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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 649 records · Page 36
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Nitinol Electroslag Remelting: Initial Slag Study

Nitinol’s unique shape memory and super-elastic properties make it attractive for many applications in biomedical, automotive, aerospace, industrial refrigeration, and waste heat reclamation industries. The fatigue performance is limited however, by non-metallic inclusions (NMI) formed during the traditional VIM/VAR or multi-VAR process. ESR is a potential alternative melt process and is commonly used to refine ingot chemistry and enhance the metallurgical structure of many superalloys and specialty steels, but no study on ESR of Nitinol has been reported to date. The key to establishing a successful ESR process is selecting a compatible slag. In this study, several different slag chemistries are evaluated for their compatibility with Nitinol. One slag chemistry is chosen, along with a control, to produce four Nitinol ESR ingots. Pursuit of a novel slag chemistry for adequate Nitinol refinement is discussed.

Fezi, Kyle↗
DOE OSTI2021

Membrane-Based Air Dehumidification Using Organic Ionic Liquid Desiccant

Membrane Ionic Liquid Desiccant Air Dehumidification (MILDAD) is a promising alternative to conventional dehumidification systems that employ mechanical compressors and refrigerant-based cooling with evaporator and condensing coils. However, its application has been limited due to high manufacturing and installation cost, durability issues, concerns with corrosion due to leakage and salt carry over into the downstream air and onto surfaces. This paper reviews substantial progress made with new systems based on combining advanced ionic membranes that are pressure resistant, thin walled with high water permeability, and non-porous with synthetic organic, non-crystalline ionic liquid desiccants. Alternative design configurations are discussed comparing cross flow shell-and-tube membrane contactors employing ionic membrane tubes through which ionic liquid desiccant air flows. Performance data for MILDAD prototypes is provided. Dehumidification of the incoming supply airstream and regeneration into exhausted building air is demonstrated. The latent effectiveness of the MILDAD system will be discussed along with some future steps to improve performance of the system.

ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION↗
DOE OSTI2022

Measurements of Electron Beam-Induced Spin-Relaxation in Frozen-Spin Hydrogen-Deuteride (HD)

Targets of solid hydrogen-deuteride (HD) can be prepared in a frozen-spin state with spin relaxation times (T1) in excess of a year. The present work has studied their potential use in experiments with electron beams. Polarization relaxation rates have been measured during exposure to sub-nanoAmp currents of 9.7 MeV electron beams from the recently commissioned Upgraded Injector Test Facility (UITF) at Jefferson Lab (JLab). These UITF measurements can be used to anticipate the expected performance at the GeV energies typical of JLab experiments, since the energy deposition in a target is almost independent of beam energy. An in-beam dilution refrigerator equipped with superconducting solenoids has been used to maintain solid HD samples at ?0.1 K and ?1 tesla, and internal NMR coils have been used to monitor hydrogen polarization. Spin-relaxation in two frozen-spin targets, with initial H-polarizations of 40% and 34%, have been tracked while exposed to beams under varying conditions of current, dose, beam duty factor and temperature. At a fixed accumulated dose, the spin-relaxation rates drop with current, suggesting depolarization by the charge cloud of the beam. Imposing a duty factor on the otherwise continuous UITF beam, with forced millisecond scale gaps, has shown no obvious correlation to polarization loss rates. After an accumulated dose of ?2 ?C/cm2, beam-off spin-relaxation rates drop from their immeasurably long pre-irradiation values to the order of weeks (with beam-on T1 values typically an order of magnitude shorter), reflecting a buildup of paramagnetic charge centers within the HD lattice. The accumulated polarization loss was approximately proportional to dose in both targets, dropping to 1/e of their initial values after ?6 ?C/cm2. Thermal equilibrium polarizations of targets not in the frozen-spin state (with intentionally short T1) have been used to deduce the in situ temperature of solid HD while under electron bombardment. A model for depolarization by beam-associated paramagnetic impurities largely accounts for the data, and suggests that improvements in heat removal could lead to significant increases in the in-beam T1.

