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At least 667 records · Page 37

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NASA NTRS1988

Interactions between HCl, NO(x), and H2O ice in the Antarctic stratosphere - Implications for ozone

The role of PSC particles in determining the distributions of HCl and chlorine radicals is studied. The thermodynamics of HCl in ice is discussed, showing that significant quantities of HCl may be dissolved in ice when PSCs form. It is argued that HCl and HNO3 will be removed from the gas phase early in the condensation process, when only small quantities of H2O have been condensed, reflecting the thermodynamic properties of the solid phases of HCl, HNO3, and H2O. Rapid heterogeneous chemical reactions then volatilize reactive chlorine gases and convert NO(x) to solid-phase nitrates, which can be removed by gravitational settling. Analysis of the suite of heterogeneous chemical processes in the polar stratosphere implies a threshold for HCl concentrations, above which chemical loss rates for ozone increase dramatically.

Wofsy, S. C.↗

NASA NTRS1988

Microbeam analysis of four chondritic interplanetary dust particles for major elements, carbon and oxygen

Chemical compositions determined using electron excited X-rays are reported for four interplanetary dust particles collected in the stratosphere. These analyses include measurements of carbon and oxygen abundances which are important elements in these primitive materials. Spot analyses show very heterogeneous compositions on a micrometer scale although average composition approaches that of C1 carbonaceous chondrites. While the spot analyses show intermediate compositions between cometary dust and carbonaceous chondrites, the heterogeneity more closely resembles that of comet Halley dust particles.

Blanford, G. E.↗

NASA NTRS1989

Using Inorganic Crystals To Grow Protein Crystals

Solid materials serve as nucleating agents. Protein crystals induced by heterogeneous nucleation and in some cases by epitaxy to grow at lower supersaturations than needed for spontaneous nucleation. Heterogeneous nucleation makes possible to grow large, defect-free single crystals of protein more readily. Such protein crystals benefits research in biochemistry and pharmacology.

Shlichta, Paul J.↗

NASA NTRS1988

A mass spectrometric study of the simultaneous reaction mechanism of TMIn and PH3 to grow InP

The reaction mechanisms for the growth of InP from various mixtures of trimethyl indium (TMIn) and PH3 by OMVPE were investigated using mass spectrometry and a D2 ambient for isotopic labeling of the reaction products. It was found that, whereas TMIn alone pyrolyzes homogeneously, forming CH3D, and PH3 alone pyrolyzes heterogeneously, producing H2, the pyrolysis reactions of TMIn and PH3 together are completely different. The pyrolysis temperatures of both TMIn and PH3 are reduced (by 50 C for TMIn and 225 C for PH3), and the sole product is CH4 at high values of the PH3/TMIn ratio. The pyrolysis reaction is shown to be coupled (as evidenced by the equal depletion of TMIn and PH3 from the vapor) and, at temperatures below 400 C, heterogeneous.

Buchan, N. I.↗

NASA NTRS1989

A distributed program composition system

A graphical technique for creating distributed computer programs is investigated and a prototype implementation is described which serves as a testbed for the concepts. The type of programs under examination is restricted to those comprising relatively heavyweight parts that intercommunicate by passing messages of typed objects. Such programs are often presented visually as a directed graph with computer program parts as the nodes and communication channels as the edges. This class of programs, called parts-based programs, is not well supported by existing computer systems; much manual work is required to describe the program to the system, establish the communication paths, accommodate the heterogeneity of data types, and to locate the parts of the program on the various systems involved. The work described solves most of these problems by providing an interface for describing parts-based programs in this class in a way that closely models the way programmers think about them: using sketches of diagraphs. Program parts, the computational modes of the larger program system are categorized in libraries and are accessed with browsers. The process of programming has the programmer draw the program graph interactively. Heterogeneity is automatically accommodated by the insertion of type translators where necessary between the parts. Many decisions are necessary in the creation of a comprehensive tool for interactive creation of programs in this class. Possibilities are explored and the issues behind such decisions are presented. An approach to program composition is described, not a carefully implemented programming environment. However, a prototype implementation is described that can demonstrate the ideas presented.

