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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 649 records · Page 36
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

A three-step model of high harmonic generation using complex classical trajectories

Highlights: • Rigorous trajectory formulation of strong field physics and high harmonic generation. • The Coulomb ground state is represented by an ensemble of complex trajectories. • Trajectories transition seamlessly from the ground state to ionization or recollision. • The ionized wavepacket is reproduced well from the complex trajectories. • Classically allowed and forbidden processes are treated in a single framework. We present a new trajectory formulation of high harmonic generation that treats classically allowed and classically forbidden processes within a single dynamical framework. Complex trajectories orbit the nucleus, producing the stationary Coulomb ground state. When the field is turned on, these complex trajectories continue their motion in the field-dressed Coulomb potential and therefore tunnel ionization, unbound evolution and recollision are described within a single, seamless framework. The new formulation can bring mechanistic understanding to a broad range of strong field physics effects.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2024

Determination of Vibrational Motions Driving Photoinduced Electron Transfer Reactions in Molecular Crystals and Organic Thin Films

The objective of this research is to develop an understanding of how nuclear motions can be used to drive and control photo-induced charge transfer and singlet fission reactions in molecular crystals and thin films. By following the structural evolution of reacting molecules and nanostructures on the timescale of their nuclear motion, we will determine what interplay of nuclear coordinates is most efficient in driving electron transfers, a necessary first step in most photovoltaic and photocatalytic processes. We will identify which nuclear coordinates effectively promote desirable electron transfer processes, or ineffectively dissipate photon energy into unwanted thermal energy, thus guiding the design and implementation of molecular systems tailored for high efficiency processes. Specifically, we aim to identify which nuclear coordinates are responsible for driving electron transfer and singlet fission reactions at different points along the reaction coordinate, particularly in regimes which deviate from Marcus theory predictions. We will do so by investigating systems with electron transfer and singlet fission occurring from non-thermalized states due to strong donor-acceptor electronic coupling. First, we will prove that specific vibrational modes are responsible for charge transfer processes in molecular crystals. Secondly, we will investigate how vibrational coherences and specific nuclear motions can be used to drive high yield singlet fission processes. Finally, we will determine how complex film morphology affects long-range charge transport, a key limiting factor in our ability to make gains in efficiency.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2020

The Strong Impact of Weak Horizontal Convergence on Continental Shallow Convection

Idealized large-eddy simulation (LES) is a basic tool for studying three-dimensional turbulence in the planetary boundary layer. LES is capable of providing benchmark solutions for parameterization development efforts. However, real small-scale atmospheric flows develop in heterogeneous and transient environments with locally varying vertical motions inherent to open multiscale interactive dynamical systems. These variations are often too subtle to detect them by state-of-the-art remote and in situ measurements, and are typically excluded from idealized simulations. The present study addresses the impact of weak [i.e., O(10-6) s-1] short-lived low-level large-scale convergence/divergence perturbations on continental shallow convection. The results show a strong response of shallow nonprecipitating convection to the applied weak large-scale dynamical forcing. Evolutions of CAPE, mean liquid water path, and cloud-top heights are significantly affected by the imposed convergence/divergence. In contrast, evolving cloud-base properties, such as the area coverage and mass flux, are only weakly affected. To contrast those impacts with microphysical sensitivity, the baseline simulations are perturbed assuming different observationally based cloud droplet number concentrations and thus different rainfall. For the tested range of microphysical perturbations, the imposed convergence/divergence provides significantly larger impact than changes in the cloud microphysics. Simulation results presented here provide a stringent test for convection parameterizations, especially important for large-scale models progressing toward resolving some nonhydrostatic effects.

Meteorology & Atmospheric Sciences↗
NASA NTRS1994

On the motion of air through the stratospheric polar vortex

Trajectory calculations using horizontal winds from the U.K. Meteorological Office data assimilation system and vertical velocities from a radiation calculation are used to simulate the three-dimensional motion of air through the stratospheric polar vortex for Northern Hemisphere (NH) and Southern Hemisphere (SH) winters since the launch of the Upper Atmosphere Research Satellite (UARS). Throughout the winter, air from the upper stratosphere moves poleward and descends into the middle stratosphere. In the SH lower to middle stratosphere, strongest descent occurs near the edge of the polar vortex, with that edge defined by mixing characteristics. The NH shows a similar pattern in late winter, but in early winter strongest descent is near the center of the vortex, except when wave activity is particularly strong. Strong barriers to latitudinal mixing exist above about 420 K throughout the winter. Below this, the polar night jet is weak in early winter, so air descending below that level mixes between polar and middle latitudes. In late winter, parcels descend less and the polar night jet moves downward, so there is less latitudinal mixing. The degree of mixing in the lower stratosphere thus depends strongly on the position and evolution of the polar night jet and on the amount of descent experienced by the air parcels; these characteristics show considerable interannual variability in both hemispheres. The computed trajectories provide a three-dimensional picture of air motion during the final warming. Large tongues of air are drawn off the vortex and stretched into increasingly long and narrow tongues extending into low latitudes. This vortex erosion process proceeds more rapidly in the NH than in he SH. In the lower stratosphere, the majority of air parcels remain confined within a lingering region of strong potential vorticity gradients into December in the SH and April in the NH, well after the vortex breaks up in the midstratosphere.

