Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Ions Separations”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 667 records · Page 37
All sourcesNASA NTRSDOE OSTI
NASA NTRS1983

Observations of optical emissions from precipitation of energetic neutral atoms and ions from the ring current

In the present investigation, results obtained at three different locations are compared, taking into account the McDonald Observatory (latitude 30.7 deg N, longitude 101.0 deg W, altitude 2050 m), Mt. Haleakala (latitude 20.7 deg N, longitude 156.6 deg W, altitude 3050 m), and Cachoeira Paulista (latitude 22.7 deg S, longitude 45.0 deg W, altitude 500 m). The intercomparison of results from the three well-separated sites makes it possible to make evaluations of the local time, storm time, and latitude variation of the ring current precipitation.

Rohrbaugh, R. P.↗
NASA NTRS1987

Theoretical study of the high-latitude ionosphere's response to multicell convection patterns

A time-dependent three-dimensional model of the high-latitude ionosphere is used to study the characteristic ionospheric signatures associated with two-, three-, and four-cell plasma convection patterns. It is found that, for two-cell convection, the antisunward flow of plasma from the dayside into the polar cap acts to maintain the densities in this region in winter. For four-cell convection, the two additional convection cells in the polar cap are in darkness most of the time, and the resulting O(+) decay acts to produce twin polar holes that are separated by a sun-aligned ridge of enhanced ionization due to theta-auroral precipitation. For three-cell convection, only one polar hole forms in the total electron density, and an additional O(+) depletion region develops near noon. In this region there are strong electric fields, high ion temperatures, and an enhanced rate of O(+) - NO(+) conversion.

Sojka, J. J.↗
NASA NTRS2005

High-Temperature Proton-Conducting Ceramics Developed

High-temperature protonic conductors (HTPC) are needed for hydrogen separation, hydrogen sensors, fuel cells, and hydrogen production from fossil fuels. The HTPC materials for hydrogen separation at high temperatures are foreseen to be metal oxides with the perovskite structure A(sup 2+)B(sup 4+)C(sup 2-, sub 3) and with the trivalent cation (M(sup 3+)) substitution at the B(sup 4+)-site to introduce oxygen vacancies. The high affinity for hydrogen ions (H(sup +)) is advantageous for protonic transport, but it increases the reactivity toward water (H2O) and carbon dioxide (CO2), which can lead to premature membrane failure. In addition, there are considerable technological challenges related to the processing of HTPC materials. The high melting point and multi-cation chemistry of HTPC materials creates difficulties in in achieving high-density, single-phase membranes by solid-state sintering. The presence of secondary phases and grain-boundary interfaces are detrimental to the protonic conduction and environmental stability of polycrystalline HTPC materials.

