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At least 667 records · Page 37

Effects of crystallization on micro-mechanical behavior of polyethylene nanocomposites using Raman spectroscopy

Recent work has shown that nanoparticles can be ordered in semicrystalline polymers by controlling the crystallization rate, specifically by forcing them to migrate to the amorphous regions of the lamellar morphology. Here, we study the micromechanical behavior of neat polyethylene and silica/polyethylene nanocomposites filled with 15 nm brush-modified silica in the quenched and slow-crystallized organized state. The molecular response to loading in tension was monitored with Raman spectroscopy using the peaks associated with crystalline and amorphous regions. The addition of nanofillers dramatically reduced the shift in the amorphous peaks, indicating that in addition to carrying some load, the brush-modified nanoparticles may be acting as tie molecules that restrict amorphous deformation. The higher degree of lamellar organization and the organization of the nanoparticles also impacted the crystalline peak shifts, but more subtly.

Polyethylene↗

Scaling behavior and giant field enhancement of the thermal conductivity in the honeycomb antiferromagnet BaCo 2⁢ (AsO 4 ) 2

The layered honeycomb material BaCo 2 (AsO 4 ) 2 is of topical interest because its magnetic state is related to that of the Kitaev magnet α-RuCl 3 . Using thermal transport to probe how magnetic excitations interact with phonons in the magnetically disordered regime, we have uncovered an unusually large enhancement of the thermal conductivity κ xx in an in-plane magnetic field H. Just above the Néel temperature T N , a field of 13 T increases κ xx by a factor of ∼ 211, which is very large compared to other magnetic insulators. Interestingly, κ xx (H, T) exhibits a scaling behavior in the entire magnetically disordered region that surrounds the ordered zigzag state. The ratio Δκ xx (H, T)/κ xx (13, T), measured throughout the disordered region, collapses to a one-parameter scaling function exp(−1/gx) (where x = μ B B/k B T and g is a constant).

36 MATERIALS SCIENCE↗

On the regeneration of fish scales: structure and mechanical behavior

Fish scales serve as a dermal armor that provides protection from physical injury. Owing to a number of outstanding properties, fish scales are inspiring new concepts for layered engineered materials and next-generation flexible armors. Although past efforts have primarily focused on the structure and mechanical behavior of ontogenetic scales, the structure–property relationships of regenerated scales have received limited attention. In the present study, common carp ( Cyprinus carpio ) acquired from the wild were held live in an aquatic laboratory at 10°C and 20°C. Ontogenetic scales were extracted from the fish for analysis, as well as regenerated scales after approximately 1 year of development and growth. Their microstructure was characterized using microscopy and Raman spectroscopy, and the mechanical properties were evaluated in uniaxial tension to failure under hydrated conditions. We note the strength, strain to fracture and toughness of the regenerated scales were significantly lower than those of ontogenetic scales from the same fish, regardless of the water temperature. Scales that regenerated at 20°C exhibited significantly higher strength, strain to fracture and toughness than those regenerated at 10°C. The regenerated scales exhibited a highly mineralized outer layer, but no distinct limiting layer or external elasmodine; they also possessed a significantly lower number of plies in the basal layer than the ontogenetic scales. The results suggest that a mineralized layer develops preferentially during scale regeneration with the topology needed for protection, prior to the development of other qualities.

59 BASIC BIOLOGICAL SCIENCES↗

2010-2012 Minneapolis - St. Paul Travel Behavior Inventory

The 2010-2012 Travel Behavior Inventory (TBI) provided Minnesota policymakers and researchers with data about travel in the Minneapolis - St. Paul region. It also updated the region's travel demand forecasting, including transit ridership for major transportation projects. The Metropolitan Council in the Minneapolis-St. Paul area conducted the survey. The TBI consists of a paper-based survey and a wearable global positioning system survey. The data collection process for these two surveys was independent, and the results are not intended to function together.

1Hz data↗

2000 Knoxville Urban Area Household Travel Behavior Survey

This survey, conducted by NuStats, was a comprehensive study of travel behavior in Knox and Blount counties in the Knoxville urban area. The purpose of the survey was to collect weekday travel characteristics of household members (ages five and older) in the counties during a 24-hour timeframe. The data will be used by the Knoxville Urban Area Metropolitan Planning Organization and local agencies to update transportation and air quality models and to identify transportation needs in the region. The survey was conducted between November 2000 and February 2001. In total, 2,674 households were recruited to participate in the survey. Of these, 1,538 households reported data from a one-day travel log, totaling 12,631 trips by 3,522 persons. Of all trips originating in the study area, three-fourths were made by persons residing in Knox County.

