Results for “Nanowire” — Page 37

NASA NTRSDate not supplied

Insertion Loss of a Multi-Plane Light Conversion Device with Few Mode Fiber Outputs Under Atmospheric Conditions

A key challenge of photon counting optical communication is delivering light with atmospherically distorted wavefronts from the telescope to detectors efficiently. When using fiber coupled single photon detectors, the efficiency of the transmittance is constrained by the modes supported by the fiber. The number of modes supported by a fiber depends on the size of the core. The larger the core, the more modes supported. However, commercial off the shelf superconducting nanowire single photon detectors (SNSPDs) are currently limited in area, which limits the core size of the fibers that can efficiently couple to the detectors. To increase the amount of light that can be delivered to the detectors, NASA Glenn Research Center is considering many different fiber/detector architectures. This paper compares insertion loss of the fiber device for two different architectures: • a multi-plane light conversion device to split the light from a 30 µm core diameter fiber into 7 separate, 15 µm core diameter few-mode fibers butt-coupled to 7 single-element SNSPDs, • and a 30 µm core diameter multimode fiber butt-coupled to a 16 multi-element, SNSPD array. The measured insertion loss for each fiber device under emulated atmospheric conditions with D/r0 between 2 and 30 is presented. The multi-plane light conversion device shows a consistent ~1 dB loss more than the multimode fiber. Also presented is the measured uneven power splitting of the multiplane light conversion device, especially at lower D/r0. How this uneven power splitting contributes to system loss called blocking loss is discussed.

Multi-plane light conversion device↗

NASA NTRS2021

A High Dynamic-Range Photon-Counting Receiver for Deep Space Optical Communication

The Deep Space Optical Communication (DSOC) project will demonstrate free-space optical communication at almost 3 AU, or 3 orders of magnitude further than any previous attempt. DSOC will utilize the 5m Palomar Hale Telescope to receive the downlink signal, which will couple the downlink light onto an optical table and into a superconducting nanowire single photon detector (SNSPD). The output of the SNSPD is digitized by the Ground Laser Receiver Signal Processing Assembly (GSPA) using a high throughput streaming time to digital converter (TDC). The GSPA is a scalable FPGA-based receiver which demodulates and decodes the DSOC downlink signal through novel signal processing algorithms implemented on Xilinx UltraScale+ FPGAs, as well as Python-based software monitor and control routines. Exploiting the unique TDC-based architecture, the GSPA supports over four orders of magnitude of downlink data rates across multiple orders of magnitude of signal and background powers. In this paper we present an overview of the hardware, firmware and software architectures to implement this system, as well as performance analysis for links ranging from near-Earth to 2.8 AU.

Srinivasan, Meera↗

NASA NTRSDate not supplied

A Real-Time Optical Ground Receiver for Photon Starved Environments

The National Aeronautics and Space Administration (NASA) Glenn Research Center (GRC) has developed a photon-counting optical ground receiver for pulse-position modulated signals. The real-time receiver system includes a fiber interconnect, superconducting nanowire single-photon detectors (SNSPDs), and a real-time field programmable gate array (FPGA) based receiver. The fiber interconnect and SNSPDs are implemented with two different configurations. In the first, a 7-channel few-mode fiber photonic lantern couples the light from the telescope to 7 single-pixel few-mode fiber coupled SNSPDs. In the second configuration, a few-mode fiber couples light to a 16-pixel monolithic SNSPD array. The real-time FPGA-based receiver performs combining of up to 16 SNSPD channels, symbol timing recovery, demodulation, and decoding. The system is scalable with data rates ranging from 20 Mbps to 267 Mbps. It is compliant with the Consultative Committee for Space Data Systems (CCSDS) Optical Communications Coding and Synchronization Standard. This standard will be used in NASA deep space and other low photon flux missions, such as in the Orion Artemis-2 Optical Communications System (O2O) demonstration, planned for the first crewed flight of Orion. This paper describes the scalable real-time optical receiver system and presents characterization test results.

