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At least 667 records · Page 37

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DOE OSTI2020

Materials Data on RbPNO2 by Materials Project

RbPNO2 crystallizes in the trigonal R-3 space group. The structure is three-dimensional. Rb1+ is bonded in a 9-coordinate geometry to two equivalent N2- and seven O2- atoms. There are one shorter (3.13 Å) and one longer (3.30 Å) Rb–N bond lengths. There are a spread of Rb–O bond distances ranging from 2.90–3.53 Å. P5+ is bonded to two equivalent N2- and two O2- atoms to form corner-sharing PN2O2 tetrahedra. There is one shorter (1.66 Å) and one longer (1.67 Å) P–N bond length. There is one shorter (1.51 Å) and one longer (1.53 Å) P–O bond length. N2- is bonded in a distorted bent 120 degrees geometry to two equivalent Rb1+ and two equivalent P5+ atoms. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted single-bond geometry to three equivalent Rb1+ and one P5+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to four equivalent Rb1+ and one P5+ atom.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Materials Data on CoAg(N3O4)2 by Materials Project

CoAgN2(NO2)4 crystallizes in the tetragonal P4/nnc space group. The structure is one-dimensional and consists of eight nitrous acid molecules and two CoAgN2 ribbons oriented in the (0, 0, 1) direction. In each CoAgN2 ribbon, Co3+ is bonded in a linear geometry to two equivalent N2+ atoms. Both Co–N bond lengths are 1.67 Å. Ag1+ is bonded in a linear geometry to two equivalent N2+ atoms. Both Ag–N bond lengths are 2.01 Å. N2+ is bonded in a linear geometry to one Co3+ and one Ag1+ atom.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Materials Data on CN2 by Materials Project

CN2 crystallizes in the tetragonal I-42d space group. The structure is three-dimensional. C4+ is bonded to four equivalent N2- atoms to form corner-sharing CN4 tetrahedra. All C–N bond lengths are 1.48 Å. N2- is bonded in a distorted trigonal planar geometry to two equivalent C4+ and one N2- atom. The N–N bond length is 1.36 Å.

36 MATERIALS SCIENCE↗

DOE OSTI2024

Dual-pump Coherent anti-Stokes Raman scattering measurements in H 2 /CH 4 Counterflow Flames

Temperature and major species concentration measurements are reported in a Williams Seshadri counterflow burner using dual-pump coherent anti-Stokes Raman scattering (DPCARS). Hencken burner H2/Air flames with equivalence ratio of 0.8-1.4 were used to characterize the accuracy of the system. The mean errors for temperature, XH2/XN2 mole fraction ratio, and XO2/XN2 mole fraction ratio are 1.0%, 14.7%, and 5.5%, respectively. The counterflow burner uses a CH4, H2, and N2 mixture as fuel and synthetic air as oxidizer. Measurements were performed along the counterflow burner central axis for two different fuel compositions: 4% H2/86% CH4/10% N2 and 87%H2/3% CH4/10% N2. The measured temperature and species mole fractions agree well with the 1-D opposed-flow diffusion flame simulation. One observation is that the fuel inlet temperature is higher than 300 K, which suggests the possibility of the stagnation plane residing closer to the fuel side. Lastly, these measurements provide valuable data for testing and validation of advanced 2-D flame models.

Murdock, Benjamin K.↗

NASA NTRS1971

Diatomic gasdynamic lasers

Predictions from a numerical model of the vibrational relaxation of anharmonic diatomic oscillators in supersonic expansions are used to show the extent to which the small anharmonicity of gases like CO can cause significant overpopulations of upper vibrational states. When mixtures of CO and N2 are considered, radiative gain on many of the vibration-rotation transitions of CO is predicted. Experiments are described that qualitatively verify the predictions by demonstrating laser oscillation in CO-N2 expansions. The resulting CO-N2 gasdynamic laser displays performance characteristics that equal or exceed those of similar CO2 lasers.

Mckenzie, R. L.↗

NASA NTRS1971

Research and investigation of gas dynamic lasers

Chemical mixing laser investigations were conducted (1) to investigate the properties of a bimolecular exchange laser system pumped by the H + Cl2 yields HCl(v) + Cl reaction, initiated by arc-dissociated H2, with lasing occurring between wavelengths of 3.4 and 4.0 microns, and (2) to establish the feasibility of an atom recombination-transfer laser employing recombination of arc-dissociated nitrogen with subsequent transfer of vibrational energy to CO2 for lasing at 10.6 microns. One-dimensional analytical results indicate higher results should be obtained with up to v = 3 to 2 transitions participating. Diagnostic and analytical results show that the reaction mechanism during mixing, a back reaction of HCl(v) with H atoms, reaction of Cl with H2(v), moderately fast V-V, V-T processes, and possible HCl(o) initial contaminant level may explain the low performance. N2-CO2 thermal mixing laser studies were extended to measure the efficiency of transfer of recombination energy in such a nonequilibrium N2 source to 10.6 microns optical energy. The low level of efficiency suggests that V-T decay processes may prevent vibrational energy freezing until much lower temperatures are achieved and that trapping of energy in long-lived electronic excitation of N2 may be a factor.

