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At least 667 records · Page 37

Dynamic Model Agnostic Reliability Evaluation of Machine-Learning Models Integrated in Instrumentation & Control Systems

In recent years, the field of machine learning (ML), specifically neural networks, has grown significantly and has spurred research in its applicability to digital instrumentation and control systems (DI&C). While ML models have shown promise in operational contexts, the trustworthiness of using such algorithms has not been adequately assessed. Failures of ML integrated systems are not well understood, and the lack of comprehensive risk modeling can degrade the trustworthiness in these systems. In recent reports by the National Institute for Standards and Technology (NIST) [1] and the Nuclear Regulatory Commission (NRC) [2], they indicate that trustworthiness in ML is a critical barrier and will play a vital role in the safe, accountable, and secure operation of intelligent systems. Thus, in this work, we demonstrate a dynamic model-agnostic method to quantify the relative reliability of AI/ML predictions by incorporating out-of-distribution (OOD) detection on the training dataset. It is well documented that most ML algorithms excel at interpolation (or near-interpolation) tasks but experience significant performance degradation at extrapolation. The method, referenced as the Laplacian distributed decay for reliability (LADDR), determines the difference between the operational and training datasets which can used to the relative reliability of AI/ML predictions. LADDR is then demonstrated on a feedforward neural network based digital twin used for the prediction of safety significant factors during a loss-of-flow transient. LADDR is used to demonstrate how training data can be used as evidence to support the relative reliability of ML/AI predictions enhancing the overall trustworthiness of the system.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Assessment of irradiation embrittlement effect on fatigue life of a pressurized-water reactor pressure vessel using the fracture toughness master curve approach

The reactor pressure vessel (RPV) is a critical structural component in pressurized-water reactors, and it is designed to withstand extreme conditions, such as high pressures, elevated temperatures, and prolonged radiation exposure. Ensuring RPV integrity is essential for the safe and reliable long-term operation of nuclear power plants, especially as aging mechanisms such as fatigue and irradiation embrittlement pose increased risks. Fatigue, caused by cyclic thermal and mechanical loading, can lead to crack initiation in localized high-stress regions. Simultaneously, neutron irradiation, particularly in the beltline region, progressively reduces fracture toughness, increasing susceptibility to brittle fracture. These combined effects of fatigue and irradiation embrittlement potentially impact the RPV structural integrity, necessitating fitness-for-service assessments. This study applies the fracture toughness master curve approach to evaluate the impact of irradiation embrittlement on RPV fatigue life. A coupled thermo-mechanical stress analysis identifies critical stress locations under normal service transients, pinpointing regions most vulnerable to fatigue crack initiation and growth. Stress intensity factors for postulated flaws at these locations are calculated, enabling an assessment of fatigue life under irradiated and unirradiated conditions. The results indicate that neutron irradiation embrittlement accelerates the conditions in which a critical crack can form and lead to failure, particularly at lower temperatures. The failure occurs where reduced fracture toughness limits the material’s resistance to crack growth. Axial cracks at nozzle corners are the most life limiting without irradiation, while circumferential cracks demonstrate longer fatigue lives. The findings highlight the importance of incorporating irradiation effects into fatigue life predictions to ensure the long-term structural integrity of RPVs.

22 - GENERAL STUDIES OF NUCLEAR REACTORS↗

Electric Vehicle Supply Equipment (EVSE) Site Assessment Report for the U.S. Army Corps of Engineers Chena Site Near Fairbanks, Alaska

