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At least 667 records · Page 37
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NASA NTRS2019

Variations in Visible/Near-Infrared Hematite Spectra Related to Grain Size and Crystallinity

Drill fines created by the Curiosity rover at Gale Crater, Mars have exhibited variable visible/near-infrared spectral features attributable to the presence of ferrous and ferric minerals. Drilled locations within the Murray formation and on the Vera Rubin Ridge (VRR) were shown by the CheMin instrument to contain significant amounts of hematite. However, typical hematite spectral features (e.g., absorptions near 530 nm and 860 nm) have varied inconsistently with hematite abundances. This suggests that other factors such as hematite grain size or crystallinity, the presence of amorphous materials, and/or photometric effects play a role in the observed spectra. Using laboratory spectra of hematite acquired at difference grain sizes, we document the variability in key spectral features. We also compare spectral parameters computed from Mastcam spectra on Mars of three hematite-bearing ChemCam calibration target (CCCT) samples with known hematite and amorphous material abundances.

Johnson, J. R.↗
NASA NTRS2019

Microstructural Record of Evolving Condensation Processes in Fine-Grained Ca-Al-Rich Inclusions from the Reduced CV3 Chondrites

Fine-grained, spinel-rich Ca-Al-rich inclusions (FGIs) in carbonaceous chondrites consist of numerous layered nodules having cores of spinel, hibonite, and/or perovskite surrounded by multiple thin layers of melilite, anorthite, diopside, and/or olivine. They are interpreted as aggregates of direct high-temperature condensates from an 16O-rich nebular gas that escaped significant melting. However, FGIs are very complex objects composed of intimate intergrowths of fine-grained refractory phases and show extremely large variations in mineralogy, modal abundance, and textures. Thus, detailed FIB/TEM analyses of FGIs are required to fully characterize their micro-to-nanometer scale textures, mineralogy, and chemical compositions and hence elucidate their formation processes and conditions in the early solar nebula. Here, we present our on-going study of pristine FGIs from the reduced CV3 chondrites Efremovka and Thiel Mountains (TIL) 07003 and 07007 that have minimal evidence for secondary parent body alteration.

Han, J.↗
NASA NTRS2019

PAH Clusters as Interstellar Very Small Grains

PAH clusters are one candidate species for the interstellar "very small grains" or "VSGs", i.e., dust grains small enough to be stochastically heated and contribute to the aromatic infrared emission bands (AIBs). This possibility motivated laboratory experiments on the infrared spectroscopy of PAH clusters using matrix isolation spectroscopy. The spectral shifts due to PAH clustering in argon matrices provide clues for the AIB contribution from PAH clusters in the interstellar medium. Here we review results from a number of small PAH species, extrapolation to the much larger PAHs believed to be present in the interstellar medium, and the implications for a PAH cluster contribution to the VSG population.

AIBs↗
NASA NTRS2018

Interstellar Dust Grain Alignment

Dust induced polarization is an efficient probe of the interstellar magnetic field. The combination of short wavelength dichroic extinction polarimetry with far-infrared/sub-mm wave emission observations, using modern instruments, allow us to measure the polarization from diffuse gas to star forming cores. With our improved understanding of the physics of grain alignment we can now better interpret the observations and evaluate the importance of the magnetic field. Radiative Alignment Torque (RAT) grain-alignment has been observationally confirmed, but some aspects and details are still being clarified. The quantitative theoretical frame work provided by RAT theory, also allows long standing questions about the interstellar environment and dust characteristics to be addressed anew - including dust composition and structure. I will review the basics of RAT alignment and its observational support and discuss some of the open questions of dust induced polarization.

Andersson, B.-G.↗
NASA NTRS2020

Mg Isotopic Compositions of Fine-Grained Ca-Al-Rich Inclusions from Reduced CV3 Chondrites and Implications on the Timescale of Nebular Condensation

Fine-grained Ca-Al-rich inclusions (FGIs) in carbonaceous chondrites are interpreted as aggregates of nebular gas-solid condensates that escaped significant melting [1]. Recent Al-Mg isotopic studies of small FGIs (<200 µm in size) from pristine CO3 chondrites have revealed significant variations in initial 26Al/27Al ratio, (26Al/27Al)(sub 0), spanning from 5.73×10(exp ˗5) to 8×10(exp ˗6) [2,3]. Importantly, [3] found a main CAI population characterized by (26Al/27Al)(sub 0) = 5.4×10(exp ˗5) that likely record the onset of dust condensation and initial coagulation events, followed by multiple thermal events over an extended time period. Thus far, a small number of large FGIs from CV3 chondrites have been analyzed, showing a narrower range of ( 26Al/27Al)(sub 0) = 5.27×10(exp ˗5) to 3.35×10(exp ˗5) [4-6], similar to those inferred from coarse-grained, igneous CAIs (CGIs) from CV3 chondrites [7]. These observed different ratios may raise a question if large FGIs in CV3 chondrites record a time interval from primary direct condensation of refractory solids to their aggregation and growth into larger inclusions. In this study, we present Al-Mg isotopic compositions of FGIs from reduced CV3 chondrites to better constrain their formation timescale relative to smaller FGIs in CO3 chondrites, as well as to CGIs in CV3 chondrites. This isotopic study is coordinated with a microstructural study to elucidate the origin and nature of FGIs in the petrologic and mineralogical context.