optical communications↗

NASA NTRSDate not supplied

A Real-Time Optical Ground Receiver for Photon Starved Environments

The National Aeronautics and Space Administration (NASA) Glenn Research Center (GRC) has developed a photon-counting optical ground receiver for pulse-position modulated signals. The real-time receiver system includes a fiber interconnect, superconducting nanowire single-photon detectors (SNSPDs), and a real-time field programmable gate array (FPGA) based receiver. The fiber interconnect and SNSPDs are implemented with two different configurations. In the first, a 7-channel few-mode fiber photonic lantern couples the light from the telescope to 7 single-pixel few-mode fiber coupled SNSPDs. In the second configuration, a few-mode fiber couples light to a 16-pixel monolithic SNSPD array. The real-time FPGA-based receiver performs combining of up to 16 SNSPD channels, symbol timing recovery, demodulation, and decoding. The system is scalable with data rates ranging from 20 Mbps to 267 Mbps. It is compliant with the Consultative Committee for Space Data Systems (CCSDS) Optical Communications Coding and Synchronization Standard. This standard will be used in NASA deep space and other low photon flux missions, such as in the Orion Artemis-2 Optical Communications System (O2O) demonstration, planned for the first crewed flight of Orion. This paper describes the scalable real-time optical receiver system and presents characterization test results.

optical communications↗

NASA NTRSDate not supplied

Design and Performance of a Multi-mode Photon-counting Receiver for the NASA O2O Mission

The NASA Orion O2O mission was designed and tested to support high-rate bi-directional optical communications between one of multiple ground sites and a crewed capsule during a 10-day mission. This paper focuses on the design and performance of the receiver that will be based at the NASA White Sands Complex, New Mexico, USA. The main receiver components consist of two 40-cm apertures, each coupled to a specialty multi-mode optical fiber; each fiber coupled to a custom array of superconducting nanowire single-photon detectors; a high-speed, high-channel-count time-to-digital converter; and custom digitizing electronics to perform deserialization, demodulation, clock recovery, and forward error correction with a powerful serially-concatenated pulse-position-modulation turbo code. We show error-free data communication performance up to the maximum required data rate of 267 Mb/s.

optical↗

NASA NTRSDate not supplied

Testing of A Photon-Counting Optical Ground Receiver With Emulated Space-to-Ground Link Effects

The National Aeronautics and Space Administration (NASA) Glenn Research Center (GRC) developed and previously characterized a photon-counting optical ground receiver system. The receiver is compliant with the Consultative Committee for Space Data Systems (CCSDS) Optical Communications Coding and Synchronization High Photon Efficiency (HPE) Standard. The standard will be used on the Optical Artemis-2 Orion (O2O) communications demonstration and the Deep Space Optical Communication (DSOC) project aboard the Psyche spacecraft. The receiver system consists of a fiber interconnect, up to sixteen superconducting nanowire single-photon detectors (SNSPDs), and a field programmable gate array (FPGA) based receive modem. Previously, the receiver system architecture was described and test results without emulated link effects were presented. SNSPD device properties, which impact detection jitter and time delay, can limit the receiver dynamic range, especially when operating with varying flux rates (>10 dB) between detectors. Codeword error-rate curves with and without simulated clock drifts attributed to Doppler shift and space transmitter clock differences are presented. Results with ±66 ppm clock differences show minimal performance impact (<0.2 dB). Test results show that the receiver dynamic range (>28 dB) is limited by changing SNSPD detection delays at high photon flux rates.

optical communications↗

NASA NTRSDate not supplied

Testing of A Photon-Counting Optical Ground Receiver With Emulated Space-to-Ground Link Effects

The National Aeronautics and Space Administration (NASA) Glenn Research Center (GRC) developed and previously characterized a photon-counting optical ground receiver system. The receiver is compliant with the Consultative Committee for Space Data Systems (CCSDS) Optical Communications Coding and Synchronization High Photon Efficiency (HPE) Standard. The standard will be used on the Optical Artemis-2 Orion (O2O) communications demonstration and the Deep Space Optical Communication (DSOC) project aboard the Psyche spacecraft. The receiver system consists of a fiber interconnect, up to sixteen superconducting nanowire single-photon detectors (SNSPDs), and a field programmable gate array (FPGA) based receive modem. Previously, the receiver system architecture was described and test results without emulated link effects were presented. SNSPD device properties, which impact detection jitter and time delay, can limit the receiver dynamic range, especially when operating with varying flux rates (>10 dB) between detectors. Codeword error-rate curves with and without simulated clock drifts attributed to Doppler shift and space transmitter clock differences are presented. Results with ±66 ppm clock differences show minimal performance impact (<0.2 dB). Test results show that the receiver dynamic range (>28 dB) is limited by changing SNSPD detection delays at high photon flux rates.