This report presents an analysis of the requirements for charging station installation and electric vehicle operation at the US Army Corps of Engineers - Chena Site, located in a cold weather climate in the Fairbanks North Star Borough, AK. The report includes findings from a site visit, and a detailed electric vehicle (EV) charging site plan with cost estimates. Cost for three 50-ampere pedestal chargers located on the edge of the existing parking lot is estimated at $\$$53,100, and the cost of three 80-ampere chargers is estimated at $\$$89,400. The authors did not assess the cost of a heated garage. The USACE Chena site reaches extreme cold temperatures of -40 Degrees Celsius (-40 Degrees Fahrenheit) and below in a typical winter, often for days on end. Considerations of operating EVs as well as electrical vehicle supply equipment (EVSE) at this site can be applicable to other cold or extremely cold locations. Interviews with EV users in cold climates and a literature review indicated that EVs operate well but have significantly decreased range compared to 21 Degrees Celsius (70 Degrees Fahrenheit) operations. Some strategies such as prewarming the vehicle while it is plugged in and using heated seats and steering wheel instead of cabin heat, can improve cold weather performance. Storing the EV in a garage would mean the battery and cabin are automatically preheated, the battery would not age as rapidly as when the vehicle is stored outside, and problems with charging the vehicle are less likely. Lowest temperate-rated Electric Vehicle Supply Equipment (EVSE), as electric vehicle chargers are known as, are rated to -40 Degrees Celsius (-40 Degrees Fahrenheit), and sometimes malfunction. No EVSE is rated to the temperatures that USACE Chena site experienced for more than a week in winter 2023-4, of -50 Degrees Celsius (-45 Degrees Fahrenheit) and which are typical for the area. If reliability is a must, entities may want to consider a heated garage to minimize potential problems with charging equipment. There is a companion technical report to this titled "Electric Vehicle and Charging Infrastructure Assessment in Cold-Weather Climates: A Case Study of Fairbanks, Alaska" that examines the data on EV and EVSE cold-weather functionality in more detail. (Esparza, Truffer Moudra, and Hodge 2024).

33 ADVANCED PROPULSION SYSTEMS↗

Optimizing the accuracy of viscoelastic characterization with AFM force–distance experiments in the time and frequency domains

Atomic Force Microscopy (AFM) force-distance (FD) experiments have emerged as an attractive alternative to traditional micro-rheology measurement techniques owing to their versatility of use in materials of a wide range of mechanical properties. Here, we show that the range of time dependent behaviour which can reliably be resolved from the typical method of FD inversion (fitting constitutive FD relations to FD data) is inherently restricted by the experimental parameters: sampling frequency, experiment length, and strain rate. Specifically, we demonstrate that violating these restrictions can result in errors in the values of the parameters of the complex modulus. In the case of complex materials, such as cells, whose behaviour is not specifically understood a priori, the physical sensibility of these parameters cannot be assessed and may lead to falsely attributing a physical phenomenon to an artifact of the violation of these restrictions. We use arguments from information theory to understand the nature of these inconsistencies as well as devise limits on the range of mechanical parameters which can be reliably obtained from FD experiments. The results further demonstrate that the nature of these restrictions depends on the domain (time or frequency) used in the inversion process, with the time domain being far more restrictive than the frequency domain. Lastly, we demonstrate how to use these restrictions to better design FD experiments to target specific timescales of a material's behaviour through our analysis of a polydimethylsiloxane (PDMS) polymer sample.

information theory↗

Incorporating FLEX Strategies in Multi-Unit Probabilistic Risk Assessment

The catastrophic Fukushima nuclear accident reminded nuclear community about the possibilities of extreme accident scenarios, including those involving multiple reactor units on the same site. As the responses to the Fukushima accident, the nuclear power industry developed and implemented a series of strategies, including the Diverse and Flexible Coping Strategies (FLEX), to enhance the coping capacities of nuclear power plants (NPPs) under extreme accidents. This study intends to examine the impact of FLEX strategies on the risk from all the reactor units on the same NPP site, including risks from accidents involving a single unit and from accidents involving multiple units. The fundamental, methodological element of this study is Multi-Unit Probabilistic Risk Assessment (MUPRA), which requires a shift in Probabilistic Risk Assessment (PRA) from a “one-reactor-at-a-time” mindset to a “considering all reactors sharing a site as a unity” one. An integrated modeling approach for multi-unit event sequence development will be leveraged to develop MUPRA model and address the intra-unit and inter-unit dependencies. Systems Analysis Programs for Hands-on Integrated Reliability Evaluations (SAPHIRE), a PRA software developed and maintained by Idaho National Laboratory (INL) for the U.S. Nuclear Regulatory Commission (NRC), will serve as the platform for MUPRA modeling. This study selects Loss Of Offsite Power (LOOP) as a representative initiating event, which may occur on a generic two-unit NPP site and impacts both reactor units on the site. First, an MUPRA model, including multi-unit event trees, will be developed to obtain single-unit and multi-unit accident scenarios. Next, different FLEX strategies will be assumed, including FLEX equipment for a unit cannot be used for another unit, FLEX equipment for multiple units can be used in a cross-connected manner, etc. Lastly, the effectiveness of each postulated FLEX strategy will be evaluated by incorporating the corresponding FLEX equipment and deployment logic in the MUPRA model.