Sayir, Ali↗
NASA NTRS2017

Organic Matter in Extraterrestrial Water-Bearing Salt Crystals

Introduction: Direct samples of early Solar System fluids are present in two thermally-metamorphosed ordinary chondrite regolith breccias (Monahans (1998) [H5] and Zag [H3-6]), which were found to contain brine-bearing halite (NaCl) crystals that have been added to the regolith of an S-type asteroid following asteroidal metamorphism [1, 2]. The brine-bearing halite grains were proposed to be formed on an icy C-type asteroids (possibly Ceres), and transferred to an S-type asteroid via cryovolcanic event(s) [3]. A unique aspect of these halites is that they contain abundant organic rich solid inclusions hosted within the halites alongside the water inclusions. Methods: We analyzed in detail the compositions of the organic solids and the amino acid content of the halite crystals with two-step laser desorption/laser ionization mass spectrometry (L(sup 2) MS), Raman spectroscopy, X-ray absorption near edge structure (XANES), nanoscale secondary ion mass spectrometry (NanoSIMS), and ultra-performance liquid chromatography fluorescence detection and quadrupole time of flight hybrid mass spectrometry (UPLC-FD/QToF-MS). Results and Discussion: The L(sup 2) MS results show signatures of low-mass polyaromatic hydro-carbons (PAHs) indicated by sequences of peaks separated by 14 atomic mass units (amu) due to successive addition of methylene (CH2) groups to the PAH skeletons [4]. Raman spectra of the micron-sized solid inclusions of the halites indicate the presence of abundant and highly variable organic matter that include a mixture of short-chain aliphatic compounds and macromolecular carbon. C-XANES analysis identified C-rich areas with peaks at 285.0 eV (aromatic C=C) and 286.6 eV (vinyl-keto C=O). However, there is no 1s-sigma* exciton peak (291.7 eV) that is indicative of the development of graphene structure [5], which suggests the organics were synthesized cold. Na-noSIMS analyses show C-rich and N-rich areas that exhibit similar isotopic values with that of the IOM in the unweathered CR chondrites and less metamorphosed meteorites [6], and are moderately enriched in N-15 (delta N-15 = 106.1-164.5 per mille). The total amino acid distribution and abundance of the Zag matrix (approximately 1,940 parts per billion [ppb]) is comparable to other ordinary chondrites (60-3,330 ppb) [7, 8]. While the Zag matrix is gamma-ABA and EACA-deficient, the halite is shown to exhibit an opposite trend and is almost depleted in amino acids. The striking difference in the amino acid contents between the halite and matrix indicates their separate synthetic origins. Conclusion: Abundant, primitive, and highly-diverse N-15-rich organic compounds were detected in brine-water bearing halite crystals that were synthesized on a cryovolcanically-active asteroid. Our study suggests that the asteroidal parent body where the halite precipitated, potentially Ceres, is a host to abundance large variety organic precursors. Insoluble organic matter and amino acids can be synthesized from similar organic precusors under hydrous conditions [9].We envision that similar organic synthetic processes could have occurred on Ceres that synthesized organic solids as well as biologically relevant molecules.

Chan, Q. H. S.↗
NASA NTRS1975

The SAR arc event observed during the December 1971 magnetic storm

Observations from five separate experiments on the Isis 2 spacecraft are used to study the atmosphere/ionosphere during the magnetic storm of December 16-20, 1971. The data are most complete in the midlatitude region, permitting a study of the SAR arc (subauroral red arc) which developed during the night of December 17-18. Ion composition and temperature, electron temperature, electron-density height profiles from the spacecraft to the F region, and the intensity of the 6300-A oxygen emission are all presented for the region of interest. It is found that the H(+) concentration had sharp gradients near the SAR arc and that the plasma temperature was significantly enhanced over typical nighttime values, reaching nearly 7000 K at 1400 km on the field line which intersected the arc. A system of time-dependent equations for atmospheric/ionospheric composition and temperature is solved using boundary conditions which were selected so that the solutions are in agreement with the observations. From these solutions, an assessment is made of the influence of (1) the efflux of plasma from the ionosphere to the magnetosphere, (2) the decrease in O/N2 at the turbopause, (3) the increase in the loss coefficient as a result of an increase in the vibrational temperature of N2, and (4) the conduction of thermal energy into the ionosphere.

Maier, E. J.↗
NASA NTRS1980

Advances in membrane technology for the NASA redox energy storage system

Anion exchange membranes used in the system serve as a charge transferring medium as well as a reactant separator and are the key enabling component in this storage technology. Each membrane formulation undergoes a series of screening tests for area-resistivity, static (non-flow) diffusion rate determination, and performance in Redox systems. The CDIL series of membranes has, by virtue of its chemical stability and high ion exchange capacity, demonstrated superior properties in the redox environment. Additional resistivity results at several acid and iron solution concentrations, iron diffusion rates, and time dependent iron fouling of the various membrane formulations are presented in comparison to past standard formulations.

