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At least 649 records · Page 36

Spectrometer for Sky-Scanning, Sun-Tracking Atmospheric Research (4STAR) Instrument Improvements

The Spectrometer for Sky-Scanning, Sun-Tracking Atmospheric Research (4STAR) combines airborne sun tracking and sky scanning with grating spectroscopy to improve knowledge of atmospheric constituents and their links to air-pollution and climate. Hyper-spectral measurements of direct-beam solar irradiance provide retrievals of gas constituents, aerosol optical depth, and aerosol and thin cloud optical properties. Sky radiance measurements in the principal and almucantar planes enhance retrievals of aerosol absorption, aerosol type, and size mode distribution. Zenith radiance measurements are used to retrieve cloud properties and phase, which in turn are used to quantify the radiative transfer below cloud layers. These airborne measurements tighten the closure between satellite and ground-based measurements. In contrast to the Ames Airborne Tracking Sunphotometer (AATS-14) predecessor instrument, new technologies for each subsystem have been incorporated into 4STAR. In particular, 4STAR utilizes a modular sun-trackingsky-scanning optical head with fiber optic signal transmission to rack mounted spectrometers, permitting miniaturization of the external optical head, and spectrometerdetector configurations that may be tailored for specific scientific objectives. This paper discusses technical challenges relating to compact optical collector design, radiometric dynamic range and stability, and broad spectral coverage at high resolution. Test results benchmarking the performance of the instrument against the AATS-14 standard and emerging science requirements are presented.

Atmopheric Research (4STAR)↗

A Comprehensive Radial Velocity Error Budget for Next Generation Doppler Spectrometers

We describe a detailed radial velocity error budget for the NASA-NSF Extreme Precision Doppler Spectrometer instrument concept NEID (NN-explore Exoplanet Investigations with Doppler spectroscopy). Such an instrument performance budget is a necessity for both identifying the variety of noise sources currently limiting Doppler measurements, and estimating the achievable performance of next generation exoplanet hunting Doppler spectrometers. For these instruments, no single source of instrumental error is expected to set the overall measurement floor. Rather, the overall instrumental measurement precision is set by the contribution of many individual error sources. We use a combination of numerical simulations, educated estimates based on published materials, extrapolations of physical models, results from laboratory measurements of spectroscopic subsystems, and informed upper limits for a variety of error sources to identify likely sources of systematic error and construct our global instrument performance error budget. While natively focused on the performance of the NEID instrument, this modular performance budget is immediately adaptable to a number of current and future instruments. Such an approach is an important step in charting a path towards improving Doppler measurement precisions to the levels necessary for discovering Earth-like planets.

