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At least 667 records · Page 37

Recovery Act: Hydroelectric Facility Improvement Project - Replacement of Current Mechanical Seal System with Rope Packing System

On January 27, 2010 the City of North Little Rock, Arkansas received notification of the awarding of a Department of Energy (DOE) grant totaling $450,000 in funding from the American Recovery and Reinvestment Act (ARRA) under the Project Title: Recovery Act: Hydroelectric Facility Improvement Project – Automated Intake Clearing Equipment and Materials Management. The purpose of the grant was for improvements to be made at the City’s hydroelectric generating facility located on the Arkansas River. Improvements were to be made through the installation of an intake maintenance device (IMD) and the purchase of a large capacity wood grinder. The wood grinder was purchased in order to receive the tree limbs, tree trunks, and other organic debris that collects at the intake of the plant during high flow. The wood grinder eliminates the periodic burning of the waste material that is cleared from the intake and reduces any additional air pollution to the area. The resulting organic mulch has been made available to the public at no charge. Design discussion and planning began immediately and the wood grinder was purchased in July of 2010 and immediately put to work mulching debris that was gathered regularly from the intake of the facility. The mulch is currently available to the public for free. A large majority of the design process was spent in discussion with the Corps of Engineers to obtain approval for drawings, documents, and permits that were required in order to make changes to the structure of the powerhouse. In April of 2011, the City’s Project Engineer, who had overseen the application, resigned and left the City’s employ. A new Systems Mechanical Engineer was hired and tasked with overseeing the project. The transfer of responsibility led to a re-examination of the original assumptions and research upon which the grant proposal was based. At that point, the project went under review and a trip was booked for July 2011 to visit facilities that currently had an IMD installed. This further study of facilities revealed that the implementation of the project as originally described, while proving the benefits described in the original grant application, would likely intensify sand intake. Increased sand intake would lead to an increase in required shutdowns for maintenance and more rapid depreciation of key equipment which would result in a loss of generation capacity. A better solution to the problem, one that continued to meet the criteria for the original grant and ARRA standards, was developed. A supporting day trip was planned to visit other facilities located on the Arkansas River to determine how they were coping with the same strong amounts of sand, silt, and debris. Upon returning from the trip to other Arkansas River facilities it was extremely clear what direction to go in order to most efficiently address the issue of generator capacity and efficiency. Of the plants visited on the Arkansas River, every one of them was running what is called a rope packing shaft sealing system as opposed to mechanical shaft seals, which the facility was running. Rope packing is a time proven sealing method that has been around for centuries. It has proved to perform very well in dirty water situations just like that of the Arkansas River. In April of 2012 a scope change proposal was submitted to the DOE for approval. In August of 2012 the City received word that the change of scope had been approved. Plans were immediately set in motion to begin the conversion from mechanical seals to a packing box at the facility. Contractors arrived on October 1st, 2012 and the project team began unwatering the unit for disassembly. The seal conversion was completed on February 29th, 2013 with start-up of the unit. Further testing and adjusting was done throughout the first two weeks of March.

13 HYDRO ENERGY↗

Alternate paddle configuration for improved wear resistance in the saltstone mixer