optical communications↗

NASA NTRSDate not supplied

Field-Programmable Gate Array Implementation of a Single Photon-Counting Receive Modem

We present a field-programmable gate array (FPGA) implementation of a single photon-counting receive modem for a pulse position modulated signal. The modem is compliant with the Consultative Committee for Space Data Systems (CCSDS) High Photon Efficiency (HPE) Optical Communications Coding and Synchronization standard and is capable of a maximum data rate of 267 Mbps. The system is designed on a commercial off-the-shelf FPGA platform and utilizes superconducting nanowire single photon counting detectors, analog to digital converters (ADC s) to sample the detectors, and two FPGAs. Symbol timing recovery, photon counting, convolutional deinterleaving, and codeword synchronization areis performed in the first FPGA. The second FPGA performs iterative decoding on each codeword of the serially concatenated pulse position modulated (SCPPM) signal. A digital filter is included to compensate for timing jitter of the detector, and the decoder throughput can be modified adjusted through reconfigurable parallelization. The decoder also implements a resource-efficient, algorithmic polynomial interleaver and deinterleaver. Both FPGAs can be reconfigured to switch between pulse position modulation (PPM)-16 and PPM-32 with code rates 1/3, 1/2, and 2/3. In this paper, we describe the receiver architecture and FPGA implementation of the timing recovery loop and SCPPM decoder, FPGA utilization for the different modes, and receive modem characterization test results.

Field-programmable Gate Array↗

NASA NTRSDate not supplied

Performance of A Real-Time Photon Counting Optical Receiver in the Presence of Emulated Channel Fading

Free-space optical communication links with terrestrial ground stations experience fading due to atmospheric scintillation and beam pointing. Fiber-coupled receiver systems experience additional fading at the interface between the fiber and free-space optics of the telescope. The National Aeronautics and Space Administration (NASA) Glenn Research Center (GRC) has characterized a real-time photon-counting optical ground receiver system with an atmospheric fade emulation system. The receiver system is comprised of a fiber interconnect, an array of superconducting nanowire single photon detectors (SNSPDs), and a field programmable gate array (FPGA) based receive modem. Two fiber interconnect/detector architectures have been studied. One architecture uses a 70-mode photonic lantern coupled to seven single pixel SNSPDs. The other architecture uses a 10-mode few-mode fiber (FMF) coupled to a 15-pixel SNSPD array. The receiver system complies with the Consultative Committee for Space Data Systems (CCSDS) Optical Communications High Photon Efficiency Coding and Synchronization Standard, which uses serially concatenated convolutionally coded pulse-position modulation (SCPPM). The CCSDS standard is designed for use in low photon flux missions, including the Orion Artemis-II Optical (O2O) communications demonstration. The standard utilizes a convolutional symbol interleaver which can be resized to mitigate different fades. The fade emulation system employed in this work emulates scintillation-induced, pointing-induced, and coupling-induced fading. This paper gives an overview of the real-time optical receiver system and the fade emulation system. It presents tests results which show the impact of fading on the performance on the receiver. The test results show that in the presence of channel fading, the 70-mode photonic lantern outperforms the 10-mode FMF under higher (D/r_0=9) turbulence conditions due to high fiber-coupling-induced fading and fiber coupling loss on the 10-mode FMF. When operating in lower turbulence (D/r_0=4), the 10-mode FMF outperforms the 70-mode photonic lantern. The paper also shows a larger convolutional interleaver improves the system performance as long as the receiver does not lose acquisition.

optical communications↗

NASA NTRSDate not supplied

Performance of a real-time photon counting optical receiver in the presence of emulated channel fading