NASA-NSF Extreme Precision Doppler Spectrometer in↗

The Resource Prospector Neutron Spectrometer System: RP's Bloodhound

The primary goal of the Resource Prospector Neutron Spectrometer System (NSS) is to locate and characterize hydrogen-bearing volatile deposits, especially subsurface ice, that may exist at the lunar poles. A key objective is to detect water-equivalent hydrogen concentrations of 0.5 wt% or greater while on a moving rover. A second objective is to determine approximate burial depth of enhanced hydrogen-bearing materials up to 1 meter below otherwise dry regolith. The instrument will be carried aboard a landed mobility system at the lunar poles. The instrument operates by measuring the changes in the leakage flux of low energy neutrons out of the regolith. These neutrons are produced by galactic cosmic rays, which are so energetic that they shatter the nuclei in surface materials. The neutrons interact with other nuclei and lose energy, becoming thermalized in the process. Hydrogen is most efficient at thermalizing neutrons owing to protons' similar mass - statistically, neutrons lose half their energy per collision with protons. With hydrogen in the soil, leakage fluxes of neutrons in the 0.5 eV to 500 keV energy range are reduced. A concentration of only1-2 wt% water-equivalent hydrogen results in a decrease in epithermal leakage flux of a factor of two. The leakage flux of thermal neutrons, from 0 to 0.5 eV in energy, can either increase or decrease depending on the hydrogen abundance and stratigraphy. As with the highly successful Lunar Prospector Neutron Spectrometer, the RP NSS detects both thermal and epithermal neutrons by using two helium-3 gas proportional counters, one covered by cadmium and the other uncovered. The former detects only epithermal neutrons with energies above approximately 0.5 eV, the latter detects both thermal (less than 0.5 eV) and epithermal energies (greater than 0.5 eV). When a neutron enters the detector tube and interacts with a helium-3 nucleus, the resulting reaction produces an energetic proton and triton that ionize the gas. The resulting electrons are accelerated toward a high-voltage anode and cascade, amplifying the net charge, which is collected at the anode. The number of electrons produced is proportional to the energy that the triton and proton deposit in the gas. A charge sensitive pre-amplifier converts the total charge to a step voltage output. A shaper amplifier then shapes this step into a uni-polar waveform with peaking time appropriate for the detection depending on the event rate. The integrated shaped waveform, representing the deposited triton/proton energy, is then measured. A histogram, or pulse height analysis, is performed to record the main capture peak and wall effect pulses. A threshold for detection is also required to limit the low amplitude counting rate such as noise floor. The system electronics consists of 2 modules - the Sensor Module (SM) front-end and the Data Processing Module (DPM) back-end circuits. SM is designed as a light-weight and low power front-end housing the two helium-3 proportional counter detectors, preamp and HVPS. It is mounted external to the rover body to detect the thermalized neutron flux with a minimum of host background. The DPM is located inside the rover; it digitizes the SM signals, performs pulse height analysis and accumulates the count rate for each spectral channel. The DPM controls high voltage and thresholding, and sends the science data to the host craft via an RS422 serial asynchronous protocol. The payload host provides all thermal management and control for the SM and DPM.

hydrogen-bearing volatile deposits↗

UV Capabilities of the CETUS Multi-Object Spectrometer (MOS) and NUV/FUV Camera

The Cosmic Evolution Through UV Spectroscopy (CETUS) concept enables parallel observations by the UV multiobject spectrometer (MOS) and near-UV/far-UV camera which operate simultaneously but independently with their separate field of views. The near-UV MOS can target up to 100 objects at a time without confusion with nearby sources or background zodiacal light. This multiplexing will allow over 100,000 galaxies to be observed over a typical mission lifetime. The MOS includes a next-generation micro-shutter array (NGMSA), an efficient aspheric Offner-like spectrometer design with a convex grating, and nanotube light traps for suppressing unwanted wavelengths. The NUV/FUV Camera has the capability to image in a range of sub-bands from 115-400 nm at the same time the MOS is operating at 180-350 nm. The UV camera has a similar Offner-like relay, selectable filters, and two separate detectors to optimize observing in either the far-UV (115-175 nm) or the near-UV (180-400 nm) utilizing a CsI Micro-Channel Plate detector (MCP) and a CCD respectively.

The Cosmic Evolution Through UV Spectroscopy (CETU↗

Snow and Water Imaging Spectrometer (SWIS): Development of a CubeSat-Compatible Instrument

The Snow and Water Imaging Spectrometer (SWIS) is a fast, high-uniformity, low-polarization sensitivity imaging spectrometer and telescope system designed for integration on a 6U CubeSat platform. Operating in the 350-1700 nm spectral region with 5.7 nm sampling, SWIS is capable of simultaneously addressing the demanding needs of coastal ocean science and snow and ice monitoring. New key technologies that facilitate the development of this instrument include a linear variable anti-reflection (LVAR) detector coating for stray light management, and a single drive on-board calibration mechanism utilizing a transmissive diffuser for solar calibration. We provide an overview of the SWIS instrument design, spacecraft configuration design, and potential science missions.

