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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 667 records · Page 37

How fast ions mitigate turbulence and enhance confinement in tokamak fusion plasmas

Along with high temperature and density, magnetic fusion requires good confinement and a degree of transport control for thermal plasmas. Meanwhile, fast ions are generated by the external heating used to raise plasma temperature and by the fusion reactions. As a result, the fusion plasmas are effectively rendered into systems with two coexisting populations of main interest — namely, the fast ions and the thermal plasma. Interestingly, several recent experiments indicate that the fast-ion population can improve the confinement of the thermal plasmas by mitigating turbulence. Here, in this Review, we describe the physical mechanisms that underpin the improved confinement and discuss recent experimental results in terms of these mechanisms.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Metamaterial-like aerogels for broadband vibration mitigation

We present metamaterial-like aerogels that provide broadband low-frequency vibration mitigation through their self-assembled locally resonant microstructures. Simulations confirm the presence of a negative dynamic stiffness for the aerogels.

Malakooti, Sadeq↗

Decomposition pathways and mitigation strategies for highly-stable hydroxyphenazine flow battery anolytes

Aqueous organic redox flow batteries are a promising technology for large-scale energy storage. The stability of the redox active organic molecules is increasingly being recognized as one of the major hurdles. Upon extended flow battery cycling, 7,8-dihydroxyphenazine-2 sulfonic acid (DHPS) undergoes desulfonation and reduction of a phenolic C–O bond to yield a mixture of 7/8-hydroxyphenazine-2-sulfonic acid, as well as hydrogenation of the aromatic ring system. Density functional theory (DFT) analysis of the charged DHPS, its ring-hydrogenated products, and variably substituted hydroxy phenazines has led to the development of a series of dihydroxylated phenazine isomers which provide insight into the effects of substitution pattern on solubility and stability. Seven dihydroxyphenazine (DHP) isomers were synthesized and their solubilities, electrochemical properties, flow battery cycling performance, and degradation pathways have been investigated. Based on theoretical and experimental results, hydroxyl substitution at the 1, 4, 6 and 9 positions yields highly stable derivatives, while substitution at the 2, 3, 7, and 8 positions results in unstable derivatives. Flow cells of 1,4- and 1,6-DHPs coupled with ferro/ferricyanide achieved high stabilities, with temporal capacity loss of 0.029 and 0.031% per day, respectively. Decomposition of 1,8- and 2,7-DHPs were found to arise from irreversible hydrogen rearrangement (tautomerization), yielding redox-inactive species. These results provide a detailed understanding of decomposition pathways and mitigation strategies for phenazine-based anolytes, and can provide general design guidelines for the development of stable redox-active organics.

25 ENERGY STORAGE↗

Integrating crystallographic and computational approaches to carbon-capture materials for the mitigation of climate change

Here, this article presents an overview of the current state of the art in the structure determination of microporous carbon-capture materials, as discussed at the recent NIST workshop “Integrating Crystallographic and Computational Approaches to Carbon-Capture Materials for the Mitigation of Climate Change”. The continual rise in anthropogenic CO 2 concentration and its effect on climate change call for the implementation of carbon capture technologies to reduce the CO 2 concentration in the atmosphere. Porous solids, including metal–organic frameworks (MOFs), are feasible candidates for gas capture and storage applications. However, determining the structure of these materials represents a significant obstacle in their development into advanced sorbents. The existing difficulties can be overcome by integrating crystallographic methods and theoretical modeling. The workshop gathered experimentalists and theorists from academia, government, and industry to review this field and identify approaches, including collaborative opportunities, required to develop tools for rapid determination of the structures of porous solid sorbents and the effect of structure on the carbon capture performance. We highlight the findings of that workshop, especially in the need for reference materials, standardized procedures and reporting of sorbent activation and adsorption measurements, standardized reporting of theoretical calculations, and round-robin structure determination.

36 MATERIALS SCIENCE↗

Mitigating X-ray-induced damage for accurate analysis of battery cathodes using transmission X-ray microscopy

Here, we investigate the impact of X-ray-induced damage on the evolution of battery cathodes using synchrotron transmission X-ray microscopy. In an operando coin cell, exposure to the X-ray beam can induce bubble formation, potentially rendering cathode particles electrochemically inactive and displacing particles from their initial position. However, utilizing external pressure on a pouch cell can mitigate bubble formation and its associated effects.

