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At least 667 records · Page 37

Advanced emergency openings for commercial aircraft

Explosively actuated openings in composite panels are proposed to enhance passenger survivability within commercial aircraft by providing improvements in emergency openings, fuselage venting, and fuel dump. The concept is to embed a tiny, highly stable explosive cord in the periphery of a load-carrying composite panel; on initiation of the cord, the panel is fractured to create a well-defined opening. The panel would be installed in the sides of the fuselage for passenger egress, in the top of the fuselage for smoke venting, and in the bottoms of the fuel cells for fuel dump. Described are the concerns with the use of explosive systems, safety improvements, advantages, experimental results, and recommended approach to gain acceptance and develop this concept.

Bement, L. J.↗

Recruiting Perovskites to Degrade Toxic Trinitrotoluene

Everybody knows TNT, the most widely used explosive material and a universal measure of the destructiveness of explosions. A long history of use and extensive manufacture of toxic TNT leads to the accumulation of these materials in soil and groundwater, which is a significant concern for environmental safety and sustainability. Reliable and cost-efficient technologies for removing or detoxifying TNT from the environment are lacking. Despite the extreme urgency, this remains an outstanding challenge that often goes unnoticed. We report here that highly controlled energy release from explosive molecules can be accomplished rather easily by preparing TNT–perovskite mixtures with a tailored perovskite surface morphology at ambient conditions. These results offer new insight into understanding the sensitivity of high explosives to detonation initiation and enable many novel applications, such as new concepts in harvesting and converting chemical energy, the design of new, improved energetics with tunable characteristics, the development of powerful fuels and miniaturized detonators, and new ways for eliminating toxins from land and water.

36 MATERIALS SCIENCE↗

Anatomy of a diffracting detonation in a circular arc of explosive

Using high-resolution numerical simulation, study diffraction of a detonation as it traverses a 270° finite-thickness condensed-phase explosive arc. This geometry admits a steady solution in a frame rotating with angular speed ω 0 , which thereby facilitates a detailed analysis of how the loss of energy from the detonation reaction zone due to the diffraction process slows the propagation of the detonation. There exists a region of subsonic flow, between the detonation shock and the curve of sonic flow (labelled the DDZ), which is responsible for setting ω 0 . Although the DDZ spans the entire thickness for thin arcs, it is localized to a region near the inside surface as the arc is thickened. Furthermore the explosive energy release near this inside surface plays a disproportionate role in the diffraction process.

42 ENGINEERING↗

On the Determination of Ejecta Structure and Explosion Asymmetry from the X-ray Knots of Cassiopeia A

We present a detailed analysis of Chandra X-ray spectra from individual ejecta knots in the supernova remnant Cassiopeia A. The spectra are fitted to give the electron temperature T(sub e), and (single) ionization age n(sub e)t. These quantities are compared with the predictions of self similar hydrodynamic models incorporating time dependent ionization and radiation losses, and Coulomb electron-ion equilibration behind the reverse shock, for a variety of different ejecta density profiles described by a uniform density core and a power law envelope. We find that the ejecta close to the 'jet' region in the NE, but not actually in the jet itself, have a systematically shallower outer envelope than ejecta elsewhere in the remnant, and we interpret this as being due to more energy of the initial explosion being directed in this polar direction as opposed to equatorially. The degree of asymmetry we infer is at the low end of that generally modelled in asymmetric core-collapse simulations, and may be used to rule out highly asymmetric explosion models.

