Effects of buoyancy-driven flow and thermal boundary conditions on physical vapor transport
A 2D numerical model was developed in order to ascertain if reduced gravity conditions are beneficial to physical vapor transport (PVT) and to determine its tolerance limits to residual accelerations. This was solved using the PHOENICS finite-volume code. Reduction of gravitational accelerations to less than 0.1 g0 was found to be sufficient to suppress buoyancy-driven convection to an extent that diffusion was the dominant transport mode, whence a greater uniformity in the growth rate could be obtained. It is shown that a uniform temperature gradient on the ampoule walls causes the vapor to be supersaturated throughout the ampoule, potentially resulting in undesirable nucleation at the walls. A 'hump' in the wall temperature profile can be used to avoid this. The prevailing transport conditions determine the size of the hump needed.