Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “INTERCEPTION”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 667 records · Page 37
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Network Security Challenges and Countermeasures for Software-Defined Smart Grids: A Survey

The rise of grid modernization has been prompted by the escalating demand for power, the deteriorating state of infrastructure, and the growing concern regarding the reliability of electric utilities. The smart grid encompasses recent advancements in electronics, technology, telecommunications, and computer capabilities. Smart grid telecommunication frameworks provide bidirectional communication to facilitate grid operations. Software-defined networking (SDN) is a proposed approach for monitoring and regulating telecommunication networks, which allows for enhanced visibility, control, and security in smart grid systems. Nevertheless, the integration of telecommunications infrastructure exposes smart grid networks to potential cyberattacks. Unauthorized individuals may exploit unauthorized access to intercept communications, introduce fabricated data into system measurements, overwhelm communication channels with false data packets, or attack centralized controllers to disable network control. An ongoing, thorough examination of cyber attacks and protection strategies for smart grid networks is essential due to the ever-changing nature of these threats. Previous surveys on smart grid security lack modern methodologies and, to the best of our knowledge, most, if not all, focus on only one sort of attack or protection. This survey examines the most recent security techniques, simultaneous multi-pronged cyber attacks, and defense utilities in order to address the challenges of future SDN smart grid research. The objective is to identify future research requirements, describe the existing security challenges, and highlight emerging threats and their potential impact on the deployment of software-defined smart grid (SD-SG).

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2020

Quantitative Analysis of the Effects of Natural and Human Factors on a Hydrological System in Zhangweinan Canal Basin

Drought is a water deficit state caused by large-scale climate change that cannot be avoided by a water resource management system. Water scarcity refers to the unsustainable utilization of water resources over a long time, which is the result of water management policies. However, water deficits caused by drought and water scarcity often occur simultaneously and are indistinguishable. This study proposes a model-based simulation framework that can quantitatively distinguish natural factors (drought) from human factors (water scarcity) in a hydrological system. The simulation was applied to the Zhangweinan Canal Basin, based on the runoff sequences from 1950 to 2004. The results show that the runoff curve number, soil depth, soil available water, soil evaporation compensation coefficient, base runoff α coefficient and the maximum canopy interception have the highest sensitivity to runoff, and that the calibrated and validated SWAT model can effectively simulate the runoff process in the Zhangweinan Canal Basin and similar areas. Abrupt changes in human activities in 1975 and water scarcity led to the disappearance of the summer peak runoff period in both wet and dry years. Human factors are the main reason for the change in the hydrological system in the study area; the runoff loss caused by human factors is four times that caused by natural factors according to the proposed variable threshold. This study proposes a model-based simulation framework that can help water resource managers to distinguish the effects of drought and water scarcity in water-stressed areas and adjust management accordingly.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Salinity Contributions from Geothermal Waters to the Rio Grande and Shallow Aquifer System in the Transboundary Mesilla (United States)/Conejos-Médanos (Mexico) Basin

Freshwater scarcity has raised concerns about the long-term availability of the water supplies within the transboundary Mesilla (United States)/Conejos-Médanos (Mexico) Basin in Texas, New Mexico, and Chihuahua. Analysis of legacy temperature data and groundwater flux estimates indicates that the region’s known geothermal systems may contribute more than 45,000 tons of dissolved solids per year to the shallow aquifer system, with around 8500 tons of dissolved solids being delivered from localized groundwater upflow zones within those geothermal systems. If this salinity flux is steady and eventually flows into the Rio Grande, it could account for 22% of the typical average annual cumulative Rio Grande salinity that leaves the basin each year—this salinity proportion could be much greater in times of low streamflow. Regional water level mapping indicates upwelling brackish waters flow towards the Rio Grande and the southern part of the Mesilla portion of the basin with some water intercepted by wells in Las Cruces and northern Chihuahua. Upwelling waters ascend from depths greater than 1 km with focused flow along fault zones, uplifted bedrock, and/or fractured igneous intrusions. Overall, this work demonstrates the utility of using heat as a groundwater tracer to identify salinity sources and further informs stakeholders on the presence of several brackish upflow zones that could notably degrade the quality of international water supplies in this developed drought-stricken region.