1Hz data↗

1982 The Twin Cities Metropolitan Area Travel Behavior Inventory

The purpose of the 1982 Travel Behavior Inventory was to update socioeconomic and travel data gathered in a 1970 home interview survey. The area in Minnesota studied included the counties of Ramsey, Hennepin, Dakota, Anoka, Washington, Carver, and Scott. The inventory collected demographic and travel data from September 1, 1982, to February 27, 1983. The survey contains data from 2,640 participating households. From participants' travel records, a total of 21,944 trips were reported by 6,059 household members for a 24-hour period.

1Hz data↗

1990 The Twin Cities Metropolitan Area Travel Behavior Inventory

The Twin Cities Metropolitan Area 1990 Travel Behavior Inventory, or home interview survey, was conducted by Twin Cities Metropolitan Council—Saint Paul to document how Twin Cities residents use the streets, highways, and transit services in the region. The survey collected demographic, socioeconomic, and travel data for 9,476 households. Respondents were asked to record their travel and activities for a 24-hour period, in which 98,535 trips were documented. In addition to the home interview survey, the study included an establishment survey, a transit survey, external station traffic counts, and an external station origin/destination survey.

1Hz data↗

2000 The Twin Cities Metropolitan Area Travel Behavior Inventory

The 2000 Twin Cities Metropolitan Area Travel Behavior Inventory, conducted by Twin Cities Metropolitan Council—Saint Paul, was the first major travel survey in the region since 1990. The 2000 inventory includes a home interview survey, an establishment survey, a transit survey, external station traffic counts, and an external station origin/destination survey. The study area under the household inventory survey included the seven counties of the regional Metropolitan Planning Organization and thirteen adjacent counties. Demographic, socioeconomic, and travel data were gathered for 6,386 households. Of these, 6,219 households completed the travel logs, which includes household members older than five years old.

1Hz data↗

Outlook on texture evolution in additively manufactured stainless steels: Prospects for hydrogen embrittlement resistance, overview of mechanical, and solidification behavior

Abstract Realizing application specific manufacture with fusion-based additive manufacturing (F-BAM) processes requires understanding of the physical phenomena that drive evolution of microstructural attributes, such as texture. Current approaches for understanding texture evolution in F-BAM are majorly considerate of the phenomena occurring only during solidification. This hinders the comprehensive understanding and control of texture during F-BAM. In this perspective article, we discuss several physical phenomena occurring during and after solidification that can determine texture in F-BAM processed stainless steels (SS). A crystal plasticity-coupled hydrogen adsorption-diffusion modeling framework is also leveraged to demonstrate the prospects of grain boundary engineering with F-BAM for enhanced hydrogen embrittlement resistance of SS. Implications of varying thermokinetics in F-BAM for solidification behavior of SS are discussed. Additionally, microstructural attributes that are key to high temperature mechanical performance of SS are highlighted. Considerations as outlined in this perspective article will enable grain boundary engineering and application specific microstructural design of SS with F-BAM. Graphical abstract

36 MATERIALS SCIENCE↗

Corrosion Behavior of Hydrophobic Coatings in Aqueous CO2 Environments

Internal corrosion is caused by gas impurities such as CO2, moisture, and H2S, leading to material degradation. To combat this, the National Energy Technology Laboratory (NETL) developed a novel hydrophobic coating to reduce surface hydrophobicity and enhance the corrosion resistance of steel. NETL’s approach uses multi-layer hydrophobic coatings, a novel and promising coating that could potentially revolutionize the industry's approach to internal corrosion mitigation. This work aims to investigate the corrosion performance of the hydrophobic coating and determine the water uptake. Electrochemical corrosion experiments were carried out on bare X65 carbon steel without and with coating in 3.5 wt.% NaCl saturated with CO2 at 20 °C to follow the water uptake as a function of exposure time. Linear polarization resistance (LPR) was used to determine the corrosion rate for carbon steel immersed in a NaCl electrolyte saturated with CO2. Electrochemical impedance spectroscopy (EIS) of uncoated and coated bare carbon steel was investigated. The analyses of impedance models and water uptake behaviors of hydrophobic coatings were studied for 200 hours during the corrosion process. The water uptake was estimated using the Brasher and Kingsbury relation. The results showed that the superhydrophobic coating that was developed used innovative nano-based materials to act as protection layers on the surface of metallic parts against mechanical aggressors, corrosion, and fouling agents.

corrosion behavior↗

Do Dominant Ants Affect Secondary Productivity, Behavior and Diversity in a Guild of Woodland Ants?

