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At least 667 records · Page 37

Numerical study of effect of secondary electron emission on discharge characteristics in low pressure capacitive RF argon discharge

Based on the drift and diffusion approximation theory, a 1D fluid model on capacitively coupled RF argon glow discharge at low pressure is established to study the effect of secondary electron emission (SEE) on the discharge characteristics. The model is numerically solved by using a finite difference method and the numerical results are obtained. The numerical results indicate that when the SEE coefficient is larger, the plasma density is higher and the time of reaching steady state is longer. It is also found that the cycle-averaged electric field, electric potential, and electron temperature change a little as the SEE coefficient is increased. Moreover, the discharge characteristics in some nonequilibrium discharge processes with different SEE coefficients have been compared. The analysis shows that when the SEE coefficient is varied from 0.01 to 0.3, the cycle-averaged electron net power absorption, electron heating rate, thermal convective term, electron energy dissipation, and ionization all have different degrees of growth. While the electron energy dissipation and ionization are quite special, there appear two peaks near each sheath region in the discharge with a relatively larger SEE coefficient. In this case, the discharge is certainly operated in a hybrid α-γ-mode.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Studies on Nd{sub x}In{sub 1−x}O{sub 3} semiconducting thin films prepared by rf magnetron sputtering

Neodymium-substituted indium oxide (Nd{sub x}In{sub 1−x}O{sub 3}, NIO) semiconducting thin films fabricated by rf sputtering were investigated. It was found that the incorporation of Nd atoms would lead to broadening the optical band gap, suppressing the grain growth, and reducing the free carrier concentration. The field-effect transistors with different NIO (5%, 15%, and 25% Nd concentration of the targets) channel layers exhibited similar electrical stability under positive gate-bias-stress, but the ones with 15% and 25% Nd concentration displayed much better stability under negative gate-bias-stress. Detailed studies showed that the content of |Nd3d{sub 5/2}{sup 5}4f{sup 4}O2p{sup −1}> electron configuration decreased as the Nd concentration increased, resulting in the reduction of holes during negative-bias-stress. And the reduction of the |Nd3d{sub 5/2}{sup 5}4f{sup 4}O2p{sup −1}> content as the Nd concentration increased was ascribed to less overlap between the metal and ligand orbitals arose from large lattice expansion.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Dust particles under the influence of crossed electric and magnetic fields in the sheath of an rf discharge

Experimental studies on the interaction of micron-sized dust particles in plasmas with external magnetic fields are presented. The particles are levitated in the sheath region of an rf discharge by gravity and electric field force under the presence of a horizontal magnetic field of up to 50 mT. It is observed that the dust particles are pushed either in the E{sup →}×B{sup →}- or in the opposite direction depending on magnetic field strength, particle properties, and discharge conditions. This transport behavior is described by a competition between horizontal ambipolar electric field force and ion and neutral drag.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Nanostructured and wide bandgap CdS:O thin films grown by reactive RF sputtering

In this study, CdS:O thin films were prepared from a 99.999% CdS target by reactive sputtering in a Ar:O{sub 2} (99:1) ambient with different RF power at room temperature. The deposited films were studied by means of XRD, SEM, EDX, Hall Effect and UV-Vis spectrometry. The incorporations of O{sub 2} into the films were observed to increase with the decrease of deposition power. The cryatallinity of the films were reduced, whereas the band gaps of the films were increased by the increase of O{sub 2} content on the films. The films were found in nano-structured grains with a compact surface. It has been seen that the highest carrier density is observed in the film with O{sub 2} at.% 21.10, while the values decreased with the further increase or decrease of O{sub 2} content on the films; indicating that specific amount of donor like O{sub 2} atoms substitute to the S atoms can improve the carrier density of the CdS:O thin film.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Spatial distribution of the plasma parameters in the RF negative ion source prototype for fusion

