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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 667 records · Page 37
All sourcesNASA NTRSDOE OSTI
NASA NTRS2016

The OMICS of Sports & Space: How Genomics is Transforming Both Fields

Join top 10 New York Times Bestseller “The Sports Gene” author David Epstein and NASA Twins Study investigator Christopher E. Mason, Ph.D., in the debate as old as physical competition—nature versus nurture. From personal experience, Epstein tackles the great debate and traces how far science has come in solving this timeless riddle, and how genetics has entered into the field of sports. He’s an investigative science reporter for ProPublica and longtime contributor to Sports Illustrated. Epstein will share insights into performance-enhancing drugs, the lucky genetics that separate a professional athlete from a less talented athlete, and his research into the death of a friend with Hypertrophic Cardiomyopathy (HCM).From an epigenomic viewpoint, Mason examines the benefits and risks for astronauts who face extreme spaceflight conditions and what it means for the future of human space travel. He is an associate professor in the Department of Physiology and Biophysics, The Feil Family Brain and Mind Research Institute (BMRI) & The Institute for Computational Biomedicine at Weill Cornell Medicine. He is also part of the Tri-Institutional Program on Computational Biology and a Medicine Fellow of Genomics, Ethics, and Law in the Information Society Project at Yale Law School.The study of omics shows tremendous potential in prevention, diagnosis and treatment of injuries and diseases but genetic discrimination and molecular privacy concerns are raised in both sports and space.

Reeves, Katherine↗
NASA NTRS2004

Lunar and Planetary Science XXXV: Big Dust, Little Dust, and Aerogel

The titles in this section include: 1) A First Look at Graphite Grains from Orgueil: Morphology, Carbon, Nitrogen and Neon Isotopic Compositions of Individual, Chemically Separated Grains; 2) Discovery of an In-Situ Presolar Silicate Grain with GEMS-Like Composition in the Bishumpur Matrix; 3) Revised Global Accretion Rates of Micrometeorites in the Last Glacial Period; 4) Isotopic Fractionation of Potassium in Stony Cosmic Spherules; 5) Crumbs from the Crust of Vesta: Achondritic Micrometeorites from the South Pole Water Well; 6) Preservation of Micrometeoroid Remains on Solar Cells Returned from Orbit; 7) High Input Rates of Micrometeoritic Sulfur, 'Smoke' Particles and Oligoelements on the Early Earth; 8) High Resolution Confocal Raman Imaging of an IDP; 9) A micro-Raman Survey of 10 IDPs and 6 Carbonaceous Chondrites; 10) Mid- and Far-Infrared Spectroscopy at the Advanced Light Source; 11) Hypervelocity Impact Energy Loss and Track Shape in Aerogels: Theory and Experiment; 12) Fiducial Marks for Location of Particles in Aerogel.

Source record↗
DOE OSTI2020

Recovery of High Purity Rare Earth Elements (REE) from Coal Ash via a Novel Electrowinning Process (Final Report)

The goal of this project was to produce a high purity, separated (>90%) rare earth oxide (REO) product from coal-based sources. This product was achieved using the following three steps: 1. Battelle’s ADP: The ADP process involves pretreatment of ash (milling and caustic leaching), leaching of pretreated ash with nitric acid, roasting of loaded acid solution containing REE, and water leaching of residual from roasting step, resulting in a REE pregnant solution. 2. Solvent Extraction (SX) Upgrading: The SX involves the extraction of REE from a pregnant REE solution using an organic extractant (note after extraction, the aqueous phase was a residual solution and the organic phase contained REE), and stripping of REE from the organic phase product obtained from the extraction using an acid solution (the stripped solution was the final purified product containing REE, organic traces, and traces of other metals for further separation in the electrowinning process). 3. Rare Earth Salts’ (RES) Electrochemical Separation and Purification Process: The staged electrochemical process was separated REO products from the mixed REE solution. Testing by RES was also included in the investigation of options to minimize the solvent extraction steps. This report covers laboratory testing, production of a high purity coal-based REO, process design of the overall REE recovery and purification process, technoeconomic assessment (TEA), and a commercialization plan discussing the overall REE recovery and purification process.

