mass flow rate (32–500 g/s, without any cold-gas injection at the arc-heater plenum) and providing assessment of the flow uniformity in the facility. The present analysis comprises computational fluid dynamics simulations of the nonequilibrium flowfield in the facility nozzle and test box, including the models tested. These simulations take into account non-uniform total enthalpy and mass flux profiles at the nozzle inlet as well as the expansion waves emanating from the nozzle exit and their effects on the model flowfields. Comparisons of computations with the experimental measurements are presented, showing reasonably good agreement. The probe survey data and accompanying analysis show that the test flow in the TP3 15-inch nozzle is highly non-uniform at most conditions, and the extent of flow non-uniformity depends on arc current and mass flow rate.

Arc-jets↗

NASA NTRS2016

Flow Characterization Studies of the 10-MW TP3 Arc-Jet Facility: Probe Sweeps

This paper reports computational simulations and analysis in support of calibration and flow characterization tests in a high enthalpy arc-jet facility at NASA Ames Research Center. These tests were conducted in the NASA Ames 10-MW TP3 facility using flat-faced stagnation calorimeters at six conditions corresponding to the steps of a simulated flight heating profile. Data were obtained using a conical nozzle test configuration in which the models were placed in a free jet downstream of the nozzle. Experimental surveys of arc-jet test flow with pitot pressure and heat flux probes were also performed at these arc-heater conditions, providing assessment of the flow uniformity and valuable data for the flow characterization. Two different sets of pitot pressure and heat probes were used: 9.1-mm sphere-cone probes (nose radius of 4.57 mm or 0.18 in) with null-point heat flux gages, and 15.9-mm (0.625 in) diameter hemisphere probes with Gardon gages. The probe survey data clearly show that the test flow in the TP3 facility is not uniform at most conditions (not even axisymmetric at some conditions), and the extent of non-uniformity is highly dependent on various arc-jet parameters such as arc current, mass flow rate, and the amount of cold-gas injection at the arc-heater plenum. The present analysis comprises computational fluid dynamics simulations of the nonequilibrium flowfield in the facility nozzle and test box, including the models tested. Comparisons of computations with the experimental measurements show reasonably good agreement except at the extreme low pressure conditions of the facility envelope.

Goekcen, Tahir↗

NASA NTRS2016

Flow Characterization Studies of the 10-MW TP3 Arc-Jet Facility: Probe Sweeps

This paper reports computational simulations and analysis in support of calibration and flow characterization tests in a high enthalpy arc-jet facility at NASA Ames Research Center. These tests were conducted in the NASA Ames 10-MW TP3 facility using flat-faced stagnation calorimeters at six conditions corresponding to the steps of a simulated flight heating profile. Data were obtained using a conical nozzle test configuration in which the models were placed in a free jet downstream of the nozzle. Experimental surveys of arc-jet test flow with pitot pressure and heat flux probes were also performed at these arc-heater conditions, providing assessment of the flow uniformity and valuable data for the flow characterization. Two different sets of pitot pressure and heat probes were used: 9.1-mm sphere-cone probes (nose radius of 4.57 mm or 0.18 in) with null-point heat flux gages, and 15.9-mm (0.625 in) diameter hemisphere probes with Gardon gages. The probe survey data clearly show that the test flow in the TP3 facility is not uniform at most conditions (not even axisymmetric at some conditions), and the extent of non-uniformity is highly dependent on various arc-jet parameters such as arc current, mass flow rate, and the amount of cold-gas injection at the arc-heater plenum. The present analysis comprises computational fluid dynamics simulations of the nonequilibrium flowfield in the facility nozzle and test box, including the models tested. Comparisons of computations with the experimental measurements show reasonably good agreement except at the extreme low pressure conditions of the facility envelope.

CFD↗

NASA NTRSDate not supplied

Component-Based Development of CFD Software FUN3D

FUN3D, a suite of Computational Fluid Dynamics simulation and design tools developed at the NASA Langley Research Center, has undergone continuous development since the late1980s. It contains a large portion of legacy code. Extending it with new capabilities becomes increasingly difficult. To improve the extensibility and reusability, FUN3D is moving toward component-based development. New features, such as Stabilized Finite Elements, Yoga, and Sparse Linear Algebra Toolkit, are integrated into the system as components. Some existing features such as the Node-Centered Finite Volume Solver, are also being refactored to components. The integration of these components poses new requirements on the development workflow. In this paper, we describe the Continuous Integration of FUN3D to support component-based development, and discuss the tools used, the practices followed, and lessons learned during the transition from the traditional approach.

