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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 667 records · Page 37

Core-Mantle Fractionation of Carbon in Earth and Mars: the Effects of Sulfur

Constraining carbon (C) fractionation between silicate magma ocean (MO) and core-forming alloy liquid during early differentiation is essential to understand the origin and early distribution of C between reservoirs such as the crust-atmosphere, mantle, and core of Earth and other terrestrial planets. Yet experimental data at high pressure (P)-temperature (T) on the effect of other light elements such as sulfur (S) in alloy liquid on alloy-silicate partitioning of C and C solubility in Fe-alloy compositions relevant for core formation is lacking. Here we have performed multi-anvil experiments at 6–13 GPa and 1800–2000 °C to examine the effects of S and Ni on the solubility limit of C in Fe-rich alloy liquid as well as partitioning behavior of C between alloy liquid and silicate melt (𝐷𝐷(sub C)(sup alloy/silicate)). The results show that C solubility in the alloy liquid as well as 𝐷𝐷(sub C)(sup alloy/silicate) decreases with increasing in S content in the alloy liquid. Empirical regression on C solubility in alloy liquid using our new experimental data and previous experiments demonstrates that C solubility significantly increases with increasing temperature, whereas unlike in S-poor or S-free alloy compositions, there is no discernible effect of Ni on C solubility in S-rich alloy liquid. Our modelling results confirm previous findings that in order to satisfy the C budget of BSE, the bulk Earth C undergoing alloy-silicate fractionation needs to be as high as those of CI-type carbonaceous chondrite, i.e., not leaving any room for volatility-induced loss of carbon during accretion. For Mars, on the other hand, an average single-stage core formation at relatively oxidized conditions (1.0 log unit below IW buffer) with 10-16 wt.% S in the core could yield a Martian mantle with a C budget similar to that of Earth’s BSE for a bulk C content of ~0.25-0.9 wt.%. For the scenario where C was delivered to the proto-Earth by a S-rich differentiated impactor at a later stage, our model calculations predict that bulk C content in the impactor can be as low as ~0.5 wt.% for an impactor mass that lies between 9-20% of present day Earth’s mass. This value is much higher than 0.05-0.1 wt.% bulk C in the impactor predicted by Li et al. (2016) because C-solubility limit of 0.3 wt.% in a S-rich alloy predicted by their models is significantly lower than the experimentally derived C-solubility of ~1.6 wt. % for the relevant S-content in the core of the impactor.

Carbon↗

The DAB model of drawing processes

The problem of automatic drawing was investigated in two ways. First, a DAB model of drawing processes was introduced. DAB stands for three types of knowledge hypothesized to support drawing abilities, namely, Drawing Knowledge, Assimilated Knowledge, and Base Knowledge. Speculation concerning the content and character of each of these subsystems of the drawing process is introduced and the overall adequacy of the model is evaluated. Second, eight experts were each asked to understand six engineering drawings and to think aloud while doing so. It is anticipated that a concurrent protocol analysis of these interviews can be carried out in the future. Meanwhile, a general description of the videotape database is provided. In conclusion, the DAB model was praised as a worthwhile first step toward solution of a difficult problem, but was considered by and large inadequate to the challenge of automatic drawing. Suggestions for improvements on the model were made.

Hochhaus, Larry W.↗

Lu-Hf constraints on the evolution of lunar basalts

It is shown that a cumulate-remelting model best explains the recently acquired data on the Lu-Hf systematics of lunar mare basalts. The model is constructed using Lu and Hf concentration data and is strengthened by Hf isotopic evidence of Unruh et al. (1984). It is shown that the similarity in MgO/FeO ratios and Cr2O3 content in high-Ti and low-Ti basalts are not important constraints on lunar basalt petrogenesis. The model demonstrates that even the very low Ti or green glass samples are remelting products of a cumulate formed after at least 80-90 percent of the lunar magma ocean had solidified. In the model, all the mare basalts and green glasses were derived from 100-150 km depth in the lunar mantle. The Lu-Hf systematics of KREEP basalts clearly indicate that they would be the final residual liquid of the lunar magma ocean.

