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At least 667 records · Page 37

Leading edge sweep effects in generic three-dimensional sidewall compression scramjet inlets

A computational and experimental study of generic 3D sidewall compression inlets is conducted to examine the effects of fore and aft leading edge sweep on the internal shock structure. Inlets with leading edge sweeps of +30 deg and -30 deg with sidewall compression angles of 6 deg were tested in the NASA Langley Mach 4 air tunnel at a geometric contraction ratio of 1.87. The principal difference in performance was determined to be in the mass capture. Spillage was identified as having two components: a pressure induced component and a sweep induced component. It was found that while the direction of the leading edge sweep had a large influence on the spillage, the pressure effects were more important.

Cozart, Aaron B.↗

Solar Radiation Pressure Estimation and Analysis of a GEO Class of High Area-to-Mass Ratio Debris Objects

A population of deep space objects is thought to be high area-to-mass ratio (AMR) debris having origins from sources in the geosynchronous orbit (GEO) belt. The typical AMR values have been observed to range anywhere from 1's to 10's of m(sup 2)/kg, and hence, higher than average solar radiation pressure effects result in long-term migration of eccentricity (0.1-0.6) and inclination over time. However, the nature of the debris orientation-dependent dynamics also results time-varying solar radiation forces about the average which complicate the short-term orbit determination processing. The orbit determination results are presented for several of these debris objects, and highlight their unique and varied dynamic attributes. Estimation or the solar pressure dynamics over time scales suitable for resolving the shorter term dynamics improves the orbit estimation, and hence, the orbit predictions needed to conduct follow-up observations.

Kelecy, Tom↗

Simulating the Compton-Getting effect for hydrogen flux measurements: Implications for IBEX-Hi and -Lo observations

The Interstellar Boundary EXplorer (IBEX), launched in 2008 October, has improved our understanding of the solar wind-local interstellar medium interaction through its detection of neutral atoms, particularly that of hydrogen (H). IBEX is able to create full maps of the sky in six-month intervals as the Earth orbits the Sun, detecting H with energies between ∼0.01 and 6 keV. Due to the relative motion of IBEX to the solar inertial frame, measurements made in the spacecraft frame introduce a Compton-Getting (CG) effect, complicating measurements at the lowest energies. In this paper we provide results from a numerical simulation that calculates fluxes of H atoms at 1 AU in the inertial and spacecraft frames (both ram and anti-ram), at energies relevant to IBEX-Hi and -Lo. We show theory behind the numerical simulations, applying a simple frame transformation to derived flux equations that provides a straightforward way to simulate fluxes in the spacecraft frame. We then show results of H energetic neutral atom fluxes simulated at IBEX-Hi energy passbands 2-6 in all frames, comparing with IBEX-Hi data along selected directions, and also show results simulated at energies relevant to IBEX-Lo. Although simulations at IBEX-Hi energies agree reasonably well with the CG correction method used for IBEX-Hi data, we demonstrate the importance of properly modeling low energy H fluxes due to inherent complexities involved with measurements made in moving frames, as well as dynamic radiation pressure effects close to the Sun.

79 ASTRONOMY AND ASTROPHYSICS↗

Pressure-induced insulator-to-metal transition in the quantum spin liquid candidate lithium ytterbium diselenide

Metallization of quantum spin liquid (QSL) materials has long been considered as a potential route toward unconventional superconductivity. Here, we investigate the pressurization of lithium ytterbium diselenide (LiYbSe 2 ), a three-dimensional QSL candidate with a pyrochlore structure. High-pressure X-ray diffraction (up to 15 GPa) and Raman spectroscopy (up to 48 GPa) reveal no significant structural changes within this pressure range. Remarkably insulating, LiYbSe 2 exhibits a resistance below 10 5 Ω only at pressures exceeding 25 GPa, accompanied by a gradual reduction of band gap upon compression. Interestingly, an insulator-to-metal transition occurs around 68 GPa, and the metallic behavior persists up to 123.5 GPa, the highest pressure achieved in this study. A possible sign of magnetic transitions is also observed. The insulator-to-metal transition in LiYbSe 2 under high pressure presents an ideal platform to explore the pressure effects on QSL candidates of spin-1/2 Yb 3+ systems with various lattice patterns.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Large Advanced Space Systems (LASS) computer-aided design program additions

