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At least 667 records · Page 37

Nanoporous Wood Chips Based Sizable, Robust, and Low-Cost Honeycomb Vacuum Insulation Panels (DOE BENEFIT Final Research Performance Progress Report (RPPR))

Conventional vacuum insulation panels (VIPs) suffer from severe limitations including high cost, vulnerability to perforation, and significant performance degradation over time due to vacuum loss. InventWood Inc. (IW) and partnering teams completely re-engineered the VIP structure by constructing arrays of isolated vacuum-cells to enable limited cutting at designated areas (in between vacuum cells) and reduced consequential vacuum loss due to puncture. The teams also replaced the expensive vacuum insulation core materials with a low-cost commercial wood pulp and recycled long fiber. The wood pulp derived VIP can deliver an overall panel insulation of R15 (<0.01W/m·K) with over 90% thermal resistance retention after cutting (R13.5 overall, R5 along the cut edges). In addition, the vacuum-cell-array design minimizes edge losses, resulting in more durable performance, longer service life (>50 years), and higher R-value per dollar towards a cost target of <$1/ft 2 ·in. It is anticipated that the Nanochip-VIP will attract strong market interest and become an affordable insulation solution for energy efficient buildings and retrofits, leading to significant reductions in energy usage.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Pull Force Evaluation of CCS Insulated End Caps

Insulated end caps installed on DC pins of Combined Charging System (CCS) inlets have been identified as potential debris sources within electric vehicle supply equipment (EVSE) connectors, increasing the risk of electric shock and fire hazards. Although standards such as IEC 62196-1:2022 specify mechanical pull-force requirements for these end caps, it remains unclear whether these requirements provide adequate robustness under real-world conditions. To address this concern, the National Charging Experience (ChargeX) Consortium's Hardware Task Force conducted evaluations of insulated end caps used in OEM CCS inlets. This study assesses the performance of insulated end caps used in OEM CCS inlets, specifically those installed on DC pins, using the procedures defined in IEC 62196-1:2022 (Section Sign) 26.7 and SAE J3400, supplemented by additional experimental conditioning. To ensure relevance to real-world conditions, NLR collaborated with charging network operators (CNOs) to guide the selection of charging inlet samples. Material analyses of the insulated end cap samples were conducted to confirm that the tested materials reflected the types and properties commonly observed in the field. The selected samples underwent temperature and humidity conditioning followed by pull-force testing to evaluate the end-cap integrity. Although SAE J3400 inlets were not directly tested due to limited diversity in available field data, the underlying end-cap principles between CCS and SAE J3400 are comparable, allowing the study's insights to be relevant to both technologies. Overall, this study provides a structured evaluation framework to inform potential refinements to mechanical pull-force requirements in charging standards.

33 ADVANCED PROPULSION SYSTEMS↗

Demonstration of Hybrid Multilayer Insulation for Fixed Thickness Applications

Once on orbit, high performing insulation systems for cryogenic systems need just as good radiation (optical) properties as conduction properties. This requires the use of radiation shields with low conductivity spacers in between. By varying the height and cross-sectional area of the spacers between the radiation shields, the relative radiation and conduction heat transfers can be manipulated. However, in most systems, there is a fixed thickness or volume allocated to the insulation. In order to understand how various combinations of different multilayer insulation (MLI) systems work together and further validate thermal models of such a hybrid MLI set up, test data is needed. The MLI systems include combinations of Load Bearing MLI (LB-MLI) and traditional MLI. To further simulate the space launch vehicle case wherein both ambient pressure and vacuum environments are addressed, different cold-side thermal insulation substrates were included for select tests.