A numerical model, based on the fluid plasma theory, has been used for description of the spatial distribution of the plasma parameters (electron density and temperature, plasma potential as well as densities of the three types of positive hydrogen ions) in the IPP prototype RF negative hydrogen ion source. The model covers the driver and the expansion plasma region of the source with their actual size and accounts for the presence of the magnetic filter field with its actual value and location as well as for the bias potential applied to the plasma grid. The obtained results show that without a magnetic filter the two 2D geometries considered, respectively, with an axial symmetry and a planar one, represent accurately the complex 3D structure of the source. The 2D model with a planar symmetry (where the E×B and diamagnetic drifts could be involved in the description) has been used for analysis of the influence, via the charged-particle and electron-energy fluxes, of the magnetic filter and of the bias potential on the spatial structure of the plasma parameters in the source. Benchmarking of results from the code to experimental data shows that the model reproduces the general trend in the axial behavior of the plasma parameters in the source.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Optical and local structural study of Gd doped ZrO{sub 2} thin films deposited by RF magnetron sputtering technique

ZrO{sub 2} samples with 0, 7, 9, 11, 13 % Gd doping have been prepared by RF magnetron sputtering deposition technique for solid oxide fuel cell application. The optical properties of the samples have been studied by transmission spectrophotometry and spectroscopic ellipsometry while the local structure surrounding Zr sites has been characterized by extended x-ray absorption fine structure (EXAFS) measurement at Zr K edge with synchrotron radiation. It has been observed that beyond 11% Gd doping, band gap decreases and refractive index increases significantly and also oxygen and Zr coordinations surrounding Zr sites increase which indicates the formation of Gd clustering in ZrO{sub 2} matrix beyond this doping concentration.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Electrical and optical properties of molybdenum doped zinc oxide films prepared by reactive RF magnetron sputtering

Molybdenum doped zinc oxide (MZO) films were deposited on to glass substrates held at temperatures in the range from 303 to 673 K by reactive RF magnetron sputtering method. The chemical composition, crystallographic structure and surface morphology, electrical and optical properties of the films were determined. The films contained the molybdenum of 2.7 at. % in ZnO. The films deposited at 303 K were of X-ray amorphous. The films formed at 473 K were of nanocrystalline in nature with wurtzite structure. The crystallite size of the films was increased with the increase of substrate temperature. The optical transmittance of the films was in the visible range was 80–85%. The molybdenum (2.7 at %) doped zinc oxide films deposited at substrate temperature of 573 K were of nanocrystalline with electrical resistivity of 7.2×10{sup −3} Ωcm, optical transmittance of 85 %, optical band gap of 3.35 eV and figure of merit 30.6 Ω{sup −1}cm{sup −1}.

36 MATERIALS SCIENCE↗

Compact RF ion source for industrial electrostatic ion accelerator

Korea Multi-purpose Accelerator Complex is developing a single-ended electrostatic ion accelerator to irradiate gaseous ions, such as hydrogen and nitrogen, on materials for industrial applications. ELV type high voltage power supply has been selected. Because of the limited space, electrical power, and robust operation, a 200 MHz RF ion source has been developed. In this paper, the accelerator system, test stand of the ion source, and its test results are described.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Self-induced steady-state magnetic field in the negative ion sources with localized rf power deposition

The study is in the scope of a recent activity on modeling of SPIDER (Source for Production of Ions of Deuterium Extracted from RF plasma) which is under development regarding the neutral beam injection heating system of ITER. The regime of non-ambipolarity in the source, established before, is completed here by introducing in the model the steady state magnetic field, self-induced in the discharge due to the dc current flowing in it. Strong changes in the discharge structure are reported.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Fine-tuning to minimize emittances of J-PARC RF-driven H{sup −} ion source

The Japan Proton Accelerator Research Complex (J-PARC) cesiated RF-driven H{sup −} ion source has been successfully operated for about one year. By the world’s brightest level beam, the J-PARC design beam power of 1 MW was successfully demonstrated. In order to minimize the transverse emittances, the rod-filter-field (RFF) was optimized by changing the triple-gap-lengths of each of pairing five piece rod-filter-magnets. The larger emittance degradation seems to be caused by impurity-gases than the RFF. The smaller beam-hole-diameter of the extraction electrode caused the more than expected improvements on not only the emittances but also the peak beam intensity.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Installation of spectrally selective imaging system in RF negative ion source