Dyson spectrometer↗

Airborne Visible/Infrared Imaging Spectrometer (AVIRIS): Sensor Improvements for 1994 and 1995

AVIRIS is a NASA-sponsored Earth-remote-sensing imaging spectrometer designed, built, and operated by JPL. In the time that AVIRIS has been operational since 1989, major improvements have been completed in most of the subsystems of the sensor during the winter maintenance cycles. As a consequence of these efforts, the capabilities of AVIRIS to reliably acquire and deliver consistently high quality, calibrated imaging spectrometer data continue to improve annually, significantly over those in 1989. Improvements to AVIRIS prior to 1994 have been described elsewhere. This paper details recent and planned improvements to AVIRIS in the sensor task.

remote↗

Miniature Magnetic Resonance Spectrometers

For the purpose of in-situ planeatry exploration, such as chemical characterization of Martian surface materials by miniature instruments, we have developed miniature Magnetic Resonance Spectrometers (MRS) namely, Nuclear Magnetic Resonance (NMR) and Electron Paramagnetic Resonance (EPR) spectrometers at JPL.

Proton-NMR↗

The Visual and Infrared Mapping Spectrometer for Cassini

The Visual and Infrared Mapping Spectrometer (VIMS) is a remote sensing instrument developed for the Cassini mission to Saturn by an international team representing the national space agencies of the United States, Italy, and France. A dual imaging spectrometer, VMS' unique design consists of two optical systems boresighted and operating in tandem, coordinated by a common electronics unit.

imaging↗

Estimation of Aerosol Optical Depth, Pressure Elevation, Water Vapor and Calculation of Apparent Surface Reflectance from Radiance Measured by the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) Using a Radiative Transfer Code

The Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) is an imaging spectrometer that measures spatial images of the total up welling spectral radiance from 400 to 2500 nm at 10 nm spectral intervals. Quantitiative research and application objectives for surface investigations require conversion of the measured radiance to surface reflectance or surface leaving radiance. In this paper we describe a set of algorithms to estimate aerosol optical depth, atmospheric water vapor, and surface pressure height from the AVIRIS measured radiance.

infrared↗

Analysis of the Pioneer Venus Large Probe Neutral Mass Spectrometer Data Yields New Insights into the Composition of Venus’ Atmosphere

We present a new analysis of mass spectral data obtained by the Pioneer Venus (PV) Large Probe Neutral Mass Spectrometer (LNMS). To analyze the LNMS data, we constructed an analytical model that accounts for spectrometer performance at each altitude, provides CO2 abundances in units of density (kg/m3), and retains the resolving power of the LNMS through use of a targeted data-fitting routine. Our results provide new insights into the composition of Venus’ atmosphere and show that densities for CO2 increase towards the surface, which is suggestive of surface outgassing. Additionally, the data reveal partial obstructions of the LNMS inlet at <17 km, which is an likely important consideration for future missions. Re-analysis of the LNMS data may assist in revealing the past, present and/or future habitability of Venus’ clouds.

mass spectral data↗

An Overview of MaGIXS-2: The second flight of the Marshall Grazing Incidence X-ray Spectrometer

The Marshall Grazing Incidence X-ray Spectrometer (MaGIXS) is a sounding rocket mission that completed a successful flight from the White Sands Missile Range on July 30, 2021. MaGIXS captured spatially resolved soft X-ray spectra from portions of two solar active regions during its roughly 5-minute flight. The instrument was originally designed as a grazing incidence slit spectrograph but flew in a slit-less configuration that produced overlapping spectroheliograms. For the second flight, MaGIXS-2, the instrument has been reconfigured to a more simplified optical layout that reuses the Wolter-I telescope and blazed varied-line space reflective grating. The field stop at the telescope focal plane and the finite conjugate spectrometer mirror pair have been removed – the telescope now directly feeds the grating. Additionally, an identical but new 2k x 1k CCD camera has been built for this flight. The MaGIXS-2 data product will again be overlapping spectroheliograms of at least one solar active region, but with improved resolution, a larger field of view and increased effective area. Here we present the updated instrument layout, the expected performance, the integration and calibration approach, and proposed future improvements, including the implementation of additional complimentary spectral diagnostics.