Fujimaki, H.↗

Retrieval of Precipitation Profiles from Multiresolution, Multifrequency, Active and Passive Microwave Observations

In this study, a technique for estimating vertical profiles of precipitation from multifrequency, multiresolution active and passive microwave observations is investigated using both simulated and airborne data. The technique is applicable to the Tropical Rainfall Measuring Mission (TRMM) satellite multi-frequency active and passive observations. These observations are characterized by various spatial and sampling resolutions. This makes the retrieval problem mathematically more difficult and ill-determined because the quality of information decreases with decreasing resolution. A model that, given reflectivity profiles and a small set of parameters (including the cloud water content, the intercept drop size distribution, and a variable describing the frozen hydrometeor properties), simulates high-resolution brightness temperatures is used. The high-resolution simulated brightness temperatures are convolved at the real sensor resolution. An optimal estimation procedure is used to minimize the differences between simulated and observed brightness temperatures. The retrieval technique is investigated using cloud model synthetic and airborne data from the Fourth Convection And Moisture Experiment. Simulated high-resolution brightness temperatures and reflectivities and airborne observation strong are convolved at the resolution of the TRMM instruments and retrievals are performed and analyzed relative to the reference data used in observations synthesis. An illustration of the possible use of the technique in satellite rainfall estimation is presented through an application to TRMM data. The study suggests improvements in combined active and passive retrievals even when the instruments resolutions are significantly different. Future work needs to better quantify the retrievals performance, especially in connection with satellite applications, and the uncertainty of the models used in retrieval.

Grecu, Mircea↗

Preflow stresses in Martian rampart ejecta blankets - A means of estimating the water content

Measurements of extents of rampart ejecta deposits as a function of the size of the parent craters support models which, for craters larger than about 6 km diameter, constrain ejecta blankets to all have a similar maximum thickness regardless of the crater size. These volatile-rich ejecta blankets may have failed under their own weights, then flowed radially outward. Assuming this to be so, some of the physicomechanical properties of the ejecta deposits at the time of their emplacement can then be determined. Finite-element studies of the stress magnitudes, distributions, and directions in hypothetical Martian rampart ejecta blankets reveal that the material most likely failed when the shear stresses were less than 500 kPa and the angle of internal friction was between 26 and 36 deg. These figures imply that the ejecta has a water content between 16 and 72%. Whether the upper limit or the lower limit is more appropriate depends on the mode of failure which one presumes: namely, viscous flow of plastic deformation.

Woronow, A.↗

Climatic modification by CO2, H2O, and aerosol

Research is reported on the effects of increasing the CO2, aerosols, and water content of the atmosphere on the surface temperature and climatology. An atmospheric model is described with the incoming solar radiation for a planetary albedo of 33 percent, surface temperature of 288 K, relative humidity of 75 percent, cloud cover of 48 percent, CO2 of 0.3 parts per thousand, and aerosol density of two million per square centimeter. The results show that if the CO2 increases by a factor of 1000 or more, the total pressure of the atmosphere increases, and the earth may become as hot as Venus. It is also shown that as the amount of dust particles in the atmosphere increases, the solar radiation decreases, and the surface temperature lowers.

Rasool, I.↗

Doppler noise considered as a function of the signal path integration of electron density

The hypothesis is advanced that observed Doppler noise during solar conjunctions is proportional to total columnar electron content along the signal path. This assumption leads directly to a geometrical model (ISED) for observed Doppler noise which is shown to be in very good agreement with Doppler noise data accumulated during the 1975 Pioneer 10, Pioneer 11 and Helios 1 solar conjunctions. An augmented model is constructed which quantitatively indicates correlation between earth observed sunspot activity and systematic, cyclical deviations from the ISED model.

Berman, A. L.↗

A simulation of air pollution model parameter estimation using data from a ground-based LIDAR remote sensor

One way to obtain estimates of the unknown parameters in a pollution dispersion model is to compare the model predictions with remotely sensed air quality data. A ground-based LIDAR sensor provides relative pollution concentration measurements as a function of space and time. The measured sensor data are compared with the dispersion model output through a numerical estimation procedure to yield parameter estimates which best fit the data. This overall process is tested in a computer simulation to study the effects of various measurement strategies. Such a simulation is useful prior to a field measurement exercise to maximize the information content in the collected data. Parametric studies of simulated data matched to a Gaussian plume dispersion model indicate the trade offs available between estimation accuracy and data acquisition strategy.

Kibler, J. F.↗

Partition coefficients for REE between garnets and liquids - Implications of non-Henry's Law behaviour for models of basalt origin and evolution

An experimental investigation of Ce, Sm and Tm rare earth element (REE) partition coefficients between coexisting garnets (both natural and synthetic) and hydrous liquids shows that Henry's Law may not be obeyed over a range of REE concentrations of geological relevance. Systematic differences between the three REE and the two garnet compositions may be explained in terms of the differences between REE ionic radii and those of the dodecahedral site into which they substitute, substantiating the Harrison and Wood (1980) model of altervalent substitution. Model calculations demonstrate that significant variation can occur in the rare earth contents of melts produced from a garnet lherzolite, if Henry's Law partition coefficients do not apply for the garnet phase.