01 COAL, LIGNITE, AND PEAT↗
NASA NTRS2020

IXPE Mission System Concept and Development Status

The Goal of the Imaging X-Ray Polarimetry Explorer (IXPE) Mi SMEX), is to expand understanding of high-energy astrophysical processes and sources, in support of NASA’s first science objective in Astrophysics: “Discover how the universe works.” IXPE, an international collaboration, will conduct X-ray imaging polarimetry for multiple categories of cosmic X-ray sources such as neutron stars, stellar-mass black holes, supernova remnants and active galactic nuclei. The Observatory uses a single science operational mode capturing the X-ray data from the targets. The IXPE Observatory consists of spacecraft and payload modules built up in parallel to form the Observatory during system integration and test. The payload includes three X-ray telescopes each consisting of a polarization-sensitive, gas pixel X-ray detector, paired with its corresponding grazing incidence mirror module assembly (MMA). A deployable boom provides the correct separation (focal length) between the detector units (DU) and MMAs. These payload elements are supported by the IXPE spacecraft which is derived from the BCP-small spacecraft architecture. This paper summarizes the IXPE mission science objectives, updates the Observatory implementation concept including the payload and spacecraft ts and summarizes the mission status since last year’s conference.

Deininger, William D.↗
NASA NTRS2007

Optimisation of the Future Routine Orbit for Mars Express

Mars Express (MEX), the first planetary mission of the European Space Agency (ESA), reached Mars on December 25th 2003. Since then it is performing routine operations. Its operational phase had to cover one Martian year, with the possibility of an extension for a second Martian year (i.e. until November 2007). The end of the mission extension is approaching but, given the good health of the payload instruments and the high science return of the mission, there is a strong will to achieve further extensions. Mars Express is also seen as an important asset, capable to provide relay functions for future Martian missions. The ESA Science Program Committee has recently approved a second extension of the MEX mission until May 2009 and even further extensions are possible. Mars Express has an eccentric quasi-polar orbit with a period of approximately 6.72 hours and a pericentre height of about 300 km. Science observations are mainly performed at pericentre (but not only). In addition the orbit has a resonance of 11 revolutions per 3 Martian days. This means that ground tracks corresponding to orbits separated by 11 revolutions are adjacent, such that a given area can be covered by the on-board camera without leaving gaps. The J2 effect of Mars causes a drift of both ascending node and argument of pericentre. The drift of argument of pericentre makes it possible to observe periodically all Mars latitudes from close distance. Illumination conditions at pericentre are influenced by both the drift of the argument of pericentre and the drift of ascending node, as well as by the rotation of Mars around the Sun. The original MEX routine orbit was optimized for the duration of the nominal mission and extension, such that it produced a balanced share of day-side observations (for the optical instruments) and night-side observations (for the radar). The orbit was thus not optimized for the time beyond the assumed extension. Indeed, the evolution of the ascending node and argument of pericentre would cause in the following years a drift of the pericentre towards night-side observation conditions, hence uninteresting for the optical instruments. In order to prevent this an optimisation process for the future routine orbit has taken place. The share between day-side and night-side observations can be controlled by adjusting the drift of argument of pericentre and ascending node. This can in particular be achieved by changing the semimajor axis, eccentricity and/or inclination. A change of inclination is inefficient compared to a change in semimajor axis and eccentricity, and has therefore been discarded. An in-plane maneuvre can be performed to change both semi-major axis and eccentricity, and thus the period of the orbit. Although an apocentre manoeuvre is cheaper in terms of deltaV, it would result in raising the pericentre height, which is unfavourable for close observations. Hence a pericentre manoeuvre is proposed, which will increase the apocentre height. A repeat cycle is still required to allow mapping areas with adjacent ground tracks, so the change of semimajor axis must result in a new resonance. Resonances 18:5, 25:7 and 7:2 have been considered as potential candidates. The resulting long term evolution of the observation conditions has been analysed. Finally it has been decided to perform a change of orbit to reach the 18:5. Another aspect of the optimisation process is the control of the ground track. The previous MEX reference trajectory included regular maneuvres at every apocentre in order to adjust the orbital period, such that the separation of the ground tracks would be optimal, regardless of the latitude of pericentre. The implementation of the actual delatVs on-board was done partly by optimizing the attitude of reaction-wheel desaturation activities. Despite of it, this strategy has a significant propellant cost, because it prevents to optimize reaction wheel de-saturation activities to minimize propellant consumption. Therore, with the aim at preserving propellant resources for a long time extension it has been agreed to stop the ground-track control. This requires now a more accurate science operation planning, with improved attitude pointing control. Finally, the approach to phase Mars Express to provide back-up relay functions for NASA Phoenix landing is explained. In the context of the routine trajectory optimisation a new requirement for close fly-bys at Phobos, with different observation geometries, has been specified. The approach to fulfill this requirement is explained.

