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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Gas chromatographic determination of small quantities of inert gases in reactive propellants is discussed. Operating conditions used for specific analyses of helium in diborane and nitrogen in oxygen difluoride are presented in tabular form.
Turbulent boundary layer flows of non-reacting gases are predicted for both interal (nozzle) and external flows. Effects of favorable pressure gradients on two eddy viscosity models were studied in rocket and hypervelocity wind tunnel flows. Nozzle flows of equilibrium air with stagnation temperatures up to 10,000 K were computed. Predictions of equilibrium nitrogen flows through hypervelocity nozzles were compared with experimental data. A slender spherically blunted cone was studied at 70,000 ft altitude and 19,000 ft/sec. in the earth's atmosphere. Comparisons with available experimental data showed good agreement. A computer program was developed and fully documented during this investigation for use by interested individuals.
An electron-bombardment ion thruster of the SERT 2 type was operated with xenon, krypton, argon, neon, nitrogen, helium, and carbon dioxide. The discharge performance with xenon, krypton, and argon was similar to that obtained previously with mercury. Mass spectrometer data indicated that the xenon contained no significant multiple ionization. Restriction of the beam area, with an associated decrease in discharge potential, was necessary to reduce multiple ionization with argon to a negligible level. This modification also resulted in more stable operation of the thruster. Performance with the remaining gases was poor because the basic thruster designed was optimized for operation with mercury.
A detailed critical review was conducted of present knowledge of the influence of biological processes on the cycling of selected atmospheric gas constituents--methane, carbon monoxide, and gaseous compounds of nitrogen (nitrous oxide, ammonia, nitric oxide, and nitrogen dioxide) and sulfur (hydrogen sulfide and sulfur dioxide). The identification was included of biological and other sources of each gas, a survey of abundance measurements reported in the literature, and a review of the atmospheric fate of each contituent. Information is provided on which to base conclusions regarding the importance of biological processes on the atmospheric distribution and surface-atmosphere exchange of each constituent, and a basis for estimating the adequacy of present knowledge of these factors. A preliminary analysis was conducted of the feasibility of monitoring the biologically influenced temporal and spatial variations in abundance of these gases in the atmosphere from satellites.
Research has been conducted by means of laboratory experiments to enhance understanding of the fundamental mechanisms of heterogeneous and homogeneous chemical reactions taking place during ablative processes that accompany the reentry or manned space vehicles into planetary atmospheres. Fundamental mechanisms of those chemical reactions believed to be important in the thermal degradation of ablative plastic heat shield materials, and the gases evolved, are described.
Four hot-cathode ionization vacuum gages were calibrated in 12 gases. The relative sensitivities of these gages were compared to several gas properties. Ionization cross section was the physical property which correlated best with gage sensitivity. The effects of gage accelerating voltage and ionization-cross-section energy level were analyzed. Recommendations for predicting gage sensitivity according to gage type were made.
A status report is presented on the anomalies observed in the behavior of transport properties near the critical point of gases and binary liquids. The shear viscosity exhibits a weak singularity near the critical point. An analysis is made of the experimental data for those transport properties, thermal conductivity and thermal diffusivity near the gas-liquid critical point and binary diffusion coefficient near the critical mixing point, that determine the critical slowing down of the thermodynamic fluctuations in the order parameter. The asymptotic behavior of the thermal conductivity appears to be closely related to the asymptotic behavior of the correlation length. The experimental data for the thermal conductivity and diffusivity are shown to be in substantial agreement with current theoretical predictions.
Study of the variation in composition of ions and neutral gases on the basis of numerical solutions of a coupled differential equation system describing the fundamental properties of the ionosphere and atmosphere within the range of the thermosphere. It is shown that changes in ion composition observed during a magnetic storm can be represented by changes in neutral gas composition in the lower thermosphere. A reduction of the O/N2 ratio in the lower thermosphere starts a sequence of events that leads to an increase in neutral gas temperature, decrease in O(+) and increase in NO(+) concentration.