Imaging Spectrometer↗

Plasma Wakes from the Baffle Scanning Mechanism on a LEO Mass Spectrometer

The Modular Spectrometer for Atmosphere and Ionosphere Characterization (MoSAIC) is a Quadrupole Mass Spectrometer (QMS) which will fly on NASA's Geospace Dynamics Constellation (GDC) mission in low Earth orbit (LEO), providing measurements of neutral and ionized gas density, temperature, composition, and wind/drift. MoSAIC includes a Baffle Scanning Mechanism (BSM) which periodically sweeps in front of the QMS aperture, enabling determination of the ion temperature and cross-track velocity. Accurate knowledge of the plasma wake formed by the BSM is critical for accurate determination of these quantities. We conduct particle-in-cell (PIC) simulations modeling the interactions between the baffle and plasma across the full range of ion densities, temperatures, and flow speeds GDC is expected to encounter. We discuss the wake physics and present an empirical model which can be implemented in the MoSAIC data analysis process to determine the relevant ion quantities.

mass spectrometer↗

Spent Fuel Assay with an Ultra-High Rate HPGe Spectrometer

Traditional verification of spent nuclear fuel (SNF) includes determination of initial enrichment, burnup and cool down time (IE, BU, CT). Along with neutron measurements, passive gamma assay provides important information for determining BU and CT. Other gamma-ray-based assay methods such as passive tomography and active delayed gamma offer the potential to measure the spatial distribution of fission products and the fissile isotopic concentration of the fuel, respectively. All fuel verification methods involving gamma-ray spectroscopy require that the spectrometers manage very high count rates while extracting the signatures of interest. PNNL has developed new digital filtering and analysis techniques to produce an ultra-high rate gamma-ray spectrometer from a standard coaxial high-purity germanium (HPGe) crystal. This 37% relative efficiency detector has been operated for SNF measurements at input count rates of 500-1300 kcps and throughput in excess of 150 kcps. Optimized filtering algorithms preserve the spectroscopic capability of the system even at these high rates. This paper will present the results of both passive and active SNF measurement performed with this system at PNNL. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

A Wide Field of View Plasma Spectrometer

Here we present a fundamentally new type of space plasma spectrometer, the wide field of view plasma spectrometer, whose field of view is >1.25π ster using fewer resources than traditional methods. The enabling component is analogous to a pinhole camera with an electrostatic energy-angle filter at the image plane. Particle energy-per-charge is selected with a tunable bias voltage applied to the filter plate relative to the pinhole aperture plate. For a given bias voltage, charged particles from different directions are focused by different angles to different locations. Particles with appropriate locations and angles can transit the filter plate and are measured using a microchannel plate detector with a position-sensitive anode. Full energy and angle coverage are obtained using a single high-voltage power supply, resulting in considerable resource savings and allowing measurements at fast timescales. Lastly, we present laboratory prototype measurements and simulations demonstrating the instrument concept and discuss optimizations of the instrument design for application to space measurements.

47 OTHER INSTRUMENTATION↗

Improved ion optics for introduction of ions into a 9.4-T Fourier transform ion cyclotron resonance mass spectrometer

Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry provides unparalleled mass accuracy and resolving power.[1],[2] With electrospray ionization (ESI), ions are typically transferred into the mass spectrometer through a skimmer, which serves as a conductance-limiting orifice. However, the skimmer allows only a small fraction of incoming ions to enter the mass spectrometer. An ion funnel, originally developed by Smith and coworkers at Pacific Northwest National Laboratory (PNNL)[3-5] provides much more efficient ion focusing and transfer. The large entrance aperture of the ion funnel allows almost all ions emanating from a heated capillary to be efficiently captured and transferred, resulting in nearly lossless transmission.