The Saltstone Production Facility has a 10-inch Readco-Kurimoto continuous mixer that mixes the premix dry feeds and low-level waste salt solution to make fresh (uncured) saltstone. Inspection of the mixer in January 2013 showed significant wear on the third, fourth and fifth paddle pairs after the conveying augers. A 2-inch Readco-Kurimoto continuous mixer was used to test alternate paddle configurations for use in the 10-inch mixer to decrease the wear rate on the paddles. Two wear tests were conducted to investigate a method of reducing wear on the mixer paddles. The first test (wear test 2a) had a paddle configuration similar to the currently installed 10-inch mixer in the SPF. This test established baseline wear. The second test (wear test 2b) had a reconfigured paddle arrangement that replaced the flat paddles with helical paddles for paddle pairs 2 - 6 and aligned paddle pair 1 with the augers. The intent of the reconfiguration was to more effectively convey the partially wetted dry feeds through the transition region and into the liquid feed where paddle wear is reduced due to dry feeds and salt solution being mixed at the intended water to premix ratio. The design of the helical paddles provides conveyance through the transition region to the liquid feed inlet. The alignment with the auger is aimed to provide a smoother transition (minimizing the discontinuity between the auger and paddle pair 1) into the downstream paddles. A soft metal with low wear resistance (6000 series aluminum) was used for the wear testing paddles to determine wear patterns while minimizing run time and maximizing wear rate. For the two paddle configurations tested using the scaled 2-inch Readco-Kurimoto continuous mixer, with the first six paddles after the augers replaced by the wear paddles and the remaining paddles were stainless steel. Since the 10-inch SPF mixer is designed with the liquid inlet centered over paddle pairs 5 and 6, the scaled 2-inch mixer was configured the same way. The wear rate from wear test 2a was approximately double the wear rate from wear test 2b for paddle pairs 4 and 5. For both configurations, there was little or no wear on paddle pairs 1, 2, 3 and 6 based on mass change, indicating that the un-wetted and fully wetted premix materials cause less wear than the partially wetted premix. Additionally, inspection of the wear surface of the paddles showed more deformation on the flat paddles than the helical paddles which was consistent with the wear rates. Aligning of the auger discharge flight with paddle pair 1 resulted in a lower wear rate paddle pair 1 rather than having them misaligned with the feed augers. During the paddle wear tests, polishing wear was observed on the inside barrel of the mixer. The polishing wear is evident on the upper housing clamshell and the lower housing clamshell primarily at paddle pairs 4 and 5, which is the transition region of the mixer. Wear on the mixer barrel increases the space between the paddles and the barrel, resulting in increased grout build up on the barrel. Since the mixer barrel cannot be reconfigured or replaced in the SPF, the method for mitigating wear on the barrel is to move the more viscous grout through the transition region as quickly as possible. In addition, the location of the liquid inlet does not allow for sufficient cleaning of the mixer since residual grout remains on paddle pairs 1 - 4. As the paddles continue to wear and the self-cleaning capability of the paddles is lost, the lack of sufficient flushing would aid in grout build up between the barrel and the paddles which could eventually lead to decreased throughput capacity of the dry feeds. Changing the paddle configuration from flat to helical resulted in no change to the rheological properties of the grout mixture. Both tests produced a grout that is within the processing range of the SPF. Based on the results of this testing, it is recommended for the currently installed SPF mixer that paddle pairs 1 through 6 be helical rather than flat, with the paddle pair 1 aligned with the feed augers in order to minimize the wear occurring in the SPF mixer. Based on the results of this testing, it is recommended that the mixer be inspected and critical measurements be taken whenever the SPF processing schedule allows in order to establish a wear rate of the 10-inch mixer paddles.5 Based on these measurements, the lifetime of paddles in the transition region can be established in order to set up a maintenance schedule for the mixer. Since replacing the entire mixer is very expensive and time intensive, replacing the worn paddles after a specific time period would allow for planned shutdowns as well as process optimization such that the mixer throughput is not compromised. In addition, further testing should be performed to determine an alternate liquid inlet location to better flush the mixer of residual grout at the end of processing. Sufficiently cleaning the mixer will help eliminate another potential source of wear. Another potential method for reducing the wear rate in the mixer is to reduce the mixer speed without affecting the throughput capacity. Since wear rate is a function of impact velocity of the grout and mixing paddles, testing could be done using the 2-inch mixer determine the optimum mixer speed to reduce wear but not adversely impact facility operations (e.g. throughput capacity and grout properties).

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Elementary Particle Physics (Final Report)