The LSS preliminary and conceptual design requires extensive iteractive analysis because of the effects of structural, thermal, and control intercoupling. A computer aided design program that will permit integrating and interfacing of required large space system (LSS) analyses is discussed. The primary objective of this program is the implementation of modeling techniques and analysis algorithms that permit interactive design and tradeoff studies of LSS concepts. Eight software modules were added to the program. The existing rigid body controls module was modified to include solar pressure effects. The new model generator modules and appendage synthesizer module are integrated (interfaced) to permit interactive definition and generation of LSS concepts. The mass properties module permits interactive specification of discrete masses and their locations. The other modules permit interactive analysis of orbital transfer requirements, antenna primary beam n, and attitude control requirements.

Farrell, C. E.↗

Structure evolution upon chemical and physical pressure in (Sr{sub 1−x}Ba{sub x}){sub 2}FeSbO{sub 6}

Here we demonstrate the gradual structural transformation from the monoclinic I2/m to tetragonal I4/m, cubic Fm-3m and hexagonal P6{sub 3}/mmc structure upon the isovalent larger-for-smaller A-site cation substitution in the B-site ordered double-perovskite system (Sr{sub 1−x}Ba{sub x}){sub 2}FeSbO{sub 6}. This is the same transformation sequence previously observed up to Fm-3m upon heating the parent Sr{sub 2}FeSbO{sub 6} phase to high temperatures. High-pressure treatment, on the other hand, transforms the hexagonal P6{sub 3}/mmc structure of the other end member Ba{sub 2}FeSbO{sub 6} back to the cubic Fm-3m structure. Hence we may conclude that chemical pressure, physical pressure and decreasing temperature all work towards the same direction in the (Sr{sub 1−x}Ba{sub x}){sub 2}FeSbO{sub 6} system. Also shown is that with increasing Ba-for-Sr substitution level, i.e. with decreasing chemical pressure effect, the degree-of-order among the B-site cations, Fe and Sb, decreases. - Graphical abstract: In the (Sr{sub 1−x}Ba{sub x}){sub 2}FeSbO{sub 6} double-perovskite system the gradual structural transformation from the monoclinic I2/m to tetragonal I4/m, cubic Fm-3m and hexagonal P6{sub 3}/mmc structure is seen upon the isovalent larger-for-smaller A-site cation substitution. High-pressure treatment under 4 GPa extends stability of the cubic Fm-3m structure within a wider substitution range of x. - Highlights: • Gradual structural transitions upon A-cation substitution in (Sr{sub 1−x}Ba{sub x}){sub 2}FeSbO{sub 6.} • With increasing x structure changes from I2/m to I4/m, Fm-3m and P6{sub 3}/mmc. • Degree of B-site order decreases with increasing x and A-site cation radius. • High-pressure treatment extends cubic Fm-3m phase stability for wider x range. • High-pressure treatment affects bond lengths mostly around the A-cation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

MODELING AND PARAMETRIC STUDY OF END-GAS AUTOIGNITION TO ALLOW THE REALIZATION OF ULTRA-LOW EMISSIONS, HIGH-EFFICIENCY HEAVY-DUTY SPARK-IGNITED NATURAL GAS ENGINES