Pepin, Jeff D. (ORCID:0000000274109979)↗
DOE OSTI2016

The [N ii] 205 μm emission in local luminous infrared galaxies

In this paper, we present the measurements of the [N ii] 205 μm line for a flux-limited sample of 122 (ultra-)luminous infrared galaxies [(U)LIRGs] and 20 additional normal galaxies, obtained with the Herschel Space Observatory (Herschel). We explore the far-infrared (FIR) color dependence of the [N ii] 205 μm (L{sub [N ii]205 μm}) to the total infrared (L{sub IR}) luminosity ratio, and find that L{sub [N ii]205 μm}/L{sub IR} only depends modestly on the 70–160 μm flux density ratio (f{sub 70}/f{sub 160}) when f{sub 70}/f{sub 160}≲0.6, whereas such dependence becomes much steeper for f{sub 70}/f{sub 160}>0.6. We also investigate the relation between L{sub [N ii]205 μm} and star formation rate (SFR), and show that L{sub [N ii]205 μm} has a nearly linear correlation with SFR, albeit the intercept of such a relation varies somewhat with f{sub 60}/f{sub 100}, consistent with our previous conclusion that [N ii] 205 μm emission can serve as an SFR indicator with an accuracy of ∼0.4 dex, or ∼0.2 dex if f{sub 60}/f{sub 100} is known independently. Furthermore, together with the Infrared Space Observatory measurements of [N ii], we use a total of ∼200 galaxies to derive the local [N ii] 205 μm luminosity function (LF) by tying it to the known IR LF with a bivariate method. As a practical application, we also compute the local SFR volume density ( ρ-dot {sub SFR}) using the newly derived SFR calibrator and LF. The resulting log ρ-dot {sub SFR}=−1.96±0.11 M{sub ⊙} yr{sup −1} Mpc{sup −3} agrees well with previous studies. Finally, we determine the electron densities (n{sub e}) of the ionized medium for a subsample of 12 (U)LIRGs with both [N ii] 205 μm and [N ii] 122 μm data, and find that n{sub e} is in the range of ∼1–100 cm{sup −3}, with a median value of 22 cm{sup −3}.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2016

ION ACCELERATION AT THE QUASI-PARALLEL BOW SHOCK: DECODING THE SIGNATURE OF INJECTION

Collisionless shocks are efficient particle accelerators. At Earth, ions with energies exceeding 100 keV are seen upstream of the bow shock when the magnetic geometry is quasi-parallel, and large-scale supernova remnant shocks can accelerate ions into cosmic-ray energies. This energization is attributed to diffusive shock acceleration; however, for this process to become active, the ions must first be sufficiently energized. How and where this initial acceleration takes place has been one of the key unresolved issues in shock acceleration theory. Using Cluster spacecraft observations, we study the signatures of ion reflection events in the turbulent transition layer upstream of the terrestrial bow shock, and with the support of a hybrid simulation of the shock, we show that these reflection signatures are characteristic of the first step in the ion injection process. These reflection events develop in particular in the region where the trailing edge of large-amplitude upstream waves intercept the local shock ramp and the upstream magnetic field changes from quasi-perpendicular to quasi-parallel. The dispersed ion velocity signature observed can be attributed to a rapid succession of ion reflections at this wave boundary. After the ions’ initial interaction with the shock, they flow upstream along the quasi-parallel magnetic field. Each subsequent wavefront in the upstream region will sweep the ions back toward the shock, where they gain energy with each transition between the upstream and the shock wave frames. Within three to five gyroperiods, some ions have gained enough parallel velocity to escape upstream, thus completing the injection process.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2016

