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At least 667 records · Page 37

Alignment and Distortion-Free Integration of Lightweight Mirrors into Meta-Shells for High-Resolution Astronomical X-Ray Optics

High-resolution, high throughput optics for x-ray astronomy requires fabrication of well-formed mirror segments and their integration with arc-second level precision. Recently, advances of fabrication of silicon mirrors developed at NASA/Goddard prompted us to develop a new method of mirror integration. The new integration scheme takes advantage of the stiffer, more thermally conductive, and lower-CTE silicon, compared to glass, to build a telescope of much lighter weight. In this paper, we address issues of aligning and bonding mirrors with this method. In this preliminary work, we demonstrated the basic viability of such scheme. Using glass mirrors, we demonstrated that alignment error of 1" and bonding error 2" can be achieved for mirrors in a single shell. We will address the immediate plan to demonstrate the bonding reliability and to develop technology to build up a mirror stack and a whole "meta-shell".

X-ray optics↗

The dependence of the strength and thickness of field‐aligned currents on solar wind and ionospheric parameters

Abstract Sheared plasma flows at the low‐latitude boundary layer (LLBL) correlate well with early afternoon auroral arcs and upward field‐aligned currents. We present a simple analytic model that relates solar wind and ionospheric parameters to the strength and thickness of field‐aligned currents (Λ) in a region of sheared velocity, such as the LLBL. We compare the predictions of the model with DMSP observations and find remarkably good scaling of the upward region 1 currents with solar wind and ionospheric parameters in region located at the boundary layer or open field lines at 1100–1700 magnetic local time. We demonstrate that and Λ ∼ L when Λ/ L < 5 where L is the auroral electrostatic scale length. The sheared boundary layer thickness (Δ m ) is inferred to be around 3000 km, which appears to have weak dependence on V sw . J ∥ has dependencies on Δ m , Σ p , n sw , and V sw . The analytic model provides a simple way to organize data and to infer boundary layer structures from ionospheric data.

Johnson, Jay R.↗

Theory and observations of upward field‐aligned currents at the magnetopause boundary layer

Abstract The dependence of the upward field‐aligned current density ( J || ) at the dayside magnetopause boundary layer is well described by a simple analytic model based on a velocity shear generator. A previous observational survey confirmed that the scaling properties predicted by the analytical model are applicable between 11 and 17 MLT. We utilize the analytic model to predict field‐aligned currents using solar wind and ionospheric parameters and compare with direct observations. The calculated and observed parallel currents are in excellent agreement, suggesting that the model may be useful to infer boundary layer structures. However, near noon, where velocity shear is small, the kinetic pressure gradients and thermal currents, which are not included in the model, could make a small but significant contribution to J || . Excluding data from noon, our least squares fit returns log( J ||,max_cal ) = (0.96 ± 0.04) log( J ||_obs ) + (0.03 ± 0.01) where J ||,max_cal = calculated J ||,max and J ||_obs = observed J || .

Wing, Simon↗

Aligned van der Waals Coupled Growth of Carbon Nanotubes to Hexagonal Boron Nitride

Abstract 1D carbon nanotubes (CNTs) are grown on hexagonal boron nitride (hBN) surfaces. The nanotubes show clear preference to align to specific crystal directions of the hBN substrate. Raman spectra confirm that the nanotubes consist of sp 2 carbon, while nanomanipulation shows that they are van der Waals coupled to the underlying hBN substrate. Scanning conductance and electric force microscopy show that the CNTs have significantly greater electrical conductance compared to the hBN. This integrated aligned growth of materials with similar lattices, yet having dissimilar dimensionality and electrical conducting properties, provides a promising route to achieving intricate nanoscale electrical circuits on high‐quality insulating substrates.

Nasseri, Mohsen↗

Tunable Magnetic and Optical Anisotropy in ZrO 2 ‐Co Vertically Aligned Nanocomposites

Abstract Metamaterials have gained great research interest in recent years owing to their potential for property tunability, multifunctionality, and property coupling. As a new group of self‐assembled thin films, vertically aligned nanocomposite (VAN)‐based hybrid metamaterials have been demonstrated with significant anisotropic physical properties and a broad range of property tailorability, such as optical anisotropy, magnetic anisotropy, hyperbolic dispersion, and enhanced second harmonic generation properties. Herein, self‐assembled ZrO 2 ‐Co nanocomposite films, with high epitaxial quality and ultra‐fine vertically aligned Co nanopillars (with an average diameter of ≈2 nm) embedded in a ZrO 2 matrix, are fabricated using a pulsed laser deposition (PLD) method. The Co pillar density can be effectively tuned by varying the Co concentration in the target, which results in tunable optical properties and magnetic properties. Specifically, a high saturation magnetization of 100 emu cm −3 , strong out‐of‐plane magnetic anisotropy and tailorable magnetization properties are achieved via tuning the Co nanopillar density. Coupled with hyperbolic dispersion of dielectric constant from 950 to 1500 nm in wavelength, plasmonic Co metal nanopillars, and the unique dielectric ZrO 2 matrix, this new nanoscale hybrid metamaterial shows great potential for future integrated optical and magnetic device designs.