Engine knock and misfire are barriers to pathways leading to high-efficiency Spark-Ignited (SI) Natural Gas (NG) engines. The general tendency to knock is highly dependent on engine operating conditions and the fuel reactivity. The problem is further complicated by the low emission limits and the wide range of chemical reactivity in pipeline-quality natural gas. Depending on the region and the source of the natural gas, its reactivity, described by its Methane Number (MN), which is analogous to the Octane Number for liquid SI fuels, can span from 65 to 95. In order to realize diesel-like efficiencies, SI NG engines must be designed to operate at high Brake Mean Effective Pressures (BMEP), near or beyond knock limits, over a wide range of fuel reactivity. This requires a deep understanding of the combustion-engine interactions pertaining to flame propagation and End-Gas Autoignition (EGAI), i.e., the autoignition of the unburned gas (end gas) ahead of the flame front. However, EGAI, if controlled, provides an opportunity to increase SI NG engine efficiency by increasing the combustion rate and the total fraction of burned fuel, mitigating the effects of the slow flame speeds characteristic of natural gas fuels, which generally reduce BMEP and increase unburned hydrocarbon emissions. For this reason, to realize diesel-like efficiencies and ultra-low emissions on SI NG engines, this work proposes the study of the main parameters influencing the modeling and prediction of NG EGAI to allow for its control. In this work, a novel EGAI detection and onset determination method was developed to reliably quantify EGAI for data analysis and engine control. The new method allowed the prediction of EGAI on SI NG engines without the need to use engine- and operating-condition-dependent thresholds and reduced the error in quantifying the fraction of the total energy released by the EGAI event by up to 40%pts. One- and three-dimensional engine models were then developed to study the engine/fuel interactions that lead to NG EGAI and its performance benefits. These models, although having decent agreement with experimental data, showed the need to account for NOx chemistry when predicting NG EGAI due to a consistently later prediction of the EGAI onset (~1.65 crank-angle degrees) and thus, a new reduced chemical mechanism for real NG fuels was developed containing NOx chemistry. The new reduced mechanism improved the EGAI onset prediction agreement to within ±0.5 crank-angle degrees and decreased simulation time during combustion by nearly 50% when using the further reduced AREIS50NOx chemical mechanism. These models were then used to study the role of NG composition on EGAI, evaluate the engine/fuel interactions leading to NG EGAI, and perform engine optimization while leveraging EGAI to increase thermal efficiency. Piston design optimization combined with a Controlled EGAI (C-EGAI) combustion mode allowed a Heavy-Duty (HD) SI NG engine to operate at diesel-like efficiencies, i.e., Brake Thermal Efficiency (BTE) ≥44%. Experimental and modeling data analysis revealed that earlier and faster heat release increases combustion efficiency by an average of 1%pts, increases work transferred to the piston resulting in a decrease in exhaust losses by 50% depending on the engine operating condition while slightly increasing heat losses. Finally, the simulation results revealed an opportunity to further enhance the BTE (up to 50%) by enabling C-EGAI combustion at leaner conditions, λ=1.4-1.6.

Bestel, Diego Bernardi↗

Development of Solar Wind Model Driven by Empirical Heat Flux and Pressure Terms

We are developing a time stationary self-consistent 2D MHD model of the solar corona and solar wind as suggested by Sittler et al. (2003). Sittler & Guhathakurta (1999) developed a semiempirical steady state model (SG model) of the solar wind in a multipole 3-streamer structure, with the model constrained by Skylab observations. Guhathakurta et al. (2006) presented a more recent version of their initial work. Sittler et al. (2003) modified the SG model by investigating time dependent MHD, ad hoc heating term with heat conduction and empirical heating solutions. Next step of development of 2D MHD models was performed by Sittler & Ofman (2006). They derived effective temperature and effective heat flux from the data-driven SG model and fit smooth analytical functions to be used in MHD calculations. Improvements of the Sittler & Ofman (2006) results now show a convergence of the 3-streamer topology into a single equatorial streamer at altitudes > 2 R(sub S). This is a new result and shows we are now able to reproduce observations of an equatorially confined streamer belt. In order to allow our solutions to be applied to more general applications, we extend that model by using magnetogram data and PFSS model as a boundary condition. Initial results were presented by Selwa et al. (2008). We choose solar minimum magnetogram data since during solar maximum the boundary conditions are more complex and the coronal magnetic field may not be described correctly by PFSS model. As the first step we studied the simplest 2D MHD case with variable heat conduction, and with empirical heat input combined with empirical momentum addition for the fast solar wind. We use realistic magnetic field data based on NSO/GONG data, and plan to extend the study to 3D. This study represents the first attempt of fully self-consistent realistic model based on real data and including semi-empirical heat flux and semi-empirical effective pressure terms.