99 GENERAL AND MISCELLANEOUS↗

Metals and methylotrophy: Via global gene expression studies

A number of minerals, such as copper, cobalt, and rare earth elements (REE), are essential modulators of microbial one-carbon metabolism. This chapter provides an overview of the gene expression study design and analysis protocols for uncovering REE-induced changes in methylotrophic bacteria. By interrogating relationships and differences in total gene expression induced by mineral micronutrients, a deeper understanding of gene regulation at a systems scale can be gained. With careful design and execution of RNA-sequencing experiments, thorough processing and assessment of read quality can be utilized to assess and adjust for possible biases. Here, by ensuring only quality data are utilized in downstream processes, differential gene expression, overrepresented analyses, and gene-set enrichment analyses provide reliable and reproducible representation of pathways and functions which are being affected by changes in environmental conditions.

59 BASIC BIOLOGICAL SCIENCES↗

Field Experience Detecting PV Underperformance in Real Time Using Existing Instrumentation

Maintenance at large-scale photovoltaic plants employs a mix of preventative and corrective maintenance practices. Large outages, such as an inverter tripping offline, are often easy to detect. More subtle sub-inverter faults and failures can accumulate and go unnoticed for months or years. A software-based fault detection method has been developed to analyze commonly measured data from large-scale PV plants for more timely detection of subtle underperformance. The method has been demonstrated on eight datasets from large-scale plants with high accuracy of detection. Results are validated using aerial infrared scanning. String outages are detected with a true positive rate of 73 percent and tracker issues are detected with a true positive rate of 88 percent. The developed method can be uniformly applied to photovoltaic plants across a range of scales and configurations to assess performance, quickly detect underperformance, and determine the source and location of failures. The results inform and improve operations and maintenance at PV plants, ultimately aiding in improved affordability, reliability, availability, and resiliency of solar electricity.

14 SOLAR ENERGY↗

Spatially-Explicit Prediction of Capacity Density Advances Geographic Characterization of Wind Power Technical Potential

Mounting interest in ambitious clean energy goals is exposing critical gaps in our understanding of onshore wind power potential. Conventional approaches to evaluating wind power technical potential at the national scale rely on coarse geographic representations of land area requirements for wind power. These methods overlook sizable spatial variation in real-world capacity densities (i.e., nameplate power capacity per unit area) and assume that potential installation densities are uniform across space. Here, we propose a data-driven approach to overcome persistent challenges in characterizing localized deployment potentials over broad extents. We use machine learning to develop predictive relationships between observed capacity densities and geospatial variables. The model is validated against a comprehensive data set of United States (U.S.) wind facilities and subjected to interrogation techniques to reveal that key explanatory features behind geographic variation of capacity density are related to wind resource as well as urban accessibility and forest cover. We demonstrate application of the model by producing a high-resolution (2 km × 2 km) national map of capacity density for use in technical potential assessments for the United States. Our findings illustrate that this methodology offers meaningful improvements in the characterization of spatial aspects of technical potential, which are increasingly critical to draw reliable and actionable planning and research insights from renewable energy scenarios.

17 WIND ENERGY↗

Assessment of Training Performance, Degradation and Robustness of Paraffin-Wax Impregnated Nb 3 Sn Demonstrator Under High Magnetic Field

In the context of high-energy physics, the use of Nb 3 Sn superconducting magnets as a cost-effective and reliable technology depends on improvements in the following areas: long development and manufacturing cycles, conductor degradation after thermal cycling, long training, as well as a demonstration in accelerator magnets with a beam aperture of the full potential of modern Nb 3 Sn conductors. In short, performance, robustness, and cost are the three issues to be addressed. The Magnet Development project (MagDev) of the Swiss Accelerator Research and Technology initiative (CHART) at the Paul Scherrer Institute (PSI) aims to contribute to the solutions to each of these issues, re-thinking the manufacturing and design process. Here in our program, every innovation is to be validated by means of a panoply of fast-turnaround tools: from non-powered and powered samples and coils, tested under background field, to low-field subscale magnets and high field short prototypes. This work presents one element in this panoply of R&D vehicles: a stress-managed Nb 3 Sn coil called BigBOX, impregnated with paraffin wax, and tested, through a collaboration with the Magnet Development Program of the United States (US-MDP), in the background field of Brookhaven National Laboratory (BNL)’s common coils dipole DCC17.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Predictive Models and Novel Accelerated Tests for the Reliability of Cell Metallization in Photovoltaic Modules (Final Report)