25 ENERGY STORAGE↗

A graph embedding‐based approach for automatic cyber‐physical power system risk assessment to prevent and mitigate threats at scale

Abstract Power systems are facing an increasing number of cyber incidents, potentially leading to damaging consequences to both physical and cyber aspects. However, the development of analytical methods for the study of large‐scale power infrastructures as cyber‐physical systems is still in its early stages. Drawing inspiration from machine‐learning techniques, the authors introduce a method inspired by the principles of graph embedding that is tailored for quantitative risk assessment and the exploration of possible mitigation strategies of large‐scale cyber‐physical power systems. The primary advantage of the graph embedding approach lies in its ability to generate numerous random walks on a graph, simulating potential access paths. Meanwhile, it enables capturing high‐dimensional structures in low‐dimensional spaces, facilitating advanced machine‐learning applications, and ensuring scalability and adaptability for comprehensive network analysis. By employing this graph embedding‐based approach, the authors present a structured and methodical framework for risk assessment in cyber‐physical systems. The proposed graph embedding‐based risk analysis framework aims to provide a more insightful perspective on cyber‐physical risk assessment and situation awareness for power systems. To validate and demonstrate its applicability, the method has been tested on two cyber‐physical power system models: the Western System Coordinating Council (WSCC) 9‐Bus System and the Illinois 200‐Bus System , thereby showing its advantages in enhancing the accuracy of risk analysis and comprehensiveness of situational awareness.

Sun, Shining↗

High-field Q-slope mitigation due to impurity profile in superconducting radio-frequency cavities

In this study, we present new insights on the origin of the high-field Q-slope in superconducting radio-frequency cavities. Consequent hydrofluoric acid rinses are used to probe the radio-frequency performance as a function of the material removal of two superconducting bulk niobium cavities prepared with low temperature nitrogen infusion. The study reveals that nitrogen infusion affects only the first few tens of nanometers below the native oxide layer. The typical high-field Q-slope behavior of electropolished cavities is indeed completely recovered after a dozen hydrofluoric acid rinses. The reappearance of the high-field Q-slope as a function of material removal was modeled by means of London's local description of screening currents in the superconductor, returning good fitting of the experimental data and suggesting that interstitial impurities layers with diffusion length of the order to tens of nanometers can mitigate high-field Q-slope.

43 PARTICLE ACCELERATORS↗

Methods to determine the radiated power in SPI-mitigated disruptions in JET

Here we present techniques for evaluating the radiated power in JET disruptions. Disrupting plasmas are shown to have non-axisymmetric radiation profiles, motivating the re-evaluation of the standard techniques for calculating the total radiated power at JET using bolometry. Four single-channel bolometers at different toroidal locations are exploited to quantify the radiation asymmetry. Toroidal radiation peaking factors integrated over the entire disruption of up to 1.5 have been observed when varying the quantity of neon in pellets used in disruptions mitigated by shattered pellet injection. Using synthetic bolometer diagnostics developed with the Cherab spectroscopy modeling framework, we can estimate the systematic error on total power calculations for relevant radiation profiles and improve estimates of the total radiated power. We show that the component of the systematic error on the total power due to the poloidal radiation profile can be reduced from 70% to 10% with suitable assumptions about the structure of the poloidal profile.

47 OTHER INSTRUMENTATION↗

Spatially dependent modeling and simulation of runaway electron mitigation in DIII-D

New simulations with the Kinetic Orbit Runaway electron (RE) Code (KORC) show RE deconfinement losses to the wall during plasma scrape off are the primary current dissipation mechanism in DIII-D experiments with high-Z impurity injection, and not collisional slowing down. The majority of simulations also exhibit an increase in the RE beam energy due to acceleration by the induced toroidal electric field, even while the RE beam current is decreasing. In this study, KORC integrates RE orbits using the relativistic guiding center equations of motion and incorporates time-sequenced, experimental reconstructions of the magnetic and electric fields and line integrated electron density to construct spatiotemporal models of electron and partially ionized impurity transport in the companion plasma. Comparisons of experimental current evolution and KORC results demonstrate the importance of including Coulomb collisions with partially ionized impurity physics, initial RE energy, pitch angle, and spatial distributions, and spatiotemporal electron and partially ionized impurity transport. The research presented here provides an initial quantification of the efficacy of RE mitigation via injected impurities and identification of the critical role played by loss of confinement due to plasma scrape off on the inner wall as compared to the relatively slow collisional damping.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Mitigation of mode-one asymmetry in laser-direct-drive inertial confinement fusion implosions