Manney, G. L.↗
NASA NTRS1994

Motion of the heliospheric termination shock 3: Incident interplanetary shocks

In this paper the response of the heliospheric termination shock to an incident interplanetary shock is examined. This paper is an extension of a recent study by Barnes (1993), which treated the analogous problem for an incident contact discontinuity. The termination shock is treated as a strong gas-dynamic shock. The post-interaction configuration consists of a moving termination shock, a postshock contact discontinuity, and either a shock or rarefaction wave propagating the disturbance signal into the downstream medium. For a decrease in dynamic pressure a rarefaction wave propagates downstream, and the new termination shock propagates inward, while, for an enhancement of dynamic pressure, the termination shock moves outwards and a weak outer shock propagates into the downstream medium; speeds of motion of the termination shock are typically of the order of approximately 100 km/s. The results are similar to those presented by Barnes (1993) indicating that the results of that paper are robust within the gas-dynamic model, in the sense of being independent of the details of the initial disturbance.

Naidu, Kamcilla↗
DOE OSTI2022

Control of electronic topology in a strongly correlated electron system

It is becoming increasingly clear that breakthrough in quantum applications necessitates materials innovation. In high demand are conductors with robust topological states that can be manipulated at will. This is what we demonstrate in the present work. We discover that the pronounced topological response of a strongly correlated “Weyl-Kondo” semimetal can be genuinely manipulated—and ultimately fully suppressed—by magnetic fields. We understand this behavior as a Zeeman-driven motion of Weyl nodes in momentum space, up to the point where the nodes meet and annihilate in a topological quantum phase transition. The topologically trivial but correlated background remains unaffected across this transition, as is shown by our investigations up to much larger fields. Our work lays the ground for systematic explorations of electronic topology, and boosts the prospect for topological quantum devices.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Translocation mechanism of xeroderma pigmentosum group D protein on single-stranded DNA and genetic disease etiology

Abstract XPD is a key nucleotide excision repair (NER) protein whose function is vital for genome integrity. During NER, XPD serves as a 5′−3′ single-strand DNA translocase that enables lesion scanning and verification in genomic DNA. Yet, its translocation mechanism is incompletely understood. Here we use molecular simulations and chain-of-replicas path optimization methods to model the ATP-driven translocation mechanisms of XPD and its bacterial homolog DinG, revealing all on-path metastable intermediates and corresponding kinetic rates. We identify the XPD(DinG) global domain motions that modulate the strength of DNA association at the opposing ends of the DNA-binding groove. During the ATP hydrolysis cycle, alternating weak and strong interactions at two defined groove constrictions enable DNA reptation and forward displacement of the ATPase. Moreover, we show that DNA- or ATP-binding residues directly involved in translocation are hotspots for genetic disease mutations. Thus, our findings shed light on the etiology of XPD-associated genetic syndromes.

Paul, Tanmoy↗
NASA NTRS1975

Investigation of electron dynamics in the magnetosphere with electron beams injected from sounding rockets

The Electron Echo experiments are described which were conducted with three sounding rockets to study the basic mechanisms by which electrons precipitate from the geomagnetic field to produce auroral X-rays during periods of geomagnetic activity. Echo I (1970) injected electron pulses at low latitude and successfully measured the returning pulses from the conjugate region. Echo II (1972) was launched from high latitude, studied the interaction of electron beams with background radiation as well as beam motion near the rocket, and obtained evidence for a beam plasma instability. Echo III (1974) detected a series of conjugate echoes during the presence of a strong convective field in the magnetosphere and conducted an unsuccessful search for beam bunching at the local plasma frequency. It is shown that the electric field measurement in the ionosphere, using incoherent backscatter radar and detectors on the rocket, was transferred to the equatorial plane as though field lines were equipotentials.