MOLECULAR HYDROGEN ABSORPTION FROM THE HALO OF A z ∼ 0.4 GALAXY

Lyman- and Werner-band absorption of molecular hydrogen (H{sub 2}) is detected in ∼50% of low-redshift (z<1) DLAs/sub-DLAs with N(H{sub 2}) > 10{sup 14.4} cm{sup −2}. However, the true origin(s) of the H{sub 2}-bearing gas remain elusive. Here we report a new detection of an H{sub 2} absorber at z{sub abs} = 0.4298 in the Hubble Space Telescope (HST)/Cosmic Origins Spectrograph spectra of quasar PKS 2128–123. The total N(H i) of 10{sup 19.50±0.15} cm{sup −2} classifies the absorber as a sub-DLA. H{sub 2} absorption is detected up to the J = 3 rotational level with a total logN(H{sub 2}) = 16.36 ± 0.08, corresponding to a molecular fraction of logf{sub H{sub 2}} = −2.84 ± 0.17. The excitation temperature of T{sub ex} = 206 ± 6 K indicates the presence of cold gas. Using detailed ionization modeling, we obtain a near-solar metallicity (i.e., [O/H] = −0.26 ± 0.19) and a dust-to-gas ratio of logκ∼−0.45 for the H{sub 2}-absorbing gas. The host galaxy of the sub-DLA is detected at an impact parameter of ρ ∼ 48 kpc with an inclination angle of i ∼ 48° and an azimuthal angle of Φ ∼ 15° with respect to the QSO sightline. We show that corotating gas in an extended disk cannot explain the observed kinematics of Mg ii absorption. Moreover, the inferred high metallicity is not consistent with the scenario of gas accretion. An outflow from the central region of the host galaxy, on the other hand, would require a large opening angle (i.e., 2θ>150{sup ∘}), much larger than the observed outflow opening angles in Seyfert galaxies, in order to intercept the QSO sightline. We thus favor a scenario in which the H{sub 2}-bearing gas is stemming from a dwarf-satellite galaxy, presumably via tidal and/or ram pressure stripping. Detection of a dwarf galaxy candidate in the HST/WFPC2 image at an impact parameter of ∼12 kpc reinforces such an idea.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2016

Intra-binary shock heating of black widow companions

The low-mass companions of evaporating binary pulsars (black widows and similar) are strongly heated on the side facing the pulsar. However, in high-quality photometric and spectroscopic data, the heating pattern does not match that expected for direct pulsar illumination. Here we explore a model where the pulsar power is intercepted by an intra-binary shock (IBS) before heating the low-mass companion. We develop a simple analytic model and implement it in the popular “ICARUS” light curve code. The model is parameterized by the wind momentum ratio β and the companion wind speed f{sub v}v{sub orb}, and assumes that the reprocessed pulsar wind emits prompt particles or radiation to heat the companion surface. We illustrate an interesting range of light curve asymmetries controlled by these parameters. The code also computes the IBS synchrotron emission pattern, and thus can model black widow X-ray light curves. As a test, we apply the results to the high-quality asymmetric optical light curves of PSR J2215+5135; the resulting fit gives a substantial improvement upon direct heating models and produces an X-ray light curve consistent with that seen. The IBS model parameters imply that at the present loss rate, the companion evaporation has a characteristic timescale of τ{sub evap}≈150 Myr. Still, the model is not fully satisfactory, indicating that there are additional unmodeled physical effects.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2018

The Feasibility and Benefits of In Situ Exploration of ‘Oumuamua-like Objects

A rapid accumulation of observations and interpretation has followed in the wake of 1I ‘Oumuamua’s passage through the inner solar system. We briefly outline the consequences that this first detection of an interstellar asteroid implies for the planet-forming process, and we assess the near-term prospects for detecting and observing (both remotely and in situ) future solar system visitors of this type. Drawing on detailed heat-transfer calculations that take both ‘Oumuamua’s unusual shape and its chaotic tumbling into account, we affirm that the lack of a detectable coma in deep images of the object very likely arises from the presence of a radiation-modified coating of high molecular weight material (rather than a refractory bulk composition). Assuming that ‘Oumuamua is a typical representative of a larger population with a kinematic distribution similar to Population I stars in the local galactic neighborhood, we calculate expected arrival rates, impact parameters, and velocities of similar objects and assess their prospects for detection using operational and forthcoming facilities. Using ‘Oumuamua as a proof of concept, we assess the prospects for missions that intercept interstellar objects using conventional chemical propulsion. Using a “launch on detection” paradigm, we estimate wait times of order of 10 years between favorable mission opportunities with the detection capabilities of the Large-scale Synoptic Survey Telescope, a figure that will be refined as the population of interstellar asteroids becomes observationally better constrained.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2019