Ling, J. S.↗
NASA NTRS1987

Yosemite Conference on Ionospheric Plasma in the Magnetosphere: Sources, Mechanisms and Consequences, meeting report

The sixth biennial Yosemite topical conference and the first as a Chapman Conference was held on February 3 to 6, 1986. Due to the recent changes in our perception of the dynamics of the ionospheric/magnetospheric system, it was deemed timely to bring researchers together to discuss and contrast the relative importance of solar versus terrestrial sources of magnetospheric plasma. Although the solar wind was once thought to dominate the supply of plasma in the Earth's magnetosphere, it is now thought that the Earth's ionosphere is a significant contributor. Polar wind and other large volume outflows of plasma have been seen at relatively high altitudes over the polar cap and are now being correlated with outflows found in the magnetotail. The auroral ion fountain and cleft ion fountain are examples of ionospheric sources of plasma in the magnetosphere, observed by the Dynamics Explorer 1 (DE 1) spacecraft. The conference was organized into six sessions: four consisting of prepared oral presentations, one poster session, and one session for open forum discussion. The first three oral sessions dealt separately with the three major topics of the conference, i.e., the sources, mechanisms, and consequences of ionospheric plasma in the magnetosphere. A special session of invited oral presentations was held to discuss extraterrestrial ionospheric/magnetospheric plasma processes. The poster session was extended over two evenings during which presenters discussed their papers on a one-on-one basis. The last session of the conferences was reserved for open discussions of those topics or ideas considered most interesting or controversial.

Gallagher, D. L.↗
NASA NTRS1991

A case study of the cusp electrodynamics by the Aureol-3 satellite - Evidence for FTE signatures?

Particle and field data from a pass of the Aureol-3 satellite through the polar cusp, several minutes after the southward turning of the IMF, are analyzed in detail. Superposed on the classical cusp, characterized by the typical ion and electron precipitations, several very narrow arcs are detected where large fluxes of electrons and ions, accelerated to 2-4 keV, precipitate simultaneously. These localized arcs correspond to the upward current sheets of a succession in latitude of narrow, alternatively upward and downward field-aligned current sheets. The data suggest that the satellite has crossed the ionospheric footprints of 2 adjacent flux transfer events separated by 100-150 km in latitude. Electric spikes and electromagnetic turbulence are typically associated with the region of downward currents.

Bosqued, Jean M.↗
NASA NTRS1974

The determination of ethanol in blood and urine by mass fragmentography

A mass fragmentographic technique for a rapid, specific and sensitive determination of ethanol in blood and urine is described. A Varian gas chromatograph coupled through an all-glass membrane separator to a Finnigan quadripole mass spectrometer and interfaced to a computer system is used for ethanol determination in blood and urine samples. A procedure for plotting calibration curves for ethanol quantitation is also described. Quantitation is achieved by plotting the peak area ratios of undeuterated-to-deuterated ethanol fragment ions against the amount of ethanol added. Representative results obtained by this technique are included.

Pereira, W. E.↗
NASA NTRS1985

Effect of R(3+) ions on the structure and properties of lanthanum borate glasses

The present investigation of glass formation in the (mole percent) systems 25La2O3 (x)R2O3 (75-x)B2O3, where R = Al, Ga, and (25-x)La2O3 (x)Ln2O3 75B2O3, where Ln = Gd, Er, Y, notes that up to 25 mol pct Al2O3 or Ga2O3 can be substituted for B2O3, while no more than about 5 mol pct Ln2O3, substituted for La2O3, caused macro-phase separation. The substitution of either R2O3 or Ln2O3 in the lanthanum borate system changes the separation distance between adjacent B3O6 chains. The effect of this structural change on the molar volume, transformation temperature, thermal expansion coefficient, and transformation-range viscosity is discussed.

Chakraborty, I. N.↗
NASA NTRS1976

Substorm phenomena and the uniqueness of the geostationary orbit for observation of dynamic processes in the magnetosphere

During the Spring equinox, both ATS-6 and ATS-5 were in geosynchronous orbit with a separation of about 11 deg longitude. A ground-based campaign was undertaken by Eather, Mende, and Judge to observe aurora at the foot of the ATS field line with a variety of instruments. Initial results support the injection boundary hypothesis of Mauk and McIlwain. Also during this period, the Cs-ion thrusters on both spacecraft were exercized in a deliberate attempt to control the spacecraft potential. Some success was achieved, and the presence of a sheath with a potential minimum about ATS-5 has been demonstrated (the sheath about ATS-6 is observed directly).