vATLAS and the LHC are delivering on the promise of discovery physics at the high energy frontier. Using 4.8 fb -1 of 2011 $\sqrt{s}$=7 TeV data and the first 5.8 fb -1 of 2012 $\sqrt{s}$=8 TeV data, ATLAS published the observation of a new particle with a mass of 126 GeV with a significance of 5.9σ that is compatible with a Standard Model (SM) Higgs. The LHC is outperforming initial projections for the 2012 run, and ATLAS is on track to integrate ~20 fb -1 of proton-proton collisions in 2012 before Long Shutdown 1 (LS1) begins in Spring 2013. University of Texas at Dallas (UTD) physicists will complete work on two ATLAS analyses this fall. The first is the search for the gauge bosons of a hypothesized dark sector. For 2011 data, UTD is responsible for the dark photon search in the electron-jet channel, and we are looking forward to an expanded leadership role in the dark photon search using the full 2012 data set. Our second analysis interest is the study of X/Y/Z exotic states having cc content, which builds on our experience in this field from the BABAR experiment After completing a measurement of the Xc(3872) production cross section this fall, we will search for evidence of the Z(4430)+ which is reported by Belle but not confirmed by BABAR. The UTD group has played a strong role in ATLAS operations, with group members serving as Pixel Run Coordinator, ATLAS Shift Leader, and Pixel/Inner Detector Shifter. For most of the current 3-year funding cycle, a group member coordinated the development of the Pixel DAQ code, and another continues to build and maintain the data quality monitoring (DQM) application that is used by the Inner Detector control room shifter. Additionally, members of our group take Pixel on-call expert shifts for DQM and DAQ. We led an optoboard lifetime study to assess concerns of premature on-detector VCSEL failure using the Pixel working prototype detector at CERN. Physicists based at UTD participated through Pixel Offline DQM and ATLAS Distributed Computing Operations Shifts (ADCoS) During Summer 2012, UTD joined upgrade activities in preparation for LS1. We took a major role in the testing of Electro-Readout (ER) Bundle testing for new Service Quarter Panels (nSQPs), and we developed two utilities to measure the timing jitter and bit error rate of the Pixel readout chain for use commissioning Pixel detector upgrades. During BABAR's heyday, the UTD group pioneered the use of e + e - annihilation events with hard Initial State Radiation (ISR) to study the charm threshold region, and we carried out the first BABAR double-cc analysis. Our most recent ISR paper, written in collaboration with A. Palano (Bari) is Exclusive Production of Ds + Ds - , D S *+ Ds - , and Ds *+ Ds *- via e+ e- Annihilation with Initial-State-Radiation was published in Physical Review D 82, 052004 (2010). Work continues on a study of ISR Λc + Λc - production, and a new search to establish and study double-ss production is starting.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Development of Methodologies for Technology Deployment for Advanced Outage Control Centers that Improve Outage Coordination, Problem Resolution and Outage Risk Management

This research effort is a part of the Light-Water Reactor Sustainability (LWRS) Program, which is a research and development (R&D) program sponsored by Department of Energy (DOE) and performed in close collaboration with industry R&D programs that provides the technical foundations for licensing and managing the long-term, safe, and economical operation of current nuclear power plants. The LWRS program serves to help the U.S. nuclear industry adopt new technologies and engineering solutions that facilitate the continued safe operation of the plants and extension of the current operating licenses. The long term viability of existing nuclear power plants in the U.S. will depend upon maintaining high capacity factors, avoiding nuclear safety issues and reducing operating costs. The slow progress in the construction on new nuclear power plants has placed in increased importance on maintaining the output of the current fleet of nuclear power plants. Recently expanded natural gas production has placed increased economic pressure on nuclear power plants due to lower cost competition. Until recently, power uprate projects had steadily increased the total output of the U.S. nuclear fleet. Errors made during power plant upgrade projects have now removed three nuclear power plants from the U.S. fleet and economic considerations have caused the permanent shutdown of a fourth plant. Additionally, several utilities have cancelled power uprate projects citing economic concerns. For the past several years net electrical generation from U.S. nuclear power plants has been declining. One of few remaining areas where significant improvements in plant capacity factors can be made is in minimizing the duration of refueling outages. Managing nuclear power plant outages is a complex and difficult task. Due to the large number of complex tasks and the uncertainty that accompanies them, outage durations routinely exceed the planned duration. The ability to complete an outage on or near schedule depends upon the performance of the outage management organization. During an outage, the outage control center (OCC) is the temporary command center for outage managers and provides several critical functions for the successful execution of the outage schedule. Essentially, the OCC functions to facilitate information inflow, assist outage management in processing information and to facilitate the dissemination of information to stakeholders. Currently, outage management activities primarily rely on telephone communication, face to face reports of status and periodic briefings in the OCC. Much of the information displayed in OCCs is static and out of date requiring an evaluation to determine if it is still valid. Several advanced communication and collaboration technologies have shown promise for facilitating the information flow into, across and out of the OCC. Additionally, advances in the areas of mobile worker technologies, computer based procedures and electronic work packages can be leveraged to improve the availability of real time status to outage managers.

99 GENERAL AND MISCELLANEOUS↗

A RHIC-style IPM in the Brookhaven AGS

Beam profiles in the two storage rings of the Relativistic Heavy-Ion Collider (RHIC) at Brookhaven National Lab (BNL) are measured with ionization profile monitors (IPMs). Each ring has a vertical and horizontal detector. An IPM measures the distribution of electrons produced in the beam line by beam ionization of background gas. These detectors have been developed at BNL in a program that began in 1996. The current detectors are a design that was based on a prototype built in 2007 and used in RHIC from 2007 to 2012. During the 2012 shutdown we refurbished this prototype and installed it into the Alternating-Gradient Synchrotron (AGS). This paper describes the new AGS IPM and shows data from the detector commissioning.

