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NASA NTRS1979

Possible effects of volcanic eruptions on stratospheric minor constituent chemistry

Although stratosphere penetrating volcanic eruptions have been infrequent during the last half century, periods have existed in the last several hundred years when such eruptions were significantly more frequent. Several mechanisms exist for these injections to affect stratospheric minor constituent chemistry, both on the long-term average and for short-term perturbations. These mechanisms are reviewed and, because of the sensitivity of current models of stratospheric ozone to chlorine perturbations, quantitative estimates are made of chlorine injection rates. It is found that, if chlorine makes up as much as 0.5 to 1% of the gases released and if the total gases released are about the same magnitude as the fine ash, then a major stratosphere penetrating eruption could deplete the ozone column by several percent. The estimate for the Agung eruption of 1963 is just under 1% an amount not excluded by the ozone record but complicated by the peak in atmospheric nuclear explosions at about the same time.

Stolarski, R. S.↗

NASA NTRS1979

Dynamics of volcanic plumes on Io

Ballistic and aerodynamic models are proposed to explain the dynamics of the volcanic plumes on Io. A ballistic model, which assumes that eruptive gas and solid-particle flows become completely and permanently decoupled over a small distance as compared with the maximum particle height, is shown to be unable to account for the observed shape of Plume 3. An aerodynamic model which assumes the entrainment and transportation of solid particles by the gas flow into the central portion of the top of the plume, with ballistic particle trajectories only after passage through the first part of their descent, is then developed. The model accounts for plume shape by the formation of a weak decompression shock near the edge of the plume stalk, which constrains horizontal expansion until a sufficient altitude is reached. Calculated plume dimensions are then compared with observations of Ionian Plumes 1 and 3.

Cook, A. F.↗

NASA NTRS1980

Volcanic features of Hawaii. A basis for comparison with Mars

Despite the difference in size Martian and Hawaiian volcanoes have numerous characteristics in common. Specific features such as lava channels, collapsed lava tubes, levees and flow fronts, all very common in Hawaii, are also abundant on the flanks of some of the Martian volcanoes. Striking differences also exist, such as the apparent lack of radial rift zones on some Martian volcanoes and the paucity of cinder and spatter cones. Some of the best photographs of Martian and Hawaiian volcanic features are presented. Descriptive legends are provided for each picture. An overview of the geological processes and structures depicted is included.

Carr, M. H.↗

NASA NTRS1979

Sulfur and halogen chemistry of the stratosphere and of volcanic eruption plumes

The major eruption of Volcan de Fuego caused an enhancement of 1.6 x 10 to the 9 kg of SO4(-) in the stratosphere 6 months after the eruption. Measurable changes in nitric acid vapor and particulate chloride were not observed. Subsequent data suggests that HCl was not injected into the stratosphere. The first simultaneous measurement of halogen and sulfur content of gases and particles in explosive eruption plumes is reported. The average percents of elements in particles were sulfur, 2.5 + or - 2.1; chlorine, 18 + or - 12; and fluorine, 38 + or - 29. The average molecular ratio of HCl/SO2 and HCl/HF were 0.41 + or - 0.26 and 14 + or - 12 in the Guatemalan eruption plumes.

Lazrus, A. L.↗

NASA NTRS1979

Scanning Auger Microprobe and atomic absorption studies of lunar volcanic volatiles

Results on lunar volatile transport processes have been obtained by studying green and brown glass droplets, orange and black core tube samples and the surface sample 74241 with the Scanning Auger Microprobe (SAM) and by Flameless Atomic Absorption Analysis (FLAA). SAM analyses show that the most dominant volatiles in the top few atomic layers of droplets are Zn and S, confirming that the surface Zn and S are good indicators of pyroclastic origin, and they are not entirely present as ZnS. In addition, FLAA thermal release profiles show that almost all the Zn and Cd are on grain surfaces, indicating that Zn and Cd were completely outgassed from lava fountain products during the volcanic eruption, were recondensed during or after the eruptions, and are thus present as surface coating.

Cirlin, E. H.↗

NASA NTRS1979

Evidence for ancient mare volcanism

The results of the present study suggest that dark-haloed impact craters are indicative of excavated mafic materials, originally emplaced as volcanic units, but subsequently buried by impact ejecta deposits from large craters and basins. Consequently, mapped light plains units should be viewed as soil units that may not reflect the origin of the underlying rock. Some observations which support these conclusions are examined.

Schultz, P. H.↗

NASA NTRS1980

An airborne system for detection of volcanic surface deformations

A technique is proposed for measuring volcanic deformation on the order of centimeters per day to centimeters per year. An airborne multifrequency pulsed radar, tracking passive ground reflectors spaced at 1 kilometer intervals over a 50 square kilometer area is employed. Identification of targets is accomplished by Doppler and range resolution techniques, with final relative position measurements accomplished by phase comparison of multifrequency signals. Atmospheric path length errors are corrected by an airborne refractometer, meteorological instruments, or other refractive index measuring devices. Anticipated system accuracy is 1-2 cm, with measuring times on the order of minutes. Potential problems exist in the high intrinsic data assimilation rate required of the system to overcome ground backscatter noise.

