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At least 667 records · Page 37

Study of in-situ degradation of thermal control surfaces

Experimental technique used in study of damage mechanism to semiconductor pigments exposed to ultraviolet radiation can be adapted for investigations of surface chemistry and may be used analytically to determine contamination.

Gilligan, J. E.↗

Degradation and recovery mechanisms in lithium-doped solar cells

Several groups of lithium-doped solar cells have been evaluated under 1-MeV electron irradiation. Many of these groups indicated superior electrical output after irradiation and recovery as compared to similarly irradiated n/p solar cells. The superior cells are those with lithium concentrations of 2 to 5 x 10 to the 14th power atoms per cu cm at the junction. An irradiation of lithium-doped cells with 28-MeV electrons indicated a tenfold advantage of lithium-doped cells over n/p cells. Studies of the changes in the lithium concentration during recovery have shown the amounts of lithium reacting is highly nonlinear in regard to the electron fluence and varies greatly with distance from the junction. The results indicate that precipitation of lithium on radiation defects may be the cause of recovery rather than ion pairing.

Downing, R. G.↗

Review of oxidative degradations of certain heterocyclic polymers

The curing and decompositions of polyphenylenes and several nitrogen-containing condensation polymers, particularly polybenzimidazoles and pyrones, are reviewed critically. It is concluded that the condensations are usually imperfect and incomplete and that in most of the published work the late stages of the condensation are complicated by the beginnings of the charring and carbonization processes. Most discussions of mechanisms in this range are highly speculative and of little value. The most promising fields for further research are at lower temperatures, where slow oxidation processes deserve study, and at higher temperatures, where it may be possible to influence carbonization processes to obtain better products.

Mayo, F. R.↗

Microbial degradation of parathion

An organism capable of utilizing parathion as the sole carbon and energy source was isolated by enrichment culture techniques. The bacterium was characterized and tentatively classified as Pseudomonas aeruginosa. A pH of 7.0 - 7.5 and temperature of 30 C were found to be optimum for the consumption of parathion. Virtually no oxygen utilization was observed with resting cell suspensions when nonsolubilized parathion was employed. The use of ethanol as solvent for parathion in resting cell studies or preincubation of cells in ethanol obviated this problem and rapid parathion oxidation was demonstrable. Approximately 80% of the parathion consumed by resting cells was present terminally as carbon dioxide. Permeability of the cell to parathion or its metabolites was contingent upon the use of ethanol as either solvent or denaturant. Metabolites were tentatively identified by thin layer chromatography.

Gibson, W. L.↗

Changes in the frequency distribution of energy deposited in short pathlengths as a function of energy degradation of the primary beam.

The frequency distributions of event size in the deposition of energy over small pathlengths have been measured after penetration of 44.3 MeV protons through various thicknesses of tissue-equivalent material. Results show that particle energy straggling of an initially monoenergetic proton beam after passage through an absorber causes the frequency distributions of energy deposited in short pathlengths of low atomic number materials to remain broad. In all cases investigated, the ratio of the most probable to the average energy losses has been significantly less than unity.

Baily, N. A.↗

Degradation of learned skills. A review and annotated bibliography

An overview of the literature dealing with the retention of learned skills is presented. Basic effects of task type, training, retention interval, and recall variables are discussed, providing a background against which more recent literature dealing with operational spaceflights tasks is compared and assessed. Detailed and summary abstracts of research reports having particular relevance to the problem of spaceflight skill retention are provided.

Gardlin, G. R.↗

Testing to determine the vacuum-ultraviolet degradation rate of thermal control coatings

Samples of S-13G that had been exposed to the salt air environment of Cape Kennedy, Florida were irradiated with simulated solar ultraviolet radiation after various cleaning treatments. In both of the the tests conducted two of the salt air exposed samples were not cleaned, two were lightly cleaned with water and detergent (i.e. rinsed), and two were vigorously scrubbed. Several other white thermal control coatings were also irradiated. The solar absorptance values of these coatings before and as a result of the ultraviolet irradiation are reported for exposure levels up to approximately 2000 ESH.

