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NASA NTRS2002

Observations of the Non-Thermal X-ray Emission from the Galactic Supernova Remnant G347.3-0.5

G347.3-0.5 (ALEX J1713.7-3946) is a member of the new class of shell-type Galactic supernova remnants (SNRs) that feature non-thermal components to their X-ray emission. We have analyzed the X-ray spectrum of this SNR over a broad energy range (0.5 to 30 key) using archived data from observations made with two satellites, the R6ntgensatellit (ROSA I) and the Advanced Satellite for Cosmology and Astrophysics (ASCA), along with data from our own observations made with the Rossi X-ray Timing Explorer (RXTE) Using a combination of the models EQUIL and SRCUT to fit thermal and non-thermal emission, respectively, from this SNR, we find evidence for a modest thermal component to G347.30.5's diffuse emission with a corresponding energy of kT approx. = 1.4 key. We also obtain an estimate of 70 Texas for the maximum energy of the cosmic-ray electrons that, have been accelerated by this SNR.

Pannuti, Thomas G.↗

NASA NTRS2002

Wave-Particle Interactions Associated with Nongyrotropic Distribution Functions: A Hybrid Simulation Study

Nongyrotropic plasma distribution functions can be formed in regions of space where guiding center motion breaks down as a result of strongly curved and weak ambient magnetic fields. Such are the conditions near the current sheet in the Earth's middle and distant magnetotail, where observations of nongyrotropic ion distributions have been made. Here a systematic parameter study of nongyrotropic proton distributions using electromagnetic hybrid simulations is made. We model the observed nongyrotropic distributions by removing a number of arc length segments from a cold ring distribution and find significant differences with the results of simulations that initially have a gyrotropic ring distribution. Model nongyrotropic distributions with initially small perpendicular thermalization produce growing fluctuations that diffuse the ions into a stable Maxwellian-like distribution within a few proton gyro periods. The growing waves produced by nongyrotropic distributions are similar to the electromagnetic proton cyclotron waves produced by a gyrotropic proton ring distribution in that they propagate parallel to the background magnetic field and occur at frequencies on the order of the proton gyrofrequency, The maximum energy of the fluctuating magnetic field increases as the initial proton distribution is made more nongyrotropic, that is, more highly bunched in perpendicular velocity space. This increase can be as much as twice the energy produced in the gyrotropic case.

Convery, P. D.↗

NASA NTRS2003

Atomic-scale Modeling of the Structure and Dynamics of Dislocations in Complex Alloys at High Temperatures

We report on the progress made during the first year of the project. Most of the progress at this point has been on the theoretical and computational side. Here are the highlights: (1) A new code, tailored for high-end desktop computing, now combines modern Accelerated Dynamics (AD) with the well-tested Embedded Atom Method (EAM); (2) The new Accelerated Dynamics allows the study of relatively slow, thermally-activated processes, such as diffusion, which are much too slow for traditional Molecular Dynamics; (3) We have benchmarked the new AD code on a rather simple and well-known process: vacancy diffusion in copper; and (4) We have begun application of the AD code to the diffusion of vacancies in ordered intermetallics.

Daw, Murray S.↗

NASA NTRS1987

Amorphous-Metal-Film Diffusion Barriers

Incorporation of N into Ni/W films reduces reactivity with Si substrate. Paper describes reactions between Si substrates and deposited amorphous Ni/W or Ni/N/W films. Thermal stability of amorphous Ni/W films as diffusion barriers in Si markedly improved by introduction of N into Ni/W films during deposition.

Nicolet, M. A.↗

NASA NTRS1985

Energy balance constraints on gravity wave induced eddy diffusion in the mesosphere and lower thermosphere

The constraints on turbulence improved by the mesospheric heat budget are reexamined, and the sufficiency of the theoretical evidence to support the hypothesis that the eddy Prandtl number is greater than one in the mesosphere is considered. The mesopause thermal structure is calculated with turbulent diffusion coefficients commonly used in chemical models and deduced from mean zonal wind deceleration. It is shown that extreme mesopause temperatures of less than 100 K are produced by the large net cooling. The results demonstrate the importance of the Prandtl number for mesospheric turbulence.