O'Connell, Thomas↗
DOE OSTI2022

CO2 Sorption in Ionic Liquid Crystals

Ionic liquid crystals (ILCs) have an affinity for certain polarizable gases such as CO2, due to their similarity to ionic liquids. We investigated three ILCs in the [1-alkyl-3-methylimidazolium+] family: n=12,14 with [BF4-] and [PF6-]: liquid crystalline analogues to ionic liquids with moderate (e.g., 1-2 mol%) CO2 solubility at atmospheric conditions: [1-butyl-3-methylimidazolium+] with [BF4-] and [PF6-]. While ionic liquids show high CO2 solubility, regenerating the CO2 is a high-energy process. Liquid crystals show low CO2 solubility but have a much lower regeneration energy requirement. Will ionic liquid crystals uptake CO2? What are the energy requirements of regenerating CO2? Conclusions: 1. C12mim BF4- shows the highest sorption at 0.12 wt% CO2 in the isotropic phase vs. C14mim BF4- with 0.097 wt% in the smectic phase. We hypothesize that the increase in chain length affects the free volume of the smectic vs. isotropic phase of C14mim BF4-, increasing the latter. 2. The change in anion from BF4- to PF6- decreased the sorption to an insignificant level more analogous to a physical adsorption onto the material in all phases. We hypothesize that the change in anion to the larger, less charge dense PF6- decreased the attractive forces between CO2 and the anion. 3. 0.12 wt% of CO2 in C12mim BF4- is small but significant. This in combination with the room temperature release of CO2 after only requiring refrigeration temperatures to occlude the CO2, making ionic liquid crystals promising materials for future.

carbon dioxide sorption↗
DOE OSTI2022

Electron subband degeneracy heat pump for cryogenic cooling

An unconventional method of solid-state cryogenic cooling utilizing the electron subband degeneracy of semiconductor heterostructures is discussed in this Letter. The working principle of using the electrons as the working medium to perform cyclic heat pumping under electrostatic subband "expansion" and "compression" is discussed. The calculated base temperature can reach below dilution refrigeration temperatures with the fundamental limit set by electron-phonon interaction. Using an ultra-wide GaAs quantum well as an example, the cooling power per unit volume is estimated to reach $0.85\ \rm \mu W/cm^3$ at $25\ \rm mK$ with a hot-side temperature of $42.5\ \rm mK$, suitable for applications such as quantum computing.

Wang, Chulin↗
DOE OSTI2023

Energy Model of an Air Source Heat Pump to Explore Performance Improvements under Cold Conditions: A Python Framework: Preprint

Replacing combustion appliances with heat pumps can be part of a strategy to electrify buildings. When their electricity is supplied by renewables, the adoption of heat pumps for space heating may help curb the carbon dioxide emissions inherent to traditional heating systems that burn natural gas or coal. When operating in very cold climates, however, heat pump performance deteriorates, sometimes requiring backup heating supplied by electric resistances or other sources to continue to function. To avoid the use of electric resistances, complementary technologies, like thermal energy storage, solar collectors, or alternative refrigerants, have been explored in recent years. In this study, we present an open-source Python-based numerical model developed to evaluate the annual hourly performance of an air source heat pump (ASHP) operating in the USA. Simulation results include coefficient of performance and heating capacity. The model, validated with experimental results, will be employed in the future to investigate the feasibility of integrating thermal energy storage and other technologies into ASHPs operating in cold climates.

cold climate↗
DOE OSTI2022

Roll-to-roll slot die coating method to create interleaving multi-layered films with chemical slurry coatings

An improved method for manufacturing a continuous self-healing barrier film is provided. The method includes slot-die coating opposing sides of a separator substrate with a curing agent slurry and a curable resin slurry using a single-sided coating line or a tandem coating line. The method also includes sequentially interleaving inner and outer protective layers via a continuous roll-to-roll process to create a multi-layered barrier film. The barrier film can optionally be formed into a barrier envelope, and an insulating core material can be inserted into the barrier envelope to define an enclosure. Evacuating and sealing the enclosure along a perimeter of the barrier envelop forms a self-healing vacuum insulation panel with excellent properties for use as a building material and in refrigeration systems, for example. The barrier film can alternatively be used in the manufacture of tires, roofing, cargo containers, food packaging, and pharmaceutical packaging, for example.