Harrison, W. J.↗

Wet oxidation as a waste treatment in closed systems

The chemistry of the wet oxidation process has been investigated in relation to production of plant nutrients from plant and human waste materials as required for a closed life-support system. Hydroponically grown lettuce plants were used as a model plant waste and oxygen gas was used as oxidant. Organic nitrogen content was decreased 88-100% depending on feed material. Production of ammonia and nitrogen gas account for all of the observed decrease in organic nitrogen content. No nitrous oxide (N2O) was detected. The implications of these results for closed life-support systems are discussed.

Onisko, B. L.↗

Cage Regional Energy Budgets from the GLAS 4TH Order Model

The status and future plans of a study to (1) assess the accuracy of regional energy balance calculations obtained from the 4th-order model, (2) determine the impact of satellite data on the calculations, and (3) determine their utility for ocean energy transport studies are discussed. An equation is presented which models the vertically-integrated, time and areally-averaged total energy content of a region of the atmosphere extending from the surface to the top of the atmosphere. All of the terms of the equation were evaluated using early versions of the GLAS FGGE IIIb analysis, and analysis with satellite data deleted. Results show that the budget is dominated by the surface fluxes, net radiation, and horizontal atmospoheric divergence.

Herman, G. F.↗

Experimental study of performance degradation of a rotating system in the NASA Lewis RC icing tunnel

The Helicopter Icing Consortium (HIC) conducted one of the first U.S. tests of a heavily instrumented model in the controlled environment of a refrigerated tunnel. In the Icing Research Tunnel (IRT) at NASA LeRC, ice was accreted on the main rotor blade of the BMTR-1 Sikorsky model helicopter under a variety of environmental conditions, such that liquid water content (LWC) and volume mean droplet diameter (VMD) ranges reflected the Federal Aviation Agency and Department of Defence icing condition envelopes. This report gives the correlated results of the data provided by NASA LeRC. The method of statistical analysis is discussed. Lift, thrust, and torque coefficients are presented as a function of icing time, as correlated with changes in ambient temperature, LWC, and VMD. The physical significance of these forces is discussed.

Korkan, Kenneth↗

Ignition and combustion of aluminum/magnesium alloy particles in O2 at high pressures

The ignition and combustion of Al, Mg, and Al/Mg alloy particles in 99 percent O2/1 percent N2 mixtures is investigated at high temperatures and pressures for rocket engine applications. The 20-micron particles contain 0, 5, 10, 20, 40, 60, 80, and 100 wt pct Mg alloyed with Al, and are ignited in oxygen using the reflected shock in a single-pulse shock tube near the endwall. Using this technique, the ignition delay and combustion times of the particles are measured at temperatures up to 3250 K as a function of Mg content for oxygen pressures of 8.5, 17, and 34 atm. An ignition model is developed that employs a simple lumped capacitance energy equation and temperature and pressure dependent particle and gas properties. Good agreement is achieved between the measured and predicted trends in the ignition delay times.

Roberts, Ted A.↗

Analysis of the GOES 6.7 micrometer channel observations during FIRE 2

Clouds form in moist environments. FIRE Phase II Cirrus Implementation Plan (August, 1990) noted the need for mesoscale measurements of upper tropospheric water vapor content. These measurements are needed for initializing and verifying numerical weather prediction models and for describing the environment in which cirrus clouds develop and dissipate. Various instruments where deployed to measure the water vapor amounts of the upper troposphere during FIRE II (e.g. Raman lidar, CLASS sonds and new cryogenic frost hygrometer on-board aircraft). The formation, maintenance and dissipation of cirrus clouds involve the time variation of the water budget of the upper troposphere. The GOES 6.7 mu m radiance observations are sensitive to the upper tropospheric relative humidity, and therefore proved extremely valuable in planning aircraft missions during the field phase of FIRE II. Warm 6.7 mu m equivalent black body temperatures indicate a relatively dry upper troposphere and were associated with regions generally free of cirrus clouds. Regions that were colder, implying more moisture was available may or may not have had cirrus clouds present. Animation of a time sequence of 6.7 mu m images was particularly useful in planning various FIRE missions. The 6.7 mu m observations can also be very valuable in the verification of model simulations and describing the upper tropospheric synoptic conditions. A quantitative analysis of the 6.7 mu m measurement is required to successfully incorporate these satellite observations into describing the upper tropospheric water vapor budget. Recently, Soden and Bretherton (1993) have proposed a method of deriving an upper tropospheric humidity based on observations from the GOES 6.7 mu m observations. The method is summarized in the next section. In their paper they compare their retrieval method to radiance simulations. Observations were also compared to ECMWF model output to assess the model performance. The FIRE experiment provides a unique opportunity to further verify the GOES upper tropospheric relative humidity retrieval scheme by providing (1) aircraft observations to cross-validate the calibration of the GOES 6.7 mu m channel, (2) accurate upper tropospheric water vapor concentrations for verification, and (3) veritical variability of upper tropospheric water vapor.

