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At least 667 records · Page 37
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Quantifying Spin-Mixed States in Ferromagnets

We quantify the presence of spin-mixed states in ferromagnetic 3D transition metals by precise measurement of the orbital moment. While central to phenomena such as Elliot-Yafet scattering, quantification of the spin-mixing parameter has hitherto been confined to theoretical calculations. We demonstrate that this information is also available by experimental means. Comparison of ferromagnetic resonance spectroscopy with x-ray magnetic circular dichroism results show that Kittel’s original derivation of the spectroscopic g factor requires modification, to include spin mixing of valence band states. Our results are supported by ab initio relativistic electronic structure theory.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2022

Room-Temperature Ferromagnetism at an Oxide-Nitride Interface

Heterointerfaces have led to the discovery of novel electronic and magnetic states because of their strongly entangled electronic degrees of freedom. Single-phase chromium compounds always exhibit antiferromagnetism following the prediction of the Goodenough-Kanamori rules. So far, exchange coupling between chromium ions via heteroanions has not been explored and the associated quantum states are unknown. In this work, we report the successful epitaxial synthesis and characterization of chromium oxide (Cr 2 O 3 )-chromium nitride (CrN) superlattices. Room-temperature ferromagnetic spin ordering is achieved at the interfaces between these two antiferromagnets, and the magnitude of the effect decays with increasing layer thickness. First-principles calculations indicate that robust ferromagnetic spin interaction between Cr 3+ ions via anion-hybridization across the interface yields the lowest total energy. This work opens the door to fundamental understanding of the unexpected and exceptional properties of oxide-nitride interfaces and provides access to hidden phases at low-dimensional quantum heterostructures.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2022

Robust Quantum Hall Ferromagnetism near a Gate-Tuned ν = 1 Landau Level Crossing

In a low-disorder two-dimensional electron system, when two Landau levels of opposite spin or pseudospin cross at the Fermi level, the dominance of the exchange energy can lead to a ferromagnetic, quantum Hall ground state whose gap is determined by the exchange energy and has skyrmions as its excitations. This is normally achieved via applying either hydrostatic pressure or uniaxial strain. Here, we study here a very high-quality, low-density, two-dimensional hole system, confined to a 30-nm-wide (001) GaAs quantum well, in which the two lowest-energy Landau levels can be gate tuned to cross at and near filling factor v = 1. As we tune the field position of the crossing from one side of v = 1 to the other by changing the hole density, the energy gap for the quantum Hall state at v =1 remains exceptionally large, and only shows a small dip near the crossing. The gap overall follows a $\sqrt{B}$ dependence, expected for the exchange energy. Our data are consistent with a robust quantum Hall ferromagnet as the ground state.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2024

Spin Polarons and Ferromagnetism in Doped Dilute Moiré-Mott Insulators

Moiré heterostructures of transition metal dichalcogenides (TMDs) exhibit Mott-insulating behavior both at half filling as well as at fractional fillings, where electronic degrees of freedom form self-organized Wigner crystal states. An open question concerns magnetic states obtained by lifting the pseudospin-1/2 degeneracy of these states at lowest temperatures. While at half filling virtual hopping is expected to induce (weak) antiferromagnetic exchange interactions, these are strongly suppressed when considering dilute filling fractions. We argue that, instead, a small concentration of doped electrons leads to the formation of spin polarons, inducing ferromagnetic order at experimentally relevant temperatures, consistent with recently observed ferromagnetic states in moiré TMD systems. Here, we predict explicit signatures of polaron formation in the magnetization profile.

Kondo lattice model↗
DOE OSTI2017

Temperature dependence of ferromagnet-antiferromagnet spin alignment and coercivity in epitaxial micromagnet bilayers

In this paper, soft x-ray photoemission electron microscopy with an in situ magnetic field has been used to study the relationship between ferromagnetic and antiferromagnetic spin alignment and the switching/reversal field of epitaxial micromagnetic structures. We investigated a model system consisting of a bilayer of ferromagnetic La 0.7 Sr 0.3 MnO 3 and antiferromagnetic LaFeO 3 where the spin axes in each layer can be driven from mutually perpendicular (spin-flop) to parallel alignment by varying the temperature between 30 and 300 K. Results show that not only does this spin alignment noticeably influence the bilayer micromagnet coercivity compared to La 0.7 Sr 0.3 MnO 3 single-layer micromagnets, but the coercivity within this materials system can be tuned over a wide range by careful balance of material properties.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Role of polar compensation in interfacial ferromagnetism of LaNiO 3 /CaMnO 3 superlattices

