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At least 667 records · Page 37
All sourcesNASA NTRSDOE OSTI
NASA NTRS1983

Investigation of the feasibility of temperature profiling optical diagnostics in the SSME fuel pre-burner

Results of an analytical investigation to determine the feasibility of temperature profiling in the space shuttle main engine (SSME) fuel preburner are presented. In this application it is desirable to measure temperature in the preburner combustor with a remote, nonintrusive optical technique. Several techniques using laser excitation were examined with a consideration of the constraints imposed by optical access in the fuel preburner and the problems associated with operation near the functioning space shuttle engine. The potential performance of practical diagnostic systems based on spontaneous Raman backscattering, laser induced fluorescence, and coherent anti-Stokes Raman spectroscopy were compared analytically. A system using collection of spontaneous Raman backscattering excited by a remotely located 5 to 10 watt laser propagated to the SSME through a small diameter optical fiber was selected as the best approach. Difficulties normally associated with Raman scattering: weak signal strength and interference due to background radiation are not expected to be problematic due to the very high density in this application, and the low flame luminosity expected in the fuel rich hydrogen oxygen flame.

Shirley, J. A.↗
NASA NTRS1983

Influence of suspended inorganic sediment on airborne laser fluorosensor measurements

The results of Poole and Esaias (1982) are presently extended to an examination of the influence of inorganic sediment on the water Raman normalization procedure, as well as an assessment of the potential for using the Raman signal to monitor surface water attenuation properties. An optically perfect lidar system is assumed which has geometric properties representative of the Airborne Oceanographic Lidar, and is mounted on an airborne platform flying at an altitude of 150 m above the water surface. The results obtained suggest that caution should be exercised in attempts to quantitatively monitor changes in optical attenuation by means of remote measurements of the Raman scattering signal.

Poole, L. R.↗
NASA NTRS1984

Stationary and non-stationary nonlinear optical spectroscopy on surface polaritons

A phenomenological theory is given for non-stationary electromagnetic surface waves propagating along the boundary plane between two homogeneous isotropic media. The description of nonlinear optical effects using shortened wave equations is demonstrated for spontaneous and simulated Raman scattering processes on surface polaritons.

Ponath, H. E.↗
NASA NTRS1983

Coupling of radiation into thin film modes by means of localized plasma resonances

The interaction between the surface plasmon mode that propagates at a metal dielectric interface and the localized plasma resonances (LPR) is investigated experimentally in Ag-island films. A stair-stepped sample geometry comprising a glass substrate, a continuous 50-nm Ag film, an LiF spacer film of thickness d = 5-60 nm, and an Ag-island film of mass thickness 3 nm is used in near-normal-reflectivity and plasmon-propagation-constant (k) determinations. The results are presented graphically and discussed. The overall shape of the reflectivity curves is found to be characteristic of Ag films, but with a dip at about 400 nm (corresponding to the absorption resonance of the island film) which is most pronounced with d = 25 nm. It is inferred that the island resonances are strongly coupled to a continuous-film dissipative mechanism at this d value. This inference is supported by the fact that the variation in k, correctd for LiF effects and plotted as a function of d, is greatest at around d = 25 nm. The implications of this finding for broad-band coupling into a thin-film mode, LPR enhancement of waveguide nonlinear effects, and new surface-enhanced-Raman-scattering geometries are indicated.

Holland, W. R.↗
NASA NTRS1984

CARS system for turbulent flame measurements

Simultaneous nitrogen number density and rotational-vibrational temperatures were measured in a turbulent diffusion flame with a Coherent Anti-Stokes Raman Scattering (CARS) instrument. The fuel jet was diluted with nitrogen (20 percent by volume) to allow temperature measurements across the entire jet mixing region. These measurements were compared with fluid dynamics computations. The CARS system incorporated a neodymium YAG laser, an intensified silicon photodiode array detector, and unique dynamic range enhancement methods. Theoretical calculations were based on a parabolic Navier-Stokes computer code. The comparison of these techniques will aid their development in the study of complex flowfields.