Brown, Robert L.↗

NASA NTRS1990

In situ analysis of CO during chemisorption and oxidation on graphite: Supported Pt by FTIR-microspectrometry

For chemisorption and oxidation on Pt/HOPG (highly-orientated pyrolytic) graphite, reflectance Fourier Transform Infrared (FTIR)-microspectrometry reveals a variable state and reactivity for CO. Even for model surface science systems, where surface heterogeneity is minimal, surface diffusion may be too slow relative to the reaction rate to avoid segregation of reactants into surface islands under steady-state conditions. Thus in CO oxidation on Pt (where the relevant surface diffusion coefficients are such that D sub O less than D sub CO) then reactant CO islands exists at the perimeters of which the surface reaction is thought to occur. Furthermore CO can chemisorb on metals in linear and bridge forms to extents which vary with precise faces predominantly exposed coverage, etc. Infrared has long been used to probe the nature of adsorbed CO on model film and heterogeneous surfaces, but it may now be that FTIR-microspectrometry will allow the state of this adsorbate and reactant to be investigated with a spatial resolution of 4.4 microns on model (and real) catalytic surfaces.

Self, Valerie A.↗

NASA NTRS1990

Chemical kinetics and modeling of planetary atmospheres

A unified overview is presented for chemical kinetics and chemical modeling in planetary atmospheres. The recent major advances in the understanding of the chemistry of the terrestrial atmosphere make the study of planets more interesting and relevant. A deeper understanding suggests that the important chemical cycles have a universal character that connects the different planets and ultimately link together the origin and evolution of the solar system. The completeness (or incompleteness) of the data base for chemical kinetics in planetary atmospheres will always be judged by comparison with that for the terrestrial atmosphere. In the latter case, the chemistry of H, O, N, and Cl species is well understood. S chemistry is poorly understood. In the atmospheres of Jovian planets and Titan, the C-H chemistry of simple species (containing 2 or less C atoms) is fairly well understood. The chemistry of higher hydrocarbons and the C-N, P-N chemistry is much less understood. In the atmosphere of Venus, the dominant chemistry is that of chlorine and sulfur, and very little is known about C1-S coupled chemistry. A new frontier for chemical kinetics both in the Earth and planetary atmospheres is the study of heterogeneous reactions. The formation of the ozone hole on Earth, the ubiquitous photochemical haze on Venus and in the Jovian planets and Titan all testify to the importance of heterogeneous reactions. It remains a challenge to connect the gas phase chemistry to the production of aerosols.

Yung, Yuk L.↗

NASA NTRS1990

A development framework for artificial intelligence based distributed operations support systems

Advanced automation is required to reduce costly human operations support requirements for complex space-based and ground control systems. Existing knowledge based technologies have been used successfully to automate individual operations tasks. Considerably less progress has been made in integrating and coordinating multiple operations applications for unified intelligent support systems. To fill this gap, SOCIAL, a tool set for developing Distributed Artificial Intelligence (DAI) systems is being constructed. SOCIAL consists of three primary language based components defining: models of interprocess communication across heterogeneous platforms; models for interprocess coordination, concurrency control, and fault management; and for accessing heterogeneous information resources. DAI applications subsystems, either new or existing, will access these distributed services non-intrusively, via high-level message-based protocols. SOCIAL will reduce the complexity of distributed communications, control, and integration, enabling developers to concentrate on the design and functionality of the target DAI system itself.

Adler, Richard M.↗

NASA NTRS1989

The interannual variability of polar stratospheric clouds and related parameters in Antarctica during September and October

Antarctic polar stratospheric cloud (PSC) sightings by the orbiting SAM II sensor during September and October show a pronounced quasi-biennial oscillation (QBO) signal, and October sightings have increased markedly over the past 10 years in years of westerly QBO phase. The QBO in PSC frequency is likely to affect the rate of Antarctic heterogeneous chemical processes and, hence, ozone depletion. Studies of the observed long-term temperature trend suggest that the decadal PSC trend probably results from the ozone decline, through its effect on stratospheric heating rates. A more detailed analysis of data from 1986 to 1987 shows that there were more PSCs in 1987, and that they persisted much later into the spring season as compared to 1986. Qualitatively similar behavior was found for the OClO column abundances and 18-km ozone depletion observed at McMurdo Station during these 2 years. These observations suggest that both the intensity and duration of heterogeneous chemical processes are likely greater during colder OBQ-westerly phase years.

Poole, Lamont R.↗

NASA NTRS1990

Effects of atmospheric transport on column abundances of nitrogen and chlorine compounds in the arctic stratosphere

In the absence of heterogeneous processes, distributions of NO(y), HNO3, Cl(x) and HCl in the polar winter stratosphere should be determined by transport. A model simulating distributions of these species in the arctic for January and February 1989 is developed using observed fields of potential vorticity and potential temperature. Comparison of model results with column measurements from the DC-8 indicates conversion of NO(x) to HNO3, condensation of HNO3, conversion of HCl to CINO3, and conversion of HCl plus CINO3 to an unmeasured species. Heterogeneous processes strongly affect abundances of NO(y) and Cl(x) species in the winter arctic stratosphere.