36 MATERIALS SCIENCE↗

Flow-aligned, single-shot fiber diffraction using a femtosecond X-ray free-electron laser

A major goal for X-ray free-electron laser (XFEL) based science is to elucidate structures of biological molecules without the need for crystals. Filament systems may provide some of the first single macromolecular structures elucidated by XFEL radiation, since they contain one-dimensional translational symmetry and thereby occupy the diffraction intensity region between the extremes of crystals and single molecules. Here, we demonstrate flow alignment of as few as 100 filaments ( Escherichia coli pili, F-actin, and amyloid fibrils), which when intersected by femtosecond X-ray pulses result in diffraction patterns similar to those obtained from classical fiber diffraction studies. We also determine that F-actin can be flow-aligned to a disorientation of approximately 5 degrees. Using this XFEL-based technique, we determine that gelsolin amyloids are comprised of stacked β-strands running perpendicular to the filament axis, and that a range of order from fibrillar to crystalline is discernable for individual α-synuclein amyloids.

59 BASIC BIOLOGICAL SCIENCES↗

Synergistic Alignment of Low Aspect‐Ratio π‐Conjugated Molecules Enables Exceptional UV–vis–NIR Polarization Detection

Abstract Polarization detection enhances signal contrast and is widely utilized in diverse advanced applications. An ongoing challenge is the development of high‐performance polarization‐sensitive photodetectors based on optically anisotropic organic semiconductors, particularly in the near‐infrared (NIR) region. While uniaxially aligned π‐conjugated polymers with high aspect ratios exhibit strong linear dichroism and have shown promise, their limited NIR performance and heavy reliance on polymer material now represent critical limitations. Here, a breakthrough is reported in achieving giant linear dichroism and exceptional polarization detection with low aspect‐ratios (AR) non‐fullerene small‐molecule (NFSM) acceptors, extending polarization sensitivity from the UV–vis to the NIR range. An impressive dichroic ratio of 27.1 at 605 nm and 12.0 at 780 nm is demonstrated. The maximum polarization photocurrent ratio is 11.2 at 780 nm under parallel versus perpendicular polarized light. This unprecedented performance originates from synergistic molecular alignment, wherein NFSMs significantly enhance the uniaxial orientation of both the polymer matrix and the NFSMs themselves during self‐assembly and thermal annealing. Besides, such a linear‐polarization‐sensitive photodetectors (LPS‐PDs) are showcased in generating degree‐of‐linear‐polarization imaging. The work establishes NFSMs as a viable material system for next‐generation of organic LPS‐PDs and provides fundamental insights into structural origins of polarization sensitivity in low AR organic semiconductors.

Xue, Yingying↗

Aligned fields double copy to Kerr-NUT-(A)dS

We find Abelian gauge fields that double copy to a large class of black hole spacetimes with spherical horizon topology known as the Kerr-NUT-(A)dS family. Using a multi-Kerr-Schild prescription, we extend the previously-known double copy structure for arbitrarily rotating general dimension black holes, to include NUT charges and an arbitrary cosmological constant. In all cases, these single copy gauge fields are ‘aligned fields’, because their nonzero components align with the principal tensor which generates the Killing structure of the spacetime. In five dimensions, we additionally derive the same single-copy field strengths via the Weyl double copy procedure.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Aligned yet large dipoles: a SMEFT study

We study a non-universal flavor scenario at the level of the Standard Model Effective Field Theory, according to which the matrix of Wilson coefficients cuW of an up-type electroweak quark dipole operator is aligned with the up-type Yukawa coupling. Such an alignment usually follows from the assumption of Minimal Flavor Violation (MFV), away from which we step by allowing the entries of cuW to be sizable along the first quark generations. A particular example, which we refer to as “inverse hierarchy MFV”, features Wilson coefficients inversely proportional to quark masses, and arises from BSM models respecting MFV and containing heavy fields that replicate the mass hierarchy of SM quarks. We then analyze the phenomenology driven by cuW at colliders and at lower-energy flavor experiments. We show that precision measurements of the process pp → Wh → γγℓν at FCC-hh could set an upper bound on |cuW| ≲ O (10 -2 )(Λ/TeV) 2 , with Λ the cutoff of the effective field theory. This bound is an order of magnitude stronger than the existing LHC bounds. Moreover, we estimate that Wh → b$\overline{b}$ℓν at HL-LHC could also give competitive bounds. In the low-energy regime, we consider bounds arising from rare kaon decays, which turn out to be loose, |c$_{uW}^{11}$ | < O (1)(Λ/TeV) 2 . We finally demonstrate that our flavor and operator assumptions can be derived from a weakly-coupled UV model, which we choose to simultaneously illustrate the UV origin of inverse hierarchy MFV.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Vertically-aligned Mn(OH) 2 nanosheet films for flexible all-solid-state electrochemical supercapacitors