Free-space optical communication links with terrestrial ground stations experience fading due to atmospheric scintillation and beam pointing. Fiber-coupled receiver systems experience additional fading at the interface between the fiber and free-space optics of the telescope. The National Aeronautics and Space Administration (NASA) Glenn Research Center (GRC) has characterized a real-time photon-counting optical ground receiver system with an atmospheric fade emulation system. The receiver system is comprised of a fiber interconnect, an array of superconducting nanowire single photon detectors (SNSPDs), and a field programmable gate array (FPGA) based receive modem. Two fiber interconnect/detector architectures have been studied. One architecture uses a 70-mode photonic lantern coupled to seven single pixel SNSPDs. The other architecture uses a 10-mode few-mode fiber (FMF) coupled to a 15-pixel SNSPD array. The receiver system complies with the Consultative Committee for Space Data Systems (CCSDS) Optical Communications High Photon Efficiency Coding and Synchronization Standard, which uses serially concatenated convolutionally coded pulse-position modulation (SCPPM). The CCSDS standard is designed for use in low photon flux missions, including the Orion Artemis-II Optical (O2O) communications demonstration. The standard utilizes a convolutional symbol interleaver which can be resized to mitigate different fades. The fade emulation system employed in this work emulates scintillation-induced, pointing-induced, and coupling-induced fading. This paper gives an overview of the real-time optical receiver system and the fade emulation system. It presents tests results which show the impact of fading on the performance on the receiver. The test results show that in the presence of channel fading, the 70-mode photonic lantern outperforms the 10-mode FMF under higher (D/r_0=9) turbulence conditions due to high fiber-coupling-induced fading and fiber coupling loss on the 10-mode FMF. When operating in lower turbulence (D/r_0=4), the 10-mode FMF outperforms the 70-mode photonic lantern. The paper also shows a larger convolutional interleaver improves the system performance as long as the receiver does not lose acquisition.

optical communications↗

NASA NTRSDate not supplied

A Photon Counting Ground Receiver for Free-Space Optical Communications

The National Aeronautics and Space Administration is developing a photon counting ground receiver for free-space optical communications. The receiver consists of a fiber interconnect, superconducting nanowire single photon counting detectors (SNSPDs), and a field programmable gate array (FPGA) based receive modem. This receiver is compliant with the Consultative Committee for Space Data Systems (CCSDS) Optical Communications High Photon Efficiency standard, which is used in the low photon flux communications regime, including on the upcoming Optical Artemis-2 Orion communications demonstration. The receiver architecture is modular, can be scaled for data rate, and is designed with primarily commercial-off-the-shelf technology. Two fiber interconnect and detector architectures are being prototyped. The first uses a few-mode-fiber coupled to a 16-channel SNSPD array and the second architecture uses a photonic lantern coupled to 7 single-pixel SNSPDs. Photon counting, symbol timing recovery, demodulation and decoding is done using several FPGA cards. This presentation describes the unique features of the ground receiver, performance test results, and challenges with using commercial SNSPDs in free-space optical communications.

Jennifer N Downey↗

DOE OSTI2020

High optical transparent two-dimensional electronic conducting system and process for generating same

Hybrid transparent conducting materials are disclosed with combine a polycrystalline film and conductive nanostructures, in which the polycrystalline film is “percolation doped” with the conductive nanostructures. The polycrystalline film preferably is a single atomic layer thickness of polycrystalline graphene, and conductive nanostructures preferably are silver nanowires.

Alam, Muhammad Ashraful↗

DOE OSTI2020

Compositions including nano-particles and a nano-structured support matrix and methods of preparation as reversible high capacity anodes in energy storage systems

The present invention relates to compositions including nano-particles and a nano-structured support matrix, methods of their preparation and applications thereof. The compositions of the present invention are particularly suitable for use as anode material for lithium-ion rechargeable batteries. The nano-structured support matrix can include nanotubes, nanowires, nanorods, and mixtures thereof. The composition can further include a substrate on which the nano-structured support matrix is formed. The substrate can include a current collector material.