Lunine, J.↗

NASA NTRS1981

An investigation of vegetation and other Earth resource/feature parameters using LANDSAT and other remote sensing data. 1: LANDSAT. 2: Remote sensing of volcanic emissions

A fanning technique based on a simplistic physical model provided a classification algorithm for mixture landscapes. Results of applications to LANDSAT inventory of 1.5 million acres of forest land in Northern Maine are presented. Signatures for potential deer year habitat in New Hampshire were developed. Volcanic activity was monitored in Nicaragua, El Salvador, and Guatemala along with the Mt. St. Helens eruption. Emphasis in the monitoring was placed on the remote sensing of SO2 concentrations in the plumes of the volcanoes.

Birnie, R. W.↗

NASA NTRS1980

Diffusion in the lower stratosphere as determined from lidar measurements of volcanic aerosol dispersion

Lidar measurements of the stratospheric aerosol layer from the Fuego volcanic eruption in 1974 are analyzed to yield estimates of effective vertical mixing coefficients K(z). The data at 19 deg N latitude give K(z) = 6.6 x 10 to the 2nd sq cm/sec for the altitude range of 19 + or - 1.5 km, while the data at 37 deg N yield K(z) = 13 x 10 to the 2nd sq cm/sec for 19 + or - 3.5 km. The variability in these values is about a factor of 2. These derived K(z) values are interpreted as being due mainly to diffusion.

Remsberg, E. E.↗

NASA NTRS1980

Io - Energy constraints and plume volcanism

Observational and theoretical considerations, including near-surface energy constraints, suggest a model of Io that features a surface layer of sulfur overlying an active silicate crust. Such a model would imply frequent contact between silicate magma intrusions and the sulfur layer. This contact could produce volcanic plumes driven by high-temperature sulfur vapor. Plumes driven by sulfur vapor meet observational constraints for a wide range of possible conditions, in contrast to the special conditions required for plume generation by SO2. Characteristics of the two models are compared, and it is suggested that high-spatial-resolution infrared radiometry could identify the driving volatile.

Reynolds, R. T.↗

NASA NTRS1981

The Tempe volcanic province of Mars and comparisons with the Snake River Plains of Idaho

The Tempe volcanic region of Mars, a relatively low plain of probable basaltic flood lava affinity, is shown to be comparable in many respects to features of the Snake River Plains of Idaho, including both scale and type of features observed. Superimposed upon the Tempe plain are a variety of features that appear structurally controlled, along an orientation of N60 deg E; comprising low shields, irregular hills that may be silicic domes, and possible composite cones. The Tempe/Snake River match is held to be the first in which direct comparison can be made between Martian and terrestrial geologic-geomorphic features without encountering problems of scale.

Plescia, J. B.↗

NASA NTRS1981

Ar-40-Ar-39 and Rb-Sr age determinations on Quaternary volcanic rocks

Ages of leucite and biotite separates from samples of the potassic volcanics of the Roman Comagmatic region are derived by the stepwise degassing variant of the Ar-39-Ar-40 dating method and compared with those derived from Rb-Sr dating in order to evaluate the abilities of the methods to date Quaternary geological events. Six of the leucite separates are found to contain Ar with very high bulk 40/36 ratios and to have well correlated Ar-40 and Ar-39 contents, yielding ages of approximately 338,000 years. Two leucites observed to contain Ar with lower bulk 40/36 ratios and Ar-40/Ar-36 ratios significantly lower than atmospheric are found to have ages in substantial agreement with those of the other leucites despite the uncertainty in the composition of the trapped component. Ages obtained for the biotites are not as precise as those of the leucites, due to difficulties in obtaining a good separation of in situ radiogenic Ar-40 from trapped Ar-40. Ages determined from Rb-Sr measurements for selected tuff samples are found to be in good agreement with the Ar-40-Ar-39 ages of the leucites. Results demonstrate the possibility of attaining precisions of better than 5% in the dating of rocks 350,000 years old by both the Ar-40-Ar-39 and the Rb-Sr methods.

Radicati Di Brozolo, F.↗

NASA NTRS1981

Spatial color variations in the volcanic plume at Loki, on Io

Multicolor Voyager 1 photographs of the Loki volcanic plume, on Io, have been analyzed to determine the nature and quantity of the scattering material within the plume. This work indicates that there are two particle populations. The first population consists of particles with radius of 0.001-0.01 microns, while the second population, which is concentrated near the source, comprises particles with radius greater than 1 micron. The population of smaller particles includes most of the particulate mass in the plume. This work increases the previously estimated particulate mass (Johnson et al., 1979) and suggests that the SO2 gas spectroscopically identified by Pearl et al. (1979) may represent transient flow from the volcano instead of an atmosphere in stable equilibrium with the local surface.