The degree to which competition by dominant species shapes ecological communities remains a largely unresolved debate. In ants, unimodal dominance–richness relationships are common and suggest that dominant species, when very abundant, competitively exclude non-dominant species. However, few studies have investigated the underlying mechanisms by which dominant ants might affect coexistence and the maintenance of species richness. In this study, we first examined the relationship between the richness of non-dominant ant species and the abundance of a dominant ant species, Formica subsericea, among forest ant assemblages in the eastern US. This relationship was hump-shaped or not significant depending on the inclusion or exclusion of an influential observation. Moreover, we found only limited evidence that F. subsericea negatively affects the productivity or behavior of non-dominant ant species. For example, at the colony-level, the size and productivity of colonies of non-dominant ant species were not different when they were in close proximity to dominant ant nests than when they were away and, in fact, was associated with increased productivity in one species. Additionally, the number of foraging workers of only one non-dominant ant species was lower at food sources near than far from dominant F. subsericea nests, while the number of foragers of other species was not negatively affected. However, foraging activity of the non-dominant ant species was greater at night when F. subsericea was inactive, suggesting a potential mechanism by which some non-dominant species avoid interactions with competitively superior species. Gaining a mechanistic understanding of how patterns of community structure arise requires linking processes from colonies to communities. Our study suggests the negative effects of dominant ant species on non-dominant species may be offset by mechanisms promoting coexistence.

Formicidae↗

A Convergence of Public-Private Benefits in Denver: Surveys and Analyses to Inform Urban Mobility-, Energy-, Infrastructure- and Behavior-Related Innovation: Preprint

Cities, public transit agencies, and new private ride hailing services seek to understand emerging traveler dynamics, the shifting demographics of urban travelers,and new energy-efficient mobility opportunities. This includes exploring how new infrastructure investments, public and private mobility services, and smart-phone mobility apps are reshaping behaviors, demands (e.g. mobility-on-demand services), travel experiences and energy-efficient urban travel preferences. Currently, cities and metropolitan regions are providing and experimenting with many new mobility options, technologies, and personalized information services at the intersection of urban mobility, energy, and infrastructure systems (e.g., new commuter rail). To date, technology alone has not been able to crack the nut of 'creating faster trip times, less congestion, safer streets, and cleaner air for its citizens through fewer cars on the road'. This paper focuses on this gap by offering new concepts and potential for integrated approaches. Accommodating more vehicles miles traveled in cities, without increases in person miles traveled (PMT), could be costly, generating: 1) tremendous demands for new infrastructure, land, road space, materials, and energy; 2) higher traffic fatality risks; and 3) worsening air quality. Therefore, this study focuses on reducing single occupancy vehicle use by enhancing integrated mobility, helping transit and ridehailing increase occupancy in ways that also reduce energy use, and improve quality of life for urban travelers and communities. This study focuses on a survey of urban travelers in Denver, as a representative case study for metropolitan regions experiencing rapid growth, ageing populations, increased urban sprawl, traffic-related delays, and inefficient energy use per PMT.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Understanding Mobility Behavior Using OpenPATH

In this presentation, we present the motivation behind the creation of NRELOpenPATH, what data the tool can collect, how the app works, and how interested parties can set up a deployment for their own project. OpenPATH is unique in it's ability to engage users in longitudinal travel diary collection with a smartphone app. The app allows projects to examine the modes of users travel, as well as the purpose of that travel. Many deployments have examined the way users travel by e-bike, and the app supports data collection across all modes to gain a holistic view of mobility behavior. The app is configurable for each deployment, and we will describe the way in which NREL hosts project deployments of our open-source project. As this presentation is a part of a panel, time for questions will be included.

ADVANCED PROPULSION SYSTEMS,ENERGY PLANNING, POLIC↗

Behavioral Approaches to Improve Consumer Uptake of Inflation Reduction Act Incentives

During this workshop, attendees will suggest how local home improvement contractors can be encouraged to support the roll out of Inflation Reduction Act (IRA) provisions with behavioral insights. Workshop sponsor, NREL, and workshop moderator, Dr. Sussman, will compile audience suggestions for states, local governments, and the US Department of Energy to inform their rollout of the IRA.

behavior↗

Blending Behavioral Science and Physics-Based Models Inform Equitable Decarbonization Pathways in the US Housing Stock: Preprint