Orbital Deflection of Comets by Directed Energy

Cometary impacts pose a long-term hazard to life on Earth. Impact mitigation techniques have been studied extensively, but they tend to focus on asteroid diversion. Typical asteroid interdiction schemes involve spacecraft physically intercepting the target, a task feasible only for targets identified decades in advance and in a narrow range of orbits—criteria unlikely to be satisfied by a threatening comet. Comets, however, are naturally perturbed from purely gravitational trajectories via solar heating of their surfaces, which activates sublimation-driven jets. Artificial heating of a comet, such as by a laser, may supplement natural heating by the Sun to purposefully manipulate its path and thereby avoid an impact. Deflection effectiveness depends on the comet’s heating response, which varies dramatically depending on factors including nucleus size, orbit, and dynamical history. These factors are incorporated into a numerical orbital model to assess the effectiveness and feasibility of using high-powered laser arrays in Earth orbit and on the ground for comet deflection. Simulation results suggest that a diffraction-limited 500 m orbital or terrestrial laser array operating at 10 GW for 1% of each day over 1 yr is sufficient to fully avert the impact of a typical 500 m diameter comet with primary nongravitational parameter A {sub 1} = 2 × 10{sup −8} au day{sup −2}. Strategies to avoid comet fragmentation during deflection are also discussed.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2017

Light and Color Curve Properties of Type Ia Supernovae: Theory Versus Observations

We study the optical light curve (LC) relations of Type Ia supernovae (SNe Ia) for their use in cosmology using high-quality photometry published by the Carnegie Supernova Project (CSP-I). We revisit the classical luminosity decline rate (Δ m {sub 15}) relation and the Lira relation, as well as investigate the time evolution of the ( B − V ) color and B ( B − V ), which serves as the basis of the color–stretch relation and Color–MAgnitude Intercept Calibrations (CMAGIC). Our analysis is based on explosion and radiation transport simulations for spherically symmetric delayed-detonation models (DDT) producing normal-bright and subluminous SNe Ia. Empirical LC relations can be understood as having the same physical underpinnings, i.e., opacities, ionization balances in the photosphere, and radioactive energy deposition changing with time from below to above the photosphere. Some three to four weeks past maximum, the photosphere recedes to {sup 56}Ni-rich layers of similar density structure, leading to a similar color evolution. An important secondary parameter is the central density ρ {sub c} of the WD because at higher densities, more electron-capture elements are produced at the expense of {sup 56}Ni production. This results in a Δ m {sub 15} spread of 0.1 mag in normal-bright and 0.7 mag in subluminous SNe Ia and ≈0.2 mag in the Lira relation. We show why color–magnitude diagrams emphasize the transition between physical regimes and enable the construction of templates that depend mostly on Δ m {sub 15} with little dispersion in both the CSP-I sample and our DDT models. This allows intrinsic SN Ia variations to be separated from the interstellar reddening characterized by E ( B − V ) and R {sub B}. Invoking different scenarios causes a wide spread in empirical relations, which may suggest one dominant scenario.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Accretion of Gas Giants Constrained by the Tidal Barrier

After protoplanets have acquired sufficient mass to open partial gaps in their natal protostellar disks, residual gas continues to diffuse onto horseshoe streamlines under the effect of viscous dissipation, and to meander in and out of the planets' Hill sphere. Within the Hill sphere, the horseshoe streamlines intercept gas flow in circumplanetary disks. The host star's tidal perturbation induces a barrier across the converging streamlines' interface. Viscous transfer of angular momentum across this tidal barrier determines the rate of mass diffusion from the horseshoe streamlines onto the circumplanetary disks, and eventually the accretion rate onto the protoplanets. Here, we carry out a series of numerical simulations to test the influence of this tidal barrier on superthermal planets. In weakly viscous disks, the protoplanets' accretion rate steeply decreases with their masses above the thermal limit. As their growth timescale exceeds the gas depletion timescale, their masses reach asymptotic values comparable to that of Jupiter. In relatively thick and strongly viscous disks, protoplanets' asymptotic masses exceed several times that of Jupiter. Two-dimensional numerical simulations show that such massive protoplanets strongly excite the eccentricity of nearby horseshoe streamlines, destabilize orderly flow, substantially enhance the diffusion rate across the tidal barrier, and elevate their growth rate until their natal disk is severely depleted. In contrast, eccentric streamlines remain stable in three-dimensional simulations. Based on the upper falloff in the observed mass distribution of known exoplanets, we suggest that their natal disks had relatively low viscosity (α ~ 10 –3 ) and modest thickness (H/R ~ 0.03–0.05).