Sittler, Edward C., Jr.↗

Effects of surface pressures and streamline metrics on the calculation of laminar heating rates

The effect of streamline geometry and pressure distributions on surface heating rates is examined for slender, spherically blunted cones. The modifications to the approximate aeroheating code include a curve fit of pressures computed by an Euler solution over a range of Mach numbers and cone angles. The streamline geometry is then found using the surface pressures and inviscid surface properties. Previously, streamlines were determined using the inviscid properties at the edge of the boundary layer when accounting for the effects of entropy-layer swallowing. Streamline calculations are now based on inviscid surface conditions rather than boundary-layer edge properties. However, the heating rates are calculated using inviscid properties at the edge of the boundary layer. Resulting heating rates compare favorably with solutions from the viscous-shock-layer equations.

Riley, Christopher J.↗

Mechanistic Approach to Analyzing and Improving Unconventional Hydrocarbon Production [Slides]

DOE research is developing the physical basis and tools needed to manage pressure effectively to increase recovery efficiency. By coupling fast, accurate physics with machine learning, DOE is producing science-based platforms any operator can use. DOE’s research portfolio is targeting hydrocarbon transport at multiple scales, with the goal of increasing recovery efficiency. DOE’s research has led to new, fast & accurate platforms for predicting gas production from fractured shales. Using data from the MSEEL-I site to calibrate our physics-based model, we have early results on pressure management. We have shown that both mechanical and chemical processes in the matrix can negatively impact production.

08 HYDROGEN↗

Air- and N2-Broadening Coefficients and Pressure-Shift Coefficients in the C-12(O2-16) Laser Bands

In this paper we report the pressure broadening and the pressure-induced line shift coefficients for 46 individual rovibrational lines in both the (12)C(16)O2, 00(sup 0)1-(10(sup 0)0-02(sup 0)0)I, and 00(sup 0)1-(10(sup 0)0-02(sup 0)0)II, laser bands (laser band I centered at 960.959/cm and laser band II centered at 1063.735/cm) determined from spectra recorded with the McMath-Pierce Fourier transform spectrometer. The results were obtained from analysis of 10 long-path laboratory absorption spectra recorded at room temperature using a multispectrum nonlinear least-squares technique. Pressure effects caused by both air and nitrogen have been investigated. The air-broadening coefficients determined in this study agree well with the values in the 1996 HITRAN database; ratios and standard deviations of the ratios of the present air-broadening measurements to the 1996 HITRAN values for the two laser bands are: 1.005(15) for laser band I and 1.005(14) for laser band II. Broadening by nitrogen is 3 to 4% larger than that of air. The pressure-induced line shift coefficients are found to be transition dependent and different for the P- and R-branch lines with same J" value. No noticeable differences in the shift coefficients caused by air and nitrogen were found. The results obtained are compared with available values previously reported in the literature.

Devi, V. Malathy↗

Quantitative measurement of electron number in nanosecond and picosecond laser-induced air breakdown

Here we present quantitative measurements of total electron numbers in laser-induced air breakdown at pressures ranging from atmospheric to 40 bar{sub g} by 10 ns and 100 ps laser pulses. A quantifiable definition for the laser-induced breakdown threshold is identified by a sharp increase in the measurable total electron numbers via dielectric-calibrated coherent microwave scattering. For the 10 ns laser pulse, the threshold of laser-induced breakdown in atmospheric air is defined as the total electron number of ∼10{sup 6}. This breakdown threshold decreases with an increase of pressure and laser photon energy (shorter wavelength), which is consistent with the theory of initial multiphoton ionization and subsequent avalanche processes. For the 100 ps laser pulse cases, a clear threshold is not present and only marginal pressure effects can be observed, which is due to the short pulse duration leading to stronger multiphoton ionization and minimal collisional avalanche ionization.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Model predictive combustion control of a Gasoline Compression Ignition engine