Strobel, D. F.↗

NASA NTRS1990

A highly durable injector faceplate design concept for O2/H2 propellants

Two different O2/H2 injector faceplate designs were used in a test bed rocket engine at the NASA Lewis Research Center facility. This test bed was operated in a pulsing mode to evaluate thrust chamber wall materials and coatings. Degradation of the sintered mesh injector face plates resulted in the substitution of a photoetched diffusion-bonded platelet faceplate. This faceplate accumulated over 4200 thermal cycles without damage or degradation. Prior testing for a total of 17,446 cycles required 19 sintered mesh faceplates. This average of 918 cycles per unit showed the diffusion bonded faceplate to have a thermal cycle capability ranging from 150 to 500 percent of that of the sintered wire unit. The test data also showed that the diffusion-bonded faceplate provided a more uniform flow of gaseous H2 through its discrete and uniformly spaced propellant orifices resulting in enhanced face cooling (no local hot spots) and increased performance. The injector faceplate designs are described and the results of the injector comparison test data are presented.

Mueggenburg, H. H.↗

NASA NTRS1993

Convective Effects During the Physical Vapor Transport Process. II - Thermosolutal Convection

The effect of an inert gas on the diffusive-convective physical vapor transport process is investigated for the case when the temperature gradient is stabilizing, and the concentration gradient destabilizing, for a wide parametric range. When an inert gas is present, the thermal and solutal convection oppose each other. The solutal field is destabilizing while the thermal field and the advective-diffusive flux stabilize the flow field. When the pressure of the inert component is increased, the stabilizing effect of the advective-diffusive flux is decreased; thus, convection becomes more vigorous. The nonlinear dynamics of the flow field here show a transition from quasi-periodic to chaotic state. When both stabilizing mechanisms are present, the flow field shows a transition to a steady state. Toward steady state, growth and amalgamation of rolls occur, which result in an overturning motion. This leads to a superposed flow consisting of one roll and a unidirectional flow. However, when the pressure is increased, the advective-diffusive stability mechanism is decreased. and oscillations of the flow field occur. The low gravity environment is effective at eliminating oscillatory behavior of the flow field and results in uniform temperature and concentration gradients.

Duval, Walter M. B.↗

NASA NTRS1994

Convection in the Physical Vapor Transport Process: Thermosolutal - Part 2

We consider the effect of an inert gas on the diffusive-convective physical vapor transport process. We investigate the case when the temperature gradient is stabilizing and the concentration gradient is destabilizing for a wide parametric range. When an inert gas is present, the thermal and solutal convection oppose each other. The solutal field is destabilizing while the thermal field and the advective-diffusive flux stabilize the flow field. When the pressure of the inert component is increased, the stabilizing effect of the advective-diffusive flux is decreased. The intensity of convection as well as the oscillatory transient time increases. Below, the critical Rayleigh number, the nonlinear dynamics of the flow field show an oscillatory approach to steady state. For parametric values in the neighborhood of the critical Rayleigh number, the flow field undergoes a chaotic transient which settles to a periodic state. The asymptotic state of the flow field shows that growth and amalgamation of cells yields an overturning motion which results in an asymmetric cellular structure. The low gravity environment yields the stabilizing advective-diffusive flow which results in uniform temperature and concentration gradients near the crystal interface.

Duval, Walter M. B.↗

NASA NTRS2008

The Lattice and Thermal Radiation Conductivity of Thermal Barrier Coatings

The lattice and radiation conductivity of thermal barrier coatings was evaluated using a laser heat flux approach. A diffusion model has been established to correlate the apparent thermal conductivity of the coating to the lattice and radiation conductivity. The radiation conductivity component can be expressed as a function of temperature and the scattering and absorption properties of the coating material. High temperature scattering and absorption of the coating systems can also be derived based on the testing results using the modeling approach. The model prediction is found to have good agreement with experimental observations.