Winckler, J. R.↗
NASA NTRS1981

Precipitation growth in convective clouds

Analytical solutions to the equations of both the growth and motion of hailstones in updrafts and of cloud water contents which vary linearly with height were used to investigate hail growth in a model cloud. A strong correlation was found between the hail embyro starting position and its trajectory and final size. A simple model of the evolution of particle size distribution by coalescence and spontaneous and binary disintegrations was formulated. Solutions for the mean mass of the distribution and the equilibrium size distribution were obtained for the case of constant collection kernel and disintegration parameters. Azimuthal scans of Doppler velocity at a number of elevation angles were used to calculate high resolution vertical profiles of particle speed and horizontal divergence (the vertical air velocity) in a region of widespread precipitation trailing a mid-latitude squall line.

Srivastava, R. C.↗
NASA NTRS1980

Solitary Rossby waves in the presence of vertical shear

The effects of vertical shear on regular neutral mode Rossby solitons driven by a horizontal shear are investigated in light of the proposition that certain features in the Jupiter atmosphere may be explained by solitary Rossby waves. Consideration is given to a two-layer quasi-geostrophic model in which the motion in each layer consists of a different zonal shear flow, with vertical shear concentrated at the interface between the layers. In the case of a strong vertical shear, it is found that only a very restricted set of flows will admit Rossby neutral model solitons. For the more realistic case of a weak vertical shear, results indicate similar, but latitudinally shifted, wave patterns in each layer. It is noted that no such slant has yet been detected in the Great Red Spot.

Weidman, P. D.↗
NASA NTRS1981

The effect of microscopic turbulence on magnetosphere-ionosphere coupling

The effect of turbulence on the coupling of the magnetosphere and ionosphere has been investigated by including an effective collision frequency in the electron equation of motion. When this term is combined with the continuity equation, the ion equation of motion and Maxwell's equations, a dispersion relation for the kinetic Alfven wave including effective collisions is found. The wave-particle interaction leads to a strong damping of the wave. Inclusion of the effects of plasma sheet kinetics yields a scale size transverse to the magnetic field which corresponds to the size of visual auroral arcs.

Lysak, R. L.↗
NASA NTRS1984

A catalog of selected compact radio sources for the construction of an extragalactic radio/optical reference frame

A catalog of 234 strong compact extragalactic radio sources that display optical counterparts is presented. This catalog identifies proposed sources for establishing an almost inertial reference frame against which the motions of the earth, solar system, galactic objects, and spacecraft may be measured. This catalog also defines those sources for which precise optical positions should be determined in order to relate this reference frame with the optical FK 5 fundamental system. The accuracy of the radio source positions of these sources is not greater than 0.1 arcsec with the majority not greater than 0.01 arcsec. Further refinement to not greater than 0.005 arcsec by future observations is expected soon.

Argue, A. N.↗
NASA NTRS1988

Eulerian measurements of horizontal accelerations in shoaling gravity waves

Laboratory and field measurements of suspended sediment in the nearshore suggest that fluid accelerations are an important factor in sediment transport by oscillatory waves. Here, Eulerian accelerations of the cross-shore velocity are calculated from measurements of velocity obtained by an array of bottom-mounted electromagnetic flow meters spanning a natural surf zone. Large shoreward accelerations of brief duration are associated with the steep front faces of both near-breaking and breaking waves. Weaker offshore accelerations of longer duration occur during passage of the more gently sloped rear faces. The acceleration field is thus strongly skewed in the shoreward direction. Power spectra and bispectra indicate, as expected, that statistics of the acceleration field are significantly influenced by high-frequency motions but are rather insensitive to surf beat.

Elgar, Steve↗
NASA NTRS1990

Eastern Aphrodite Terra on Venus - Characteristics, structure, and mode of origin

Altimetric and radar-image cross-strike discontinuities (CSDs) are found to cut across the nearly east-west strike of Eastern Aphrodite (EA) Terra, dividing or segmenting it into offset domains. Each of these domains is characterized by a discontinuous central chasma or trough. These features have been mapped in the altimetric and radar image data of EA on the basis of abrupt termination of riftlike central chasma, offset, and segmentation of the center highlands, and radar image discontinuities previously mapped in Western Aphrodite in terms of length, orientation, and influence on the central highlands and adjacent lowlands. It is concluded that EA displays a variety of geological and geophysical characteristics similar to those occuring at divergent boundaries. The surface map characteristics are the result of a great horizontal motion of the crust diverging from a well-defined linear region, a process that can occur whether the surface is part of a thick and strong plate detached from mantle convection or part of a thin and weak layer attached to a deep convective limb.