Yatteau, John H.↗

NASA NTRS1990

The polar stratospheric cloud event of January 24, 1989. I - Microphysics

Rapid adiabatic cooling induced by synoptic forcing led to polar stratospheric cloud (PSC) formation on January 24, 1989, at altitudes sampled by the ER-2 aircraft. Particle characteristics measured by the Forward Scattering Spectrometer Probe (FSSP) on the ER-2 were compared to those calculated using a theoretical PSC microphysics model. Although calculations were sensitive to local changes in cooling rate, generally favorable agreement was found, that in particle surface area being especially important since this parameter dictates heterogeneous chemical rates. The overall model performance suggests that the current approach for simulating Type 1 (nitric acid trihydrate) PSC formation under rapid cooling conditions is well founded and can be used to study the effects of heterogeneous chemistry on stratospheric composition.

Poole, L. R.↗

NASA NTRS1990

HI and FIR emission from S0 galaxies

A large body of work has accumulated in recent years which throws into disarray the traditional assumption that S0 systems are inert, non-starforming galaxies with uniform, old stellar populations. The copious 21-cm data have been recently reviewed and assessed by Wardle and Knapp (1986). This work showed that roughly a third of the several hundred observed S0's contain detectable amounts of neutral hydrogen (HI). More recently, Pogge and Eskridge (1987) have shown that a significant fraction of HI-rich systems also exhibit H alpha emission. Thronson et al. (1989) report detection of CO line emission from two thirds of the S0's in their sample. Both of these last papers, however, report on fairly small data sets (approx. 20 objects each). From co-added Infrared Astronomy Satellite (IRAS) data, Knapp et al. (1989) report that roughly two thirds of a sample of several hundred S0's are detected at 60 and 100 microns. Work by Bally and Thronson (1989) and Walsh et al. (1989) has shown that, while a large number of S0's follow a relation between radio continuum and far infrared radiation (FIR) emission similar to that found for spirals, significant numbers of both radio-bright, and FIR-bright S0's exist. Clearly, a large number of factors are involved in determining the state of the interstellar medium in S0 galaxies. The class is probably heterogeneous, suggesting that large data samples are required to sort out various sorts of objects. The 21 cm and FIR samples are the two largest currently available. It is therefore of interest to compare the two and see where this leads. The following results are already clear: HI and FIR flux data can be used to isolate strong candidates for systems which have gained their HI gas via accretion; a rough power-law relationship exists for galaxies which are undergoing relatively normal star-forming activity; a heterogeneous class of galaxies with strong FIR emission compared to their HI emission exists. Further work is required to determine the various physical processes responsible for this last class.

Eskridge, Paul B.↗

NASA NTRS1990

Containerless processing of undercooled melts

All practical solidification processes involve some level of melt undercooling. Usually in bulk liquids crystallization is initiated at a heterogeneous nucleation site at low undercooling. The realization of appreciable levels of liquid undercooling requires some control over the kinetics of crystal nucleation. One level of control is available in containerless processing where the capability to melt and solidify samples without a container removes a major source of impurities and heterogeneous nucleation sites which can be effective in promoting large undercooling and in studying other potential nucleants. The microgravity environment offers a unique opportunity for containerless processing of large liquid samples with negligible melt disturbance and continuous temperature measurement throughout processing. Perhaps the most important potential for microgravity containerless processing lies in the significant structural control to develop distinct microstructures and metastable phases during solidification at high undercooling.

Perepezko, J. H.↗

NASA NTRS1991

The surface and through crack problems in layered orthotropic plates

An analytical method is developed for a relatively accurate calculation of Stress Intensity Factors in a laminated orthotropic plate containing a through or part-through crack. The laminated plate is assumed to be under bending or membrane loading and the mode 1 problem is considered. First three transverse shear deformation plate theories (Mindlin's displacement based first-order theory, Reissner's stress-based first-order theory, and a simple-higher order theory due to Reddy) are reviewed and examined for homogeneous, laminated and heterogeneous orthotropic plates. Based on a general linear laminated plate theory, a method by which the stress intensity factors can be obtained in orthotropic laminated and heterogeneous plates with a through crack is developed. Examples are given for both symmetrically and unsymmetrically laminated plates and the effects of various material properties on the stress intensity factors are studied. In order to implement the line-spring model which is used later to study the surface crack problem, the corresponding plane elasticity problem of a two-bonded orthotropic plated containing a crack perpendicular to the interface is also considered. Three different crack profiles: an internal crack, an edge crack, and a crack terminating at the interface are considered. The effect of the different material combinations, geometries, and material orthotropy on the stress intensity factors and on the power of stress singularity for a crack terminating at the interface is fully examined. The Line Spring model of Rice and Levy is used for the part-through crack problem. The surface crack is assumed to lie in one of the two-layered laminated orthotropic plates due to the limitation of the available plane strain results. All problems considered are of the mixed boundary value type and are reduced to Cauchy type of singular integral equations which are then solved numerically.