Zhu, Dongming↗

NASA NTRS1997

High Temperature Degradation Mechanisms in Polymer Matrix Composites

Polymer matrix composites are increasingly used in demanding structural applications in which they may be exposed to harsh environments. The durability of such materials is a major concern, potentially limiting both the integrity of the structures and their useful lifetimes. The goal of the current investigation is to develop a mechanism-based model of the chemical degradation which occurs, such that given the external chemical environment and temperatures throughout the laminate, laminate geometry, and ply and/or constituent material properties, we can calculate the concentration of diffusing substances and extent of chemical degradation as functions of time and position throughout the laminate. This objective is met through the development and use of analytical models, coupled to an analysis-driven experimental program which offers both quantitative and qualitative information on the degradation mechanism. Preliminary analyses using coupled diffusion/reaction model are used to gain insight into the physics of the degradation mechanisms and to identify crucial material parameters. An experimental program is defined based on the results of the preliminary analysis which allows the determination of the necessary material coefficients. Thermogravimetric analyses are carried out in nitrogen, air, and oxygen to provide quantitative information on thermal and oxidative reactions. Powdered samples are used to eliminate diffusion effects. Tests in both inert and oxidative environments allow the separation of thermal and oxidative contributions to specimen mass loss. The concentration dependency of the oxidative reactions is determined from the tests in pure oxygen. Short term isothermal tests at different temperatures are carried out on neat resin and unidirectional macroscopic specimens to identify diffusion effects. Mass loss, specimen shrinkage, the formation of degraded surface layers and surface cracking are recorded as functions of exposure time. Geometry effects in the neat resin, and anisotropic diffusion effects in the composites, are identified through the use of specimens with different aspect ratios. The data is used with the model to determine reaction coefficients and effective diffusion coefficients. The empirical and analytical correlations confirm the preliminary model results which suggest that mass loss at lower temperatures is dominated by oxidative reactions and that these reaction are limited by diffusion of oxygen from the surface. The mechanism-based model is able to successfully capture the basic physics of the degradation phenomena under a wide range of test conditions. The analysis-based test design is successful in separating out oxidative, thermal, and diffusion effects to allow the determination of material coefficients. This success confirms the basic picture of the process; however, a more complete understanding of some aspects of the physics are required before truly predictive capability can be achieved.

Cunningham, Ronan A.↗

NASA NTRS1996

High Temperature Degradation Mechanisms in Polymer Matrix Composites

Polymer matrix composites are increasingly used in demanding structural applications in which they may be exposed to harsh environments. The durability of such materials is a major concern, potentially limiting both the integrity of the structures and their useful lifetimes. The goal of the current investigation is to develop a mechanism-based model of the chemical degradation which occurs, such that given the external chemical environment and temperatures throughout the laminate, laminate geometry, and ply and/or constituent material properties, we can calculate the concentration of diffusing substances and extent of chemical degradation as functions of time and position throughout the laminate. This objective is met through the development and use of analytical models, coupled to an analysis-driven experimental program which offers both quantitative and qualitative information on the degradation mechanism. Preliminary analyses using a coupled diffusion/reaction model are used to gain insight into the physics of the degradation mechanisms and to identify crucial material parameters. An experimental program is defined based on the results of the preliminary analysis which allows the determination of the necessary material coefficients. Thermogravimetric analyses are carried out in nitrogen, air, and oxygen to provide quantitative information on thermal and oxidative reactions. Powdered samples are used to eliminate diffusion effects. Tests in both inert and oxidative environments allow the separation of thermal and oxidative contributions to specimen mass loss. The concentration dependency of the oxidative reactions is determined from the tests in pure oxygen. Short term isothermal tests at different temperatures are carried out on neat resin and unidirectional macroscopic specimens to identify diffusion effects. Mass loss, specimen shrinkage, the formation of degraded surface layers and surface cracking are recorded as functions of exposure time. Geometry effects in the neat resin, and anisotropic diffusion effects in the composites, are identified through the use of specimens with different aspect ratios. The data is used with the model to determine reaction coefficients and effective diffusion coefficients. The empirical and analytical correlations confirm the preliminary model results which suggest that mass loss at lower temperatures is dominated by oxidative reactions and that these reaction are limited by diffusion of oxygen from the surface. The mechanism-based model is able to successfully capture the basic physics of the degradation phenomena under a wide range of test conditions. The analysis-based test design is successful in separating out oxidative, thermal, and diffusion effects to allow the determination of material coefficients. This success confirms the basic picture of the process; however, a more complete understanding of some aspects of the physics are required before truly predictive capability can be achieved.