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2025

Evaluating Short-warning Mitigation via Intentional Robust Disruption of a Hypothetical Impact of Asteroid 2023 NT1

We investigate various short-warning mitigation scenarios via fragmentation for a hypothetical impact of asteroid 2023 NT1, a near-Earth object (NEO) that was discovered on 2023 July 15, two days after its closest approach to Earth on July 13. The asteroid passed by Earth within ∼0.25 lunar distances, with a closest approach of ∼1 × 10 5 km and a velocity of 11.27 km s −1 . Its size remains largely uncertain, with an estimated diameter range of 26–58 m and a most probable estimate of 34 m (JPL Sentry, 2023 September 15; weighted by the NEO size frequency distribution). If 2023 NT1 had collided with Earth, it could have caused significant local damage. Assuming a spherical asteroid with a diameter of 34 m, uniform density of 2.6 g cm −3 , and impact velocity of 15.59 km s −1 , a collision would have yielded an estimated impact energy of ∼1.5 Mt, approximately 3 times the energy of the Chelyabinsk airburst in 2013. We analyze the effectiveness of mitigation via intentional robust disruption for objects similar to 2023 NT1. We utilize Pulverize It (PI), a NASA Innovative Advanced Concepts study of planetary defense via fragmentation, to model potential mitigation scenarios through simulations of hypervelocity asteroid disruption and atmospheric ground effects in the case of a terminal defense mode. Simulations suggest that PI is an effective multimodal approach for planetary defense that can operate in extremely short interdiction modes, in addition to long interdiction timescales with extended warning. Our simulations support the proposition that threats like 2023 NT1 can be effectively mitigated with intercepts of 1 day (or less) prior to impact, yielding minimal to no ground damage.

Asteroids↗
DOE OSTI2022

Thermodynamics of the Inner Heliosheath

We derive annual sky maps of the proton temperature in the inner heliosheath (IHS), and track their temporal evolution over the years 2009–2016 of Interstellar Boundary Explorer observations. Other associated thermodynamic parameters also determined are the density, kappa (the parameter that characterizes kappa distributions), temperature rate, polytropic index, and entropy. We exploit the theory of kappa distributions and their connection with polytropes, to (i) express a new polytropic quantity Π that remains invariant along streamlines where temperature and density may vary, (ii) parameterize the proton flux in terms of the Π invariant and kappa, and (iii) derive the temperature and density, respectively, from the slope and intercept of the linear relationship between kappa and logarithm of Π. We find the following thermodynamic characteristics: (1) temperature sky maps and histograms shifted to their lowest values in 2012 and their highest in 2015; (2) temperature negatively correlated with density, reflecting the subisothermal polytropic behavior; (3) temperature positively correlated with kappa, revealing characteristics of the mechanism responsible for generating kappa distributions; (4) processes in IHS are subisothermal tending toward isobaric, consistent with previously published results; (5) linear relationship between kappa and polytropic indices, revealing characteristics of the particle potential energy; and (6) entropy positively correlated with polytropic index, aligned with the underlying theory that entropy increases toward the isothermal state where the kappa distribution reduces to the Maxwell–Boltzmann description.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2016