Han, J.↗
NASA NTRS2020

Mineralogy and Petrology of Fine-Grained Calcium-Aluminum-Rich Inclusions from the Reduced CV3 Chondrite Thiel Mountains 07007

Calcium-Aluminum-rich inclusions (CAIs) are among the oldest Solar System solids, and studies of these objects have played an essential role in developing an understanding of chemical and physical processes that initiated and characterized key events related to the Solar System’s formation and evolution. CAIs occur as μm- to cm-sized inclusions in chondritic meteorites, particularly in carbonaceous chondrites, and consist of various refractory silicate and oxide phases (e.g., melilite, spinel, Al-Ti-rich diopside, hibonite, and corundum) that are predicted by thermodynamic models to be among the first solids to con-dense from a cooling gas of solar composition. Fine grained CAIs (FGIs) are important samples to probe volatility-driven condensation processes in the solar nebula, because they have escaped thermal processes (e.g., melting) experienced by coarse-grained CAIs. In order to explore the primary nebular history of FGIs, a detailed mineralogical and petrologic study is necessary. In this research effort, we constrained the mineralogy and petrology of two CAIs 07-10 and -11 from the reduced CV3 chondrite Thiel Mountains (TIL) 07007, with the aim of evaluating their provenance as nebular condensates.

Anderkin, C. J.↗
NASA NTRS2020

Investigating Relationships Between Geochemistry and Physical Grain Characteristics Along a Glacio-Fluvial-Aeolian Sediment Transport Pathway Using µXRF

Iceland’s basaltic volcanic rocks and glacial, fluvial, and aeolian landscapes resemble those studied on Mars, which makes it an ideal location to study the evolution of basaltic landscapes, the weathering and alteration of basaltic sediments in cold and wet environments, and the generation of a basaltic sedimentary record. The SAND-E: Semi-Autonomous Navigation for Detrital Environments project examines physical and chemical changes in sediments transported through basaltic fluvial and aeolian environments, and tests operational scenarios, which include a drone and a robotic rover instrumented with autonomous terrain analysis software. As part of the SAND-E project, we examined a glacial outwash plain at Skjaldbreiðauhraun, in SW Iceland. This study uses micro X-ray fluorescence (μXRF) to examine the chemical and physical properties of unconsolidated sediment-size fractions from 710 μm to < 63 μm along a downstream transect from a glacial sourced watershed. μXRF is ideally suited for this task because it maps elemental distributions at sub-grain scales thereby allowing a direct correlation between grainsize, grain shape, and chemistry. It is also a good analog technique for the Mars 2020 mission equipped with the PIXL (Planetary Instrument for X-ray Lithochemistry) that will be deployed at Jezero Crater, Mars.

Champion, E.↗
NASA NTRSDate not supplied

Mineralogical and Al-Mg Isotopic Study of Fine-Grained Ca-Al-Rich Inclusions

Fine-grained Ca-Al-rich inclusions (FGIs) in carbonaceous chondrites are interpreted as aggregates of nebular gas-solid condensates that escaped significant melting.Thus far, a small number of FGIs from CV3 chondrites have been analyzed, showing a range of (26Al/27Al)0=~5.4×10−5to ~3.4×10−5.These values are similar to (26Al/27Al)0inferred from coarse-grained, igneous CAIs (CGIs) from CV3 chondrites.This observed spread in (26Al/27Al)0values indicates the CAI formation over an extended time period. However, more analyses are needed to determine if the FGIs formed continuously over a significant time period or by multiple episodic events of nebular condensation. In this study, we present high-precision Al-Mg isotopic data of FGIs from reduced CV3 chondrites to better constrain their formation timescale relative to CGIs in CV3 chondrites, as well as to smaller FGIs in CO3 chondrites. This isotopic study is coordinated with a FIB/TEM study to elucidate the origin and nature of FGIs in the petrologic and mineralogical context.