Antcliff, R. R.↗
NASA NTRS1984

Applications of excimer lasers for atmospheric species measurements

Excimer lasers are proven sources of high pulse energy and high average power coherent radiation at several wavelength regions throughout the ultraviolet spectrum. If designed properly, excimer lasers can be operated with both low divergence and narrow spectral bandwidth, and using an oscillator - injection-locked amplifier configuration they can be tuned over a 10 to 20 A bandwidth without appreciable loss in energy. Additional wavelength coverage from excimer lasers can be obtained by stimulated Raman scattering. With the development of magnetic switching for the high voltage, high power switches, the electric discharge excimer laser can also be operated reliably for extended periods of time at high pulse rates. All these features make excimer lasers ideal sources of ultraviolet radiation for a variety of remote and in-situ atmospheric species measurements.

Laudenslager, J. B.↗
NASA NTRS1984

Combustion diagnostics by nonintrusive methods; Thermophysics Conference, 18th, Montreal, Canada, June 1-3, 1983, Selected Papers

The state of the art in coherent anti-Stokes Raman scattering (CARS) and laser-induced fluorescence (LIF) is outlined, and current diagnostic capabilities in particle and combustion diagnostics are demonstrated. The development and application of CARS to combustion systems is discussed, and the use of LIF for flow diagnostics is addressed. Nonintrusive particle diagnostics is treated, and a variety of nonintrusive techniques applied to combustion environments is considered.

Mccay, T. D.↗
NASA NTRS1986

Vibration-Free Raman Doppler Velocimeter

New method under development to measure flow velocity of molecules directly by nonintrusive laser techniques. This method, combined with vibration-free design, makes flow-velocity measurements practical in severe vibrational environments. Raman scattering and retroreflection combine to yield useful technique for wind-tunnel gas-flow mapping. Nonintrusive measurements of gas velocity, temperature, and pressure possible in highly vibrational environment.

Exton, R. J.↗
NASA NTRS1984

Absolute spectrophotometry of Titan, Uranus, and Neptune 3500-10,500 A

The present absolute measurements of Titan, Uranus and Neptune geometric albedo spectra in the 3500-10,500 A range have a resolution of about 7 A, together with high SNR, in virtue of the exceptional effeciency of the spectrograph and Reticon detector employed. The high precision and spectral resolution of the data, which are in excellent agreement with the Uranus albedo measurements of Lockwood et al. (1983), make possible quantitative measurements of the effects of Raman scattering by H2 in the Uranus and Neptune atmospheres.

Neff, J. S.↗
NASA NTRS1983

Calculation of high-pressure phase transitions in solid N2 and the pressure dependence of intramolecular mode frequencies

A calculation that minimizes the energy of solid N2 with respect to a rhombohedral distortion of the Pm 3n structure shows that a low-temperature phase transition occurs into the R 3c calcite structure at P = 19.2 kbar with a volume change of 0.125 cu cm/mole. This transition agrees with recent Raman scattering measurements. Another transition from R 3c into R3(bar)m is predicted at P = 67.5 kbar, with a volume change of 0.1 cu cm/mole. The pressure dependence of the intramolecular mode frequencies for the R 3c structure are in reasonably good agreement with the two main branches observed experimentally.

Chandrasekharan, V.↗
NASA NTRS1985

Multiple Raman up-conversion of radiation from pre-existing Langmuir turbulence

Little is known regarding the mechanisms involved in the production of radiation at frequencies which are much higher than the maximum plasma frequency in nonmagnetic plasmas. It is pointed out that radiation at high multiples of the plasma frequency has been observed in laser-pellet experiments, in relativistic beam-plasma interactions, and in low-energy beam-plasma interactions. Radiation at twice the plasma frequency can be produced by coalescence of two Langmuir waves. Another approach is based on radiation near the plasma frequency or its second harmonic, produced by instability or by external sources. Raman scatter from preexisting Langmuir turbulence is permitted repeatedly. At each step such scattering will produce frequency upshifts (anti-Stokes process) and downshifts (Stokes process). The present paper is concerned with this process. Attention is given to equilibrium spectra, analytic approximations, laser-plasma interaction and coherent radiation from relativistic electron beams.

Russell, D.↗
NASA NTRS1984

Optical properties and photoexcitation of a novel liquid form of soluble polyacetylene

Optical absorption, fluorescence emission, Raman scattering, and time-resolved emission experiments are reported on a new liquid form of soluble polyacetylene. This liquid consists of separate polyene chains, grown on activated sites of a polybutadiene chain. The depolarization ratios as well as the time-resolved spectrum of the secondary emission were measured. The relevant spectral features are discussed and analyzed in terms of the lack of interchain interactions which characterize the polymer in solution.