NEW CONSTRAINTS ON A COMPLEX RELATION BETWEEN GLOBULAR CLUSTER COLORS AND ENVIRONMENT

We present an analysis of high-quality photometry for globular clusters (GCs) in the Virgo cluster core region, based on data from the Next Generation Virgo Cluster Survey (NGVS) pilot field, and in the Milky Way (MW), based on Very Large Telescope/X-Shooter spectrophotometry. We find significant discrepancies in color–color diagrams between sub-samples from different environments, confirming that the environment has a strong influence on the integrated colors of GCs. GC color distributions along a single color are not sufficient to capture the differences we observe in color–color space. While the average photometric colors become bluer with increasing radial distance to the cD galaxy M87, we also find a relation between the environment and the slope and intercept of the color–color relations. A denser environment seems to produce a larger dynamic range in certain color indices. We argue that these results are not due solely to differential extinction, Initial Mass Function variations, calibration uncertainties, or overall age/metallicity variations. We therefore suggest that the relation between the environment and GC colors is, at least in part, due to chemical abundance variations, which affect stellar spectra and stellar evolution tracks. Our results demonstrate that stellar population diagnostics derived from model predictions which are calibrated on one particular sample of GCs may not be appropriate for all extragalactic GCs. These results advocate a more complex model of the assembly history of GC systems in massive galaxies that goes beyond the simple bimodality found in previous decades.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2017

Recalibration of the M {sub BH}– σ {sub ⋆} Relation for AGN

We present a recalibration of the M {sub BH}– σ {sub ⋆} relation, based on a sample of 16 reverberation-mapped galaxies with newly determined bulge stellar velocity dispersions ( σ {sub ⋆}) from integral-field spectroscopy (IFS), and a sample of 32 quiescent galaxies with publicly available IFS. For both samples, σ {sub ⋆} is determined via two different methods that are popular in the literature, and we provide fits for each sample based on both sets of σ {sub ⋆}. We find the fit to the active galactic nucleus sample is shallower than the fit to the quiescent galaxy sample, and that the slopes for each sample are in agreement with previous investigations. However, the intercepts to the quiescent galaxy relations are notably higher than those found in previous studies, due to the systematically lower σ {sub ⋆} measurements that we obtain from IFS. We find that this may be driven, in part, by poorly constrained measurements of bulge effective radius ( r{sub e}) for the quiescent galaxy sample, which may bias the σ {sub ⋆} measurements low. We use these quiescent galaxy parameterizations, as well as one from the literature, to recalculate the virial scaling factor f . We assess the potential biases in each measurement, and suggest f = 4.82 ± 1.67 as the best currently available estimate. However, we caution that the details of how σ {sub ⋆} is measured can significantly affect f , and there is still much room for improvement.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2018

Agricultural Burning and Air Quality over Northern India: A Synergistic Analysis using NASA’s A-train Satellite Data and Ground Measurements

In recent years, New Delhi, the capital city of India, has been ranked among the most polluted cities in the world in terms of air quality related to Particulate Matter (PM). In this paper, we show that the PM 2.5 , a major component of the measure of air quality, over New Delhi is strongly impacted by the agricultural fires in the north-western Indian states of Punjab and Haryana during the post-monsoon season (October and November). Using data from NASA’s A-train sensors (MODIS, OMI, and CALIOP) in conjunction with the ground-level PM 2.5 mass concentration measured at the US Embassy site in New Delhi (2013-2015), and back-trajectory analysis, it is shown that the smoke particles produced from numerous fires in Punjab and Haryana are advected over the national capital region under the influence of north-westerly winds, thereby greatly increasing the ground-level PM 2.5 from 50 µg/m -3 before the onset of burning in early October to as high as 300 µg/m -3 (24-hour averaged, 7-day running mean) during the peak burning period in early November. Relationships between the satellite measurements of fire counts and aerosols in the crop burning region and PM 2.5 over New Delhi are found to be strongly correlated. A linear regression analysis reveals that increments in the fire counts, aerosol optical depth, UV Aerosol Index, and aerosol absorption optical depth by 100, 1.0, 1.0, and 0.1 over the burning areas result in an increase in PM 2.5 by 20, 47, 134, and 142 µg/m -3 , respectively, over New Delhi. Back-trajectory analysis shows that about 74%, 62%, and 51% of total number of daily trajectories for altitudes 10 m, 500 m, and 1500 m, respectively, intercepted the biomass burning region before arriving at the receptor location in New Delhi; this further corroborates the transport mechanism observed in the satellite data. A 15-year long record of A-train satellite measurements shows an increasing number of agricultural fires (29% higher) and aerosol loading during the second half of the record (2009-2015) compared to that during the first half (2002-2008), which is one of the major concerns for the deteriorating air quality in the region.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2015

Molecular characterization of free tropospheric aerosol collected at the Pico Mountain Observatory: a case study with a long-range transported biomass burning plume