J Han↗
NASA NTRS2021

Mineralogy and Surface Modification of Small Grains Recovered from the Asteroid 162173 Ryugu

Surface material on airless bodies exposed to the interplanetary space experienced the bombardment by low-energy (~1 keV/nucleon) solar wind particles and micrometeoroid impacts. These processes, alongside the resultant surface modifications, and spectral darkening and reddening are called space weathering [1]. Space weathering of the Moon and the asteroid 25143 Itokawa belonging to S-type asteroids have been investigated intensively [e.g. 1-5]. The Hayabusa 2 spacecraft returned samples from the asteroid 162173 Ryugu C-type asteroid. The Ryugu samples give us the first opportunity to investigate space weathering of C-type asteroids. The Mineralogy-Petrology Fine (M-P F or Sand) sub-team mainly investigates small grains (typically ~100 μm across). The main purposes of the M-P F sub-team are to understand the variationof mineralogy of the allocated grains and the nature of space weathering of the asteroid Ryugu. The M-P F sub-team is comprised of 51 members belonging to 25 universities and laboratories

T. Noguchi↗
NASA NTRSDate not supplied

Engineering 6-Phosphogluconate Improves Grain Yield in Heat-Stressed Maize

Endosperm starch synthesis is a primary determinant of grain yield and is sensitive to high-temperature stress. The maize chloroplast-localized 6-phosphogluconate dehydrogenase (6PGDH), PGD3, is critical for endosperm starch accumulation. Maize also has two cytosolic isozymes, PGD1 and PGD2, that are not required for kernel development. We found that cytosolic PGD1 and PGD2 isozymes have heat-stable activity, while amyloplast-localized PGD3 activity is labile under heat stress conditions. We targeted heat-stable 6PGDH to endosperm amyloplasts by fusing the Waxy1 chloroplast targeting the peptide coding sequence to the Pgd1 and Pgd2 open reading frames (ORFs). These WPGD1 and WPGD2 fusion proteins import into isolated chloroplasts, demonstrating a functional targeting sequence. Transgenic maize plants expressing WPGD1 and WPGD2 with an endosperm-specific promoter increased 6PGDH activity with enhanced heat stability in vitro. WPGD1 and WPGD2 transgenes complement the pgd3-defective kernel phenotype, indicating the fusion proteins are targeted to the amyloplast. In the field, the WPGD1 and WPGD2 transgenes can mitigate grain yield losses in high-nighttime-temperature conditions by increasing kernel number. These results provide insight into the subcellular distribution of metabolic activities in the endosperm and suggest the amyloplast pentose phosphate pathway is a heat-sensitive step in maize kernel metabolism that contributes to yield loss during heat stress.

Synthetic Biology↗
NASA NTRSDate not supplied

Characteristics of Mineralogy and Space Weathering Observed on the Grains in the Fine Fraction Samples Returned From the C-type Asteroid Ryugu.

Samples returned from near-Earth C-type asteroid Ryugu by the JAXA Hayabusa2 spacecraft have been investigated from June, 2021. Our Min-Pet Fine ("sand") sub-team have investigated mineralogy and petrology and space weathering of grains in the fine fraction of the samples. Space weathering is alteration induced mainly by solar wind irradiation and micrometeoroid impact. Here, we report mineralogy and microstructural and chemical features related to space weathering of Ryugu grains.

Takaaki Noguchi↗
NASA NTRSDate not supplied

A Record of Nebular and Parent Body Processes of Grossite-Bearing, Fine-Grained Refractory Inclusions from Reduced CV3 Chondrites

Grossite (CaAl4O7) is predicted to condense as the third major phase, after corundum and hibonite, from a cooling gas of solar composition and likely preserves an important record of physico-chemical conditions in the early Solar System. However, this mineral is relatively rare in CAIs from most carbonaceous chondrite groups, except for CH chondrites. In particular, from CV3 chondrites where CAIs are large and abundant, only six grossitebearing CAIs have been reported and studied, and most of them were coarse-grained Type A inclusions. Here, we report the occurrence of grossite-bearing, fine-grained inclusions (FGIs) from reduced CV3 chondrites. We present preliminary results of a FIB/TEM study of one grossite-bearing FGI that provide clues to constrain its formation and alteration history in the solar nebula and on the parent body and to address the overall rarity of grossite in CAIs.

J. Han↗
NASA NTRS2023

Characterizing Space Weathering Features in Grains From Asteroid Ryugu

Airless bodies such as asteroids are characterized by a lack of a protective atmosphere to guard against the effects of micrometeorite bombardment and solar wind irradiation. These processes, cumulatively known as space weathering, alter the microstructural and chemical properties of grains on asteroidal surfaces, signatures of which are recognized as vesiculated textures, amorphous grain rims, and fe-bearing nanoparticles. The accumulation of these features also causes changes in the optical properties of the surface regolith, complicating the interpretation of remote sensing data and the characterization of returned samples.