Polar compensation can play an important role in the determination of interfacial electronic and magnetic properties in oxide heterostructures. Using x-ray absorption spectroscopy, x-ray magnetic circular dichroism, bulk magnetometry, and transport measurements, we find that interfacial charge redistribution via polar compensation is essential for explaining the evolution of interfacial ferromagnetism in LaNiO 3 /CaMnO 3 superlattices as a function of LaNiO 3 layer thickness. In insulating superlattices (four unit cells or less of LaNiO 3 ), magnetism is dominated by Ni-Mn superexchange, while itinerant electron-based Mn-Mn double exchange plays a role in thicker metallic superlattices. X-ray magnetic circular dichroism and resonant x-ray scattering show that Ni-Mn superexchange contributes to the magnetization even in metallic superlattices. This Ni-Mn superexchange interaction can be explained in terms of polar compensation at the LaNiO 3 -CaMnO 3 interface. Finally, these results highlight the different mechanisms responsible for interfacial ferromagnetism and the importance of understanding compensation due to polar mismatch at oxide-based interfaces when engineering magnetic properties.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Enhanced magnetic moments in Mn-doped FeCo clusters owing to ferromagnetic surface Mn atoms

Here, we provide an avenue to achieve optimized magnetic properties without relying on rare-earth elements. In particular, we focus on transition-metal nanoparticles with magnetic ordering that is rarely seen in bulk. By using first-principles real-space pseudopotential calculations, we show that Mn can exhibit ferromagnetic behavior similar to Fe when Mn is placed on the surface of a FeCo cluster. This ferromagnetic behavior of surface Mn is in sharp contrast with Mn bulk and Mn-based alloys, which are either antiferromagnetic or paramagnetic. The local magnetic moment carried by a surface Mn atom is larger than those of Fe and Co, leading to an increase of the total magnetic moment. We find that surface-Mn-induced magnetic enhancement is robust in ternary MnFeCo clusters with different sizes and various chemical compositions. Our theoretical findings provide a useful guide for designing new nanoparticles with a large magnetic moment.

36 MATERIALS SCIENCE↗
DOE OSTI2023

High-temperature ferromagnetism in Cr 1+x Pt 5-x P

In this work, we present the growth and basic magnetic and transport properties of Cr 1+x Pt 5-x P. We show that single crystals can readily be grown from a high-temperature solution created by adding dilute quantities of Cr to Pt-P based melts. Like other 1-5-1 compounds, Cr 1+x Pt 5-x P adopts a tetragonal P4/mmm, structure composed facesharing CrPts like slabs that are broken up along the c-axis by sheets of P atoms. EDS and X-ray diffraction measurements both suggest Cr 1+x Pt 5-x P has mixed occupancy between Cr and Pt atoms, similar to what is found in the closely related compound CrPtg, giving real compositions of Cr 1.5 Pt 4.5 P (x = 0.5). We report that Cr 1.5 Pt 4.5 P orders ferromagnetically at T c = 464.5 K with a saturated moment of ≈ 2.1 μs/Cr at 1.8 K. Likely owing to the strong spin-orbit coupling associated with the large quantity of high Z, Pt atoms, Cr 1.5 Pt 4.5 P has exceptionally strong planar anisotropy with estimated anisotropy fields of 345 kOe and 220 kOe at 1.8 K and 300 K respectively. The resistance of Cr 1.5 Pt 4.5 P has a metallic temperature dependence with relatively weak magnetoresistance. Electronic band structure calculations show that CrPt 5 P has a large peak in the density of states near the Fermi level which is split into spin majority and minority bands in the ferromagnetic state. Furthermore, the calculations suggest substantial hybridization between Cr-3d and Pt-5d states near the Fermi level, in agreement with the experimentally measured anisotropy.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Thickness dependent itinerant ferromagnetism in ultrathin Ba-doped SrRu O 3 films