Boedeker, L. R.↗

NASA NTRS1972

Evaluation of advanced bladder technology

Research conducted during this period is reported. Studies presented include: (1) diffusion and permeation of CO2, O2, N2, and NO2 through polytetra fluoroethylene; (2) diffusion, permeation and solubility of simple gases (CO2, O2, N2, CH4, C2H6, C3H8, and C2H4) through a copolymer of hexafluoro propylene and tetrafluoro ethylene (FEP); (3) viscous flow and diffusion of gases throug small apertures; (4) diffusion and permeation of O2, N2, CO2, CH4, C2H6, and C3H8 through nitroso rubber; and (5) results of gas transport studies with carborane siloxane, nitroso rubber, silicone membrane, krytox coating on teflon, and FEP coated glass cloth. Publications generated under this program are listed.

Christensen, M. V.↗

NASA NTRS1972

Microphysical, microchemical and adhesive properties of lunar material. 3: Gas interaction with lunar material

Knowledge of the reactivity of lunar material surfaces is important for understanding the effects of the lunar or space environment upon this material, particularly its nature, behavior and exposure history in comparison to terrestrial materials. Adsorptive properties are one of the important techniques for such studies. Gas adsorption measurements were made on an Apollo 12 ultrahigh vacuum-stored sample and Apollo 14 and 15 N2-stored samples. Surface area measurements were made on the latter two. Adsorbate gases used were N2, A, O2 and H2O. Krypton was used for the surface area determinations. Runs were made at room and liquid nitrogen temperature in volumetric and gravimetric systems. It was found that the adsorptive/desorptive behavior was in general significantly different from that of terrestrial materials of similar type and form. Specifically (1) the UHV-stored sample exhibited very high initial adsorption indicative of high surface reactivity, and (2) the N2-stored samples at room and liquid nitrogen temperatures showed that more gas was desorbed than introduced during adsorption, indicative of gas release from the samples. The high reactivity is a scribed cosmic ray track and solar wind damage.

Grossman, J. J.↗

NASA NTRS1972

Experimental study of wall boundary layer growth in the 10 deg half angle conical nozzle of a reflected shock tunnel

Calibration studies of shock-tunnel nozzle flow were made in both N2 and Ar for a reservoir temperature of 2000 deg K and reservoir pressures of 15, 85, and 130 atm. The results for both test gases showed that the boundary layer was turbulent and the growth nonlinear, with the thickness being greater in Ar than N2 at comparable reservoir conditions. The boundary-layer thickness decreased with increasing reservoir pressure, but only small differences occurred between the two largest reservoir pressures. Good correlations of the boundary layer and displacement thickness were obtained for both N2 and Ar in terms of Reynolds number based on a reference temperature.

Menees, G. P.↗

NASA NTRS1972

The electron heating rate and ion chemistry in the thermosphere above Wallops Island during the solar eclipse of 7 March 1970.

Measurement of the N2 concentration and temperature, the ion composition and concentrations, and the electron temperature up to 290 km about 30 and 5 min before totality during the Mar. 7, 1970, eclipse. The rockets traveled similar trajectories, thus permitting the purely temporal changes between flights to be resolved. The neutral temperature and N2 concentration changed little, but the electron temperature decreased by as much as 20% in the lower F region. The ion concentration decreased by about 30% in the F region and about 50% in the E region, with little change in relative ion composition. The electron cooling rates decreased by a factor of 6 in the lower F region, approximately in proportion to the change in the visible solar disk. A smaller than expected decrease in the cooling rate below 150 km between the two flights indicates a hardening of the solar spectrum and suggests a significant heat contribution from the solar corona near totality. The ion composition measurements were consistent with solutions of the ion continuity equations. A proper fit required a factor-of-three enhancement of the flux below 200 A, an amount also consistent with the electron heat balance analysis. Reactions involving the minor ions N(+) and N2(+) were found to be important for the ion chemistry of the major ions O2(+) and NO(+), especially at the time of eclipse.-

Brace, L. H.↗

NASA NTRS1972

Longitudinal variations of thermospheric composition indicating magnetic control of polar heat input.

Measurement of neutral N2, O, and He densities from Ogo 6 over the south polar region during magnetically quiet periods in late August and early September 1969. It is found that N2 densities, when they are extrapolated to a common altitude, maximize at about 0800 UT near 70 deg invariant latitude. The density of He has a minimum at this time, and the density of O has a slight maximum. It is proposed that these phenomena are the result of cyclic variations in soft electron precipitation, which heats the thermosphere either directly or through enhanced Joule heating. This heat energy would increase the gas temperature, the increase in the gas temperature leading to the N2 increase, and would vary the composition by generation of a wind system.

Hedin, A. E.↗

NASA NTRS1972

Upper atmospheric probing by resonance fluorescence excited by tunable laser radiation.