Cunningham, Ronan A.↗

NASA NTRS1993

Effects of thermal-solutal convection on temperature and solutal fields under various gravitational orientations

Semiconductor crystals such as Hg(1-x)CD(x)Te grown by unidirectional solidification Bridgmann method have shown compositional segregations in both the axial and radial directions. Due to the wide separation between the liquidus and the solidus of its pseudobinary phase diagram, there is a diffusion layer of higher HgTe content built up in the melt near the melt-solid interface which gives a solute concentration gradient in the axial direction. The value of effective diffusion coefficient calculated from fitting of the data to 1D model varies with Hg(1-x)Cd(x)Te growth conditions. This indicates that the growth condition of the Hg(1-x)Cd(x)Te is not purely diffusion controlled. Because of the higher thermal conductivity in the melt than that in the crystal in the growth system, there is a thermal leakage through the fused silica crucible wall near the melt-solid interface. This gives a thermal gradient in the radial direction. Hart, and Thorpe, Hutt and Soulsby have shown that under such conditon a fluid will become convectively unstable as a result of different diffusitivities of temperature and solute. It is quite important to understand the effects of this thermosolute convection on the compositonal segregation in both axial and radial directions in the unidirectionally solidified crystals under various gravitational directions. To reach this goal, we start with a simplified problem to study the effects of thermal-solutal convection on the temperature and solutal fields under various gravitional orientations. We begin by reviewing model governing equations.

Wang, Jai-Ching↗

NASA NTRS1983

The problem of cooling the cold Io torus

Two models are developed for the transport of ions inward from Io's orbit, the first using the assumption that radial diffusion is the dominant transport mechanism while the second uses a combination of diffusive and convective transport. The models include thermal and number density transport, radiation, ionization and pickup of local neutrals, recombination, charge exchange, and Coulomb interactions. It is found that pure diffusive transport can account for the dramatic inward depletion of the torus only by invoking recombination or by postulating a massive increase in the production rate of torus ions sometime prior to the Voyager mission. Recombination is determined to be far too slow to be the cause of the observed density decrease inside of Io. The model combining convection and diffusion is shown to reasonably match the data, but only if a diffusion coefficient 100 times less than that derived from Pioneer observations is used. In addition, it is shown that the Pioneer derived diffusion rate combined with Voyager temperature and density measurements indicate a large nonradiative sink of energy in the inner torus.

Richardson, J. D.↗

NASA NTRS2010

The Lattice and Thermal Radiation Conductivity of Thermal Barrier Coatings: Models and Experiments

The lattice and radiation conductivity of ZrO2-Y2O3 thermal barrier coatings was evaluated using a laser heat flux approach. A diffusion model has been established to correlate the coating apparent thermal conductivity to the lattice and radiation conductivity. The radiation conductivity component can be expressed as a function of temperature, coating material scattering, and absorption properties. High temperature scattering and absorption of the coating systems can be also derived based on the testing results using the modeling approach. A comparison has been made for the gray and nongray coating models in the plasma-sprayed thermal barrier coatings. The model prediction is found to have a good agreement with experimental observations.