43 PARTICLE ACCELERATORS↗

Data Sharing Report Characterization of Isotope Row Facilities Oak Ridge National Laboratory Oak Ridge TN

The U.S. Department of Energy (DOE) Oak Ridge Office of Environmental Management (EM-OR) requested that Oak Ridge Associated Universities (ORAU), working under the Oak Ridge Institute for Science and Education (ORISE) contract, provide technical and independent waste management planning support using funds provided by the American Recovery and Reinvestment Act (ARRA). Specifically, DOE EM-OR requested ORAU to plan and implement a survey approach, focused on characterizing the Isotope Row Facilities located at the Oak Ridge National Laboratory (ORNL) for future determination of an appropriate disposition pathway for building debris and systems, should the buildings be demolished. The characterization effort was designed to identify and quantify radiological and chemical contamination associated with building structures and process systems. The Isotope Row Facilities discussed in this report include Bldgs. 3030, 3031, 3032, 3033, 3033A, 3034, 3036, 3093, and 3118, and are located in the northeast quadrant of the main ORNL campus area, between Hillside and Central Avenues. Construction of the isotope production facilities was initiated in the late 1940s, with the exception of Bldgs. 3033A and 3118, which were enclosed in the early 1960s. The Isotope Row facilities were intended for the purpose of light industrial use for the processing, assemblage, and storage of radionuclides used for a variety of applications (ORNL 1952 and ORAU 2013). The Isotope Row Facilities provided laboratory and support services as part of the Isotopes Production and Distribution Program until 1989 when DOE mandated their shutdown (ORNL 1990). These facilities performed diverse research and developmental experiments in support of isotopes production. As a result of the many years of operations, various projects, and final cessation of operations, production was followed by inclusion into the surveillance and maintenance (S&M) project for eventual decontamination and decommissioning (D&D). The process for D&D and final dismantlement of facilities requires that the known contaminants of concern (COCs) be evaluated and quantified and to identify and quantify any additional contaminants in order to satisfy the waste acceptance criteria requirements for the desired disposal pathway. Known facility contaminants include, but are not limited to, asbestos-containing material (ACM), radiological contaminants, and chemical contaminants including polychlorinated biphenyls (PCBs) and metals.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Transition Core Properties during Conversion of the NBSR from HEU to LEU Fuel

The transition of the NBSR from HEU to LEU fuel is challenging due to reactivity constraints and the need to maintain an uninterrupted science program, the mission of the NBSR. The transition cannot occur with a full change of HEU to LEU fuel elements since the excess reactivity would be large enough that the NBSR would violate the technical specification for shutdown margin. Manufacturing LEU fuel elements to represent irradiated fuel elements would be cost prohibitive since 26 one-of-a-kind fuel elements would need to be manufactured. For this report a gradual transition from the present HEU fuel to the proposed LEU fuel was studied. The gradual change approach would follow the present fuel management scheme and replace four HEU fuel elements with four LEU fuel elements each cycle. This manuscript reports the results of a series of calculations to predict the neutronic characteristics and how the neutronics will change during the transition from HEU to LEU in the NBSR.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

CRADA Final Report For CRADA NO. CR-12-006 [Operation and Testing of an SO 2 -depolarized Electrolyzer (SDE) for the Purpose of Hydrogen and Sulfuric Acid Production]