42 ENGINEERING↗

Installation protocol for charge transfer dissociation mass spectrometry on ion trapping mass spectrometers

Abstract Rationale Charge transfer dissociation (CTD) is a novel fragmentation technique that demonstrates enhanced structural characterization for a wide variety of molecules compared to standard fragmentation techniques like collision‐induced dissociation (CID). Alternative fragmentation techniques, such as electron transfer dissociation, electron capture dissociation, and ultraviolet photodissociation, also overcome many of the shortfalls of CID, but none of them are a silver bullet that can adequately characterize a wide variety of structures and charge states of target compounds. Given the diversity of structural classes and their occasional obstinance towards certain activation techniques, alternative fragmentation techniques are required that rely on novel or alternative modes of activation. Methods Herein, we present a step‐by‐step protocol for the installation of CTD on a quadrupole ion trap mass spectrometer and best practices for optimizing the signal‐to‐noise ratio and acquisition times for CTD mass spectra. Results In addition to two CTD installations in the Jackson laboratory, CTD has also been installed, and is currently in operation, on two 3D ion trap mass spectrometers in France: one in the laboratory of Dr. David Ropartz and Dr. Hélène Rogneaux at INRAE in Nantes, and the other in the laboratory of Dr. Jean‐Yves Salpin at Université d'Évry Val‐d'Essonne, part of the Paris‐Saclay University system. Conclusions Here, we provide a visual protocol to help others accomplish the instrument modification.

47 OTHER INSTRUMENTATION↗

The Aerogel Cerenkov detector for the SHMS magnetic spectrometer in Hall C at Jefferson Lab

Hadronic reactions producing strange quarks such as exclusive or semi-inclusive kaon production, play an important role in studies of hadron structure and the dynamics that bind the most basic elements of nuclear physics. The small-angle capability of the new Super High Momentum Spectrometer (SHMS) in Hall C, coupled with its high momentum reach - up to the anticipated 11-GeV beam energy in Hall C - and coincidence capability with the well-understood High Momentum Spectrometer, will allow for probes of such hadron structure involving strangeness down to the smallest distance scales to date. To cleanly select the kaons, a threshold aerogel Cerenkov detector has been constructed for the SHMS. The detector consists of an aerogel tray followed by a diffusion box. Four trays for aerogel of nominal refractive indices of n =1.030, 1.020, 1.015 and 1.011 were constructed. The tray combination will allow for identification of kaons from 1 GeV/c up to 7.2 GeV/c, reaching 10 -2 proton and 10 -3 pion rejection, with kaon detection efficiency better than 95%. The diffusion box of the detector is equipped with 14 five-inch diameter photomultiplier tubes. Its interior walls are covered with Gore diffusive reflector, which is superior to the commonly used Millipore paper and improved the detector performance by 35%. The inner surface of the two aerogel trays with higher refractive index is covered with Millipore paper, however, those two trays with lower aerogel refractive index are again covered with Gore diffusive reflector for higher performance. The measured mean number of photoelectrons in saturation is ~12 for n =1.030, ~8 for n =1.020, ~10 for n =1.015, and ~5.5 for n =1.011. Here the design details, the results of component characterization, and initial performance tests and optimization of the detector are presented.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

A low-background γγ-coincidence spectrometer for radioisotope studies

The performance of a new, low-background NaI(Tl) spectrometer, based on γγ-coincidence counting, is discussed. We present experimental coincidence efficiencies, timing resolutions, background count rates, and minimum detectable activities. The spectrometer has been simulated using Geant4, and the results are used for estimating coincidence efficiencies for volume sources. To test the device, we measured the cosmogenic 26 Al activity in a small (17.7 g) meteorite fragment. Here, we find a value of 52.9±7.8 dpm / kg, in agreement with the activity measured previously in a much larger fragment of the same meteorite using a HPGe detector.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