Gasoline Compression Ignition is a novel combustion concept that derives its superiority from the high compression ratio of a compression ignition engine as well as the properties of gasoline fuel, such as longer ignition delay and higher volatility compared to diesel. Here, this combustion concept was experimentally tested on a 12.4L Class 8 truck engine. Based on these experimental data, prior efforts by the authors focused on the development of an engine model for a heavy-duty engine operating on a low-reactivity fuel. This engine model was leveraged within this study to investigate a combustion control strategy at different engine conditions and injection methods and was augmented to incorporate cycle-to-cycle combustion variations. State estimation is performed by means of a Kalman filter which feeds into a model predictive controller. The model predictive controller chooses control actions based on a predefined cost function under consideration of bounds reflecting physical constraints. The engine model was utilized to establish a state-space model that serves the Kalman filter and model predictive controller for estimation and prediction. A comparative study investigating control actions and engine behavior was performed with and without limiting in-cylinder peak pressure as well as combustion noise, which is of particular interest for early pilot injection strategies. In addition, the proposed control architecture was investigated at two different levels of cycle-to-cycle variations and compared to the performance of a control structure with input disturbance rejection. For increased cycle-to-cycle variations, disturbance estimation reduces state fluctuations and control effort. In general, this investigation highlights control aspects specific to a compression-ignited combustion regime with low-reactivity fuel. The control algorithm is able to maintain the desired references for brake mean effective pressure and combustion phasing while controlling peak in-cylinder pressure and combustion noise.

42 ENGINEERING↗

Fuel Property Characterization and Prediction

The Fuel Property Characterization and Prediction effect with the Co-Optimization of Fuels and Engines (Co-Optima) initiative is focused on the measurement or prediction of key fuel properties. Efforts under the Vehicle Technologies Office (VTO) have focused on understanding how fuel evaporation phenomena can impact auto-ignition, mixing, and pollutant formation by studying the most important azeotropic interactions between alcohols and gasoline components utilizing a novel Differential Scanning Calorimetry/Thermogravimetric Analysis instrument coupled to a Mass Spectrometer (DSC/TGA/MS). In another effort, Nuclear Magnetic Resonance (NMR) measurements were utilized to understand how oxygenate clusters and networks contribute to vapor pressure effects. This is critical for predicting fuel droplet evaporation and effects on combustion. A method was developed on the Advanced Fuel Ignition Delay Analyzer (AFIDA) to rapidly measure the Research Octane Number (RON) and Sensitivity (S) of samples utilizing small volumes, which will aid in the pace of development of new fuels having targeted properties. Additionally, the AFIDA was employed to develop a method for fast measurement of phi-sensitivity in a bench-scale test that will allow studies of molecular structure effects on mechanism kinetics of this poorly understood kinetic phenomena. A flow reactor was also utilized to investigate the mechanistic basis of phi-sensitivity by identifying and quantitating key species in autoignition mechanisms that can explain phi-sensitivity. The outcomes of these efforts will help ensure that the Co-Optima program can advance the underlying science needed to develop biomass-derived-fuel and advanced engine technologies that will work in tandem to achieve Co-Optima's efficiency, environmental, and economic goals.

33 ADVANCED PROPULSION SYSTEMS↗

Investigation of fuel film formation and soot emissions in a GDI engine during cold-start with Split-injection strategies

This study investigates the impact of fuel-film formation on engine-out soot emissions in a gasoline direct injection (GDI) engine under cold-start conditions. Split-injection strategies were applied by varying the number of injections, injection duration, and total fuel quantity to affect wall wetting and control the average in-cylinder equivalence ratio. A combined experimental and numerical approach was employed to analyze fuel-film deposition, combustion efficiency, and engine-out soot and unburnt hydrocarbons (UHC) emissions. In particular, fuel film distribution estimated by means of non-reacting, 3-D, computational fluid dynamics (CFD) simulations, together with experimentally measured soot data, were used to investigate fuel film formation and its role in soot generation. In the experiments, a skip-fired engine control strategy was applied to mimic the transient nature of engine cold-start operation. The results indicate that, under the same total number of injections, increasing the average in-cylinder equivalence ratio through longer injection durations improves combustion stability, as indicated by the decrease of the coefficient of variation of IMEP n (Net Indicated Mean Effective Pressure) from 6.0 % to 0.6 %. However, this strategy leads to higher soot emissions, which increased by nearly an order of magnitude, primarily due to enhanced wall-film formation. In contrast, increasing the number of injections while maintaining a constant equivalence ratio significantly impacts fuel-film deposition and, consequently, soot emissions, with a fivefold reduction of the measured engine-out soot, decreasing from 3.5 mg to 0.7 mg. A soot-film correlation was developed and achieved a high coefficient of determination (r 2 = 0.95) and was further extended to account for spark timing effects. These findings confirm the effectiveness of split-injection for avoiding wall film formation and soot emissions, and the critical role of fuel film in soot generation, supporting the hypothesis that pool fires play a crucial role in contributing to soot formation under these cold-start conditions. In conclusion, the study also indicates the value of a predictive soot-film correlation for developing cold-start emission control strategies.