Studies of metallization corrosion m photovoltaics have mainly been limited to comparisons of modules placed in accelerated chambers to fielded modules [1]. Damp Heat accelerated tests and phenomenological equations [2] are used to assess metallization corrosion without understanding the effect of UV light and temperature and humidity cycles on encapsulant adhesion degradation. The roles of encapsulant in-and out-diffusions of moisture and encapsulant impurities are important. Furthermore, few photovoltaic metallization corrosion studies included the role of bias and leakage currents, which are crucial in the electrochemical reaction of metallization. Leakage currents can highly accelerate the corrosion mechanism and are important to include in the studies of corrosion. In our research plan, we will address the following gaps in the PV community's understanding of metallization corrosion: (1) metallization corrosion with bias, humidity, and impurities in the encapsulant or metallization; (2) humidity diffusion through fresh and degraded encapsulants; and (3) comparison of model predictions with outdoor field modules and SunPower's extensive data for its back-contact and front-contact fleets [2] along with NREL's store of >20 year old modules. Our goal is to build models and accelerated tests to predict long term degradation of metallization corrosion of photovoltaic modules in the field. Our studies will include metals used in c-Si solar cells (Cu, Ag, and Al) and commonly used encapsulants (EV A (ethylene vinyl acetate), TPO (thermoplastic olefin), and silicone).

14 SOLAR ENERGY↗

Adaptive cold-load pickup considerations in 2-stage microgrid unit commitment for enhancing microgrid resilience

In an extended main grid outage spanning multiple days, load shedding serves as a critical mechanism for islanded microgrids to maintain essential power and energy reserves that are indispensable for fulfilling reliability and resiliency mandates. However, using load shedding for such purposes leads to increasing occurrence of cold load pickup (CLPU) events. Here, this study presents an innovative adaptive CLPU model that introduces a method for determining and incorporating parameters related to CLPU power and energy requirements into a two-stage microgrid unit commitment (MGUC) algorithm. In contrast to the traditional fixed-CLPU-curve approach, this model calculates CLPU duration, power, and energy demands by considering outage durations and ambient temperature variations within the MGUC process. By integrating the adaptive CLPU model into the MGUC problem formulation, it allows for the optimal allocation of energy resources throughout the entire scheduling horizon to fulfill the CLPU requirements when scheduling multiple CLPU events. The performance of the enhanced MGUC algorithm considering CLPU needs is assessed using actual load and photovoltaic (PV) data. Simulation results demonstrate significant improvements in dispatch optimality evaluated by the amount of load served, customer comfort, energy storage operation, and adherence to energy schedules. These enhancements collectively contribute to reliable and resilient microgrid operation.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Loss Landscape Analysis for Reliable Quantized ML Models for Scientific Sensing

In this paper, we propose a method to perform empirical analysis of the loss landscape of machine learning (ML) models. The method is applied to two ML models for scientific sensing, which necessitates quantization to be deployed and are subject to noise and perturbations due to experimental conditions. Our method allows assessing the robustness of ML models to such effects as a function of quantization precision and under different regularization techniques -- two crucial concerns that remained underexplored so far. By investigating the interplay between performance, efficiency, and robustness by means of loss landscape analysis, we both established a strong correlation between gently-shaped landscapes and robustness to input and weight perturbations and observed other intriguing and non-obvious phenomena. Our method allows a systematic exploration of such trade-offs a priori, i.e., without training and testing multiple models, leading to more efficient development workflows. This work also highlights the importance of incorporating robustness into the Pareto optimization of ML models, enabling more reliable and adaptive scientific sensing systems.

Baldi, Tommaso [Pisa, Scuola Normale Superiore]↗

Decomprolute is a benchmarking platform designed for multiomics-based tumor deconvolution

Tumor deconvolution is a reliable way to disentangle the diverse cell types that comprise solid tumors. To date, however, both the algorithms developed to deconvolve tumor samples, and the gold standard datasets used to assess the algorithms are geared toward the analysis of gene expression (e.g., RNA-seq) rather than protein levels in tumor cells. While gene expression is less expensive to measure, protein levels provide a more accurate view of immune markers. To facilitate the development as well as improve the reproducibility and reusability of multi-omic deconvolution algorithms, we introduce Decomprolute, a Common Workflow Language framework that leverages containerization to compare tumor deconvolution algorithms across multiomic data sets. Decomprolute incorporates the large-scale multiomic data sets produced by the Clinical Proteomic Tumor Analysis Consortium (CPTAC), which include matched mRNA expression and proteomic data from thousands of tumors across multiple cancer types to build a fully open-source, containerized proteogenomic tumor deconvolution benchmarking platform. The platform consists of modular architecture and it comes with well-defined input and output formats at each module. As a result, it is robust and extendable easily with additional algorithms or analyses. The platform is available for access and use at http://pnnl-compbio.github.io/decomprolute.

