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At least 667 records · Page 37

The saturated activities of Na-22, Mn-54, and Co-56 and the depth of sampling of soils

A multivariate linear regression study shows that the saturated activities of Na-22, Co-56, and Mn-54 are functions of the chemical composition and the reciprocal of the cube root of the sample weight. A procedure for taking the temporal variation in these short-lived radionuclides into account is described. The regression results are used to estimate the average depths of sampling of soil material. The data indicate that all 28 samples were in the same conditions of exposure when recovered as they had been for the last approximately 10 years. The saturation activity of Mn-54 is a very weak function of time.

Keith, J. E.↗

Estimates on the production of CO and H2 from the oxidation of hydrocarbon emissions from vegetation

Extrapolating from extensive field measurements on foliar emissions in the U.S. approximate global inputs of isoprene and terpenes of 3.5 times 10 to the 14th power and 4.8 times 10 to the 14th power g(C)/yr, respectively, are obtained. The oxidation of these hydrocarbons could contribute in an important way to the atmospheric sources of CO (4.2-13.3 times 10 to the 14th power g/yr) and H2 (10-35 times 10 to the 12th power g/yr), and to organic species soluble in rainwater

Zimmerman, P. R.↗

Temperature dependence of the deactivation of O/1D/ by CO from 113-333 K

Absolute rate constants for the deactivation of O(1D) by CO have been measured at temperatures between 113 and 333 K. A very small temperature dependence is observed and is described by the Arrhenius expression (4.7 + or - 0.9) times 10 to the -11th power exp(126 + or 33)/RT cu cm/molecule-sec, where E is in cal/mol.

Davidson, J. A.↗

Calculation of CO concentration for liquid fueled gas turbine combustor

The extensive computation time required for the numerical integration of the differential equations obtained in studies of the concentrations of pollutants emitted by gas turbine combustors, can be reduced significantly by assuming the heat releasing hydrocarbon reactions to be in local equilibrium. In determining the CO and NO concentrations produced in spray combustion, it is, therefore, tempting to use the same local equilibrium assumption in order to simplify the kinetic calculations. An investigation of the validity of the local equilibrium assumption is conducted by using a simple analytical model, and then by actually carrying out the kinetic and local equilibrium calculations for typical case.

Patil, P. B.↗

The hot corrosion of Co-25Cr-10Ni-5Ta-3Al-0.5Y alloy /S-57/

A cobalt-base alloy, Co-25Cr-10Ni-5Ta-3Al-0.5Y (S-57), was subjected to hot corrosion in Mach 0.3 burner-rig combustion gases at maximum alloy temperatures of 900 and 1000 C. Various salt concentrations were injected into the burner: 0.5, 2,5, and 10 parts per million synthetic sea salt and 4 parts per million sodium sulfate (Na2SO4). The extent of corrosion was determined by measuring the maximum depth of corrosion in the alloy, and the corrosion process was studied by metallography, X-ray diffraction, scanning electron microscopy, and electron microprobe analysis. While S-57 was found to possess only moderate oxidation resistance at these temperatures, this alloy resisted significant hot corrosion attack under all but the most severe test conditions. The process of hot corrosion attack under the most severe conditions of this study was primarily sulfidation.

Santoro, G. J.↗

Co-apsidal autonomous terminal rendezvous in Mars orbit

The autonomous (or unmanned) Mars Orbit Rendezvous may be divided into four phases: approach, terminal, station-keeping, and docking. The paper outlines a feasible concept for the terminal rendezvous phase. A co-apsidal terminal rendezvous technique is described which utilizes the advantages of aligning the lines of apsides of two coplanar elliptic orbits of slightly different periods but of the same apoapsis distance. An initial maneuver nulling the inclination between the orbits is followed by another maneuver to align the two lines of apsides. A proper phasing maneuver is then executed at the coapsidal point, and the final rendezvous maneuver is performed at the same coapsidal point to complete the terminal rendezvous transfer. Cases are formulated in order of complexity with a view to illustrate the basic ideas of this technique. Pertinent calculations are also presented.

Tang, C. C. H.↗

K-shell photoabsorption coefficients of O2, CO2, CO, and N2O

The total photoabsorption coefficient has been measured from 500 to 600 eV around the K edge of oxygen in gases O2, CO2, CO, and N2O by means of a gold continuum source and crystal spectrometer with better than 1-eV resolution. The cross sections are dominated by discrete molecular-orbital transitions below the K-edge energy. A few Rydberg transitions were barely detectable. Broad shape resonances appear at or above the K edge. Additional broad, weak features above the K edge possibly arise from shake up. Quantitative results are given that have about 10% accuracy except on the very strong peaks. All the measured features are discussed in relation to other related measurements and theory.

Barrus, D. M.↗

CO observations of the galactic star-forming region W58

Observations of (C-12)O and (C-13)O have been made in the direction of the strong galactic radio source W58, which contains the compact H II regions K3-50 and ON-3. An extended molecular cloud with dimensions of 55 x 40 pc is associated with the northern part of the H II region complex. The density of the molecular cloud increases from west to east; the molecular cloud is bounded on the east by a larger H I cloud. Present star-formation activity is taking place at the position of maximum molecular density, at what appears to be the interface of the H I cloud and the H II region complex. The velocity structure of the CO cloud and the compact H II regions are in agreement with the blister model. Radio continuum and H I line observations show indications of a shell structure in the southwest of W58. Present star formation in W58 may be caused by this expanding shell.