The electronic and magnetic properties in AB⁢O 3 perovskite oxides are extremely sensitive to lattice structure, but also to dimensionality, such as the thickness in thin film-form. Here, we report the thickness-dependent electromagnetic properties of ultrathin epitaxially stabilized Sr 1-x ⁢Ba x ⁢Ru⁢O 3 (x = 0.08, 0.2) thin films on a SrTi⁢O 3 (001) substrate. The results reveal that the barium doping (0.08 ≤ x ≤ 0.20) reduces Ru⁢O 6 orthorhombic distortions existing in SrRu⁢O 3 and induces a tetragonal distortion, as evidenced by out-of-plane lattice expansion. A metal-to-insulator transition, accompanied by a ferromagnetic to nonmagnetic transition occurs with reducing film thickness from 10 to 3 unit cells for both x = 0.08 and 0.2, regardless of the doping level. The results suggest that the effects of compositional vacancies and surface/interface contributions introduced via dimensional confinement are more dominant than A-site chemical disorder or structural distortion for the loss of metallicity and ferromagnetism in ultra-thin epitaxial films.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Buffer-layer effect on the ferromagnetism of manganite heterojunctions

Identifying and understanding interfacial magnetic structures of transition-metal oxides are of great importance not only for fundamental physics but also for potential device applications. Among them, manganite and ruthenate heterostructures have attracted considerable interest due to their intriguing interfacial properties induced by complex magnetic interactions. Here, we report the observation of dramatic buffer-layer dependence of ferromagnetism in ultrathin (L⁢a 2/3 ⁢C⁢a 1/3 )⁢Mn⁢O 3 (LCMO)-based heterostructures. Though all trilayers are nonmetallic, the SrRu⁢O 3 -buffered LCMO trilayer exhibits enhanced ferromagnetism with the Curie temperature (𝑇 C ∼ 198K) much higher than for CaRu⁢O 3 (𝑇 C ∼ 99K)- and SrTi⁢O 3 (𝑇 C ∼ 42K)-buffered counterparts, as well as the monolithic LCMO films with similar thickness. Combining atomically resolved scanning transmission electron microscopy imaging with electron energy loss spectroscopy mapping, we reveal that asymmetric interfaces exist in the SrRu⁢O 3 buffered trilayer, with one exhibiting 1 unit-cell Sr diffusion into LCMO, which is responsible for the 𝑇 C enhancement. In contrast, charge transfer, which has been proposed previously as a possible mechanism, is excluded in this study. In conclusion, our results may pave a promising road toward effective atomic control of interfacial magnetism.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2021

Defect-mediated ferromagnetism in correlated two-dimensional transition metal phosphorus trisulfides

Controlling the magnetic spin states of two-dimensional (2D) van der Waals (vdW) materials with strong electronic or magnetic correlation is important for spintronic applications but challenging. Crystal defects that are often present in 2D materials such as transition metal phosphorus trisulfides (MPS 3 ) could influence their physical properties. Here, we report the effect of sulfur vacancies on the magnetic exchange interactions and spin ordering of few-layered vdW magnetic Ni 1-x Co x PS 3 nanosheets. Magnetic and structural characterization in corroboration with theoretical calculations reveal that sulfur vacancies effectively suppress the strong intralayer antiferromagnetic correlation, giving rise to a weak ferromagnetic ground state in Ni 1-x Co x PS 3 nanosheets. Notably, the magnetic field required to tune this ferromagnetic state (<300 Oe) is much lower than the value needed to tune a typical vdW antiferromagnet (> several thousand oersted). These findings provide a previously unexplored route for controlling competing correlated states and magnetic ordering by defect engineering in vdW materials.

36 MATERIALS SCIENCE↗
DOE OSTI2014

Observation of Majorana fermions in ferromagnetic atomic chains on a superconductor

Majorana fermions are predicted to localize at the edge of a topological superconductor, a state of matter that can form when a ferromagnetic system is placed in proximity to a conventional superconductor with strong spin-orbit interaction. With the goal of realizing a one-dimensional topological superconductor, we have fabricated ferromagnetic iron (Fe) atomic chains on the surface of superconducting lead (Pb). Using high-resolution spectroscopic imaging techniques, we show that the onset of superconductivity, which gaps the electronic density of states in the bulk of the Fe chains, is accompanied by the appearance of zero-energy end-states. As a result, this spatially resolved signature provides strong evidence, corroborated by other observations, for the formation of a topological phase and edge-bound Majorana fermions in our atomic chains.