Demonstration that the use of the Fabry-Perot interferometer as a filter with transmission windows occurring at regular intervals in wave numbers provides a highly sensitive method for detection of atmospheric gases using their rotational Raman spectra excited by a suitable laser. Some of the operating advantages include signal gains of several orders of magnitude, a simple direct interpretation of the results in terms of the density and types of the gaseous constituents, size and weight reductions from conventional apparatus, ease of operation, and relative freedom from interference from other molecules in the scattering volume. This method is compared with the techniques that have been discussed in the literature by other workers in the field.
The inert gases were measured mass-spectrometrically in 12 fragments and one dust sample from Luna 16. The fragments were classified petrologically by microscopic inspection. The major petrologic types were breccias and basalts. The He-4/Ne-20 ratio of the breccias (average 49) was systematically smaller than that of the basalts (average 78), probably because of He-Ne fractionation during or after the formation of the breccias. We suggest that the He-4/Ne-20 ratios of bulk fines in general may reflect the proportions of basaltic and breccia (plus cindery glasses) fragments in the fines. Exposure ages of four fragments are several hundred million years. The Ar-40/Ar-36 slopes of breccias and basalts are identical: 0.65.
Description of a modified flight-type SERT II ion thruster operated with xenon, krypton, argon, neon, nitrogen, helium, and carbon dioxide. The discharge performance with xenon, krypton, and argon was found to be similar to that obtained previously with mercury. Mass spectrometer data indicated that xenon could be operated efficiently with no significant multiple ionization. Restriction of the beam area, with an associated decrease in discharge potential, was necessary to reduce multiple ionization with argon to a negligible level. This modification also resulted in more stable operation of the thruster. Performance with the remaining gases was poor, but some future performance improvements may be realizable.
Gas rich meteorites and lunar materials solar rare gases component observed and predicted relative abundance agreement indicating absence of fractionation in solar nebula formation
Sensitivity of gage for one gas can be correlated to its sensitivity for other gases by the ratio of gas ionization cross sections. Ionization cross sections which best correlate with gage sensitivites vary according to gage type and ionization cross section energy level.
A device for sampling particulates in gases is described. The device is used to obtain samples of the upper atmosphere. The equipment used a common source of gas pressure to provide the driving gas of an air ejector pump. The sample collection cylinder has many slit impactors running longitudinally on the outer surface of a cylinder and terminating just short of each end of the cylinder.
The treatment of radiant emission and absorption by combustion gases are discussed. Typical applications include: (1) rocket combustion chambers and exhausts, (2) turbojet engines and exhausts, and (3) industrial furnaces. Some mention is made of radiant heat transfer problems in planetary atmospheres, in stellar atmospheres, and in reentry plasmas. Particular consideration is given to the temperature range from 500K to 3000K and the pressure range from 0.001 atmosphere to 30 atmospheres. Strong emphasis is given to the combustion products of hydrocarbon fuels with oxygen, specifically to carbon dioxide, water vapor, and carbon monoxide. In addition, species such as HF, HC1, CN, OH, and NO are treated.
Review of the results of measurements of noble gases in powdered aliquots of 11 H-chondrites whose trace element contents have been previously determined by Laul et al. (1973). The measurements were made on a 4.5-inch radius, Reynolds-type mass spectrometer, using conventional techniques.
A method based on perturbation theory for mixtures is applied to the prediction of thermodynamic properties of gases dissolved in electrolyte solutions. The theory is compared with experimental data for the dependence of the solute activity coefficient on concentration, temperature, and pressure; calculations are included for partial molal enthalpy and volume of the dissolved gas. The theory is also compared with previous theories for salt effects and found to be superior. The calculations are best for salting-out systems. The qualitative feature of salting-in is predicted by the theory, but quantitative predictions are not satisfactory for such systems; this is attributed to approximations made in evaluating the perturbation terms.
The problem of nonlinear rarefied Couette flow with heat transfer has been studied for both monatomic and diatomic gases using the Boltzmann equation with the Bhatnagar-Gross-Krook type models as the governing equation and the method of discrete ordinates as a tool. The calculated results have been compared with the existing experimental data in order to test the accuracy and the applicability of the statistical models for this one-dimensional problem. The calculated density results are found to be in good agreement with available experimental data; the calculated heat flux solution for the linear case is found to always be lower than the experimental data of Teagan and Springer. The comparisons made here indicate that the statistical models are indeed reasonably accurate so that their use is justified in the type of problems investigated.