L. E. Melendez↗
NASA NTRS2023

Ceramic Capacitor Grain Size Analysis Using Electron Backscatter Diffraction (EBSD)

The overall scope of this NESC study was to identify (or develop) a tool, methodology, or process that can inspect a ceramic capacitor and consistently return repeatable grain size distribution results. It is important to note that the development of a machine learning technique was considered as an option for this study, but only if an existing automated tool was not available. This report explains why the Electron Backscatter Diffraction analysis method for grain structure and size distribution was deemed a suitable candidate for this work.

Electron Backscatter Diffraction↗
NASA NTRSDate not supplied

Cr-Rich and Al-Rich Oxide Grains With 16O-Rich Compositions in Ryugu Samples

Samples returned from asteroid Ryugu by JAXA’s Hayabusa2 mission are CI-like, with abundant hydrated and secondary phases [1]. Rare anhydrous minerals occur in the matrix of the major lithology and in chemically distinct clasts. Oxygen isotopic analysis of coarse (> 10 µm) anhydrous Mg-rich silicates revealed a bimodal distribution, with some grains having compositions similar to amoeboid olivine aggregates (AOAs) and others having compositions similar to chondrule phenocrysts [2, 3]. We previously analyzed < 2 µm-sized Mg-rich silicates within a clast that also showed a range of O isotopic compositions (δ18O from -38 to +5 ‰) [4]. In this study, we conducted coordinated isotopic and mineralogical analysis of anhydrous oxide grains found in the matrix of Ryugu samples

A. N. Nguyen↗
NASA NTRSDate not supplied

Identification of Presolar Grains in Quick Look Samples of Asteroid Bennu Returned By the OSIRIS-REx Mission

The OSIRIS-REx spacecraft returned regolith sample from the B-type asteroid Bennu on September 24, 2023. The first samples to be analyzed, termed the Quick Look samples, are comprised of material collected from the avionics deck of the OSIRIS-REx sample canister. Initial mineralogical analysis of the Quick Look sample revealed a diversity of components, including hydrated and anhydrous silicates, sulfides, magnetite, phosphates, and abundant organic matter. Each constituent has their own origin and history, and their study can inform us of the history of Bennu and its parent asteroid. The analysis plan for asteroid Bennu samples is guided by hypotheses that address specific periods of Bennu’s history, from the pre-accretionary epoch to the OSIRIS-REx epoch. The pre-accretionary epoch studies aim to characterize materials that predate the formation of the solar system. One hypothesis that falls under this epoch is that Bennu contains presolar materials derived from diverse sources. These presolar materials include stardust grains that condensed from the outflows of evolved stars or the ejecta of novae and supernovae (SN), as well as organic matter that formed in the interstellar medium. Here we report the identification of C-rich presolar stardust grains in the Bennu Quick Look sample. Isotopically anomalous organic matter in this sample is reported in.

A N Nguyen↗
NASA NTRSDate not supplied

Carbon Tracers of Aqueous Processes: Isotopic Analysis of Cr Carbonate Grains With Implications for Bennu Samples

Carbonate grains in carbonaceous chondrites record aqueous alteration events on the asteroidal parent bodies, including evidence for episodic alteration, timing of alteration, and time and temperature evolution of volatiles. Spectral features in the 3.4 μm region at asteroid Bennu have been interpreted as coming from carbonate minerals. Coordinated analysis of carbonate grains will be a valuable tool for analysis of Bennu samples, and related analysis of analog materials provides important context for understanding aqueous alteration of carbonaceous asteroids more broadly. To that end, our team is analyzing carbonates in Bennu analog materials, using Raman spectroscopy to identify carbonates and assess the maturity of related organic materials, vacuum reflectance spectroscopy from the ultraviolet through thermal infrared range to constrain contributions from carbonates and organics, X-ray microtomography and electron probe microanalysis (EPMA) to assess the distribution of void space, transmission electron microscopy to characterize space weathering effects, and EPMA and secondary ion mass spectrometry (SIMS) to measure composition and isotopic ratios. Here, we describe in situ analysis of carbon and oxygen isotopes from carbonates in Grosvenor Mountains (GRO) 95577.

K E Miller↗
NASA NTRS2024

Presolar Grains in Bennu: Constraints From C and N Isotopic Compositions

Primitive chondrites, including CI and CM types, are known to contain a rich variety of presolar grains that were seeded into the protoplanetary disk from neighboring stars and stellar objects prior to aggregation into asteroidal parent bodies. Stepped combustion using the FINESSE instrument at the Open University (OU) was employed to determine whether material from Bennu contains populations of presolar grains similar to those of CI and CM chondrites as well as recently returned samples from Ryugu.

M M Grady↗