Over the past several years, Savannah River National Laboratory (SRNL) has led a team of collaborators under the Department of Energy’s (DOE) nuclear hydrogen production program to develop the Hybrid Sulfur (HyS) Process. HyS is a 2-step water-splitting process consisting of high temperature decomposition of sulfuric acid to generate SO 2 , followed by the electrolysis of aqueous SO 2 to generate hydrogen and sulfuric acid. The latter is fed back into the high temperature reactor. SRNL designed and built an SO 2 -depolarized electrolyzer (SDE) and a test facility. Over 40 SDE’s were tested using different catalysts, membranes and other components. SRNL demonstrated that an SDE could be operated continuously for approximately 200 hours under certain conditions without buildup of sulfur at the SDE’s cathode, thus solving a key technical problem with SDE technology. Air Products and Chemicals, Inc. (APCI) is a major supplier of hydrogen production systems, and they have proprietary technology that could benefit from the SDE developed by SRNS, or some improved version thereof. However, to demonstrate that SRNL’s SDE is a truly viable approach to the electrolyzer design, continuous operation for far greater periods of time than 200 hours must be demonstrated, and the electrolyzer must be scaled up to greater hydrogen production capacities. SRNL and Air Products entered into a Cooperative Research and Development Agreement with the objective of demonstrating the effectiveness of the SDE for hydrogen and sulfuric acid production and to demonstrate long-term continuous operation so as to dramatically increase the confidence in the SDE design for commercial operation. SRNL prepared a detailed technical report documenting previous SDE development, including the current SDE design and operating conditions that led to the 200-hour sulfurfree testing. SRNL refurbished its single cell SDE test facility and qualified the equipment for continuous operation. A new membrane electrode assembly (MEA) was fabricated and installed in the single cell electrolyzer (60 cm 2 active cell area). Shakedown testing was conducted, and several modifications were made to the test facility equipment. Seven different MEAs were used during testing. Beginning on May 20, 2013, SRNL was able to test the SDE continuously for 1200 hours, including 1000 hours under power to generate hydrogen at an average rate of 10.8 liters per hour. The SDE was not removed or repaired during the 50-day test and was successfully restarted after each shutdown. The test was intentionally stopped after 1200 hours (1000 hours of hydrogen production) due to funding constraints. Post-test examination of the MEA using Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray Microanalysis (EDAX) showed no elemental sulfur deposits or sulfur layer inside the cell, thus successfully achieving the test goals. The results demonstrated that the SDE could be operated for extended periods without major performance degradation or the buildup of sulfur inside the MEA. Air Products conducted an assessment of the economic viability of the SDE based on the “as tested” design. The results indicated that the SDE faces significant economic obstacles in its current state. Further development and scale-up are necessary before the SDE is ready for commercialization.

08 HYDROGEN↗

Coastal Ohio Wind Project for Reduced Barriers to Deployment of Offshore Wind Energy

The Coastal Ohio Wind Project was created to establish the viability of wind turbines on the coastal and offshore regions of Northern Ohio. The project’s main goal was to improve operational unit strategies used for environmental impact assessment of offshore turbines on lake wildlife by optimizing and fusing data from the multi-instrument surveillance system and providing an engineering analysis of potential design/operational alternatives for offshore wind turbines. The project also developed a general economic model for offshore WTG deployment to quantify potential revenue losses due to wind turbine shutdown related to ice and avian issues. In a previous phase of this project (Award Number: DE-FG36-06GO86096), we developed a surveillance system that was used to collect different parameters such as passage rates, flight paths, flight directions, and flight altitudes of nocturnal migrating species, movements of birds and bats, and bird calls for assessing patterns and peak passage rates during migration. To derive such parameters we used thermal IR imaging cameras, acoustic recorders, and marine radar Furuno (XANK250), which was coupled with a XIR3000B digitizing card from Russell Technologies and open source radR processing software. The integration yielded a development of different computational techniques and methods, which we further developed and optimized as a combined surveillance system. To accomplish this task we implemented marine radar calibration, optimization of processing parameters, and fusion of the multi-sensor data in order to make inferences about the potential avian targets. The main goal of the data fusion from the multi-sensor environment was aimed at reduction of uncertainties while providing acceptable confidence levels with detailed information about the migration patterns. Another component comprised of an assessment of wind resources in a near lake environment and an investigation of the effectiveness of ice coating materials to mitigate adverse effects of ice formation on wind turbine structures. Firstly, a Zephir LiDAR system was acquired and installed at Woodlands School in Huron, Ohio, which is located near Lake Erie. Wind resource data were obtained at ten measurement heights, 200m, 150m, 100m, 80m, 60m, 40m, 38m, 30m, 20m, and 10m. The Woodlands School’s wind turbine anemometer also measured the wind speed at the hub height. These data were collected for approximately one year. The hub anemometer data correlated well with the LiDAR wind speed measurements at the same height. The data also showed that on several days different power levels were recorded by the turbine at the same wind speed as indicated by the hub anemometer. The corresponding LiDAR data showed that this difference can be attributed to variability in the wind over the turbine rotor swept area, which the hub anemometer could not detect. The observation suggests that single point hub wind velocity measurements are inadequate to accurately estimate the power generated by a turbine at all times since the hub wind speed is not a good indicator of the wind speed over the turbine rotor swept area when winds are changing rapidly. To assess the effectiveness of ice coatings to mitigate the impact of ice on turbine structures, a closed-loop icing research tunnel (IRT) was designed and constructed. By controlling the temperature, air speed, water content and liquid droplet size, the tunnel enabled consistent and repeatable ice accretion under a variety of conditions with temperatures between approximately 0°C and -20°C and wind speeds up to 40 miles per hour in the tunnel’s test section. The tunnel’s cooling unit maintained the tunnel temperature within ±0.2°C. The coatings evaluated in the study were Boyd Coatings Research Company’s CRC6040R3, MicroPhase Coatings Inc.’s PhaseBreak TP, ESL and Flex coatings. Similar overall performance was observed in all coatings tested in that water droplets form on the test articles beginning at the stagnation region and spreading in the downstream direction in time. When comparing ice accumulation characteristics for the four coatings tested, for ice thickness during accumulation the CRC6040R3 had the least, followed by the ESL, Flex, and TP. However, when comparing the coatings’ ability to reduce ice adhesion, the Flex showed the highest adhesion reduction, followed by the ESL, TP and CRC 6040R3 coatings. The ice accumulated on the Flex coated surface shed under gravity when rotated 90 degrees following the tests while the other coatings required application of varying degrees of force to remove the ice. In conclusion, the ice coatings tested were not sufficient in preventing ice accumulation on all surfaces. However, Flex coating shows promise in mitigating ice on the rotor blades under the gravitational and centrifugal forces. Only the effect of gravity in shedding the ice was considered in this study. Further research will be needed to evaluate this coating on rotating blades in the icing tunnel to characterize its effectiveness. Lastly, the development of economic feasibility models used existing approaches adapted for offshore deployment in marine settings to one more suitable for Lake Erie deployment. Two different wind turbine models were tested and dynamic return on investment (ROI) model scenarios were generated. For the purpose of estimating power generation three bladed wind turbines of 3 MW capacity were selected including Model1- Leitwind LTW101-3.000-kW and Model2-Vostro V90-3.0 MW. The analysis were based on the revenue aspect of decision making of deploying wind turbines in the Ohio coastal region. The installation cost, maintenance and operational aspects were disregarded due to unavailability of data. The adjusted varying price (residential and industrial sector) and projected future price of electricity in different years suggested that the Leitwind model could generate $\$ $32.4 million of revenue in 25 years if the supply electricity is in the residential sector, while it would be $\$ $14.7million if the supply is in the industrial sector. For the Vostro model these figures are $\$ $28.6 million for residential sector and $\$ $12.9 million for industrial sector for 25 years.