Erdogan, Fazil↗

NASA NTRS1991

Distributed Access View Integrated Database (DAVID) system

The Distributed Access View Integrated Database (DAVID) System, which was adopted by the Astrophysics Division for their Astrophysics Data System, is a solution to the system heterogeneity problem. The heterogeneous components of the Astrophysics problem is outlined. The Library and Library Consortium levels of the DAVID approach are described. The 'books' and 'kits' level is discussed. The Universal Object Typer Management System level is described. The relation of the DAVID project with the Small Business Innovative Research (SBIR) program is explained.

Jacobs, Barry E.↗

NASA NTRS1991

An investigation of voids formation mechanisms and their effects on freeze and thaw processes of lithium and lithium fluoride

The mechanisms of void formation during the cooldown and freezing of lithium coolant within the primary loop of SP-100 type systems are investigated. These mechanisms are: (1) homogeneous nucleation; (2) heterogeneous nucleation; (3) normal segregation of helium gas dissolved in liquid lithium; and (4) shrinkage of lithium during freezing. To evaluate the void formation potential due to segregation, a numerical scheme that couples the freezing and mass diffusion processes in both the solid and liquid regions is developed. The results indicated that the formation of He bubbles is unlikely by either homogeneous or heterogeneous nucleation during the cooldown process. However, homogeneous nucleation of He bubbles following the segregation of dissolved He in liquid lithium ahead of the solid-liquid interface is likely to occur. Results also show that total volume of He void is insignificant when compared to that of shrinkage voids. In viewing this, the subsequent research focuses on the effects of shrinkage void forming during freezing of lithium on subsequent thaw processes are investigated using a numerical scheme that is based on a single (solid/liquid) cell approach. The cases of lithium-fluoride are also investigated to show the effect of larger volume shrinkage upon freezing on the freeze and thaw processes. Results show that a void forming at the wall appreciably reduces the solid-liquid interface velocity, during both freeze and thaw, and causes a substantial rise in the wall temperature during thaw. However, in the case of Li, the maximum wall temperature was much lower than the melting temperature of PWC-11, which is used as the structure material in the SP-100 system. Hence, it is included that a formation of hot spots is unlikely during the startup or restart of the SP-100 system.

El-Genk, Mohamed S.↗

NASA NTRS1990

Finite-element models of continental extension

Numerical models of the initial deformation of extending continental lithosphere, computed to investigate the control of preexisting thermal and mechanical heterogeneities on the style of deformation, are presented. The finite element method is used to calculate deformation with a viscoelastic-plastic model for the lithosphere. Comparisons of the results of analytic models and finite-element models using this method show that good results may be obtained by the numerical technique, even with elements containing both brittle and viscoelastic sampling points. It is shown that the gross style of initial extensional deformation is controlled by the depth and width of the initial heterogeneity which localizes deformation.

Lynch, H. David↗

NASA NTRS1991

Ultrastructural and cytochemical evidence for single impulse initiation zones in vestibular macular nerve fibers of rat

Cupric ion-ferricyanide labeling methods and related ferrocyanide-stained tissues were used to locate the characterize, at the ultrastructural level, presumptive impulse initiation zones in the three types of vestibular macular nerve fibers. Large-diameter, M-type vestibular nerve fibers terminate in a calyx at the heminode, and labeling is coextensive with the base of the calyx. Intermediate, M/U-type nerve fibers have short, unmyelinated preterminal segments that sometimes bifurcate intamacularly, and small-diameter, U-type nerve fibers have long, unmyelinated preterminal axons and up to three branches. Preterminals of these nerve fibers display ultrastructural heterogeneity that is correlated with labeling patterns for sodium channels and/or associated polyanionic sites. They have a nodelike ultrastructure and label heavily from near the heminode to the base of the macula. Their intramacular branches, less organized ultrastructurally, label only slightly. Results indicate that vestibular nerve fibers have one impulse initiation zone, located near the heminode, that varies in length according to nerve fiber type. Structural heterogeneity may favor impulse conduction in the central direction, and length of the impulse initiation zone could influence nerve discharge patterns.

Ross, Muriel D.↗