Kumta, Prashant Nagesh↗

DOE OSTI2021

Curvature-mediated spin textures in magnetic multi-layered nanotubes

The scientific and technological exploration of artificially designed three-dimensional magnetic nanostructures opens the path to exciting novel physical phenomena, originating from the increased complexity in spin textures, topology, and frustration in three dimensions. Theory predicts that the equilibrium magnetic ground state of two-dimensional systems which reflects the competition between symmetric (Heisenberg) and antisymmetric (Dzyaloshinskii-Moriya interaction (DMI)) exchange interaction is significantly modified on curved surfaces when the radius of local curvature becomes comparable to fundamental magnetic length scales. Here, we present an experimental study of the spin texture in an 8 nm thin magnetic multilayer with growth-induced in-plane anisotropy and DMI deposited onto the curved surface of a 1.8 {\mu}m long non-magnetic carbon nanowire with a 67 nm radius. Using magnetic soft x-ray tomography the three-dimensional spin configuration in this nanotube was retrieved with about 30nm spatial resolution. The transition between two vortex configurations on the two ends of the nanotube with opposite circulation occurs through a domain wall that is aligned at an inclined angle relative to the wire axis. Three-dimensional micromagnetic simulations support the experimental observations and represent a visualization of the curvature-mediated DMI. They also allow a quantitative estimate of the DMI value for the magnetic multilayered nanotube.

Josten, Elisabeth↗

DOE OSTI2021

Alkali metal-sulfur secondary battery containing cathode material particulates

Provided is a rechargeable alkali metal-sulfur cell comprising an anode active material layer, an electrolyte, and a cathode active material layer comprising multiple particulates, wherein at least one of the particulates comprises one or a plurality of sulfur-containing material particles being embraced or encapsulated by a thin layer of a conductive sulfonated elastomer composite having from 0.01% to 50% by weight of a conductive reinforcement material dispersed in a sulfonated elastomeric matrix material, wherein the conductive reinforcement material is selected from graphene sheets, carbon nanotubes, carbon nanofibers, metal nanowires, conductive polymer fibers, or a combination thereof and the composite has a recoverable tensile strain from 2% to 500%, a lithium ion conductivity from 10−7 S/cm to 5×10−2 S/cm, and a thickness from 0.5 nm to 10 μm. This battery exhibits an excellent combination of high sulfur content, high sulfur utilization efficiency, high energy density, and long cycle life.

Zhamu, Aruna↗

DOE OSTI2022

Emulsion stereolithography and 3D printing of multimaterials and nanoscale material gradients

A functionally graded material is formed by pipetting individual micro-or-nano-litter droplets with a variety of materials including multi-nanostructured material (nanowires, carbon nanotubes, enzymes, multi-element and/or multi-color, multi-biomolecules) and UV polymerization of the flat hydrogel meniscus surface formed at the carrier fluid interface. After step-by-step droplet pipetting and subsequent layer-by-layer UV polymerization via a digital mask, the complete fabricated part without supporting layers is taken out of the carrier fluid while the un-cured micro-litter residue is conveniently suctioned out of the carrier fluid.

Zheng, Xiaoyu↗

DOE OSTI2023

Assessing the Role of Interfacial and Metal Sites in Pt/TiO2-Catalyzed Acetic Acid Hydrodeoxygenation