Israel, F. P.↗

Vibrational kinetics in CO electric discharge lasers - Modeling and experiments

A model of CO laser vibrational kinetics is developed, and predicted vibrational distributions are compared with measurements. The experimental distributions were obtained at various flow locations in a transverse CW discharge in supersonic (M = 3) flow. Good qualitative agreement is obtained in the comparisons, including the prediction of a total inversion at low discharge current densities. The major area of discrepancy is an observed loss in vibrational energy downstream of the discharge which is not predicted by the model. This discrepancy may be due to three-dimensional effects in the experiment which are not included in the model. Possible kinetic effects which may contribute to vibrational energy loss are also examined.

Stanton, A. C.↗

CO/+/ in comet Schwassmann-Wachmann 1 near minimum brightness

A spectrum of comet Schwassmann-Wachmann 1, taken when the comet was in a quiescent state 6.19 AU from the sun, shows the 1-0, 2-0, 3-0 and 4-0 vibrational transitions of the A2Pi-X2Sigma band system of CO(+) and a weak solar reflection continuum. It is noted that such emission has never been observed in this comet when in a quiescent state. Mechanisms for outbursts in the comet are discussed.

Larson, S. M.↗

Photodissociation of CO2 into CO plus O/1D/

It is shown that the photodissociation of CO2(1Sigma/g/plus) into CO(X1Sigma/plus/) plus O(1D) with a quantum yield of unity is consistent with all known data on the CO2 ultraviolet absorption band between 1675 and 1400 A. Astrophysical data from the atmospheres of Mars and Venus are not inconsistent with this interpretation and cometary data seem to support it.

Delsemme, A. H.↗

Quantum mechanical study of elastic scattering and rotational excitation of CO by electrons

Coupling calculations of differential, integral, and momentum transfer cross sections for pure elastic scattering and rotational excitation of CO by electron impact are reported. The calculations are based on a static charge distribution that has correct dipole and quadrupole moments, has cusps at the nuclei, and is augmented by an SCF treatment of charge polarization and a local approximation for exchange. The rotationally summed cross sections, with no adjustable parameters in the scattering calculation, are in reasonably good agreement with the experimental cross sections but are somewhat larger at small scattering angles.

Onda, K.↗

Detection of CO J = 21-20 /124.2 microns/ and J = 22-21 /118.6 microns/ emission from the Orion nebula

The first observation of far-infrared molecular line emission from the interstellar medium is reported. Strong emission from the J = 21-20 and J = 22-21 rotational transitions of carbon monoxide was detected in the Kleinmann-Low/shocked H2 region of the Orion Molecular Cloud. The results imply that the region is optically thin in these lines and that much of the carbon is in the form of CO. This work also represents the first use of an antimony-doped germanium photoconductor in an astronomical application.

Watson, D. M.↗

The STD/MHD codes - Comparison of analyses with experiments at AEDC/HPDE, Reynolds Metal Co., and Hercules, Inc

Data from sufficiently well-instrumented, short-duration experiments at AEDC/HPDE, Reynolds Metal Co., and Hercules, Inc., are compared to analyses with multidimensional and time-dependent simulations with the STD/MHD computer codes. These analyses reveal detailed features of major transient events, severe loss mechanisms, and anomalous MHD behavior. In particular, these analyses predicted higher-than-design voltage drops, Hall voltage overshoots, and asymmetric voltage drops before the experimental data were available. The predictions obtained with these analyses are in excellent agreement with the experimental data and the failure predictions are consistent with the experiments. The design of large, high-interaction or advanced MHD experiments will require application of sophisticated, detailed and comprehensive computational procedures in order to account for the critical mechanisms which led to the observed behavior in these experiments.

Vetter, A. A.↗

A theoretical study of selected singlet and triplet states of CO molecule

The results of the configuration calculations of six singlet electronic states and one triplet electronic state of CO are presented. The potential energy curves, spectroscopic constants, and electron transition moments are calculated, along with electronic dipole moment functions for three states. The self consistent field and configuration calculations used to obtain the electronic wave functions are described. The theoretical results are found to be in good agreement with the experimental measurements, and in the case of the dipole moment function calculations, preferable to them.

Cooper, D. M.↗

On the use of pressure broadening data to assess the accuracy of CO-He interaction potentials

The results of SCF-CI calculations of the intermolecular potential surface for CO and He are compared with pressure broadening data. Coupled states calculations were performed for both the electron gas and the more accurate SCF-CI potentials at collision energies from 15 to 1200/cm, and Boltzmann averages over collision energy were taken to compare with experimental results at liquid nitrogen (77 K), dry ice (195 K) and room (295 K) temperatures. The cross sections from the SCF-CI potential are shown to be in slightly better agreement with experiment than those from the electron gas potential, although both are consistent with the data to within experimental uncertainties. Closer examination of the experimental results reveals that this essential equivalence is due not to any inherent insensitivity of the pressure broadening technique, but to the uncertainties in the experimental values. It is thus concluded that more accurate experimental values are required to place meaningful constraints on the intermolecular potential.

Green, S.↗

Measurements of plasmaspheric columnar electron content from ATS6 at Boulder, CO and Lorman, MS from December, 1976 to May, 1978

TEC measurements were made of the ionosphere and plasmasphere at Boulder, CO and Lorman, MS using the ATS-6 radio beacon, and winter diurnal behavior is compared for three time periods over North American and Europe. Analyses indicate that during the winter of 1976-1977 at Lorman, and the winter of 1977-1978 at Boulder, the plasmasphere content had no diurnal variation, although in the winter of 1974-1975 the peak occurred at night. Differences in diurnal behavior over North America and Europe are explained by a combination of plasma flow in and out of local and conjugate ionospheres. The difference appears to be temporal rather than spatial, thus, the cross-L drift of plasma tubes under the influence of electric fields is suggested to be an influence on the diurnal variation of the plasmaspheric columnar electron content.

Davies, K.↗