Cryogenic Fluid Management↗

Absorption Voltages and Insulation Resistance in Ceramic Capacitors with Cracks

Time dependence of absorption voltages (Vabs) in different types of low-voltage X5R and X7R ceramic capacitors was monitored for a maximum duration of hundred hours after polarization. To evaluate the effect of mechanical defects on Vabs, cracks in the dielectric were introduced either mechanically or by thermal shock. The maximum absorption voltage, time to roll-off, and the rate of voltage decrease are shown to depend on the crack-related leakage currents and insulation resistance in the parts. A simple model that is based on the Dow equivalent circuit for capacitors with absorption has been developed to assess the insulation resistance of capacitors. Standard measurements of the insulation resistance, contrary to the measurements based on Vabs, are not sensitive to the presence of mechanical defects and fail to reveal capacitors with cracks. Index Terms: Ceramic capacitor, insulation resistance, dielectric absorption, cracking.

cracking↗

Advanced Cryogenic Insulation Systems

New materials in recent decades have enabled advances in thermal insulation systems for storage and transfer of cryogens. To preserve the cold and achieve efficient cryogenic systems, a combination of materials, testing, and engineering is required. The total heat leak into any cryogenic assembly is comprised of three main parts: 1) heat leak through the insulation, 2) heat leak through the support structures, and 3) heat leak attributed to piping penetrations and feedthroughs (and their negative effects on the insulation). This "cold triangle" approach provides a basis for evaluating performance benefits of new materials and analyzing the cost effectiveness in overall system design. Provided are thermophysical data for aerogels, aerogel composites, novel multilayered composites, and glass bubbles for standard test conditions of 293 K and 78 K under conditions from high vacuum to ambient pressure. Examples of cryogenic storage tanks show the relative importance of both insulation and structural materials for achieving designs of highest energy efficiency.

Multilayer Insulation↗

Summary of Testing Results for the Structural Heat Intercept, Insulation, and Vibration Evaluation Rig (SHIIVER)

Testing was completed on the Structural Heat Intercept, Insulation, and Vibration Evaluation Rig (SHIIVER) between August 2019 and January 2020. SHIIVER was designed to be a test bed for the scaling of cryogenic fluid management technologies as applied to large upper stages and long duration in-space stages. The baseline SHIIVER design consists of uninsulated structural skirts attached to a propellant tank insulated with polyurethane Spray-On Foam Insulation (SOFI). The initial testing of the SHIIVER hardware was with liquid hydrogen and sought to demonstrate the use of boil-off vapor to intercept heat on a structural skirt, multilayer insulation (MLI) on the tank domes, and the radio frequency mass gauge (RFMG). Testing was completed in four stages: a baseline thermal vacuum test prior to installation of the MLI on the tank domes, a thermal vacuum test after the MLI installation, a reverberant acoustic test, and a subsequent thermal vacuum test to verify that no damage occurred during the reverberant acoustic testing. Each thermal vacuum test with chamber wall at ambient temperature and vacuum level in the 10-6 torr range was conducted continuously between approximately 90% full and 25% full. Test results showed that the vapor cooling reduced the heat load to the tank by approximately 10%, but the boil-off by less than 3% at 50% full, with and without MLI installed on the domes. The MLI installed on the domes reduced the heat load to the tank by approximately 40% at all fill levels, but the boil-off by approximately 25% at 90% full and 45% below 65% full. The RFMG performed well over all fill ranges, and several RF tank modes were used to gauge the mass of fluid in the tank. SHIIVER was then exposed to an acoustic environment of 147 dB OASPL (overall sound pressure level) in a reverberant chamber. The acoustic environment envelopes the upper stage internal acoustic level of several different modern launch vehicles. No structural or thermal performance changes were observed after exposure to the acoustic environment. Final thermal vacuum testing after the acoustic testing showed no degradation to the MLI due to the acoustic environment as measured via system heat loads

SHIIVER↗

Modernization of Insulative Reusable Thermal Protection Systems (IRTPS)