Nonuniformities present in the laser illumination and target in laser-driven inertial confinement fusion experiments lead to an asymmetric compression of the target, resulting in an inefficient conversion of shell kinetic energy to thermal energy of the hot-spot plasma. In this paper, the effects of asymmetric compression of cryogenic deuterium tritium laser-direct-drive implosions are examined using a suite of nuclear and x-ray diagnostics on the OMEGA laser. The neutron-averaged hot-spot velocity (u → hs ) and apparent ion temperature (T i ) asymmetry are determined from neutron time-of-flight measurements of the primary deuterium tritium fusion neutron energy spectrum, while the areal density (ρR) of the compressed fuel surrounding the hot spot is inferred from measurements of the scattered neutron energy spectrum. Here, the low-mode perturbations of the hot-spot shape are characterized from x-ray self-emission images recorded along three quasi-orthogonal lines of sight. Implosions with significant mode-1 laser drive asymmetries show large hot-spot velocities (>100 km/s) in a direction consistent with the hot-spot elongation observed in x-ray images, measured T i asymmetry, and ρR asymmetry. Laser drive corrections have been applied through shifting the initial target location in order to mitigate the observed asymmetry. With the asymmetry corrected, a more-symmetric hot spot is observed with reduced u → hs , T i asymmetry, ρR asymmetry, and a 30% increase in the fusion yield.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Detrimental effects and mitigation of the joint feature in double shell implosion simulations

Double shell capsules provide an attractive option in inertial confinement fusion experiments due to their potential for achieving a low-convergence, robust burn. However, these designs suffer from symmetry degradation and accompanying reduced fuel confinement due to the currently necessary joint between the two hemispheres of the outer shell. Here, the gap widens as a result of the excess ablation pressure produced by x rays that penetrate the joint during the drive phase, and this perturbation grows and imprints onto the inner shell during the collision. xRAGE Eulerian radiation-hydrodynamic simulations predict significant reductions in deuterium–tritium fusion yields compared to joint-less simulations when the depth of the outer joint is increased, whereas the performance is less sensitive to the depth of the inner gap. Here we examine the technique of plating the insides of the outer gap with a high-Z material to mitigate the impact of this feature. Gold-plating in quantities comparable to or exceeding the “missing” outer shell mass shows promise toward restoring both implosion symmetry and yield closer to the joint-less levels, and synthetic diagnostics suggest that high-energy x-ray radiographs can capture this shape retention of the inner and outer shells in experiments.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Hydrogen Mitigation Process Testing at Nevada Solar One

The National Renewable Energy Laboratory (NREL) and Acciona Solar Power (ASP) developed and installed a process that addresses the issue of hydrogen buildup in Acciona's Nevada Solar One power plant. Our method selectively removes hydrogen from the expansion tanks of the power plant to control hydrogen levels in the circulating heat-transfer fluid (HTF). During previous work, we developed a sensor that measures hydrogen partial pressure in the expansion-tank headspace gas. We demonstrated that our sensor measures hydrogen levels over a wide range of partial pressure from 10 mbar down to 0.003 mbar. More recently, we conceived and developed an integrated process module that performs both hydrogen sensing and separating functions. The sensor/separator measures hydrogen partial pressure in the headspace gas in the same way as our original sensor design. Additionally, the integrated module separates hydrogen from the headspace gas to reduce hydrogen to the level needed to maintain the performance of receivers in the collector field. Laboratory testing at NREL showed that the sensor function had an accuracy of +/-7%, and the hydrogen extraction rate for separator function was consistent with our modeling predictions. The primary benefit of this module is its simple design, both in terms of function and incorporation into the HTF subsystem of the power plant. Most recently, NREL and ASP completed installation and initial testing of a mitigation process at ASP's Nevada Solar One power plant in Boulder City, Nevada. In this paper, we report on the completed installation, initial testing, and plans to bring the process to full automation, so that it can be operated unattended on a daily schedule.

chemical elements↗

Effects and mitigation of pulsed power radiation on optical fiber velocimetry

We report optical fiber diagnostics are extensively used in pulsed power experiments, such as the Sandia Z machine. However, radiation produced in a pulsed power environment can significantly affect these measurements. Catastrophic fiber darkening may be mitigated with shielding, but no flexible material can stop all radiation produced by the machine and/or target. Radiation-induced refractive index modulations are particularly challenging for optical interferometry. Several approaches for radiation-tolerant photonic Doppler velocimetry are discussed here.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Gas scintillation mitigation in gas Cherenkov detectors for inertial confinement fusion (invited)

Gas Cherenkov detectors provide a time resolved measurement of the fusion burn in inertial confinement fusion experiments. The fusion rate delivers critical benchmark figures, such as burn width and bang time. Recent detector improvements pushed temporal resolution to 10 ps to make burn width measurements on igniting targets possible. First high temporal resolution measurements using CO 2 gas fills had a background signal with a long decay length (tail), which was caused by gas scintillation. This gas scintillation limits the ability of the detector to resolve short burn width and high frequency features in the fusion rate measurements. A thorough investigation of the cause of the tail and mitigation options for gas scintillation is presented here. As a near-term resolution, neon gas is being used to extract fusion burn histories. Paths forward for the next generation of gas Cherenkov detectors are identified including the usage of oxygen as a Cherenkov medium.