Laming, J. Martin↗

Predicting Large-scale Effects During Cookoff of Plastic-Bonded Explosives (PBX 9501 PBX 9502 and LX-14)

In this study, we have made reasonable cookoff predictions of large-scale explosive systems by using pressure-dependent kinetics determined from small-scale experiments. Scale-up is determined by properly accounting for pressure generated from gaseous decomposition products and the volume that these reactive gases occupy, e.g. trapped within the explosive, the system, or vented. The pressure effect on the decomposition rates has been determined for different explosives by using both vented and sealed experiments at low densities. Low-density explosives are usually permeable to decomposition gases and can be used in both vented and sealed configurations to determine pressure-dependent reaction rates. In contrast, explosives that are near the theoretical maximum density (TMD) are not as permeable to decomposition gases, and pressure-dependent kinetics are difficult to determine. Ignition in explosives at high densities can be predicted by using pressure-dependent rates determined from the low-density experiments as long as gas volume changes associated with bulk thermal expansion are also considered. In the current work, cookoff of the plastic-bonded explosives PBX 9501 and PBX 9502 is reviewed and new experimental work on LX-14 is presented. Reactive gases are formed inside these heated explosives causing large internal pressures. The pressure is released differently for each of these explosives. For PBX 9501, permeability is increased and internal pressure is relieved as the nitroplasticizer melts and decomposes. Internal pressure in PBX 9502 is relieved as the material is damaged by cracks and spalling. For LX-14, internal pressure is not relieved until the explosive thermally ignites. The current paper is an extension of work presented at the 26th ICDERS symposium [1].

42 ENGINEERING↗

Bis(1,2,4-oxadiazole)bis(methylene) Dinitrate: A High-Energy Melt-Castable Explosive and Energetic Propellant Plasticizing Ingredient

Here, we discuss the synthesis of bis(1,2,4-oxadiazole)bis(methylene) dinitrate, determination of its crystal structure by X-ray diffractometry, calculations of its explosive performance, and sensitivity measurements. Steps taken to optimize the synthesis process and to improve yields of the dinitrate are also discussed. Bis(1,2,4-oxadiazole)bis(methylene) dinitrate has a calculated detonation pressure 50% higher than that of TNT. The dinitrate compound exhibits a relatively high decomposition temperature that is rarely observed for nitrate-based compounds. The dinitrate was found to have lower sensitivities to impact and friction compared with RDX. Finally, it is believed that intramolecular hydrogen bonding observed in the crystal lattice assists in the relatively high thermal stability and relatively low sensitivity of the material.

36 MATERIALS SCIENCE↗

SN 2019yvq Does Not Conform to SN Ia Explosion Models

We present new photometric and spectroscopic observations of SN 2019yvq, a Type Ia supernova (SN Ia) exhibiting several peculiar properties including an excess of UV/optical flux within days of explosion, a high Si ii velocity, and a low peak luminosity. Photometry near the time of first light places new constraints on the rapid rise of the UV/optical flux excess. Furthermore, a near-infrared spectrum at +173 days after maximum light places strict limits on the presence of H or He emission, effectively excluding the presence of a nearby nondegenerate star at the time of explosion. New optical spectra, acquired at +128 and +150 days after maximum light, confirm the presence of [Ca ii] λ7300 and persistent Ca ii NIR triplet emission as SN 2019yvq transitions into the nebular phase. The lack of [O i]$\lambda 6300$ emission disfavors the violent merger of two C/O white dwarfs (WDs) but the merger of a C/O WD with a He WD cannot be excluded. We compare our findings with several models in the literature postulated to explain the early flux excess including double-detonation explosions, 56 Ni mixing into the outer ejecta during ignition, and interaction with H- and He-deficient circumstellar material. Each model may be able to explain both the early flux excess and the nebular [Ca ii] emission, but none of the models can reconcile the high photospheric velocities with the low peak luminosity without introducing new discrepancies.