17 WIND ENERGY↗

Beam-based measurement of the center of the new STAR pipe

During the RHIC Shutdown preceding Run13 for polarized protons, various upgrades were brought to the STAR detector, one of which being the partial installation of the Forward GEM Tracker (FGT). This installation includes a new beam pipe at the center of the detector with an internal radius half the size of what the replaced pipe was, from 40 mm to 20 mm. The following reviews the results of a vertical aperture scans in the STAR interaction region performed at injection energy with both beams, and gives an estimate of the measured transverse offset of the new STAR pipe.

43 PARTICLE ACCELERATORS↗

Accelerator/Experiment Operations - FY 2013

The low-energy and high-energy neutrino beams, the SeaQuest beam, and the Test Beam in the Meson area were shutoff on May 1, 2012 to begin work on the accelerator upgrades for NOvA (ANU), and for overall accelerator system maintenance. The shutdown of the Main Injector ended July 30, 2013, with the startup of the Accelerator systems for commissioning. Vacuum issues in the Main Injector delayed Commissioning and neutrino running until September.

Dixon, R.↗

Analysis of Loss-of-Offsite-Power Events 1998–2012

Loss of offsite power (LOOP) can have a major negative impact on a power plant’s ability to achieve and maintain safe shutdown conditions. Risk analyses performed loss of all alternating current power contributes over 70% of the overall risk at some U.S. nuclear plants. LOOP event and subsequent restoration of offsite power are important inputs to plant probabilistic risk assessments. This report presents a statistical and engineering analysis of LOOP frequencies and durations at U.S. commercial nuclear power plants. The data used in this study are based on the operating experience from fiscal year 1998 through 2012. Frequencies and durations were determined for four event categories: plant-centered, switchyard-centered, grid-related, and weather-related. The EDG failure modes considered are failure to start, failure to load and run, and failure to run more than 1 hour. The component reliability estimates and the reliability data are trended for the most recent 10-year period while yearly estimates for reliability are provided for the entire active period. A statistically significant increase in industry performance was identified for plant-centered and switchyard-centered LOOP frequencies. There is no statistically significant trend in LOOP durations.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

The Decline and Fall of the Superconducting Super Collider (Final Report)

In October 1993 the US Congress terminated the Superconducting Super Collider — at the time the largest pure-science project ever attempted, with a total cost estimated to exceed $10 billion. It was a stunning loss for the US high-energy physics community, which until that moment had perched for decades at the pinnacle of American science. Ever since 1993, this once-dominant scientific community has been in gradual decline. With the 2010 startup of research on the CERN Large Hadron Collider and the 2011 shutdown of the Fermilab Tevatron, world leadership in elementary-particle physics has crossed the Atlantic and returned to Europe.