Soden, B. J.↗

Microphysical Characterization of Ice in Hurricane Erin for Wideband Passive Microwave Comparisons

In order to better understand the characteristics of frozen hydrometeors in hurricane systems, computed brightness temperatures were compared with observations of Hurricane Erin from CAMEX-4 radiometers on the ER-2 aircraft. These wideband observations ranged from 10.7 to 183 plus or minus 10 GHz. In order to initialize the cloud profiles used in the radiative transfer calculations, radar reflectivities from an ER-2 instrument were converted to mass contents at specified height levels. Dropsonde data from the ER-2 and modeled Hurricane Andrew data were used to generate profiles of temperature, pressure, and relative humidity and to provide surface wind speed and ocean temperature. Four different ice (size and density) parameterizations were used to compute brightness temperature values. The comparisons between the calculated and observed brightness temperatures show that in general the Grenfell and Warren particle size distribution does the best job of matching the observations for most of the high frequencies. These high frequencies (greater than or equal to 85 GHz) are particularly sensitive to frozen particles. The Sehkon and Srivastava particle size distribution produced brightness temperatures that were too cold in most cases. On the other hand, the fluffy snow particle parameterizations with and without a melting layer produced brightness temperatures that were much warmer than the observations at these high frequencies. All low frequency calculations track the observations well except in the eye of Hurricane Erin where the surface wind speed and/or near surface temperatures were not properly adjusted to warm the brightness temperature calculations to values closer to the observations. Overall, this work shows that selecting a proper ice particle parameterization can be difficult and additional in situ measurements are needed to define appropriate parameterizations.

Skofronick-Jackson, G.↗

Partial resolution of sources of n-alkanes in the saline portion of the Parachute Creek Member, Green River Formation (Piceance Creek Basin, Colorado)

Systematic variations in the 13C contents of individual extractable n-alkanes (C16-C29) can be modelled quantitatively and interpreted as indicating contributions from at least five distinct sources. These appear to be cyanobacterial (C16-C18, delta 13C = -37% vs PDB), phytoplanktonic (C16-C23, delta = -32%), chemoautotrophic bacterial (C20-C29, delta = -38%), phytoplanktonic or heterotrophic bacterial (C20-C29, delta = -30%), and vascular plants (C23-C29, delta = -29%). Hydrous pyrolysis of related kerogens yields large quantities of additional n-alkanes with different and much more uniform delta values. The latter materials are apparently derived from the thermolysis of aliphatic biopolymers whose presence in the Green River Oil Shale has been recognized visually.

Non-NASA Center↗

On the ionospheric impact of recent storm events on satellite-based augmentation systems in middle and low-latitude sectors

The Ionospheric correction algorithms have been characterized extensively for the mid-latitude region of the ionosphere where benign conditions usually exist. The United States Federal Aviation Administration's (FAA) Wide Area Augmentation System (WAAS) for civil aircraft navigation is focused primarily on the Conterminous United States (CONUS). Other Satellite-based Augmentation Systems (SBAS) include the European Geostationary Navigation Overlay Service (EGNOS) and the Japanese Global Navigation Satellite System (MSAS). Researchers are facing a more serious challenge in addressing the ionospheric impact on navigation using SBAS in other parts of the world such as the South American region on India. At equatorial latitudes, geophysical conditions lead to the so-called Appleton-Hartree (equatorial) anomaly phenomenon, which results in significantly larger ionospheric range delays and range delay spatial gradients than is observed in the CONUS or European sectors. In this paper, we use GPS measurements of geomagnetic storm days to perform a quantitative assessment of WAAS-type ionospheric correction algorithms in other parts of the world such as the low-latitude Brazil and mid-latitude Europe. For the study, we access a world-wide network of 400+ dual frequency GPS receivers.

validation↗