Collins, S. A.↗

NASA NTRS1982

Late Cenozoic alkaline volcanism in the northwestern Caribbean - Tectonic setting and Sr isotopic characteristics

The northwestern corner of the Caribbean plate has at least sixteen centers of alkalic volcanism, most of which is Quaternary in age. Sr-87/Sr-86 ratios of the rocks in these centers are used to distinguish three geographical groups: a low-ratio group (0.7026-0.7031) at the Nicaraguan Rise, an intermediate-ratio group (0.7036-0.7038) in northeastern Costa Rica, and a high-ratio group (0.7047-0.7063) in Hispaniola. It is suggested that the increased radiogenic strontium in both Costa Rica and Hispaniola may have come from volatile-rich fluids escaping from adjacent subducting slabs of oceanic crust. The isotopic differences between the two areas is explained by the relative longevity and high rate of subduction in Costa Rica compared to that in Hispaniola. The Costa Rican alkaline rocks cover a segment of the Cocos plate which is being subducted at a smaller angle (about 35 deg) than at the rest of the Central American arc.

Wadge, G.↗

NASA NTRS1982

Remote sensing studies of lunar dark-halo impact craters - Preliminary results and implications for early volcanism

A summary of the nature and origin of lunar dark-halo craters is presented. New remote sensing data for dark-haloed impact craters were obtained and interpreted. A variety of spectral, thermal, radar, and photogeologic data are presented which confirm the hypothesis that Copernicus H crater excavated mare basalt from beneath lighter deposits emplaced by the Copernicus impact event. Multispectral imagery suggests that analogous impact re-exposure of basaltic material on the ejecta blankets of other large Copernican and Eratosthenian craters resulted in the formation of other dark-halo craters. Preliminary analyses of near-infrared spectra of dark-haloed impact craters in the Schickard-Schiller region are consistent with the hypothesis that basaltic material was excavated from beneath light plains. These light plains may have been emplaced as a result of the Orientale impact event. Additional evidence is presented which suggests that both pre- and post-Orientale volcanic activity was more prevalent in this region than has previously been recognized.

Hawke, B. R.↗

NASA NTRS1982

An Io thermal model with intermittent volcanism

Observations have indicated that heat flow out of Io at present may be several times greater than the heat input from enhanced tidal heating; this may indicate that the observed heat flow is intermittent, rather than continuous. A two-dimensional time-dependent thermal model of Io was constructed to examine the relationship between enhanced tidal heating, heat flow within the body, and surface volcanism. From the models one can conclude that (1) a simple homogeneous body cannot maintain enhanced tidal heating in a thin crust, but such heating is possible if the crust contains an insulating layer, as of sulfur; (2) this sulfur layer will be subject to melting by heat from the interior, resulting in hotspots which can expel heat much more rapidly than tidal heating inputs it; and (3) the location of these hotspots will vary in time and space; they can appear anywhere on the surface, even if tidal heating is concentrated at the poles, and they seem to occur roughly 10% of the time.

Consolmagno, G. J.↗

NASA NTRS1982

A model study of Fuego volcanic aerosol dispersion in the lower stratosphere

A zonally averaged time-dependent primitive equation model is used to simulate the dispersion of both a carbon 14 injection and the volcanic aerosol from the 1974 Fuego eruption. It is noted that both injections occurred at low latitudes to midlatitudes in the Northern Hemisphere. The eddy flux terms, which account for the major portion of the transport in the lower stratosphere of this model, are specified in a manner similar to that of Harwood and Pyle (1975). Comparisons with data underline the ability of the model to simulate the vertical character of the tracer while maintaining reasonable meridional transport times. For the aerosol study, the simulated 1/e decay time at 37 deg N and for the 16- to 21-km altitude region is 9 months, whereas lidar measurements at the same latitude give a decay time of 8 months. The simulated vertical width at half-maximum for the aerosol tracer at 37 deg N and 19 deg N and for 6 months after the event possesses values of 5.0 km and 3.6 km, respectively, whereas the observed lidar values are 4.4 km and 3.0 km, respectively. The tracer transport to the Southern Hemisphere also is in qualitative agreement with the limited data that are available.

Remsberg, E. E.↗

NASA NTRS1982

SAGE measurements of Mount St. Helens volcanic aerosols

The SAGE satellite system was used to make measurements on the optical extinction produced by stratospheric aerosols from the Mount St. Helens eruption. Two periods of observation were analyzed. In the first period (May 21 to 31, 1980), SAGE moved southward from latitude 60 N, and crossed the United States approximately one week after the May 18th eruption. Enhancements in stratospheric extinction were confined to latitudes between about 55 N and 25 N and longitudes between 10 W and 140 W. Individual layers were observed up to altitudes of 23 km. The geographical location of these layers corresponded closely to that expected on the basis of high-altitude meteorological data. During June and much of July, SAGE was, by reason of its geographical position and other orbital characteristics, unable to make further measurements on the northern hemisphere. Between July 19th and August 12th a second southward pass over the northern hemisphere occurred and further observations were made. The volcanic aerosol in the stratosphere was now found to be widely distributed over the hemisphere, the maximum concentrations being north of 50 N. The aerosol showed considerable inhomogeneity and had reached as far south as 15 N but little, if any, had crossed the equator into the southern hemisphere. Individual layers at different heights were still distinguishable. The total stratospheric aerosol loading on this occasion appeared to be greater than in May and corresponded to an increase in global stratospheric mass of between 50 and 100 percent.

Kent, G. S.↗