43 PARTICLE ACCELERATORS↗

Report on LLRF

The RF system for the Pohang Light Source (PLS) storage ring was upgraded for the PLS-II project to improve from 2.5GeV/200mA to 3.0GeV/400mA. The key points of machine upgrade are to implement superconducting RF (SRF) cavities and digital low-level RF (LLRF) system. Two SRF cryomodules with cryogenic system were installed and tested during summer shutdown period of 2012. And the user service beam operation has started with the SRF system since 2013. The RF system is operating at 3.0GeV/200mA with two superconducting RF (SRF) cavities.

Source record↗

Advanced Gasification (Annual Report)

The Advanced Gasification team is addressing many factors that impact the current and future development and deployment of gasification-based power generation. For example, the service life of gasifiers does not meet the performance needs of users, failing to achieve an online gasifier availability of 85-95 percent in utility applications and 95 percent in applications such as chemical production. The inability to meet these goals has created a potential roadblock to widespread acceptance and commercialization of advanced gasification technologies, with refractory liners, sensors, and syngas coolers among key components identified as negatively impacting gasifier availability. Ash originating from impurities in gasifier carbon feedstock is the root cause of many problems; attacking or fouling components, leading to their unplanned shutdowns for repair, replacement, or cleaning. Technology gaps exist in the understanding of how fuel properties impact carbon conversion, slag viscosity, and downstream fouling. Fuel flexibility has potential advantages for gasifier operators to lower fuel cost or impact future carbon emission credits, but operators need to know how feedstock changes impact gasifier operation. Mixed feedstock combinations have not been studied as to how ash properties impact gasifier operation, efficiency, and capacity factors. Further gaps exist in technology which specifically target reducing the cost of multiple and mixed feed stocks at 90 percent capture, including low-rank coal (half the U.S. coal supply) and affordable gas clean-up technology.

Additives↗

AGC-3 Experiment Irradiation Monitoring Data Qualification (Final Report)

The Graphite Technology Development Program will run a series of six experiments to quantify the effects of irradiation on nuclear grade graphite. The third experiment, Advanced Graphite Creep 3 (AGC 3), began with Advanced Test Reactor (ATR) Cycle 152B on November 27, 2012, and ended with ATR Cycle 155B on April 23, 2014. This report documents qualification of AGC 3 experiment irradiation monitoring data for use by the Very High Temperature Reactor (VHTR) Technology Development Office (TDO) Program for research and development activities required to design and license the first VHTR nuclear plant. Qualified data meet the requirements for data collection and use as described in the experiment planning and quality assurance documents. Failed data do not meet the requirements. Trend data may not meet the requirements, but may still provide some useable information. All thermocouples (TCs) functioned throughout the AGC 3 experiment. There was one interval between December 18, 2012, and December 20, 2012, where 10 NULL values were reported for various TCs. These NULL values were deleted from the Nuclear Data Management and Analysis System database. All temperature data are Qualified for use by the VHTR TDO Program. Argon, helium, and total gas flow data were within expected ranges and are Qualified for use by the VHTR TDO Program. Total gas flow was approximately 50 sccm through the AGC 3 experiment capsule. Helium gas flow was briefly increased to 100 sccm during ATR shutdowns. At the start of the AGC 3 experiment, moisture in the outflow gas line was stuck at a constant value of 335.6174 ppmv for the first cycle (Cycle 152B). When the AGC 3 experiment capsule was reinstalled in ATR for Cycle 154B, a new moisture filter was installed. Moisture data from Cycle 152B are Failed. All moisture data from the final three cycles (Cycles 154B, 155A, and 155B) are Qualified for use by the VHTR TDO Program.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Quantity of 135 I released from the AGR-1, AGR-2, and AGR-3/4 experiments and discovery of 131 I at the FPMS traps during the AGR-3/4 experiment