79 ASTRONOMY AND ASTROPHYSICS↗

GRB 161219B/SN 2016jca: a powerful stellar collapse

ABSTRACT We report observations and analysis of the nearby gamma-ray burst GRB 161219B (redshift z = 0.1475) and the associated Type Ic supernova (SN) 2016jca. GRB 161219B had an isotropic gamma-ray energy of ∼1.6 × 1050 erg. Its afterglow is likely refreshed at an epoch preceding the first photometric points (0.6 d), which slows down the decay rates. Combined analysis of the SN light curve and multiwavelength observations of the afterglow suggest that the GRB jet was broad during the afterglow phase (full opening angle ∼42° ± 3°). Our spectral series shows broad absorption lines typical of GRB supernovae (SNe), which testify to the presence of material with velocities up to ∼0.25c. The spectrum at 3.73 d allows for the very early identification of an SN associated with a GRB. Reproducing it requires a large photospheric velocity ($35\, 000 \pm 7000$ km s−1). The kinetic energy of the SN is estimated through models to be Ekin≈4 × 1052 erg in spherical symmetry. The ejected mass in the explosion was Mej≈6.5 ± 1.5 M⊙, much less than that of other GRB-SNe, demonstrating diversity among these events. The total amount of 56Ni in the explosion was 0.27 ± 0.05 M⊙. The observed spectra require the presence of freshly synthesized 56Ni at the highest velocities, at least three times more than a standard GRB-SN. We also find evidence for a decreasing 56Ni abundance as a function of decreasing velocity. This suggests that SN 2016jca was a highly aspherical explosion viewed close to on-axis, powered by a compact remnant. Applying a typical correction for asymmetry, the energy of SN 2016jca was ∼(1–3) × 1052 erg, confirming that most of the energy produced by GRB-SNe goes into the kinetic energy of the SN ejecta.

Ashall, C.↗

High-Pressure Characterization of Two Stereoisomers of Tetranitroester Cyclobutane

The high-pressure behavior of two stereoisomeric cyclobutane nitric ester materials were studied at room temperature to near 25 GPa via Raman spectroscopy and powder X-ray diffraction. The materials investigated included [cis-trans-cis]- and [all-cis]-tetranitrate ester cyclobutanes. Over the course of these studies no evidence of polymorphism was observed, highlighting the stability of the ambient pressure crystal structures of the cyclobutanes to conditions near the detonation pressure of the material. Differences were observed between the bulk moduli of the two stereoisomers, suggesting potential tunability in materials response under dynamic conditions through the use of isomeric materials. Finally, such findings suggest that these high-performance materials can serve as TNT replacement in novel melt-castable energetic formulations without the concern of uncontrolled polymorphism that might otherwise affect the performance and safety of a munition.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Risk of Increased Fragmentation Events Due to Low Altitude Large Constellation Spacecraft

Orbital debris experts and industry leaders are concerned about the added hazard that thousands of additional spacecraft would have on the future orbital debris environment. Large constellations proposals plan to deploy spacecraft at altitudes from 1100 km to 1300 km, where fragmentation debris can take thousands of years or longer to decay naturally, while other proposals include deploying spacecraft at station-keeping altitudes from 300 km to 600 km. Although these lower altitude spacecraft are compliant with the 25-year rule, there is still an increased risk of accidental explosions generating high velocity fragments that could damage international spacecraft assets. The NASA Orbital Debris Program Office (ODPO) has conducted several parametric studies that examine the potential negative environmental impacts of large constellation deployments. This study addresses the lower altitude constellations and the potential risk that they impose on the future environment during mission operations. The projected future environment is generated as the average of 100 LEGEND Monte Carlo (MC) simulation runs while adjusting parameters such as average probability of explosion and operational lifetime per constellation. Results of the effect of accidental explosions of large constellation spacecraft on the environment below 600 km altitude are analyzed.

Vavrin, A.↗

Direct Real-Time Detection of Vapors from Explosive Compounds

The real-time detection of vapors from low volatility explosives including PETN, tetryl, RDX and nitroglycerine along with various compositions containing these substances is demonstrated. This was accomplished with an atmospheric flow tube (AFT) using a non-radioactive ionization source and coupled to a mass spectrometer. Direct vapor detection was demonstrated in less than 5 seconds at ambient temperature without sample pre-concentration. The several seconds of residence time of analytes in the AFT provides a significant opportunity for reactant ions to interact with analyte vapors to achieve ionization. This extended reaction time, combined with the selective ionization using the nitrate reactant ions (NO3- and NO3-•HNO3), enables highly sensitive explosives detection. Observed signals from diluted explosive vapors indicate detection limits below 10 ppqv using selected ion monitoring (SIM) of the explosive-nitrate adduct at m/z 349, 378, 284 and 289 for tetryl, PETN, RDX and NG respectively. Also provided is a demonstration of the vapor detection from 10 different energetic formulations, including double base propellants, plastic explosives and commercial blasting explosives using SIM for the NG, PETN and RDX product ions.