60 APPLIED LIFE SCIENCES↗

Resilience of uranium mononitride/zirconium carbide composites and uranium-zirconium carbonitride in hot hydrogen for nuclear thermal propulsion

Nuclear thermal rockets require fuels capable of withstanding flowing hydrogen propellant up to 3200 K. Presently, there has not been a fuel type that reliably operates at these conditions. A promising candidate anticipated to endure this demanding environment is a ceramic-ceramic composite comprising of uranium mononitride and zirconium carbide. Further, this investigation assesses the behavior and resilience of variations of this composite and its resultant homogenized form (uranium-zirconium carbonitride) under two hot hydrogen conditions (2273 K and 3000 K). The findings revealed that composites that homogenize into UZrCN exhibit superior structural integrity in hydrogen compared to heterogeneous counterparts. Consequently, this study underscores the potential of homogenized uranium-zirconium carbonitride for enhanced performance in nuclear thermal propulsion applications.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Comparative Density Functional Theory Study of Magnetic Exchange Couplings in Dinuclear Transition-Metal Complexes

Multicenter transition-metal complexes (MCTMs) with magnetically interacting ions have been proposed as components for information-processing devices and storage units. For any practical application of MCTMs as magnetic units, it is crucial to characterize their magnetic behavior, and in particular, the isotropic magnetic exchange coupling, J, between its magnetic centers. Due to the large size of typical MCTMs, density functional theory is the only practical electronic structure method for evaluating the J coupling. Here, we assess the accuracy of different density functional approximations for predicting the magnetic couplings of eight dinuclear transition-metal complexes, including five dimanganese, two dicopper, and one divanadium with known reliable experimental J couplings spanning from ferromagnetic to strong antiferromagnetic. The density functionals considered include global hybrid functionals which mix semilocal density functional approximations and exact exchange with a fixed admixing parameter, six local hybrid functionals where the admixing parameters are extended to be spatially dependent, the SCAN and r 2 SCAN meta-generalized gradient approximations (GGAs), and two widely used GGAs. We found that global hybrids tested in this work have a tendency to over-correct the error in magnetic coupling parameters from the Perdew–Burke–Ernzerhof (PBE) GGA as seen for manganese complexes. The performance of local hybrid density functionals shows no improvement in terms of bias and is scattered without a clear trend, suggesting that more efforts are needed for the extension from global to local hybrid density functionals for this particular property. The SCAN and r 2 SCAN meta-GGAs are found to perform as well as benchmark global hybrids on most tested complexes. We further analyze the charge density redistribution of meta-GGAs as well as global and local hybrid density functionals with respect to that of PBE, in connection to the self-interaction error or delocalization error.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Downscaled Daily 1 km Climate Data (NEX-GDDP-CMIP6) for Southeast Texas. Full ensemble of downscaled CMIP6 climate projections at 1 km daily resolution.

For the SETx-UIFL, the daily NASA Earth Exchange Global Daily Downscaled Projections (NEX-GDDP-CMIP6) dataset climate projections were downscaled from approximately 27 km to 1 km. The SETx dataset provides very high-resolution climate data for the historical period (1950–2014) and future scenarios derived from CMIP6 global models under the four Tier 1 Shared Socioeconomic Pathways (SSPs 1.26, 2.45, 3.70, and 5.85), developed for the IPCC Sixth Assessment Report. A subset of ten NEX-GDDP-CMIP6 models was selected to represent a balance of model families, climate sensitivities, and availability across scenarios, ensuring a diverse and reliable ensemble for regional analysis. Selected models: BCC-CSM2-MR, CESM2, CMCC-ESM2, CNRM-ESM2-1, EC-Earth3, FGOALS-g3, GFDL-CM4, MPI-ESM1-2-HR, MRI-ESM2-0, NorESM2-MM. Daily variables downscaled include tasmax, tasmin, tas, pr, hurs, huss, rsds, rlds, and sfcWind.