Insulative thermal protection systems, such as Flexible Reusable Surface Insulation blankets and High Temperature Reusable Surface Insulation tiles, were developed for the Shuttle Orbiter to enable reuse of the vehicle for low-earth orbit missions. Since reusability is essential to many new industry launch and space vehicles, Shuttle-derived thermal protection materials (TPMs) are being sought for their flight proven performance. Alumina Enhanced Thermal Barrier (AETB) is the state-of-the-art tile material that was developed in the 90’s. AETB along with associated coatings, reaction cured glass (RCG) and Toughened Unipiece Fibrous Insulation (TUFI), are currently made by NASA using heritage raw materials derived from lifetime purchases. Finding viable replacements for raw materials that have changed in nature or are obsolete is important for continuation of these TPMs. In some cases, the use of modern raw materials has been shown to yield tile with reduced performance, most notably in mechanical properties. ​ In this work, the production of AETB will be discussed to better understand the process-structure-property relationships and for allowing use of these modern alternatives. A small-scale tile casting system was developed for rapid and efficient exploration of the manufacturing variables such raw material selection and pre-processing, casting process parameters, and billet firing protocols. An optical transmission defect characterization technique was implemented to correlate process variables to structure. Comparisons between TUFI/RCG coated AETB derived from heritage and modern raw materials will be shown including AHF arc jet test results completed under a collaboration with Stratolaunch.

thermal protection materials↗

Interdigital Capacitance Sensor for Cable Insulation Test and Monitoring

A substantial body of work suggests feasibility to measure cable jacket and insulation conditions using various forms of interdigital capacitance (IDC) sensors. The sensors can either be used to manually test local cable conditions or as permanently installed sensors. Eligible cables subject to these measurements do not include shielded cables but the set of candidate cables is expanded from only unjacketed cables by the ability to assess insulation condition through the jacket. Dual gap IDC sensors are confirmed to be able to sense the insulation condition beneath a polymer jacket and, moreover, the IDC is the only known way to assess the insulation condition through the jacket. PNNL has filed a patent for this approach and is exploring commercial partnerships to exploit IDC technology for actionable field measurements.

NDE, cable, IDC, capacitance, permittivity, insula↗

NorthernSTAR Project Overcoat: Exterior Insulation Strategies for 1.5-Story Roof Applications in Cold Climates

This is a repository for all NorthernSTAR Overcoat insulation retrofit projects. Both houses received Overcoat insulation retrofit on roof only, performed by Cocoon Insulation. 1 - St. Louis Park house - St. Louis Park, MN 2 - Edina house - Edina, MN In this second study, the team wished to analyze the before and after air-tightness data from roof only ETMMS retrofits on 1.5-story homes in cold and very cold climates. To identify homes to analyze, we reached out to our national network of energy professionals, home performance contractors, and general contractors who had expressed interest in promoting roof-only External Thermal Moisture Management System (ETMMS) to clients. Five projects by three contractors were submitted for consideration as they were being done to mitigate severe ice dams for homeowners. Only two of the five projects followed a roof only ETMMS protocol. Data from the other three projects, however, were reviewed with the air-tightness data of 250 roof-only, interior-applied energy retrofits on 1.5-story homes provided by three NorthernSTAR industry partners. These data represent homes in the general market as well as homes that were part of the state of Minnesota weatherization program.

adhered applied membrane↗

Engineering magnetic topological insulators in Eu 5 M 2 X 6 Zintl compounds

Magnetic topological insulators provide a prominent material platform for quantum anomalous Hall physics and axion electrodynamics. However, the lack of material realizations with cleanly gapped surfaces hinders technological utilization of these exotic quantum phenomena. Here, using the Zintl concept and the properties of nonsymmorphic space groups, we computationally engineer magnetic topological insulators. Specifically, we explore Eu 5 M 2 X 6 (M=metal, X=pnictide) Zintl compounds and find that Eu 5 Ga 2 Sb 6 , Eu 5 Tl 2 Sb 6 , and Eu 5 In 2 Bi 6 form stable structures with nontrivial Z 2 indices. We also show that epitaxial and uniaxial strain can be used to control the Z 2 index and the bulk energy gap. Lastly, we discuss experimental progress towards the synthesis of the proposed candidates and provide insights that can be used in the search for robust magnetic topological insulators in Zintl compounds.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Exterior Insulation Implications for Heating and Cooling Systems in Cold Climates