Carranza, Manuel↗
NASA NTRS1989

The art and science of flow control

The ability to actively or passively manipulate a flow field to effect a desired change is of immense technological importance. In this article, methods of control to achieve transition delay, separation postponement, lift enhancement, drag reduction, turbulence augmentation, or noise suppression are considered. Emphasis is placed on external boundary-layer flows although applicability of some of the methods reviewed for internal flows will be mentioned. Attempts will be made to present a unified view of the different methods of control to achieve a variety of end results. Performance penalties associated with a particular method such as cost, complexity, or trade-off will be elaborated.

Gad-El-hak, Mohamed↗
NASA NTRS1996

Histomorphometric study of tibia of rats exposed aboard American Spacelab Life Sciences 2 Shuttle Mission

Tibial bones of rats flown onboard the SLS-2 shuttle mission were studied. Trabecular bone parameters were investigated, including growth plate height, trabecular bone volume, thickness and number, and trabecular separation in the primary and secondary spongiosa. Several histomorphometric changes were noted, allowing researchers to conclude that exposure to microgravity resulted in osteopenia of spongy bone of tibial metaphysis. The roles of bone formation and bone resorption are discussed.

NASA Center ARC↗
NASA NTRS1988

Impact, and its implications for geology

The publication of seminal texts on geology and on meteoritics in the 1790s, laid the groundwork for the emergence of each discipline as a modern branch of science. Within the past three decades, impact cratering has become universally accepted as a process that sculptures the surfaces of planets and satellites throughout the solar system. Nevertheless, one finds in-depth discussions of impact processes mainly in books on the Moon or in surveys of the Solar System. The historical source of the separation between meteoritics and geology is easy to identify. It began with Hutton. Meteorite impact is an extraordinary event acting instantaneously from outside the Earth. It violates Hutton's principles, which were enlarged upon and firmly established as fundamental to the geological sciences by Lyell. The split between meteoritics and geology surely would have healed as early as 1892 if the investigations conducted by Gilbert (1843-1918) at the crater in northern Arizona had yielded convincing evidence of meteorite impact. The 1950s and 1960s saw a burgeoning of interest in impact processes. The same period witnessed the so-called revolution in the Earth Sciences, when geologists yielded up the idea of fixed continents and began to view the Earth's lithosphere as a dynamic array of horizontally moving plates. Plate tectonics, however, is fully consistent with the geological concepts inherited from Hutton: the plates slowly split, slide, and suture, driven by forces intrinsic to the globe.

Marvin, Ursula B.↗
DOE OSTI2021

Direct Chemical Vapor Deposition Synthesis of Porous Single-Layer Graphene Membranes with High Gas Permeances and Selectivities

Single-layer graphene containing molecular-sized in-plane pores is regarded as a promising membrane material for high-performance gas separations due to its atomic thickness and low gas transport resistance. However, typical etching-based pore generation methods cannot decouple pore nucleation and pore growth, resulting in a trade-off between high areal pore density and high selectivity. In contrast, intrinsic pores in graphene formed during chemical vapor deposition are not created by etching. Therefore, intrinsically porous graphene can exhibit high pore density while maintaining its gas selectivity. Here in this work, the density of intrinsic graphene pores is systematically controlled for the first time, while appropriate pore sizes for gas sieving are precisely maintained. As a result, single-layer graphene membranes with the highest H 2 /CH 4 separation performances recorded to date (H 2 permeance > 4000 GPU and H 2 /CH 4 selectivity > 2000) are fabricated by manipulating growth temperature, precursor concentration, and non-covalent decoration of the graphene surface. Moreover, it is identified that nanoscale molecular fouling of the graphene surface during gas separation where graphene pores are partially blocked by hydrocarbon contaminants under experimental conditions, controls both selectivity and temperature dependent permeance. Overall, the direct synthesis of porous single-layer graphene exploits its tremendous potential as high-performance gas-sieving membranes.