Consideration of the application of the measurement of resonance fluorescence radiation excited by tunable laser radiation to the detection of atomic, molecular, and ionic species in the upper atmosphere. The species considered are N2, N2(+), NO, NO(+), O2(+), CO, CO(+), CH, Na, K, and Ca. Calculations of the resonance scattering cross sections, photon returns, and signal-to-noise ratios are given for these species for a range of conditions. Based on a probing altitude of 100 km, the detections of N2, NO, CO, CH, O2, and the trace metals appear feasible with state-of-the-art systems and within the concentration range present in the atmosphere.

Saunders, A. R.↗

NASA NTRS1972

Empirical model of global thermospheric temperature and composition based on data from the OGO-6 quadrupole mass spectrometer

An empirical global model for magnetically quiet conditions has been derived from longitudinally averaged N2, O, and He densities by means of an expansion in spherical harmonics. The data were obtained by the OGO-6 neutral mass spectrometer and cover the altitude range 400 to 600 km for the period 27 June 1969 to 13 May 1971. The accuracy of the analytical description is of the order of the experimental error for He and O and about three times experimental error for N2, thus providing a reasonable overall representation of the satellite observations. Two model schemes are used: one representing densities extrapolated to 450 km and one representing densities extrapolated to 120 km with exospheric temperatures inferred from N2 densities. Using the best fit model parameters the global thermospheric structure is presented in the form of a number of contour plots.

Hedin, A. E.↗

NASA NTRS1972

The photolysis of ozone

Ozone was photolyzed at 25 C with steady illumination at several wavelengths from 2288 to 2850 A, at O3 pressures from 0.1 to 2.7 torr, and at absorbed intensities from 0.15 to 65 microns/min. Experiments were done in pure dry O3, and in the presence of He, CO2, N2, H2O, H2, N2O, He-CO2, He-H2O, CO2-H2O, O2-N2O, CO2-O2, and N2O5-O2-CO2 mixtures. The results show that in the absence of added gases or in the presence of He, the quantum yield of O3 consumption is 5.5 independent of conditions, except at pressures below 0.4 torr. In the presence of CO2 or N2, ozone consumption falls toward 4.0. The primary photolytic act produces O(1 D) and siglet O2, presumably O2(1 delta), at all wavelengths below 3000 A. Relative quenching constants O(1 D) removal by various gases were measured at 2288, 2537, and 2800 A. For O3, CO2, and N2, the relative rates are 1.0/0.4 to 0.5/0.08 to 0.11 at all wavelengths. For H2O the constant at 2537 A is 1.5 relative to that for O3. With N2O, a noticeable wavelength effect is observed and the relative rate constants are 1.5, 2 to 3, 4.0 for O3 compared to N2O at 2800, 2537, and 2288 A, respectively.

Lissi, E.↗

NASA NTRS1972

Foreign-gas-broadening effects in the 15-micron CO2 bands.

The effects of N2, O2, Ar, and He on the absorption of radiation by the 15-micron perpendicular CO2 bands are reported. The investigation was carried out at medium resolution and at gas pressures less than 1 atm. The results of the study are presented in the form of a band-averaged broadening coefficient for N2, band-averaged broadening factors for O2, Ar, and He, and wavelength dependent broadening coefficients for N2, O2, Ar, and He. Comparisons are made with other experimental and theoretical results. In addition transmittances were calculated for homogeneous paths using some of the molecular parameters determined in the study and compared with measured transmittances.

Reichle, H. G., Jr.↗

NASA NTRS1972

Diatomic gasdynamic lasers.

Mckenzie, R. L.↗

NASA NTRS1973

Diurnal and semidiurnal nitrogen density and temperature variations from thermosphere probe measurements.

Amplitudes and phases for the diurnal and semidiurnal variations of thermospheric molecular nitrogen density and temperature are determined from data obtained by six rocket-launched thermosphere probes. The semidiurnal tide is significant for the lower thermosphere variations, where it could dominate in the N2 density at 140 km and in the temperature for altitudes between 170 and 200 km. At exospheric heights, the magnitudes of the semidiurnal modes in density and temperature are significantly smaller than those of the diurnal mode. The temperature phase is height-dependent in both diurnal and semidiurnal components below 200 km, thus contributing to phase differences between N2 density and temperature in both modes. No significant phase differences are apparent between N2 density and thermospheric temperature above 250 km.

Newton, G. P.↗

NASA NTRS1974

CO2 photodissociation and vibrational excitation in the planetary atmospheres

The principal subjects of investigation were the determination of the CO2 photodissociation quantum yields at the wavelengths from 1200 A to 1500 A, and the efficiency of electronic-to-vibrational energy transfer in the systems 0(1D) + CO, N2, CO2 yields 0(3P) + CO N2, CO2 vibrational energies. Measurements on the photodissociation quantum yield of CO2 in the 1200-1500 A region show that it is wavelength dependent, and for the six atomic line sources used, the quantum yield varied from 0.2 to 0.8. The data appear to fit the interpretation of stable CO2 bound states mixed with repulsive or predissociating states, since the low quantum yields coincide with the maximum structure in the CO2 absorption spectrum. The first reliable measurements were made on the efficiency of electronic-to-vibrational energy transfer in the systems 0(1D)-CO and 0(1D)-N2, using a uv resonance fluorescence technique. The 0(1D)-CO2 interaction was investigated by infrared techniques.

Slanger, T. G.↗