Biswas, Kaushik↗
DOE OSTI2022

Tube-in-tube ionic liquid heat exchanger employing a selectively permeable tube

A tube-in-tube heat exchanger utilizes a selectively permeable tube having a selective permeable layer to allow the refrigerant to transfer into an ionic liquid to generate heating or cooling. The ionic liquid then provides heating or cooling to a heat transfer fluid through a non-permeable layer or tube. The system may be configured as a shell and tube design, with the third fluid free to flow on the outside of the shell, or as a shell and tube-in-tube, with a central tube containing a first liquid, a second tube containing a second liquid, and an outer shell containing the third liquid. The selectively permeable tube may include an anion or cation selectively permeable layer and this layer may be supported by a support layer or tube.

Bahar, Bamdad↗
DOE OSTI2023

Modeling Assessment of Residential Air-to-Water Heat Pumps Coupled with Cooling Thermal Storage

This study explored the performance and operating cost viability of air-to-water heat pumps (AWHPs) coupled with thermal energy storage (TES) in efficient new residential construction. AWHPs are an emerging technology in this country, but offer promise in terms of high efficiency, fully contained and factory charged outdoor refrigeration system, and hydronic delivery capabilities, which facilitates zoning, ducts in conditioned space, and TES integration for summer load-shifting. Although this AWHP+TES strategy is not yet mainstream, the authors feel that in ten years as decarbonization efforts proceed and TOU rates become more common, strategies such as this will be more accessible. Validated EnergyPlus simulation models were developed based on detailed monitoring data collected over several years at Pacific Gas and Electric's CVRH laboratory test homes located in Stockton, California. One of the CVRH test homes (1,962 ft 2 two-story) had been testing various AWHP systems and configurations over the past six years. The validated model was then updated with high efficiency IECC ZERH envelope and component requirements for climate zones 1-5, including ducts in conditioned space thermal distribution. Simulations were completed for the 1,962 ft 2 home in each climate zone for a minimum efficiency ASHP, an AWHP coupled with a fan coil, and an AWHP coupled with TES sized to eliminate summer on-peak compressor operation. To maintain consistency in reporting energy use estimates, all cases were run with a similar indoor thermostat control strategy to pre-cool the house below the nominal 76 degrees Fahrenheit set point prior to the on-peak period and float slightly above the set point during the peak period. The AWHP+TES configuration was controlled to alternately condition the indoor space or to charge the TES tanks prior to the beginning of the on-peak. Three composite TOU rates were developed based on existing TOU rates across the U.S. to provide differing economic scenarios to evaluate customer bill impacts throughout the summer. Two of the TOU rates had short three-hour peak periods, while the third rate had a longer seven-hour duration peak period. AWHP modeling projections were based on the observed field performance of the Chiltrix CX34 variable speed unit. Other products on the market or entering the market in the near term would likely perform differently.

25 ENERGY STORAGE↗
DOE OSTI2023

Air Source Heat Pumps in Very Cold Climates

Air source heat pumps (ASHPs) in heating mode use a refrigeration cycle to remove heat from the outside air and transfer it into a building. Therefore, ASHPs have the potential to save energy compared to conventional heat sources that create the heat as opposed to transferring it from outside. Many cold climate ASHPs available on the market today can operate at outside temperatures of -25 degrees C (-13 degrees F) or even lower. As a result of technological advances and other factors, there is growing interest in ASHPs in cold climates, including very cold regions such as Alaska. However, guidance on the selection, installation, and operation of ASHPs in these very cold climates is limited, as significant data gaps exist regarding the performance of ASHPs in very cold environments. To address these data gaps and guide future innovations, our research team has studied the field performance of several ASHP installations in Alaska and done lab evaluations of several ASHP models using a cold chamber. While a cold chamber cannot fully reflect field conditions, it allowed for changing one variable at a time and gaining additional understanding of the behavior of ASHPs that would be difficult to gain from field studies only. This study focused on two main variables: the temperature in the chamber (representing the outdoor temperature) and the level of thermal loading of the ASHP. The results from the field as well as the lab show that ASHPs can operate with relatively high efficiency even in very cold climates if used in appropriate situations and in an appropriate way. It was found that not only the outside temperature, but also the level of thermal loading is a significant factor affecting the ASHP efficiency and needs to be carefully considered when sizing and operating ASHPs in very cold climates.