Deforest, S. E.↗
NASA NTRS1988

Solar, planetary, and other inert gases in two sieve fractions of a disaggregated Allende sample - A study by stepwise heating extraction

Inert gases released by stepwise heating of unaltered, strongly magnetic, and weakly magnetic samples from the 0-64 micron and the 105-250 micron fractions of a disaggregated and sieved sample of the Allende meteorite reveal the occurrence of both solar and planetary neon. The origin of the solar neon is thought to be implantation of solar wind ions. The origin of the planetary neon remains unresolved. Heavy isotope enriched components of krypton and xenon have been detected and there are some indications that a light krypton component may also be present. Other than a larger concentration of Xe-129 in the weakly magnetic samples, the signatures of the magnetic separates are isotopically very similar.

Palma, R. L.↗
NASA NTRS1990

Ultraviolet gas absorption and dust extinction toward M8

Interstellar absorption lines are analyzed using high-resolution IUE spectra of 11 stars in the young cluster NGC 6530 located in the M8 region. High-velocity clouds at -35 km/s and -60 km/s are seen toward all cluster stars. The components arise in gases that are part of large interstellar bubbles centered on the cluster and driven by stellar winds of the most luminous members. Absorption lines of species of different ionization states are separated in velocity. The velocity stratification is best explained as a 'champagne' flow of ionized gas away from the cluster. The C IV/Si IV ratios toward the hotter cluster members are consistent with simple photoionization models if the gas-phase C/Si ratio is increased by preferential accretion onto dust grains. High ion column densities in the central cluster decline with distance from W93, suggesting that radiation from a hot source near W93 has photoionized gas in the central cluster.

Boggs, Don↗
NASA NTRS1998

Observation of Isolated Structures of the Low Latitude Boundary Layer with the INTERBALL/Tail Probe

We analyze the structure of magnetospheric transients observed at the dusk-side low-latitude magnetopause with the Interball Tail Probe. Ion and magnetic field measurements are used to investigate one particular transient in more detail. This transient has distinct non-symmetric structure with the plasma characteristics and the flow properties of the leading part of the transient being quite different from those in the trailing part of the transient. The region separating these two parts corresponds to the change of the sign in the B(n) component. These observations support an earlier conclusion that some plasma irregularities within the Low Latitude Boundary Layer (LLBL), formed as a result of sporadic reconnection, disconnect from the magnetopause, propagate and dissipate in the magnetosphere, and form what we call Disconnected Magnetosheath Transfer Events (DMTEs).

Vaisberg, 0. L.↗
NASA NTRS1999

Source Distributions of Substorm Ions Observed in the Near-Earth Magnetotail

This study employs Geotail plasma observations and numerical modeling to determine sources of the ions observed in the near-Earth magnetotail near midnight during a substorm. The growth phase has the low-latitude boundary layer as its most important source of ions at Geotail, but during the expansion phase the plasma mantle is dominant. The mantle distribution shows evidence of two distinct entry mechanisms: entry through a high latitude reconnection region resulting in an accelerated component, and entry through open field lines traditionally identified with the mantle source. The two entry mechanisms are separated in time, with the high-latitude reconnection region disappearing prior to substorm onset.