Free tropospheric aerosol was sampled at the Pico Mountain Observatory located at 2225 m above mean sea level on Pico Island of the Azores archipelago in the North Atlantic. The observatory is located ~ 3900 km east and downwind of North America, which enables studies of free tropospheric air transported over long distances. Aerosol samples collected on filters from June to October 2012 were analyzed to characterize organic carbon, elemental carbon, and inorganic ions. The average ambient concentration of aerosol was 0.9 ± 0.7 μg m -3 . On average, organic aerosol components represent the largest mass fraction of the total measured aerosol (60 ± 51%), followed by sulfate (23 ± 28%), nitrate (13 ± 10%), chloride (2 ± 3%), and elemental carbon (2 ± 2%). Water-soluble organic matter (WSOM) extracted from two aerosol samples (9/24 and 9/25) collected consecutively during a pollution event were analyzed using ultrahigh-resolution electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry. Approximately 4000 molecular formulas were assigned to each of the mass spectra in the range of m/z 100–1000. The majority of the assigned molecular formulas had unsaturated structures with CHO and CHNO elemental compositions. FLEXPART retroplume analyses showed the sampled air masses were very aged (average plume age > 12 days). These aged aerosol WSOM compounds had an average O/C ratio of ~ 0.45, which is relatively low compared to O/C ratios of other aged aerosol. The increase in aerosol loading during the measurement period of 9/24 was linked to biomass burning emissions from North America by FLEXPART retroplume analysis and Moderate Resolution Imaging Spectroradiometer (MODIS) fire counts. This was confirmed with biomass burning markers detected in the WSOM and with the morphology and mixing state of particles as determined by scanning electron microscopy. The presence of markers characteristic of aqueous-phase reactions of phenolic species suggests that the aerosol collected at the Pico Mountain Observatory had undergone cloud processing before reaching the site. Finally, the air masses of 9/25 were more aged and influenced by marine emissions, as indicated by the presence of organosulfates and other species characteristic of marine aerosol. The change in the air masses for the two samples was corroborated by the changes in ethane, propane, and ozone, morphology of particles, as well as by the FLEXPART retroplume simulations. This paper presents the first detailed molecular characterization of free tropospheric aged aerosol intercepted at a lower free troposphere remote location and provides evidence of low oxygenation after long-range transport. We hypothesize this is a result of the selective removal of highly aged and polar species during long-range transport, because the aerosol underwent a combination of atmospheric processes during transport facilitating aqueous-phase removal (e.g., clouds processing) and fragmentation (e.g., photolysis) of components.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Droplet collection efficiencies inferred from satellite retrievals constrain effective radiative forcing of aerosol–cloud interactions

Abstract. Process-oriented observational constraints for the anthropogenic effective radiative forcing due to aerosol–cloud interactions (ERFaci) are highly desirable because the uncertainty associated with ERFaci poses a significant challenge to climate prediction. The contoured frequency by optical depth diagram (CFODD) analysis supports the evaluation of model representation of cloud liquid-to-rain conversion processes because the slope of a CFODD, generated from joint MODerate Resolution Imaging Spectroradiometer (MODIS)-CloudSat cloud retrievals, provides an estimate of cloud droplet collection efficiency in single-layer warm liquid clouds. Here, we present an updated CFODD analysis as an observational constraint on the ERFaci due to warm rain processes and apply it to the U.S. Department of Energy's Energy Exascale Earth System Model version 2 (E3SMv2). A series of sensitivity experiments shows that E3SMv2 droplet collection efficiencies and ERFaci are highly sensitive to autoconversion, i.e., the rate of mass transfer from cloud liquid to rain, yielding a strong correlation between the CFODD slope and the shortwave component of ERFaci (ERFaciSW; Pearson's R=-0.91). E3SMv2's CFODD slope (0.20 ± 0.04) is in agreement with observations (0.20 ± 0.03). The strong sensitivity of ERFaciSW to the CFODD slope provides a useful constraint on highly uncertain warm rain processes, whereby ERFaciSW, constrained by MODIS-CloudSat, is estimated by calculating the intercept of the linear association between the ERFaciSW and the CFODD slopes, using the MODIS-CloudSat CFODD slope as a reference.

Beall, Charlotte M. (ORCID:0000000311370835)↗