The New York State Energy Research and Development Authority (NYSERDA) is interested in finding cost-effective solutions for deep energy retrofits (DERs) related to exterior wall insulation in a cold climate, with targets of 50% peak load reduction and 50% space conditioning energy savings. The U.S. Department of Energy Building America team, IBACOS, in collaboration with GreenHomes America, Inc. (GHA), was contracted by NYSERDA to research exterior wall insulation solutions. In addition to exterior wall insulation, the strategies included energy upgrades where needed in the attic, mechanical and ventilation systems, basement, band joist, walls, and floors. Under Building America, IBACOS is studying the impact of a “thermal enclosure” DER on the sizing of the space conditioning system and the occupant comfort if the thermal capacity of the heating and cooling system is dramatically downsized without any change in the existing heating and cooling distribution system (e.g., size, tightness and supply outlet configurations).

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Exterior Insulation Implications for Heating and Cooling Systems in Cold Climates

The New York State Energy Research and Development Authority (NYSERDA) is interested in finding cost-effective solutions for deep energy retrofits (DERs) related to exterior wall insulation in a cold climate, with targets of 50% peak load reduction and 50% space conditioning energy savings. The U.S. Department of Energy Building America team, IBACOS, in collaboration with GreenHomes America, Inc. (GHA), was contracted by NYSERDA to research exterior wall insulation solutions. In addition to exterior wall insulation, the strategies included energy upgrades where needed in the attic, mechanical and ventilation systems, basement, band joist, walls, and floors. Under Building America, IBACOS is studying the impact of a “thermal enclosure” DER on the sizing of the space conditioning system and the occupant comfort if the thermal capacity of the heating and cooling system is dramatically downsized without any change in the existing heating and cooling distribution system (e.g., size, tightness and supply outlet configurations).

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Ultrafast Spin-to-Charge Conversion at the Surface of Topological Insulator Thin Films

Strong spin–orbit coupling, resulting in the formation of spin–momentum–locked surface states, endows topological insulators with superior spin–to–charge conversion characteristics, though the dynamics that govern it have remained elusive. Here, an all–optical method is presented, which enables unprecedented tracking of the ultrafast dynamics of spin–to–charge conversion in a prototypical topological insulator Bi 2 Se 3 /ferromagnetic Co heterostructure, down to the sub–picosecond timescale. Compared to pure Bi 2 Se 3 or Co, a giant terahertz emission is observed in the heterostructure that originates from spin–to–charge conversion, in which the topological surface states play a crucial role. A 0.12 ps timescale is identified that sets a technological speed limit of spin–to–charge conversion processes in topological insulators. Additionally, it is shown that the spin–to–charge conversion efficiency is temperature independent in Bi 2 Se 3 as expected from the nature of the surface states, paving the way for designing next–generation high–speed optospintronic devices based on topological insulators at room temperature.

36 MATERIALS SCIENCE↗

Surface Local Impurity Scattering as a Probe for Topological Kondo Insulators

Shortly after the discovery of topological band insulators, topological Kondo insulators (TKIs) is also theoretically predicted. The latter has ignited revival interest in the properties of Kondo insulators. Currently, the feasibility of topological nature in SmB 6 is intensively analyzed by several complementary probes. Here by starting with a minimal-orbital Anderson lattice model, the local electronic structure is explored in a Kondo insulator. It is showed that the two strong topological regimes sandwiching the weak topological regime give rise to a single Dirac cone, which is located near the center or corner of the surface Brillouin zone. It is further found that, when a single impurity is placed on the surface, low-energy resonance states are induced in the weak scattering limit for the strong TKI regimes and the resonance level moves monotonically across the hybridization gap with the strength of impurity scattering potential; while low energy states can only be induced in the unitary scattering limit for the weak TKI regime, where the resonance level moves universally toward the center of the hybridization gap. These impurity-induced low-energy quasiparticles will lead to characteristic signatures in scanning tunneling microscopy/spectroscopy, which has recently found success in probing into exotic properties in heavy fermion systems.

