Vapor phase hydrodeoxygenation of furfural to 2-methylfuran on molybdenum carbide catalysts
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Here we provide direct evidence for the formation of an Fe V (O)(OH) species in non-haem iron catalysis using ambient mass spectrometry.
An important activity/selectivity trade-off occurs at increased olefin oligomerization temperatures. Jet-range product decreases and paraffin formation increases at high oligomerization temperatures.
A major challenge for the design of noble metal nanocatalysts is the ability of surface engineering to enhance the activity and stability with minimum use of the noble metals.
The stability of zeolite Sn-beta (Sn-β) was greatly improved for glucose isomerization to fructose and fructose yield of 41.5% has been obtained when dioxane/water was used as solvent. The effect of dioxane/water solvent mixtures for fructose dehydration on Amberlyst-131 was also studied and it was found that small amounts of water in dioxane increase the yield of HMF (up to 74%) by limiting the formation of oligomers like difructose anhydride (III). 56% yield of HMF from glucose, maltose, trehalose or cellobiose and 60% from sucrose were produced when hydrolysis of disaccharides, glucose isomerization and fructose dehydration were coupled in a mixture of dioxane/water (5 wt%).
The facet-dependent strain effects on the hydrogen evolution reaction catalyzed by CoP were studied using density functional theory methods. We show that both atomic and electronic effects need to be taken into consideration to understand the strain effects. For the (111) surface, tensile strain promotes hydrogen evolution at all the levels of hydrogen coverage. For the (101) surface, a moderate tensile strain of ~3% endows this facet with optimum performance.
Herein is reported the electrocatalytic reduction of CO 2 with the complex [Ni(bis-NHC)(dmpe)] 2+ ( 1 ) (bis-NHC = 1,l′:3,3′-bis(1,3-propanediyl)dibenzimidazolin-2,2′-diylidene; dmpe = 1,2-bis(dimethylphosphino)ethane).
We explored the production of levoglucosenone from levoglucosan using propylsulfonic acid functionalized silica; 59% selectivity was obtained at 100% conversion.
This work explores the concept of structurally tailored and engineered macromolecular (STEM) networks by proposing a novel metal-free approach to prepare the networks.
Metallic Pd and/or reduced Pd oxide on Pd–TiO 2 is found to be the intrinsic active site for O 2 removal.
Isolated Fe sites achieve enhanced intrinsic activity for nitrate electroreduction to ammonia with ∼100% selectivity, which effectively inhibit water dissociation through a nitrate-preoccupation mechanism.
Zirconia supported tungstates catalyze octadecanol dehydration, an important step in the carbon preserving conversion of triglycerides to fuels.