Engine Cold-start↗

Raman Spectrum of Gaseous Propane in Methane

Pressure effects on the Raman spectrum of gaseous propane in methane are investigated. It is found that propane Raman bands located in the range 2700–3100 cm{sup –1} shift to lower frequencies although Raman bands in the range 300–1600 cm{sup –1} change negligibly as the density of the medium containing the analyzed propane increases.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The Effect of Inlet Pressure and Temperature on the Efficiency of a Single-stage Impulse Turbine Having an 11.0-inch Pitch-line Diameter Wheel

Efficiency tests have been conducted on a single-stage impulse engine having an 11-inch pitch-line diameter wheel with inserted buckets and a fabricated nozzle diaphragm. The tests were made to determine the effect of inlet pressure, Inlet temperature, speed, and pressure ratio on the turbine efficiency. An analysis is presented that relates the effect of inlet pressure and temperature to the Reynolds number of the flow. The agreement between the analysis and the experimental data indicates that the changes in turbine efficiency with Inlet pressure and temperature may be principally a Reynolds number effect.

TURBINES, EXHAUST - EFFICIENCY↗

Impact of fuel and engine operating conditions on efficiency of a heavy duty truck engine running compression ignition mode using energy and exergy analysis

Gasoline compression ignition using a single gasoline-type fuel for direct/port injection has been shown as a method to achieve low temperature combustion with low engine-out NO x and soot emissions and high indicated thermal efficiency. However, key technical barriers to achieving low temperature combustion on multi-cylinder engines include the air handling system (limited amount of exhaust gas recirculation) as well as mechanical engine limitations (e.g. peak pressure rise rate). In light of these limitations, high temperature combustion with reduced amounts of exhaust gas recirculation appears more practical. Previous studies by the authors demonstrated that utilizing port and direct injection of E85 gasoline simultaneously resulted in the best performance and the highest brake thermal efficiency of 47.1%, which was 1.2% higher compared to diesel baseline. For further efficiency improvement, a better understanding of energy and exergy loss mechanisms is required. As such, in this work first and second law thermodynamics analysis were applied to experiments with gasoline compression ignition at an engine speed of 1038 rpm and brake mean effective pressure of 1.4 MPa on a 12.4 L multi-cylinder heavy-duty diesel engine. The impact on the efficiency, losses, and irreversibility with respect to various parameters such as fuel, injection strategy, intake condition, and port injected water mass was quantified. The peak efficiency of ideal cycles and the combined efficiency with a waste heat recovery system were also estimated in this study to assess opportunities for further efficiency gains. It was found that the combustion irreversibility was dominated by the combustion temperature rather than the fuel structure. Despite its highest brake thermal efficiency, E85 gasoline generated the highest exergy destruction due to its lowest combustion temperature. For the same reason, retarding the combustion phasing or adopting a port and direct injection strategy increased the exergy destruction. The combustion duration loss was more notable than the phasing loss and was affected by both the combustion duration and shape of heat release profile. Water port injection increased the exhaust energy, but the available energy dropped significantly attributed to the decrease in the exhaust temperature, rendering waste heat recovery ineffective. The second law analysis serves as a helpful tool in conjunction with the first law analysis to explore pathways to maximize engine efficiency.

33 ADVANCED PROPULSION SYSTEMS↗