36 MATERIALS SCIENCE↗

Surface plasmons at the interface of metamaterial and topological insulator

We investigate the propagation of surface plasmon polaritons (SPPs) at the boundary of metamaterial and topological insulators. Instances of Bi{sub 2}Se{sub 3}, Bi{sub 2}Te{sub 3} and metamaterial boundaries are investigated. The topological insulators under consideration are three dimensional topological insulators of the second generation. Dispersion relations, absorption characteristics and propagation lengths of SPPs are calculated. The variation of bulk dielectric functions of topological insulators and metamaterial is considered by means of the Drude model and effective medium approximation theory. The key parameters making a dramatic impact on propagation lengths are acknowledged and mechanisms for engineering dispersion properties are suggested.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Non-local order in Mott insulators, duality and Wilson loops

It is shown that the Mott insulating and superfluid phases of bosons in an optical lattice may be distinguished by a non-local ‘parity order parameter’ which is directly accessible via single site resolution imaging. In one dimension, the lattice Bose model is dual to a classical interface roughening problem. We use known exact results from the latter to prove that the parity order parameter exhibits long range order in the Mott insulating phase, consistent with recent experiments by Endres et al. [M. Endres, M. Cheneau, T. Fukuhara, C. Weitenberg, P. Schauß, C. Gross, L. Mazza, M.C. Bañuls, L. Pollet, I. Bloch, et al., Science 334 (2011) 200]. In two spatial dimensions, the parity order parameter can be expressed in terms of an equal time Wilson loop of a non-trivial U(1) gauge theory in 2+1 dimensions which exhibits a transition between a Coulomb and a confining phase. The negative logarithm of the parity order parameter obeys a perimeter law in the Mott insulator and is enhanced by a logarithmic factor in the superfluid. -- Highlights: •Number statistics of cold atoms in optical lattices show non-local correlations. •These correlations are measurable via single site resolution imaging. •Incompressible phases exhibit an area law in particle number fluctuations. •This leads to long-range parity order of Mott-insulators in one dimension. •Parity order in 2d is connected with a Wilson-loop in a lattice gauge theory.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Evolution of Landau levels in graphene-based topological insulators in the presence of wedge disclinations

In this paper we consider modification of electronic properties of graphene-based topological insulator in the presence of wedge disclination and magnetic field by adopting the Kane–Mele model with intrinsic spin–orbit coupling. Using the properly defined Dirac–Weyl equation for this system, an exact solution for the Landau levels is obtained. The influence of the topological defect on the evolution of Landau levels is discussed. - Highlights: • Landau levels in graphene-based topological insulator. • Graphene-based topological insulator in the presence of disclination. • Kane–Mele model in topological insulator with wedge disclination.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Effective thermal conductivity of insulation materials for cryogenic LH 2 storage tanks: A review

An accurate estimation of the effective thermal conductivity of various insulation materials is essential in the evaluation of heat leak and boil-off rate from liquid hydrogen storage tanks. In this work, we review the existing experimental data and various proposed correlations for predicting the effective conductivity of insulation systems consisting of powders, foams, fibrous materials, and multilayer systems. We also propose a first principles-based correlation that may be used to estimate the dependence of the effective conductivity as a function of temperature, interstitial gas composition, pressure, and structural properties of the material. We validate the proposed correlation using available experimental data for some common insulation materials. Further improvements and testing of the proposed correlation using laboratory scale data obtained using potential LH 2 tank insulation materials are also discussed.

08 HYDROGEN↗