A spectrally selective imaging system has been installed in the RF negative ion source in the International Thermonuclear Experimental Reactor-relevant negative ion beam test facility ELISE (Extraction from a Large Ion Source Experiment) to investigate distribution of hydrogen Balmer-α emission (H{sub α}) close to the production surface of hydrogen negative ion. We selected a GigE vision camera coupled with an optical band-path filter, which can be controlled remotely using high speed network connection. A distribution of H{sub α} emission near the bias plate has been clearly observed. The same time trend on H{sub α} intensities measured by the imaging diagnostic and the optical emission spectroscopy is confirmed.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Irreversible thermochromic response of RF sputtered nanocrystalline BaWO{sub 4} films for smart window applications

We report irreversible thermochromic behaviour of BaWO{sub 4} (BWO) films for the first time. BWO films have been deposited at different substrate temperatures (RT, 200, 400, 600 and 800 °C) using RF magnetron sputtering in pure argon plasma. BWO films deposited at 800 °C exhibit crystalline nature. Also, BWO films deposited in the temperature range of 400 - 600 °C exhibit WO{sub 3} as a secondary phase and its weight percentage decreases with an increase in deposition temperature, whereas the films deposited at 800 °C exhibited pure tetragonal phase. FESEM images revealed that as the average particle sizes of the films are higher as compared with the thickness of the films and is explained based on Avrami type nucleation and growth. The transmittance of the films decreases with an increase in deposition temperature up to 600 °C and increases thereafter. Films deposited at 600 °C show ≤ 20% transmittance, looking at the films deposited at room temperature and 800 °C exhibits 90 and 70%, respectively. The refractive index and extinction coefficient of the films show profound dependence on crystallinity and packing density. The optical bandgap of BWO films increases significantly with an increase in O{sub 2}% during the deposition. The optical bandgap of the BWO films deposited at different temperatures in pure argon plasma, are in the range of 3.7 to 3.94 eV whereas the films deposited at 600 °C under different O{sub 2} plasma are in the range of 3.6 - 4.5 eV. The formations of colour centres are associated with the oxygen vacancies, which are clearly seen from the optical bandgap studies. The observed irreversible thermochromic behaviour in BWO films is attributed to the presence of oxygen vacancies that arises due to the electrons trapped at oxygen vacancies causing an inter valence charge transfer of W{sup 5+} to W{sup 6+} and is confirmed through the change in the optical density (ΔOD). Further, the Raman spectra are being used to quantify the presence of oxygen vacancies and the formation of pure BWO phase. The obtained optical responses of BWO films are promising for solar cell and smart window applications.

36 MATERIALS SCIENCE↗

Status of the RF-driven H{sup −} ion source for J-PARC linac

For the upgrade of the Japan Proton Accelerator Research Complex linac beam current, a cesiated RF-driven negative hydrogen ion source was installed during the 2014 summer shutdown period, with subsequent operations commencing on September 29, 2014. The ion source has been successfully operating with a beam current and duty factor of 33 mA and 1.25% (500 μs and 25 Hz), respectively. The result of recent beam operation has demonstrated that the ion source is capable of continuous operation for approximately 1100 h. The spark rate at the beam extractor was observed to be at a frequency of less than once a day, which is an acceptable level for user operation. Although an antenna failure occurred during operation on October 26, 2014, no subsequent serious issues have occurred since then.

43 PARTICLE ACCELERATORS↗

Hydroxyapatite coating on biodegradable AZ31 and Mg-Ca alloys prepared by RF-magnetron sputtering

A thin film of hydroxyapatite (HA) was deposited on AZ31 and Mg-Ca alloys by using radio frequency (RF) magnetron sputtering. The thickness of the HA coating was determined to be 750 nm. The phase composition, microstructure, and surface morphology of the HA coatings were investigated using X-ray diffraction and scanning electron microscopy. In vitro degradation behaviour of the HA coated alloys was evaluated in simulated body fluid (SBF) and 3.5wt.% NaCl solution using electrochemical method. The coatings homogeneously covered the entire surface of the substrates. The coating structure corresponded to a nanostructured HA. The ultrathin coating significantly improved the degradation resistance of the alloy. Nanocrystalline HA coating significantly improved the corrosion resistance of the Mg-Ca and AZ31 magnesium alloys. The polarization resistance (Rp) of the coated Mg-Ca alloy was more than two-order of magnitude higher and the corrosion current density I{sub corr} reduced by ∼ 98% as compared to the base alloy.