Nadj-Perge, Stevan↗
DOE OSTI2019

Nearly ferromagnetic spin-triplet superconductivity

Spin-triplet superconductors potentially host topological excitations that are of interest for quantum information processing. We report the discovery of spin-triplet superconductivity in UTe 2 , featuring a transition temperature of 1.6 kelvin and a very large and anisotropic upper critical field exceeding 40 teslas. This superconducting phase stability suggests that UTe 2 is related to ferromagnetic superconductors such as UGe 2 , URhGe, and UCoGe. However, the lack of magnetic order and the observation of quantum critical scaling place UTe 2 at the paramagnetic end of this ferromagnetic superconductor series. A large intrinsic zero-temperature reservoir of ungapped fermions indicates a highly unconventional type of superconducting pairing.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2019

Emergent ferromagnetism near three-quarters filling in twisted bilayer graphene

When two sheets of graphene are stacked at a small twist angle, the resulting flat superlattice minibands are expected to strongly enhance electron-electron interactions. Here, we present evidence that near three-quarters ( 3 4 ) filling of the conduction miniband, these enhanced interactions drive the twisted bilayer graphene into a ferromagnetic state. In a narrow density range around an apparent insulating state at 3 4 , we observe emergent ferromagnetic hysteresis, with a giant anomalous Hall (AH) effect as large as 10.4 kilohms and indications of chiral edge states. Notably, the magnetization of the sample can be reversed by applying a small direct current. Although the AH resistance is not quantized, and dissipation is present, our measurements suggest that the system may be an incipient Chern insulator.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Screening properties of multiply connected ferromagnet–superconductor hybrid structures

Superconducting phase transition temperature T{sub c} of a ferromagnet/superconductor (SF) hybrid structure consisting of a hollow superconducting (S) cylinder (shell) with the central part (core) filled with a ferromagnetic (F) metal has been analyzed on the basis of linearized Usadel equations. It has been shown that the proximity effect between the S and F metals, as well as the exchange interaction, may induce an inhomogeneous superconducting state with Δ ~ exp(iLθ + ipz), which is characterized by nonzero circulation of phase L and wavenumber p describing the Larkin–Ovchinnikov–Fulde–Ferrell (LOFF) instability along the cylinder axis. The transitions between the states with different values of L and p, which are accompanied by a nonmonotonic dependence of superconducting transition temperature T{sub c} and effective magnetic field penetration depth Λ into the SF structure on the characteristic size of the ferromagnetic region, have been investigated.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2017

Relaxation of the magnetic state of a ferromagnetic–superconducting layered structure

We have proposed a real-time method of neutron reflectometry. The magnetic state of the Ta/V/FM/Nb/Si ferromagnetic–superconducting system has been analyzed. Relaxation of the inhomogeneous magnetic state with a characteristic time of several hours, which depends on the magnetic field magnitude and temperature, has been observed. The relaxation of the domain structure has changed upon a transition of the V and Nb layers to the superconducting state. It has been concluded that real-time reflectometry data for polarized neutrons are important for determining the origin of magnetism in ferromagnetic–superconducting layered structures.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2018

Influence of Ferromagnetic Carbon Nanotubes on Magnetic Transitions in Liquid Crystals

Magnetic field-induced orientational transitions in suspensions of carbon nanotubes (CNTs) in nematic liquid crystals have been studied in the framework of a continuum theory. Ferromagnetic CNTs are considered that possess, in addition to a large anisotropy of diamagnetic susceptibility, an additional magnetic moment due to ferromagnetic particles either situated on the CNT surface or encapsulated inside. It is established that, depending on the energy of coupling between disperse CNTs and liquid-crystalline matrix, the external magnetic field induces various sequences of orientational transitions. A threshold value of the coupling energy is determined, above which a transition from the initial homogeneous planar phase to inhomogeneous state (angular phase) becomes possible. At coupling energies below the threshold, the increasing magnetic field induces the following sequence of orientational transitions: homogeneous planar phase–inhomogeneous (angular) phase–homogeneous homeotropic phase–inhomogeneous angular phase. It is established that, depending on the intensity of segregation phenomena, these transitions can be of the first or second order. Analytical expressions for the fields of second-order transitions between phases are found. On an example of the optical phase difference between the ordinary and extraordinary rays of light passing through the cell of CNT suspension, it is shown that the suspension can exhibit optical bistability during the first-order orientational transition.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2018

Tuning the ferromagnetic tri-critical point and quantum critical point in Ce(Pd 1- x Ni x ) 2 P 2 under high magnetic fields [Poster]

We recently uncovered a ferromagnetic quantum phase transition in the Kondo lattice alloy series Ce(Pd 1-x Ni x ) 2 P 2 near x cr ≈ 0.7 (Fig.1a). This provides the rare opportunity to study phenomena associated with ferromagnetic quantum fluctuations and to contrast them with predictions from different theories.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