47 OTHER INSTRUMENTATION↗

Study of perovskite CsPbBr 3 detector polarization and its mitigation with ultrahigh x-ray flux

High-flux capable semiconductor x-ray detectors are essential in various applications, but the detrimental effects of detector polarization limit their use in many cases. Here, for this work, we studied the polarization of perovskite CsPbBr 3 semiconductor detectors using ultrahigh flux synchrotron x rays (10 6 –10 12 photons s –1 mm –2 at 58.61 keV). The CsPbBr 3 detectors did not show immediate polarization prominently until a flux higher than 10 10 photons s –1 mm –2 . Using the pump-and-probe technique, we visualized the spatial and temporal effects of polarization. The polarized region, represented by reduced photocurrent, extended beyond the area under direct irradiation, and the reduced photocurrent persisted after potential de-polarization treatments. We found that stronger applied electric fields and fewer carrier traps can mitigate polarization, represented by less photocurrent deficit. By examining the detectors’ current response under controlled ambient light, low, and high-flux x rays, we studied the trap filling and release behavior of CsPbBr 3 . We discovered that the polarization is caused by partial detector damage due to deep defects generated by ultrahigh flux x-ray irradiation. Our work provides insight into CsPbBr 3 polarization under extremely intense x-ray radiation and shows that reducing crystal defects and increasing detector bias voltage are effective solutions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Mitigation of deceleration-phase Rayleigh–Taylor instability growth in inertial confinement fusion implosions

Rayleigh–Taylor growth during shell deceleration is one of the main limiting factors for target performance in inertial confinement fusion implosions. Here, using analytical scaling laws and hydrodynamic simulations, we show that such amplification can be mitigated by reducing the initial mass density in the central target region. The perturbation growth reduction is caused by a smaller hot-spot convergence ratio during deceleration, increased density scale length, and enhanced ablation stabilization. The required central density reduction can be achieved using the dynamic shell formation concept.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Stochastic and a posteriori optimization to mitigate coil manufacturing errors in stellarator design

Abstract It was recently shown in Wechsung et al (2022 Proc. Natl Acad. Sci. USA 119 e2202084119) that there exist electromagnetic coils that generate magnetic fields, which are excellent approximations to quasi-symmetric fields and have very good particle confinement properties. Using a Gaussian process-based model for coil perturbations, we investigate the impact of manufacturing errors on the performance of these coils. We show that even fairly small errors result in noticeable performance degradation. While stochastic optimization yields minor improvements, it is not possible to mitigate these errors significantly. As an alternative to stochastic optimization, we then formulate a new optimization problem for computing optimal adjustments of the coil positions and currents without changing the shapes of the coil. These a-posteriori adjustments are able to reduce the impact of coil errors by an order of magnitude, providing a new perspective for dealing with manufacturing tolerances in stellarator design.

Physics↗

Type-I ELM mitigation by continuous lithium granule gravitational injection into the upper tungsten divertor in EAST

Large edge-localized modes (ELMs) were mitigated by gravitational injection of lithium granules into the upper X-point region of the experimental advanced superconducting tokamak (EAST) device with tungsten plasma-facing components. The maximum ELM size was reduced by ~70% in high β N H-mode plasmas. Large ELM stabilization was sustained for up to about 40 energy confinement times, with constant core radiated power and no evidence of high-Z or low-Z impurity accumulation. The lithium granules injection reduced the edge plasma pedestal density and temperature and their gradients, due to increased edge radiation and reduced recycling from the plasma-facing components. Ideal stability calculations using the ELITE code indicate that the stabilization of large ELMs correlates with improved stability of intermediate-n peeling-ballooning modes, due to reduced edge current resulting from the profile changes. The pedestal pressure reduction was partially offset by a core density increase, which resulted in a modest ~7% drop in core stored energy and normalized energy confinement time. We surmise that the remnant small ELMs are triggered by the penetration of multiple Li granules just past the separatrix, similar to small ELMs triggered by deuterium pellet Futatani et al (2014 Nucl. Fusion 54 073008). This study extends previous ELM elimination with Li powder injection Maingi et al (2018 Nucl. Fusion 58 024003) in EAST because (1) use of small, dust-like powder and the related potential health hazards were eliminated, and (2) use of macroscopic granules should be more applicable to future devices, due to deeper penetration than dust particles, e.g. inside the separatrix with velocities ~10 m s -1 in EAST.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