36 MATERIALS SCIENCE↗

Competition between alpha-decay and spontaneous fission at isotopes of superheavy elements Rf, Db, and Sg

The most important decay modes for heavy and superheavy nuclei are their α-decay and spontaneous fission. This work investigates the evolution and the competition of these decay modes in long isotopic sequences. The partial half-lives are given by minimal sets of parameters extracted from the fit of experimental data and theoretical results. A summary of the experimental and calculated α-decay and spontaneous fission half-lives of the isotopes of elements Rf, Db, and Sg is presented. Some half-life extrapolations for nuclides not yet known are also obtained.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Exploiting adiabatically switched RF-field for manipulating spin hyperpolarization induced by parahydrogen

A method for precise manipulation of non-thermal nuclear spin polarization by switching a RF-field is presented. The method harnesses adiabatic correlation of spin states in the rotating frame. A detailed theory behind the technique is outlined; examples of two-spin and three-spin systems prepared in a non-equilibrium state by Para-Hydrogen Induced Polarization (PHIP) are considered. We demonstrate that the method is suitable for converting the initial multiplet polarization of spins into net polarization: compensation of positive and negative lines in nuclear magnetic resonance spectra, which is detrimental when the spectral resolution is low, is avoided. Such a conversion is performed for real two-spin and three-spin systems polarized by means of PHIP. Potential applications of the presented technique are discussed for manipulating PHIP and its recent modification termed signal amplification by reversible exchange as well as for preparing and observing long-lived spin states.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Properties of RF sputtered cadmium telluride (CdTe) thin films: Influence of deposition pressure

Influence of deposition pressure on structural, morphology, electrical and optical properties of CdTe thin films deposited at low substrate temperature (100°C) by RF magnetron sputtering was investigated. The formation of CdTe was confirmed by low angle XRD and Raman spectroscopy. The low angle XRD analysis revealed that the CdTe films have zinc blende (cubic) structure with crystallites having preferred orientation in (111) direction. Raman spectra show the longitudinal optical (LO) phonon mode peak ∼ 165.4 cm{sup -1} suggesting high quality CdTe film were obtained over the entire range of deposition pressure studied. Scanning electron microscopy analysis showed that films are smooth, homogenous, and crack-free with no evidence of voids. The EDAX data revealed that CdTe films deposited at low deposition pressure are high-quality stoichiometric. However, for all deposition pressures, films are rich in Cd relative to Te. The UV-Visible spectroscopy analysis show the blue shift in absorption edge with increasing the deposition pressure while the band gap show decreasing trend. The highest electrical conductivity was obtained for the film deposited at deposition pressure 1 Pa which indicates that the optimized deposition pressure for our sputtering unit is 1 Pa. Based on the experimental results, these CdTe films can be useful for the application in the flexible solar cells and other opto-electronic devices.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Optical characterization of Mg-doped ZnO thin films deposited by RF magnetron sputtering technique

This paper reports the in-depth analysis on optical characteristics of magnesium (Mg) doped zinc oxide (ZnO) thin films grown on p-silicon (Si) substrates by RF magnetron sputtering technique. The variable angle ellipsometer is used for the optical characterization of as-deposited thin films. The optical reflectance, transmission spectra and thickness of as-deposited thin films are measured in the spectral range of 300-800 nm with the help of the spectroscopic ellipsometer. The effect of Mg-doping on optical parameters such as optical bandgap, absorption coefficient, absorbance, extinction coefficient, refractive Index and dielectric constant for as-deposited thin films are extracted to show its application in optoelectronic and photonic devices.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