chemical vapor deposition↗
DOE OSTI2023

Spatially Distributed Ramp Reversal Memory in VO 2

Ramp‐reversal memory has recently been discovered in several insulator‐to‐metal transition materials where a non‐volatile resistance change can be set by repeatedly driving the material partway through the transition. This study uses optical microscopy to track the location and internal structure of accumulated memory as a thin film of VO 2 is temperature cycled through multiple training subloops. These measurements reveal that the gain of insulator phase fraction between consecutive subloops occurs primarily through front propagation at the insulator‐metal boundaries. By analyzing transition temperature maps, it is found, surprisingly, that the memory is also stored deep inside both insulating and metallic clusters throughout the entire sample, making the metal‐insulator coexistence landscape more rugged. This non‐volatile memory is reset after heating the sample to higher temperatures, as expected. Diffusion of point defects is proposed to account for the observed memory writing and subsequent erasing over the entire sample surface. By spatially mapping the location and character of non‐volatile memory encoding in VO 2 , this study results enable the targeting of specific local regions in the film where the full insulator‐to‐metal resistivity change can be harnessed in order to maximize the working range of memory elements for conventional and neuromorphic computing applications.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Selective Recovery of Critical Minerals from Simulated Electronic Wastes Via Reaction‐Diffusion Coupling

Abstract Atom‐ and energy‐efficient chemical separations are urgently needed to meet the surging demand for critical materials that has strained supply chains and threatened environmental damage. In this study, we used reaction‐diffusion coupling to separate iron, neodymium, and dysprosium ions from model feedstocks of permanent magnets, which are typically found in electronic wastes. Feedstock solutions were placed in contact with a hydrogel loaded with potassium hydroxide and/or dibutyl phosphate, resulting in complex precipitation patterns as the various metal ions diffused into the reaction medium. Specifically, we observed the precipitation of up to 40 mM of iron from the feedstock, followed by the enrichment of 73 % dysprosium, and the extraction of >95 % neodymium product at a further distance from the solution‐gel interface. We designed a series of experiments and simulations to determine the relevant ion diffusivities, D Nd =5.4×10 −10 and D Dy =5.1×10 −10 m 2 /s, and precipitation rates, k Nd =1.0×10 −5 and k Dy =5.0×10 −3 m 9 mol −3 s −1 , which enabled a numerical model to be established for predicting the distribution of products in the reaction medium. Our proof‐of‐concept study validates reaction‐diffusion coupling as an effective and versatile approach for critical materials separations, without relying on ligands, membranes, resins, or other specialty chemicals.

Wang, Qingpu [Physical and Computational Sciences ↗
DOE OSTI2020

Tunable Metal–Organic Frameworks Based on 8-Connected Metal Trimers for High Ethane Uptake

Metal trimers [M 3 (O/OH)](OOCR) 6 are among the most important structural building blocks. From these trimers, a great success has been achieved in the design of 6- or 9-connected framework materials with various topological features and outstanding gas-sorption properties. In comparison, 8-connected trimer-based MOFs are rare. Given multiple competitive pathways for the formation of 6- or 9-connected frameworks, it remains challenging to identify synthetic or structural parameters that can be used to direct self-assembly process towards trimer-based 8-connected materials. Here, we reveal a viable strategy called angle bending modulation for creating a prototypical MOF type based on 8-connected M 3 (OH)(OOCR) 5 (Py-R) 3 trimers, M = Zn, Co, Fe). As a proof of concept, we synthesized six members in this family using three types of ligands (CPM-80, -81, and -82). These materials do not possess open-metal sites and show excellent uptake capacity for various hydrocarbon gas molecules and inverse C 2 H 6 /C 2 H 4 selectivity. CPM-81-Co, made from 2,5-furandicarboxylate and isonicotinate, features selectivity of 1.80 with high uptake capacity for ethane (123 cm 3 /g -1 ) and ethylene (113 cm 3 /g -1 ) at 298 K and 1 bar.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Comparison of MCNP thermal scattering laws to inelastic neutron scattering data