A just energy transition is an imperative of the Biden-Harris Administration, emphasizing the equitable distribution of benefits through energy-efficient and decarbonizing household technologies. Understanding the factors that increase a household's willingness to adopt these technologies helps policymakers implement more targeted and effective approaches. Our research addresses this by blending 550,000 housing stock types and energy simulation data with a nationally representative survey on residential technology adoption and decision-making (n=10,000). We identify energy equity gaps across tenure and income, highlighting disparities in energy burdens and insecurity. Findings show that households with prior modification experience are more willing to renovate, suggesting that small-scale retrofit programs could foster greater willingness. Energy secure but burdened homeowners are least willing to modify, highlighting the need to consider energy bill perceptions in policy design. Nearly half of US households that are energy burdened also face energy insecurity, with a significant gap in assistance for low-income households. We emphasize the need to understand household perceptions to improve policy. This research underscores the importance of understanding household behaviors to improve policy effectiveness, offering actionable insights for policymakers to promote equitable housing upgrades and advance a decarbonized future.

behavioral science↗

Oxidation Behavior of Irradiated and Unirradiated NBG-25 Graphite

This presentation discusses The xxidation behavior of irradiated and unirradiated NBG-25 Graphite results of thermogravimetric analysis of same-source specimens from the AGC-1 experiement. Minimal annealing effects, Substantial increase in OR with Irradiation using Conventional Rate Analysis, Apparent Dose Dependency, Examination of Onset (Alternate Analysis) Shows Competing Irradiation Effects, and Similar Test Matrix (without annealing) now under way with NBG-18 Graphite is reviewed.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Identification of Novel, Replicable Genetic Risk Loci for Suicidal Thoughts and Behaviors Among US Military Veterans

Importance: Suicide is a leading cause of death; however, the molecular genetic basis of suicidal thoughts and behaviors (SITB) remains unknown. Objective: To identify novel, replicable genomic risk loci for SITB. Design, Setting, and Participants: This genome-wide association study included 633 778 US military veterans with and without SITB, as identified through electronic health records. GWAS was performed separately by ancestry, controlling for sex, age, and genetic substructure. Cross-ancestry risk loci were identified through meta-analysis. Study enrollment began in 2011 and is ongoing. Data were analyzed from November 2021 to August 2022. Main Outcome and Measures: SITB. Results: A total of 633 778 US military veterans were included in the analysis (57 152 [9%] female; 121 118 [19.1%] African ancestry, 8285 [1.3%] Asian ancestry, 452 767 [71.4%] European ancestry, and 51 608 [8.1%] Hispanic ancestry), including 121 211 individuals with SITB (19.1%). Meta-analysis identified more than 200 GWS (P < 5 × 10 -8 ) cross-ancestry risk single-nucleotide variants for SITB concentrated in 7 regions on chromosomes 2, 6, 9, 11, 14, 16, and 18. Top single-nucleotide variants were largely intronic in nature; 5 were independently replicated in ISGC, including rs6557168 in ESR1, rs12808482 in DRD2, rs77641763 in EXD3, rs10671545 in DCC, and rs36006172 in TRAF3. Associations for FBXL19 and AC018880.2 were not replicated. Gene-based analyses implicated 24 additional GWS cross-ancestry risk genes, including FURIN, TSNARE1, and the NCAM1-TTC12-ANKK1-DRD2 gene cluster. Cross-ancestry enrichment analyses revealed significant enrichment for expression in brain and pituitary tissue, synapse and ubiquitination processes, amphetamine addiction, parathyroid hormone synthesis, axon guidance, and dopaminergic pathways. Seven other unique European ancestry–specific GWS loci were identified, 2 of which (POM121L2 and METTL15/LINC02758) were replicated. Two additional GWS ancestry-specific loci were identified within the African ancestry (PET112/GATB) and Hispanic ancestry (intergenic locus on chromosome 4) subsets, both of which were replicated. Further, no GWS loci were identified within the Asian ancestry subset; however, significant enrichment was observed for axon guidance, cyclic adenosine monophosphate signaling, focal adhesion, glutamatergic synapse, and oxytocin signaling pathways across all ancestries. Within the European ancestry subset, genetic correlations (r > 0.75) were observed between the SITB phenotype and a suicide attempt-only phenotype, depression, and posttraumatic stress disorder. Additionally, polygenic risk score analyses revealed that the Million Veteran Program polygenic risk score had nominally significant main effects in 2 independent samples of veterans of European and African ancestry.

60 APPLIED LIFE SCIENCES↗