computational fluid dynamics software↗

NASA NTRS1991

Control algorithm implementation for a redundant degree of freedom manipulator

This project's purpose is to develop and implement control algorithms for a kinematically redundant robotic manipulator. The manipulator is being developed concurrently by Odetics Inc., under internal research and development funding. This SBIR contract supports algorithm conception, development, and simulation, as well as software implementation and integration with the manipulator hardware. The Odetics Dexterous Manipulator is a lightweight, high strength, modular manipulator being developed for space and commercial applications. It has seven fully active degrees of freedom, is electrically powered, and is fully operational in 1 G. The manipulator consists of five self-contained modules. These modules join via simple quick-disconnect couplings and self-mating connectors which allow rapid assembly/disassembly for reconfiguration, transport, or servicing. Each joint incorporates a unique drive train design which provides zero backlash operation, is insensitive to wear, and is single fault tolerant to motor or servo amplifier failure. The sensing system is also designed to be single fault tolerant. Although the initial prototype is not space qualified, the design is well-suited to meeting space qualification requirements. The control algorithm design approach is to develop a hierarchical system with well defined access and interfaces at each level. The high level endpoint/configuration control algorithm transforms manipulator endpoint position/orientation commands to joint angle commands, providing task space motion. At the same time, the kinematic redundancy is resolved by controlling the configuration (pose) of the manipulator, using several different optimizing criteria. The center level of the hierarchy servos the joints to their commanded trajectories using both linear feedback and model-based nonlinear control techniques. The lowest control level uses sensed joint torque to close torque servo loops, with the goal of improving the manipulator dynamic behavior. The control algorithms are subjected to a dynamic simulation before implementation.

Cohan, Steve↗

NASA NTRSDate not supplied

Multiscale Modeling of Thermoplastics Using Atomistic-informed Micromechanics

A multiscale model was developed for predicting the thermoelastic behavior of semi-crystalline thermoplastic materials for composite aerospace applications. At the highest scale containing the semi-crystalline spherulite in an amorphous matrix, the generalized method of cells, or high fidelity method of cells, was used to perform the homogenization calculations to obtain the effective properties. Models were developed assuming a cubic, or spherical shape, for the spherulite to understand if the morphology of the spherulite affects the effective thermoelastic properties. The generalized method of cells was used to model at the repeating unit cells at the subscales of the microstructure including the lamellae stacks and granular crystal blocks. The scales are integrated using the multiscale micromechanics method in the NASA Multiscale Analysis Tool. Data from molecular dynamics simulations were used as inputs for the amorphous and crystalline constituents. Convergence studies were performed to determine the best level of discretization for the repeating unit cell at the highest scale. Effective Young’s modulus, shear modulus, Poisson’s ratio, coefficient of thermal expansion, and thermal conductivity were predicted for polyether ether ketone and polyether ketone ketone, and very good agreement between the model utilizing the cubic spherulite and the experimental data, where available, was observed for polyether ketone ketone. Normalization of the data for the bulk polyether ketone ketone, against amorphous data, improved the predictions as compared to experimental data. Overall, the high fidelity method of cells predicted a stiffer response then the generalized method of cells as the crystallinity was increased. The shape of the spherulite had a minimal effect on the predicted bulk properties of the polymers.

thermoplastics↗

NASA NTRS2016

Yield and Failure Behavior Investigated for Cross-Linked Phenolic Resins Using Molecular Dynamics

Molecular dynamics simulations were conducted to fundamentally evaluate the yield and failure behavior of cross-linked phenolic resins at temperatures below the glass transition. Yield stress was investigated at various temperatures, strain rates, and degrees of cross-linking. The onset of non-linear behavior in the cross-linked phenolic structures was caused by localized irreversible molecular rearrangements through the rotation of methylene linkers followed by the formation or annihilation of neighboring hydrogen bonds. The yield stress results, with respect to temperature and strain rate, could be fit by existing models used to describe yield behavior of amorphous glasses. The degree of cross-linking only indirectly influences the maximum yield stress through its influence on glass transition temperature (Tg), however there is a strong relationship between the degree of cross-linking and the failure mechanism. Low cross-linked samples were able to separate through void formation, whereas the highly cross-linked structures exhibited bond scission.

Molecular dynamics↗