We report that the arrangement of the electrode materials is a significant contributor for constructing high performance supercapacitor. Here, vertically-aligned Mn(OH) 2 nanosheet thin films were synthesized by cathodic electrodeposition technique on flexible Au coated polyethylene terephthalate substrates. Morphologies, microstructures, chemical compositions and valence state of the nanosheet films were characterized systematically. It shows that the nanosheets arranged vertically to the substrate, forming a porous nanowall structures and creating large open framework, which greatly facilitate the adsorption or diffusion of electrolyte ions for faradaic redox reaction. Electrochemical tests of the films show the specific capacitance as high as 240.2 F g -1 at 1.0 A g -1 . The films were employed to assemble symmetric all-solid-state supercapacitors with LiCl/PVA gel severed as solid electrolyte. Finally, the solid devices exhibit high volumetric capacitance of 39.3 mF cm -3 at the current density 0.3 mA cm -3 with robust cycling stability. The superior performance is attributed to the vertically-aligned configuration.

36 MATERIALS SCIENCE↗

Nickel-Coated Super-Aligned Carbon Nanotube Reinforced Copper Composite for Improved Strength and Conductivity

Nickel (Ni)-coated super-aligned carbon nanotube (SACNT) films-reinforced copper (Cu) matrix composites were fabricated by electrodeposition. The microstructure, mechanical property and electrical conductivity of the prepared composites have been studied systematically. The results show that the mechanical properties of SACNT/Cu were significantly improved by coating SACNT with Ni. When the volume fraction of SACNT is 10.0%, the tensile strength and yield strength of the composite can reach 477.8 and 295.5 MPa, respectively, corresponding to 147 and 170% improvement compared to pure Cu prepared by the same method. Meanwhile, due to the super-aligned arrangement of SACNTs and the homogeneous distribution of Ni, which is not mixing or dissolving with Cu, the conductivities of all the Ni-coated SACNT-reinforced Cu composites are above 58% IACS, which is about 4 times higher than the results in previous research. The enhancement of the strength of the SACNT/Cu composites comes from the combined contribution of load transfer and grain refinement strengthening.

36 MATERIALS SCIENCE↗

Morphogenesis of aligned collagen fibers in the annulus fibrosus: Mammals versus avians

Highlights: • The cross-aligned collagen arrangement of the AF is created after the physical transition of the notochord to the NP. • Notochord is a passive element in the mouse and bulges due to the external forces. • Notochord acts as an active force-producing structure in chicken embryos. The mammalian intervertebral disc (IVD) consists of a gel-like, disordered nucleus pulposus (NP) surrounded by a highly ordered collagen structure, the annulus fibrosus (AF). While this concentric array of lamellae has been amply studied, its physical origin is poorly understood. The notochord is a rod-like organ located in the mid-line of the growing embryo and plays an essential role in IVD development. The aim of this study was to elucidate the effect of notochord development on the collagen fiber arrangement evolution in the AF. To that end, we studied IVD development in mouse embryos and compared these observations to those from chicken embryos, which do not form the typical laminar structure around the NP. In mouse, cross-aligned collagen arrangement of the AF forms from the sclerotome upon bulging of the notochord to become NP. By contrast, the notochord in the chicken embryo swells substantially without the physical restrictions of the future vertebrae and thus do not bulge. From these observations, we conclude that physical and geometrical constrictions are essential for the formation of the highly structured AF.

60 APPLIED LIFE SCIENCES↗

Aligned-SWCNT film laminated nanocomposites: Role of the film on mechanical and electrical properties

Here in this study, well-aligned single-walled carbon nanotube (SWCNT) films were utilized as lamellae to prepare a multifunctional nanocomposite by a feasible ‘layer-by-layer’ preparation method. This structural design can not only dramatically reduce the agglomeration effect of SWCNTs, but also achieve high in-plane stiffness. It was found that the well-aligned SWCNT films contribute to the high stress-transfer between CNTs and present good wettability with epoxy matrix, thereby improving the mechanical enhancement. Interestingly, this laminated structure possesses distinct electrical behaviors under different loading conditions. The electrical resistance linearly increases with the increase of in-plane tensile strain but is insensitive to bending. This work could provide in-depth understanding on the mechanical and electrical properties of CNT-based laminated nanocomposites.