Crumpler, L. S.↗
NASA NTRS1992

Study of explosive and nonexplosive cyclogenesis during FGGE

Explosive cyclogenesis during the winter of the First Global GARP Experiment (January-February 1979) is analyzed using the revised European Centre for Medium Range Weather Forecasts (ECMWF) analyses. Explosive cyclogenesis is defined as a decrease in the sea level pressure at the rate of 1 mb/h for at least 12 h. Diagnostics for 23 explosively developing cases and 16 nonexplosive cases are evaluated. Parameters compared include the dry static stability, low-level relative vorticity, vorticity advection, upper-level divergence, and kinematic vertical velocities. These parameters are compared statistically at the initial, 12-, and 24-h time periods. Parameters for which the explosive and nonexplosive cyclone ensembles were statistically separable are the kinematic vertical velocity and the upper-level divergence and vorticity advection. The strong upper-level processes for the explosive cases at the initial time indicate the importance of upper-tropospheric features in producing the stronger vertical motions and more rapid cyclogenesis.

Wash, Carlyle H.↗
NASA NTRS1991

Theoretical constraints in the design of multivariable control systems

The research being performed under NASA Grant NAG1-1361 involves a more clear understanding and definition of the constraints involved in the pole-zero placement or assignment process for multiple input, multiple output systems. Complete state feedback to more than a single controller under conditions of complete controllability and observability is redundant if pole placement alone is the design objective. The additional feedback gains, above and beyond those required for pole placement can be used for eignevalue assignment or zero placement of individual closed loop transfer functions. Because both poles and zeros of individual closed loop transfer functions strongly affect the dynamic response to a pilot command input, the pole-zero placement problem is important. When fewer controllers than degrees of freedom of motion are available, complete design freedom is not possible, the transmission zeros constrain the regions of possible pole-zero placement. The effect of transmission zero constraints on the design possibilities, selection of transmission zeros and the avoidance of producing non-minimum phase transfer functions is the subject of the research being performed under this grant.

Rynaski, E. G.↗
NASA NTRS2003

Continuous Tuning and Calibration of Vibratory Gyroscopes

A method of control and operation of an inertial reference unit (IRU) based on vibratory gyroscopes provides for continuously repeated cycles of tuning and calibration. The method is intended especially for application to an IRU containing vibratory gyroscopes that are integral parts of microelectromechanical systems (MEMS) and that have cloverleaf designs, as described in several previous NASA Tech Briefs articles. The method provides for minimization of several measures of spurious gyroscope output, including zero-rate offset (ZRO), angle random walk (ARW), and rate drift. These benefits are afforded both at startup and thereafter during continuing operation, in the presence of unknown rotation rates and changes in temperature. A vibratory gyroscope contains a precision mechanically resonant structure containing two normal modes of vibration nominally degenerate in frequency and strongly coupled via a Coriolis term. In the case of the cloverleaf design MEMS gyro, these normal modes of vibration are plate rocking modes. The rocking motion of the plate is described by giving two angles, theta(sub 1) and theta(sub 2). A proof mass consisting of a post orthogonal to the plate ensures a high degree of Coriolis coupling of vibratory energy from one mode into the other under inertial rotation. The plate is driven and sensed capacitively across a few-microns-wide gap, and the normal mode frequencies can be tuned electrostatically by DC voltages applied across this gap. In order to sense rotation, the resonator plate is caused to rock in the theta(sub 1) direction, then any small motions in the theta(sub 2) direction are sensed, rebalanced, and interpreted as inertial rotation. In this scenario, the "drive" has been assigned to the theta(sub 1) direction, and the "sense" has been assigned to the theta(sub 2) direction.

Hayworth, Ken↗
NASA NTRS2012

Integrated Flight/Structural Mode Control for Very Flexible Aircraft Using L1 Adaptive Output Feedback Controller

This paper explores application of adaptive control architecture to a light, high-aspect ratio, flexible aircraft configuration that exhibits strong rigid body/flexible mode coupling. Specifically, an L(sub 1) adaptive output feedback controller is developed for a semi-span wind tunnel model capable of motion. The wind tunnel mount allows the semi-span model to translate vertically and pitch at the wing root, resulting in better simulation of an aircraft s rigid body motion. The control objective is to design a pitch control with altitude hold while suppressing body freedom flutter. The controller is an output feedback nominal controller (LQG) augmented by an L(sub 1) adaptive loop. A modification to the L(sub 1) output feedback is proposed to make it more suitable for flexible structures. The new control law relaxes the required bounds on the unmatched uncertainty and allows dependence on the state as well as time, i.e. a more general unmatched nonlinearity. The paper presents controller development and simulated performance responses. Simulation is conducted by using full state flexible wing models derived from test data at 10 different dynamic pressure conditions. An L(sub 1) adaptive output feedback controller is designed for a single test point and is then applied to all the test cases. The simulation results show that the L(sub 1) augmented controller can stabilize and meet the performance requirements for all 10 test conditions ranging from 30 psf to 130 psf dynamic pressure.

Che, Jiaxing↗