Gilligan, J. E.↗

Degradation and reuse of radiative thermal protection system materials for the space shuttle

Three silicide coated columbium alloys and two cobalt alloys were subjected to identical simulated reentry profiling exposures in both static (controlled vacuum leak) and dynamic (hypersonic plasma shear) environments. Primary emphasis in the columbium alloy evaluation was on the Cb752 and C129Y alloys with a lesser amount on FS85. Commercial silicide coatings of the R512E and VH109 formulations were used. The coated specimens were intentionally defected to provide the types of coating flaws that are expected in service. Temperatures were profiled up to peak temperatures of either 2350 F or 2500 F for 15 minutes in each cycle.

Bartlett, E. S.↗

Radiative property degradation of water impinging on thermally-controlled surfaces under space conditions.

Review of the results of an investigation aimed at determining experimentally the directional monochromatic reflectance changes caused under high-vacuum space conditions by a water spray impinging on thermally controlled surfaces consisting of three paint specimens (Z93, S13G, and 92-007) and an aluminum foil. The first two paints and the aluminum foil suffered considerable physical damage, but only small changes resulted in the reflectance of the paints while the reflectance of the aluminum foil decreased with increase in exposure time to the water jet. Only the 92-007 Dow Corning paint retained the same physical and reflective characteristics.

Maples, D.↗

Water and processes of degradation in the Martian landscape.

Some large channels on Mars show features, notably bars and braiding, that indicate an origin by the action of running water. Smaller channels on steep slopes may have been produced by runoff of precipitation. Dendritic canyon systems suggest ground water sapping, which may have been an effective agent in cliff retreat generally. Extensive plains developed as cliffs retreated and, although modified by later wind action, may be regarded as relict landforms from a fluvial stage of Martian history.

Milton, D. J.↗

A study of degradation of plates for nickel-cadmium spacecraft cells

The relative merits of coining and not coining of sintered nickel-oxide and cadmium plates was investigated. A survey of the industry including cell manufactures and users was made and results summarized. Sample plate materials from most commercial cell suppliers were obtained and characterized for properties that may correlate with the tendency toward physical disintegration during handling and over long periods of time in the cell. Special test methods were developed to obtain comparative data in a short time. A wide range of physical properties and coining thicknesses was observed, resulting in a range of responses. The stronger, less brittle materials resisted loss of sinter better than weaker materials whether or not coined. Coining improved handling and resistance to electrochemical cycling in all materials tested. An apparent exception was found to be due to improper coining of a tapered edge.

Scott, W. R.↗

Gain degradation and efficiencies of spiral electron multipliers

The characteristics of spiral electron multipliers as functions of accumulated counts were investigated. The mean gain of the multipliers showed a steady decline from about 100 million when new, to about one million after 100 billion events when biased in a saturation mode. For prolonged use in a space environment, improved life expectancy might be obtained with a varying bias voltage adjusted to maintain the gain comfortably above a given discrimination level. Pulse-height distributions at various stages of the lifetime and variations of efficiency with energy of detected electrons are presented.

Judge, R. J. R.↗

Real-time correction of atmospherically degraded telescope images through image sharpening

We present a new technique for the correction of atmospheric distortion in telescope images. Most of this distortion arises from a random phase variation of the incoming light across the telescope aperture. This variation limits the resolving power of even large telescopes to about one arc second. If the sharpness of the images is defined in a suitable way, this sharpness is maximized only when the phase distortion of the incoming light is zero. We present computer simulations of a simple feedback system in which active optical elements, set to maximize the sharpness, correct most of the atmospheric distortion. Photon statistics set the limiting magnitude of the object for which a practical feedback system can work. Details in a sixth magnitude object smaller than 0.1 sec of arc should be resolvable. The system can be conveniently employed within existing telescopes.

Muller, R. A.↗