atmospheric pressure ionization↗

Woolwich, Bruceton, Los Alamos: Munroe Jets and the Trinity Gadget

Prewar work on the hydrodynamics of explosives and U.S./UK scientific cooperation well beyond Los Alamos contributed to the design of the explosive lenses for the Trinity gadget. Researchers were deliberately brought together and encouraged to share ideas by the leaders of the wartime laboratory. James Tuck, one of the British mission scientists, made particularly interesting contributions in this area, but this paper is not a claim of British or any other individual parentage. Rather, it highlights the importance of collaboration at Los Alamos and more widely.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

HEATING MECHANISMS IN THE LOW SOLAR ATMOSPHERE THROUGH MAGNETIC RECONNECTION IN CURRENT SHEETS

We simulate several magnetic reconnection processes in the low solar chromosphere/photosphere; the radiation cooling, heat conduction and ambipolar diffusion are all included. Our numerical results indicate that both the high temperature (≳8 × 10{sup 4} K) and low temperature (∼10{sup 4} K) magnetic reconnection events can happen in the low solar atmosphere (100–600 km above the solar surface). The plasma β controlled by plasma density and magnetic fields is one important factor to decide how much the plasma can be heated up. The low temperature event is formed in a high β magnetic reconnection process, Joule heating is the main mechanism to heat plasma and the maximum temperature increase is only several thousand Kelvin. The high temperature explosions can be generated in a low β magnetic reconnection process, slow and fast-mode shocks attached at the edges of the well developed plasmoids are the main physical mechanisms to heat the plasma from several thousand Kelvin to over 8 × 10{sup 4} K. Gravity in the low chromosphere can strongly hinder the plasmoid instability and the formation of slow-mode shocks in a vertical current sheet. Only small secondary islands are formed; these islands, however, are not as well developed as those in the horizontal current sheets. This work can be applied to understand the heating mechanism in the low solar atmosphere and could possibly be extended to explain the formation of common low temperature Ellerman bombs (∼10{sup 4} K) and the high temperature Interface Region Imaging Spectrograph (IRIS) bombs (≳8 × 10{sup 4}) in the future.

79 ASTRONOMY AND ASTROPHYSICS↗

Probing detonator performance through radio wave emissions

Experiments were performed using a copper antenna to observe transient electric fields generated by shocked Pentaerythritol Tetranitrate (PETN), which behaves as a piezoelectric explosive. PETN pellets were shocked using a detonator and polyvinyl chloride (PVC) as shock attenuation. The amount of attenuation was varied until an initiation threshold was found to increase the probability of a deflagration-to-detonation (DDT) transition occurring. These experiments showed distinct transient shifts in frequency over the duration of the experiments. Correlation was observed between certain shifts in frequency and if the PETN pellet detonated.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Explosion dynamics of thin flat foils at high current density

This paper presents characteristic features of the explosion of thin flat foils for currents and pulse risetimes ranging from 8 kA at 350 ns to 1000 kA at ~100 ns. Foils made of aluminum, copper, nickel, and titanium with thicknesses of 1–100 µm are tested. Various diagnostics in the optical, UV, and x-ray spectral ranges are used to image the exploding foils from initial breakdown to complete destruction or pinching. It is shown that foil explosion is a complex process that depends on many factors, but features common to all foils are found that do not depend on the parameters of the generators or, accordingly, on the energy deposited in the foil: for example, the breakdown of flat foils under different conditions occurs at the edges of the foil. For the first time, the formation of a precursor over the central part of the foil is shown, which significantly changes the dynamics of the foil explosion.

36 MATERIALS SCIENCE↗