Neutron transport computations employ thermal scattering laws (TSLs) to account for the influence of material structure and collective excitations at low energy (≲ 10 eV). Recent work has been undertaken to improve TSL accuracy and expand the number of available materials in the Evaluated Nuclear Data File (ENDF). However, comparison of TSL to measured data is often sparse. In this work, we present a method to evaluate TSL accuracy in the Monte Carlo N-Particle (MCNP) code by simulating inelastic neutron scattering (INS) measurement and comparing to data. The method is briefly described with example application to the recently released ENDF-VIII TSL library for polyethylene as well as a cryogenic PE TSL we are separately developing.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2022

Revealing aggregation of non-fullerene acceptors in intermixed phase by ultraviolet-visible absorption spectroscopy

Non-fullerene acceptor (NFA) aggregation is crucial in determining bulk-heterojunction (BHJ) organic photovoltaic (OPV) performance. However, it is still a big challenge to characterize the nanostructure of NFAs in the disordered donor-acceptor intermixed phase. Here, we demonstrate a method to characterize NFA aggregation and composition in the intermixed phase by measuring NFA concentration-dependent ultraviolet-visible (UV-vis) absorption spectroscopy of BHJ films. In various polymer:NFA films, an absorption shift as a function of increasing molecular concentration (ASIMC) phenomenon is observed, and different NFA aggregation behaviors can be distinguished. The ASIMC method was then applied to study the influence of processing conditions on the NFA concentration in the intermixed phase of devices to establish a correlation with device efficiency. The current work provides a feasible tool to study the nanostructure of NFAs in the complex polymer matrix and to understand the variations in the NFA concentration in the intermixed phase under non-equilibrium conditions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Selective Crystallization for Green Separations of Lanthanides Using 5-(Pyrimidyl)Tetrazolate

In an effort to develop facile, low-cost, and environmentally benign separations of lanthanides, the coordination chemistry and selective crystallization of Ln 3+ cations with the water-soluble ligand 5-(pyrimidyl)tetrazolate (pmtz) have been investigated. The wide range of coordination modes of pmtz allows for discrimination between these cations, and five distinct compound types can be prepared that are dependent on the lanthanide employed. La 3+ leads to the formation of [La(pmtz) 2 (H 2 O) 6 ]Cl (S1). [Ln(pmtz) 3 (H 2 O) 3 ]·(3+n)H 2 O is obtained with Ce 3+ and Pr 3+ (S2). Ce 3+ can also form [(Ce(pmtz) 2 (H 2 O) 3 ) 2 (μ-pmtz)](pmtz)·11H 2 O (S3). [(Ln(pmtz) 2 (H 2 O) 3 ) 2 (μ-pmtz)] 2 (pmtz) 2 ·14H 2 O (S4) is formed with Nd 3+ and Sm 3+ . Here, the smaller Ln 3+ cations, Dy 3+ to Lu 3+ , all yield [Ln(H 2 O) 8 ](pmtz) 3 ·3H 2 O (S5). This selective crystallization of Ln 3+ cations based primarily on ionic radii provides a simple method for achieving group separations.

Bai, Zhuanling↗
DOE OSTI2020

Interfacial Assembly and Jamming of Polyelectrolyte Surfactants: A Simple Route To Print Liquids in Low-Viscosity Solution

Nanoparticle surfactants (NPSs) assembled at the oil-water interface can significantly lower the interfacial tension and be used to structure liquids. However, to realize the three-dimensional printing of one liquid in another, high-viscosity liquids, for example, silicone oil, have been generally used. In this work, we present a simple, low-cost approach to print water in low-viscosity toluene by using a new type of polyelectrolyte surfactant, sodium carboxymethyl cellulose surfactant (CMCS), that forms and assembles at the oil-water interface. The interfacial activity of CMCSs can be enhanced by tuning parameters, such as pH and concentration, and the incorporation of a rigid ligand affords excellent mechanical strength to the resultant assemblies. With CMCS jammed at the interface, liquids can be easily printed or molded to the desired shapes, with biocompatible walls that can be used to encapsulate and adsorb active materials. This study opens a new pathway to generate complex, all-liquid devices with a myriad of potential applications in biology, catalysis, and chemical separation.

36 MATERIALS SCIENCE↗