Tubino, R.↗
NASA NTRS1986

Remote detection of OH

This is a remote measurement technique utilizing a XeCl excimer laser tuned to the Q sub 21 1 rotational transition of the 0-0, A-X band at 307.847 nm. A wavemeter is under development to monitor, on a pulse-to-pulse basis, both the laser lineshape and absolute wavelength. Fluorescence is detected with a multiple Fabry-Perot type filter with a spectral resolution on the order of 0.001 nm. This is tuned to the overlapping Q sub 2 2, Q sub 12 2, Q sub 2 3, and Q sub 12 3 rotational transitions at 308.986 nm. The fringe pattern from this filter is imaged using a discrete, multi-anode detector which has a photon gain of 10 to the 8th power. This permits the simultaneous monitoring of OH fluorescence, N2 and/or O2 rotational Raman scattering and broadband background levels. The use of three etalons in series provides sufficient rejection, approx. greater than 10 to the 10th power, against the laser radiation only 1.2 nm away.

Mcdermid, I. Stuart↗
NASA NTRS1986

Multispecies CARS measurements in turbulent combustion

A coherent anti-Stokes Raman scattering (CARS) instrument was upgraded to more accurately measure the number density of oxygen molecules. This instrument is designed to simultaneously measure nitrogen number density, oxygen number density, and the ro-vibrational temperature of nitrogen. The CARS is a nonintrusive diagnostic technique which utilizes a pulsed Nd:YAG laser, broadband dye lasers, a complex optical system, and an intensified photodiode array detector to sample hostile combustion environments. Measurements were made in a flame produced by a coaxial subsonic diffusion hydrogen-air burner. These data were used as a data base for comparison with the results of two separate computational fluid dynamics calculations. Complications which had arisen in previous studies with regard to interpretation of the oxygen data were eliminated.

Antcliff, Richard R.↗
NASA NTRS1986

The geometric albedos of Uranus and Neptune between 2100 and 3350 A

Results are reported from large aperture IUE observations of the stratospheres of Uranus and Neptune. The data were collected using 16 Cyg A and B as solar analog stars. The spectra observed were similar to geometric albedos of the predicted in terms of Rayleigh-Raman scattering in the 2200-2800 A region. A falloff was observed near visible wavelengths, a factor which might be attributable to low-altitude haze absorbing in the 3000-4000 A interval. The data also indicated that the Uranus stratosphere does not strongly absorb UV radiation, and is not a good heating source. The stratospheric haze constituents over Uranus could therefore be condensates of CH4 and H2 photochemistry.

Wagener, R.↗
NASA NTRS1986

Laser remote sensing of the atmosphere

A guide to the extant literature concerning remote sensing of the atmosphere by laser-based devices is presented, with emphasis on surveys of the field as well as the most important recent results. Topics surveyed include measurements of aerosol constituents using lidar, the differential absorption lidar technique, the use of laser long-path differential absorption, Raman scattering techniques, and fluorescence lidar techniques. Special attention is given to measuring wind velocity using CO2 heterodyne lidar systems.

Grant, William B.↗
NASA NTRS1987

Laser remote sensing techniques

The properties and advantages of remote sensing lasers are discussed. The theory of nonresonant techniques, which is based on the lidar equation and elastic backscatter, and their applications to aerosol and meteorological parameters are examined. The characteristics and applications of the differential absorption lidar technique, the fluorescence technique, and Raman scattering are described. The use of a laser heterodyne radiometer and fiber optics for remote sensing is studied. Future developments in the field of remote sensing, in particular the improvement of laser sources, the fabrication of compact remote sensing instruments, and space-borne applications for lidar, are considered.

Grant, William B.↗
NASA NTRS1987

Laser techniques in high-pressure geophysics

Laser techniques in conjunction with the diamond-anvil cell can be used to study high-pressure properties of materials important to a wide range of problems in earth and planetary science. Spontaneous Raman scattering of crystalline and amorphous solids at high pressure demonstrates that dramatic changes in structure and bonding occur on compression. High-pressure Brillouin scattering is sensitive to the pressure variations of single-crystal elastic moduli and acoustic velocities. Laser heating techniques with the diamond-anvil cell can be used to study phase transitions, including melting, under deep-earth conditions. Finally, laser-induced ruby fluorescence has been essential for the development of techniques for generating the maximum pressures now possible with the diamond-anvil cell, and currently provides a calibrated in situ measure of pressure well above 100 gigapascals.

Hemley, R. J.↗