Ashour-Abdalla, M.↗
NASA NTRS2021

Simultaneous UV Images and High-Latitude Particle and Field Measurements During an Auroral Dawn Storm at Jupiter

We present multi-instrument Juno observations on day-of-year 86, 2017 that link particles and fields in Jupiter's polar magnetosphere to transient UV emissions in Jupiter's northern auroral region known as dawn storms. Juno ranged from 42°N to 51°N in magnetic latitude and 5.8–7.8 Jovian radii (1 RJ = 71,492 km) during this period. These dawn storm emissions consisted of two separate, elongated structures which extended into the nightside, rotated with the planet, had enhanced brightness (up to at least 1.4 megaRayleigh) and high color ratios. The color ratio is a proxy for the atmospheric penetration depth and therefore the energy of the electrons that produce the UV emissions. Juno observed electrons and ions on magnetic field lines mapping to these emissions. The electrons were primarily field-aligned, bidirectional, and, at times, exhibited sudden intensity decreases below ∼10 keV coincident with intensity enhancements up to energies of ∼1,000 keV, consistent with the high color ratio observations. The more energetic electron distributions had characteristic energies of ∼160–280 keV and downward energy fluxes (∼70–135 mW m−2) that were a significant fraction needed to produce the UV emissions for this event. Magnetic field perturbations up to ∼0.7% of the local magnetic field showing evidence of upward and downward field-aligned currents, whistler mode waves, and broadband kilometric radio emissions were also observed along Juno's trajectory during this time frame. These high-latitude observations show similarities to those in the equatorial magnetosphere associated with dynamics processes such as interchange events, plasma injections, and/or tail reconnection.

R. W. Ebert↗
NASA NTRS1991

Station keeping strategy for multiple spacecraft interferometry

The feasibility of multiple spacecraft stationkeeping for submillimeter and optical interferometry is examined. A condition for interferometry is that two or more spacecraft must control their relative positions with better than 1 mn accuracy indefinitely in both radial and transverse directions although separated by as much as 1 Km in LEO and 100 Km in GEO. They must also maneuver through a useful area of the U-V plane of an arbitrary astronomical source. The problem is first outlined and a solution which utilizes gravity gradient forces to do most of the work and ion thrusters for additional maneuvering is proposed. All the perturbing forces are shown to be small compared to the ion thruster requirements. An inertial position and attitude control strategy is suggested which utilizes existing or soon to be available sensors and actuators. Finally, the fuel and power system mass requirements are estimated and found to be within reason for a 10 year mission.

Decou, Anthony B.↗
NASA NTRS2011

Wind and Temperature Spectrometry of the Upper Atmosphere in Low-Earth Orbit

Wind and Temperature Spectrometry (WATS) is a new approach to measure the full wind vector, temperature, and relative densities of major neutral species in the Earth's thermosphere. The method uses an energy-angle spectrometer moving through the tenuous upper atmosphere to measure directly the angular and energy distributions of the air stream that enters the spectrometer. The angular distribution gives the direction of the total velocity of the air entering the spectrometer, and the energy distribution gives the magnitude of the total velocity. The wind velocity vector is uniquely determined since the measured total velocity depends on the wind vector and the orbiting velocity vector. The orbiting spectrometer moves supersonically, Mach 8 or greater, through the air and must point within a few degrees of its orbital velocity vector (the ram direction). Pointing knowledge is critical; for example, pointing errors 0.1 lead to errors of about 10 m/s in the wind. The WATS method may also be applied without modification to measure the ion-drift vector, ion temperature, and relative ion densities of major ionic species in the ionosphere. In such an application it may be called IDTS: Ion-Drift Temperature Spectrometry. A spectrometer-based coordinate system with one axis instantaneously pointing along the ram direction makes it possible to transform the Maxwellian velocity distribution of the air molecules to a Maxwellian energy-angle distribution for the molecular flux entering the spectrometer. This implementation of WATS is called the gas kinetic method (GKM) because it is applied to the case of the Maxwellian distribution. The WATS method follows from the recognition that in a supersonic platform moving at 8,000 m/s, the measurement of small wind velocities in the air on the order of a few 100 m/s and less requires precise knowledge of the angle of incidence of the neutral atoms and molecules. The same is true for the case of ion-drift measurements. WATS also provides a general approach that can obtain non-equilibrium distributions as may exist in the upper regions of the thermosphere, above 500 km and into the exosphere. Finally, WATS serves as a mass spectrometer, with very low mass resolution of roughly 1 part in 3, but easily separating atomic oxygen from molecular nitrogen.

Herrero, Federico↗