Persad, Geeta↗

CCF Parameter Estimations, 2020 Update

This report documents the quantitative results of the common-cause failure (CCF) data collection effort (which included data through 2020) and summarizes the results of the parameter estimation quantification process performed on CCF data in the U.S. Nuclear Regulatory Commission (NRC) CCF database. This is the 2020 update to NUREG/CR-5497, updating data and parameter estimations for CCFs. This release, CCF Parameter Estimation 2020, reflects the CCF data contained within the CCF database, https://rads.inl.gov/Pages/CCF.aspx, by executing (in August 2021) the CCF query rules in the folder SPAR Rules 2020. The data covers the period from 1/1/2006 to 12/31/2020, the most recent 15-year period in which data are available. The use of the most recent rolling 15-year data in parameter estimation differs from previous updates, in which 1/1/1997 was used as the starting date (e.g., 1/1/1997 to 12/31/2015 for the 2015 update, 1/1/1997 to 12/31/2012 for the 2012 update). The new date range (i.e., the most recent 15-year period), was selected for this CCF update so as to be consistent with the date range chosen for the component reliability parameter estimation, and with the effort to include sufficient data for analysis while simultaneously reflecting the most recent industry performance. These results are appropriate for use in probabilistic risk assessment (PRA) studies, including the Standardized Plant Analysis Risk (SPAR) models of commercial nuclear power plants (NPPs) in the U.S. This update may be referred as: U.S. Nuclear Regulatory Commission, "CCF Parameter Estimations, 2020 Update," https://nrcoe.inl.gov/publicdocs/CCF/ccfparamest2020.pdf, November 2021.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Constitutive Model Development for Aging Polymer Encapsulants (ASC P&EM FY2021 L2 Milestone 7836)

This SAND report fulfills the completion requirements for the ASC Physics and Engineering Modeling Level 2 Milestone 7836 during Fiscal Year 2021. The Sandia Simplified potential energy clock (SPEC) non-linear viscoelastic constitutive model was developed to predict a whole host of polymer glass physical behaviors in order to provide a tool to assess the effects of stress on these materials over their lifecycle. Polymer glasses are used extensively in applications such as electronics packaging, where encapsulants and adhesives can be critical to device performance. In this work, the focus is on assessing the performance of the model in predicting material evolution associated with long-term physical aging, an area that the model has not been fully vetted in. These predictions are key to utilizing models to help demonstrate electronics packaging component reliability over decades long service lives, a task that is very costly and time consuming to execute experimentally. The initiating hypothesis for the work was that a model calibration process can be defined that enables confidence in physical aging predictions under ND relevant environments and timescales without sacrificing other predictive capabilities. To test the hypothesis, an extensive suite of calibration and aging data was assembled from a combination of prior work and collaborating projects (Aging and Lifetimes as well as the DoD Joint Munitions Program) for two mission relevant epoxy encapsulants, 828DGEBA/DEA and 828DGEBA/T403. Multiple model calibration processes were developed and evaluated against the entire set of data for each material. A qualitative assessment of each calibration's ability to predict the wide range of aging responses was key to ranking the calibrations against each other. During this evaluation, predictions that were identified as non-physical, i.e., demonstrated something that was qualitatively different than known material behavior, were heavily weighted against the calibration performance. Thus, unphysical predictions for one aspect of aging response could generate a lower overall rating for a calibration process even if that process generated better quantitative predictions for another aspect of aging response. This insurance that all predictions are qualitatively correct is important to the overall aim of utilizing the model to predict residual stress evolution, which will depend on the interplay amongst the different material aging responses. The DSC-focused calibration procedure generated the best all-around aging predictions for both materials, demonstrating material models that can qualitatively predict the whole host of different physical aging responses that have been measured. This step forward in predictive capability comes from an unanticipated source, utilization of calorimetry measurements to specify model parameters. The DSC-focused calibration technique performed better than compression-focused techniques that more heavily weigh measurements more closely related to the structural responses to be predicted. Indeed, the DSC-focused calibration procedure was only possible due to recent incorporation of the enthalpy and heat capacity features into SPEC that was newly verified during this L2 milestone. Fundamentally similar aspects of the two material model calibrations as well as parametric studies to assess sensitives of the aging predictions are discussed within the report. A perspective on the next steps to the overall goal of residual stress evolution predictions under stockpile conditions closes the report.

36 MATERIALS SCIENCE↗