Zhu, Dongming↗

NASA NTRS1973

Surface segregation in titanium as monitored by Auger electron spectroscopy

Investigation of the surface diffusion and segregation of bulk impurities in titanium single crystals under well-defined and controlled experimental conditions. It is shown that an atomically clean titanium single-crystal surface can be obtained by argon ion bombardment within the temperature range from 700 to 800 C. It is demonstrated by Auger electron spectroscopy that, if such clean surfaces are subjected to thermal treatment, bulk impurities, especially sulfur, diffuse out to the crystal surface, and that the rate of surface segregation increases with increasing temperature.

Khan, I. H.↗

NASA NTRS1995

The neutral atomic phases of the interstellar medium

We calculate the thermal equilibrium gas temperature of the diffuse interstellar medium. Our method incorporates a new photoelectric heating rate from small grains and polycyclic aromatic hydrocarbons (PAHs) that accounts for a size distribution of particles extending from 100 to 3 A radius. We also include a detailed treatment of the ionization rates and heating due to the soft X-ray background and due to cosmic rays. Phase diagrams (thermal pressure P versus hydrogen density n) are presented for gas that is illuminated by local interstellar far-ultraviolet (FUV) and X-ray radiation fields. A stable two-phase medium is produced with thermal pressure in the range P/k approximately = to 10(exp 3-4) K/cc. We demonstrate that photoelectric heating from PAHs dominates in the warm neutral phase (WNM) and cold neutral phase (CNM). If the C II (158 micrometers cooling per hydrogen nucleus in the solar neighborhood represents an average value for the Galaxy, we predict L(sub CII) approximately = to 7 x 10(exp 7) solar luminosities from the CNM in the Galaxy, comparable to that observed by the Cosmic Background Explorer (COBE). We discuss the dependence of the results on absorbing column density, gas phase abundances, dust abundances and metallicity, FUV field, and the X-ray radiation field. These results will be useful in modeling the multiphase structure of high-velocity clouds in the halo, the interstellar matter (ISM) at other galactocentric radii, and the ISM in external galaxies and galactic nuclei.

Wolfire, M. G.↗

NASA NTRS1999

Diffusion Flame Tip Instabilities of a Wide Sample in Microgravity

This work is a study of diffusion flame tip instabilities of a wide thermally thin sample in a microgravity environment. The purpose of this work is to determine the thermodiffusive and hydrodynamic instability mechanisms which cause a spreading diffusion flame to become corrugated and later fragment into smaller separate flames that we call flamelets. These thermodiffusive and hydrodynamic mechanisms are prominent forces in the near limit because buoyancy is quashed in the microgravity environment. A fundamental knowledge of the underlying mechanisms controlling the extinction limit of a diffusion flame can be applied to any real world device involving a spreading diffusion flame as well as fire safety applications on earth and in space. Our work, which combines microgravity experiments, theoretical models, and numerical computation, is a joint effort between NASA and Michigan State University. Experiments in the 2.2 second drop tower at NASA Lewis Research Center in the Microgravity Combustion Branch have been a preliminary step in locating a region where these instabilities are prevalent. These positive results will be discussed as well as the second phase of our project and future plans and recommendations.

Oravecz, Lisa↗

NASA NTRS1978

Some effects of ablation on transport properties in the Jovian atmosphere

In this paper the transport properties at the inner and outer boundary for mixing between ablation products and a Jovian-like atmosphere are calculated. The dominant species at these boundaries are C, H, O, He, H+, and e. Accurate potential energy curves are obtained for the fifteen possible two-body interactions among these species by fitting good semiempirical potentials for which transport collision cross sections have been tabulated to accurate experimental and theoretical information. Results are obtained for the viscosity and translational thermal conductivity of the pure species and the binary diffusion coefficients from 1000 K to 25,000 K. In addition, the mixture translational thermal conductivity and viscosity are calculated at the inner and outer mixing boundaries. This information is required for calculating flowfield properties and surface heating. The most important conclusion is that the translational thermal conductivity is substantially lower at the inner mixing boundary than it is at the outer mixing boundary.

Biolsi, L.↗