A series of three Advanced Gas Reactor (AGR) experiments have been conducted in the Advanced Test Reactor (ATR) at Idaho National Laboratory (INL). From 2006 through 2014, these experiments supported the development and qualification of the new U.S. tristructural isotropic (TRISO) particle fuel for Very High Temperature Reactors (VHTR). Each AGR experiment consisted of multiple fueled capsules, each plumbed for independent temperature control using a mix of helium and neon gases. The gas leaving a capsule was routed to individual Fission Product Monitor (FPM) detectors. For intact fuel particles, the TRISO particle coatings provide a substantial barrier to fission product release. However, particles with failed coatings, whether because of a minute percentage of initially defective particles, those which fail during irradiation, or those designed to fail (DTF) particles, can release fission products to the flowing gas stream. Because reactive fission product elements like iodine and cesium quickly deposit on cooler capsule components and piping structures as the effluent gas leaves the reactor core, only the noble fission gas isotopes of Kr and Xe tend to reach FPM detectors. The FPM system utilizes High Purity Germanium (HPGe) detectors coupled with a thallium activated sodium iodide NaI(Tl) scintillator. The HPGe detector provides individual isotopic information, while the NaI(Tl) scintillator is used as a gross count rate meter. During irradiation, the 135m Xe concentration reaching the FPM detectors is from both direct fission and by decay of the accumulated 135 I. About 2.5 hours after irradiation (ten 15.3 minute 135m Xe half lives) the directly produced 135m Xe has decayed and only the longer lived 135 I remains as a source. Decay systematics dictate that 135m Xe will be in secular equilibrium with its 135 I parent, such that its production rate very nearly equals the decay rate of the parent, and its concentration in the flowing gas stream will appear to decay with the parent half life. This equilibrium condition enables the determination of the amount of 135 I released from the fuel particles by measurement of the 135m Xe at the FPM following reactor shutdown. In this paper, the 135 I released will be reported and compared to similar releases for noble gases as well as the unexpected finding of 131 I deposition from intentional impure gas injection into capsule 11 of experiment AGR 3/4.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Improved Method for the Production of Tetrahydrofuran From Biomass

Statement of the Problem: Tetrahydrofuran (THF) is a large volume, commodity chemical used as a basic building block for polyurethane stretch fibers (Spandex), other elastomers, solvents for PVC cements, pharmaceuticals, and coatings. Current THF production requires petroleum-based raw materials and significant energy inputs, representing inefficient use of petroleum resources and placing the U.S. at a manufacturing disadvantage compared to chemical manufacturers in other world areas. Pulp and paper manufacture is one of the largest industries in the U.S., representing about 6% of the manufacturing sector of the U.S. GDP. In recent decades, the pulp and paper industry has struggled with a declining market, poor profitability, and competition from other world areas, leading to the shutdown of many U.S. pulp and paper mills, and loss of U.S. employment. The production of chemicals, such as THF from pulp and paper waste hydrolysate, can provide new technologies and products from pulp and paper manufacture which can enhance industry profitability. The iCARD technology will produce and sell THF from selected pulp and paper byproduct hydrolysates without deleterious effect on ongoing pulp production of the mill. Overall Objective: The overall goal of this Small Business Innovation Research Phase II Project was to complete the research, development, and design tasks required to commercialize an innovative technology using catalytic reactive distillation to achieve process intensification for the manufacture of “green” THF from pulp mill waste hydrolysate. The new technology will benefit the U.S. pulp and paper industry by providing new technologies and products from pulp and paper manufacture, which can enhance industry profitability, and increase industry employment. Development of commercially competitive biomass based technologies will reduce consumption of scarce hydrocarbon resources, and improve long term U.S. competitiveness in global markets. Conclusions: The novel catalytic reactive distillation technology successfully demonstrated the technical and economic feasibility of the manufacture of THF production from dilute aqueous biomass solutions. New catalyst compositions were developed with catalytic activity for conversion of furfural to THF which exceed the activity of conventional catalysts by 2 to 3 orders of magnitude. The feasibility of achieving selectivity to the desired THF product approaching 100% was demonstrated. The novel catalysts also demonstrated catalyst stability far superior to conventional furfural decarbonylation catalysts. The novel technology also demonstrated the ability to produce other valuable commercial products such as tetrahydrofurfuryl alcohol, 1,5-pentanediol, 2-methyl furan, and 2-tetrahydromethylfuran as co-products with THF. Based on the use of waste pulp mill hydrolysate as the biomass raw material source, the new technology will produce THF for a total manufacturing cost less than the raw material cost for the hydrocarbon-based feed stocks for conventional THF production. Commercial Applications: Selective catalytic reactive distillation of pulp mill waste hydrolysate will allow commercial production of “green” THF from biomass feedstocks for the production of “green” elastomer fibers, and industrial solvents. The new technology will benefit the U.S. pulp and paper industry by providing new technologies and products from pulp and paper manufacture, which can enhance industry profitability, and increase industry employment. Development of commercially competitive biomass based technologies will reduce consumption of scarce hydrocarbon resources, and improve long term U.S. competitiveness in global markets.

09 BIOMASS FUELS↗