Thermochemical conversion of biomass to produce drop-in quality biofuels typically involves hydrodeoxygenation (HDO) steps following catalytic fast pyrolysis (CFP) to remove excess oxygen and create a more-stable bio-oil product. HDO reactions are performed by co-feeding the CFP vapor-phase product and H2 gas over a bi-functional catalyst. Noble-metal catalysts supported on reducible metal oxides (e.g., Pt/TiO2) are active and selective toward these HDO reactions. Griffin and co-workers showed that Pt/TiO2 catalysts promote the desired deoxygenation steps for m-cresol HDO while mitigating undesired C-C bond-breaking steps that reduce the overall value/energy density of the biofuel. Such model-compound studies to inform the design of improved catalysts for HDO chemistry are necessary to improve the overall process economics/efficiencies for biofuels production. One important class of bio-derived compounds that has not been studied extensively with respect to HDO chemistry, particularly at the atomic level, is carboxylic acids. Past experimental work indicates that Pt/C and Pt/TiO2 catalysts are selective toward C-C and C-O bond-dissociation products for acetic acid HDO, respectively. To understand the role of Pt/TiO2 active sites in this observed change in selectivity and guide catalyst development, the work in this presentation focuses on modeling the role of Pt-metal and Pt-TiO2-interfacial sites in promoting key C-C bond-breaking, C-O bond-breaking, and (de)hydrogenation steps in acetic acid HDO. Density functional theory (DFT) calculations were performed using the Vienna Ab initio Simulation Package (VASP). The exchange-correlation functional was approximated by the Perdew-Burke-Ernzerhof functional. Dispersion interactions were captured using the D3 method. Projector augmented-wave potentials described electron-ion interactions, and electron wavefunctions were expanded via a planewave basis with an energy cutoff of 500 eV. Activation barriers were calculated using the climbing image nudged elastic band method. Results and Discussion: To discern the role of Pt-metal and Pt-TiO2 interface sites in promoting acetic acid HDO chemistry, Pt(111) slab and anatase TiO2(101)-supported Pt-nanowire (PtNW/OH-TiO2) surface models were constructed, respectively. Because H2 is co-fed in HDO reactions, the anatase support was terminated with OH groups. Interfacial vacancies have been shown to facilitate Ru/TiO2-catalyzed phenol HDO; thus, an interfacial model with an OH vacancy was also considered (PtNW/OHv-TiO2). Pt-TiO2-interface sites stabilize adsorption of all studied acetic acid HDO surface intermediates relative to terrace Pt-metal sites, particularly when an interfacial-OH vacancy is present. Oxygenated species prefer to bind at the OH vacancy through the O atom, suggesting a preference for C-O over C-C bond cleavage at these sites. This hypothesis is supported by net-negative and net-positive average shifts in the reaction energy and activation energy barriers for C-O and C-C bond-breaking steps, respectively, at Pt-TiO2-interface sites relative to Pt-metal sites. Using the calculated energetics, the predicted minimum-energy pathway was determined for each surface. Pt(111) is predicted to follow decarboxylation, producing undesired methane and carbon dioxide. Conversely, PtNW/OH-TiO2 and PtNW/OHv-TiO2 are both predicted to produce desired acetaldehyde and ethane. The interfacial vacancy may also play a key role in facilitating the first C-O bond-breaking step in acetic acid HDO, lowering the barrier by 0.6 eV relative to the defect-free interface model. These results demonstrate the critical role of the Pt-TiO2 interface in the shift in acetic acid HDO selectivity experimentally observed on Pt/C and Pt/TiO2 catalysts. The results herein demonstrate the important role of the Pt-TiO2 interface and interfacial oxygen vacancies in improving the carbon efficiency for HDO reactions in CFP upgrading.

BIOMASS FUELS,INORGANIC, ORGANIC, PHYSICAL, AND AN↗

DOE OSTI2023

Large active-area superconducting microwire detector array with single-photon sensitivity in the near-infrared

Superconducting nanowire single photon detectors (SNSPDs) are the highest-performing technology for time-resolved single-photon counting from the UV to the near-infrared. The recent discovery of single-photon sensitivity in micrometer-scale superconducting wires is a promising pathway to explore for large active area devices with application to dark matter searches and fundamental physics experiments. We present 8-pixel $1 mm^2$ superconducting microwire single photon detectors (SMSPDs) with $1\,\mathrm{\mu m}$-wide wires fabricated from WSi and MoSi films of various stoichiometries using electron-beam and optical lithography. Devices made from all materials and fabrication techniques show saturated internal detection efficiency at 1064 nm in at least one pixel, and the best performing device made from silicon-rich WSi shows single-photon sensitivity in all 8 pixels and saturated internal detection efficiency in 6/8 pixels. This detector is the largest reported active-area SMSPD or SNSPD with near-IR sensitivity published to date, and the first report of an SMSPD array. By further optimizing the photolithography techniques presented in this work, a viable pathway exists to realize larger devices with $cm^2$-scale active area and beyond.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