36 MATERIALS SCIENCE↗

Twinning-mediated anomalous alignment of rutile films revealed by synchrotron X-ray nanodiffraction

Nanotwin structures in materials engender fascinating exotic properties. However, twinning usually alter the crystal orientation, resulting in random orientation and limited performances. Here, we report a well-aligned rutile TiO 2 nanotwin film with superior preferential orientation than its isostructural substrate. By means of the synchrotron X-ray Laue nanodiffraction technique, the crystal orientation, twin boundaries, and deviatoric stresses of the film were quantitatively imaged at unprecedented spatial resolution to unravel the underlying mechanism of this anomalous alignment. Massive {101}-type rutile nanotwins were observed, and a crystallographic relationship of the heteroepitaxy was proposed. The rapid twinning and twin-controlled heteroepitaxy are responsible for the texture improvement. This work would open up opportunities for rational design of better twin-based functional materials, and implies the powerful capabilities of X-ray nanodiffraction technique for multidisciplinary applications.

36 MATERIALS SCIENCE↗

Well-aligned polycrystalline lanthanum silicate oxyapatite grown by reactive diffusion between solid La{sub 2}SiO{sub 5} and gases [SiO+1/2O{sub 2}]

The c-axis-oriented polycrystalline lanthanum silicate oxyapatite, La{sub 9.48}(Si{sub 5.89}□{sub 0.11})O{sub 26} (□ denotes a vacancy in the Si site), was successfully prepared by the reactive diffusion between randomly grain-oriented La{sub 2}SiO{sub 5} polycrystal and [SiO+1/2O{sub 2}] gases at 1873 K in Ar atmosphere. The polycrystal was characterized using optical microscopy, scanning electron microscopy equipped with energy dispersive X-ray spectroscopy, micro-Raman spectroscopy, X-ray diffractometry, and impedance spectroscopy. The crystal structure (space group P6{sub 3}/m) showed the deficiency of Si site at ca. 1.9%. The bulk oxide-ion conductivity along the grain-alignment direction steadily increased from 9.2 × 10{sup −3} to 1.17 × 10{sup −2} S/cm with increasing temperature from 923 to 1073 K. The activation energy of conduction was 0.23(2) eV. - Graphical abstract: We have successfully prepared the highly c-axis-oriented polycrystalline La{sub 9.48}(Si{sub 5.89}□{sub 0.11})O{sub 26} by the reactive diffusion between randomly grain-oriented La{sub 2}SiO{sub 5} polycrystal and [SiO + 1/2O{sub 2}] gases at 1873 K in Ar atmosphere. The crystal structure (space group P6{sub 3}/m) showed the deficiency of Si site of ca. 1.9%. - Highlights: • The c-axis-oriented polycrystalline La{sub 9.48}(Si{sub 5.89}□{sub 0.11})O{sub 26} is successfully prepared. • Crystal structure of La{sub 9.48}(Si{sub 5.89}□{sub 0.11})O{sub 26} is determined by single-crystal XRD. • The polycrystal shows relatively high oxide ion conductivity along the common c-axis. • Reactive diffusion is successfully used for the preparation of grain-aligned ceramics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Prolate-to-oblate transition and backbending along the yrast line induced by quasiparticle alignment

The yrast lines in Kr isotopes with N = 42, 44, and 46 are investigated in a beyond mean field framework with both prolate-oblate coexistence and quasiparticle alignment taken into account. Quasiparticle orbitals with high-j and low-Ω on the oblate side are shown to be responsible for the sharp backbending observed in 82Kr, by driving the yrast shape from prolate to oblate. This suggests that quasiparticle alignment may not be neglected in the investigation of the shape evolution along the yrast line.

79 ASTRONOMY AND ASTROPHYSICS↗

Impact of globally spin-aligned vector mesons on the search for the chiral magnetic effect in heavy-ion collisions

In high-energy heavy-ion collisions, the chiral magnetic effect (CME) is predicted to arise from the interplay between the chirality imbalance of quarks in the nuclear medium and the intense magnetic field, and will cause a charge separation along the magnetic field direction. While the search for the CME is still ongoing in experiments at Relativistic Heavy Ion Collider (RHIC) and the Large Hadron Collider (LHC), the CME-sensitive observables need to be scrutinized to exclude the non-CME contributions. In this work, we examine the influence of globally spin-aligned ρ mesons on the γ 112 correlator, the R Ψ 2 (ΔS) correlator, and the signed balance functions, via a toy model and a multiphase transport model (AMPT). The global spin alignment of vector mesons could originate from non-CME mechanisms in heavy-ion collisions, and is characterized by the 00-component of the spin density matrix, ρ 00 . Here, we find that the CME observables show similar dependence on ρ 00 , and could receive a positive (negative) contribution from ρ-decay pions, if the ρ 00 of ρ mesons is larger (smaller) than 1/3. Since pions are the most abundant particles in such collisions, the ρ 00 measurements for ρ mesons become crucial to the interpretation of the CME data.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