air source heat pump↗
DOE OSTI2023

Exploration of Heat-Driven Ejector High-Temperature Heat Pumps

Heat-driven ejector heat pumps use a supersonic ejector as a thermo-compressor to replace the mechanical compressor. Supersonic ejectors have many advantages in high-temperature heat pump (HTHP) applications, including high operating temperature tolerance, no need for lubrication, low maintenance, and low cost. The coefficient of performance of ejector HTHPs could be improved by selecting binary fluids with unique thermodynamic properties. Although supersonic ejectors have been widely used in refrigeration systems, their application in spaces and water heating is limited. This study explores the theoretical potential of ejector HTHPs with a sink temperature of 100°C–130°C and a lift temperature of 10°C–30°C. Ejector HTHPs were evaluated with single-fluid ejectors (SFEs) and binary-fluid ejectors (BFEs). A comprehensive, geometry-free theoretical model of BFEs was developed to predict the theoretical maximum entrainment ratios. HFE7500 and R718 (water) were selected as working fluids for SFEs and BFEs. SFEs operating with R718 provided a higher coefficient of performance of ejector HTHPs than SFEs operating with HFE7500 and BFEs. This study preliminarily demonstrates the technical potential of ejector HTHP applications in recovering moderate-temperature heat sources

Wang, Pengtao↗
DOE OSTI2023

An Update on the Colossus mK platform at Fermilab

As part of the efforts of the Superconducting Quantum Materials and Systems National Quantum Center at Fermilab, we will construct a large millikelvin refrigeration platform known as Colossus. The Colossus platform will be used for quantum computing applications, along with physics and sensing experiments. At the preceding CEC/ICMC meeting in 2021, we reported on the conceptual design of the platform. In the intervening time, the design of the system has been completed and passed through review, with construction now underway. This paper provides an update on the overall design of the system, and the status of and timeline for construction.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2023

Warm Compressor system Overview and status of the PIP-II cryogenic system

The Proton Improvement Plan-II (PIP-II) is a major upgrade to the Fermilab accelerator complex, featuring a new 800-MeV Superconducting Radio-Frequency (SRF) linear accelerator (Linac) powering the accelerator complex to provide the world's most intense high-energy neutrino beam. The PIP-II Linac consists of 23 SRF cryomodules operating at 2 K, 5 K, and 40 K temperature levels supplied by a single helium cryoplant providing 2.5 kW of cooling capacity at 2.0 K. The PIP-II cryogenic system consists of two major systems: a helium cryogenic plant and a cryogenic distribution system. The cryogenic plant includes a refrigerator cold box, a warm compressor system, and helium storage, recovery, and purification systems. The cryogenic distribution system includes a distribution box, intermediate transfer line, and a tunnel transfer line consisting of modular bayonet cans which supply and return cryogens to the cryomodules. A turnaround can is located at the end of the Linac to turnaround cryogenic flows. This paper describes the layout, design, and current status of the PIP-II cryogenic system.

43 PARTICLE ACCELERATORS↗
DOE OSTI2023

A hybrid method to evaluate the life cycle climate performance of heat pumps

Heat pumps have a significant impact on the climate, and numerous studies exist discussing the environmental impact of heat pumps quantitatively. Life Cycle Climate Performance (LCCP) is a widely accepted metric and can evaluate the carbon footprint of heat pumps from cradle to grave. LCCP calculation typically requires inputs like annual energy consumption, the material used, refrigerant type, and charge level, which are usually the intermediate or final results from heat pump simulation tools. Thus, a platform linking the heat pump simulation software, local weather conditions, and LCCP evaluation tool can simplify the heat pump design process, especially for complicated systems. This paper presents an LCCP evaluation tool accessing the outputs from the DOE Heat Pump Design Model and the building loads and temperature bin data from AHRI standard 210/240. As for case studies, this paper investigates the LCCP values and life cycle electricity costs (LCEC) of a given cooling-based heat pump with R410A in five typical US cities. In conclusion, this cooling-based heat pump has the highest LCCP value at Chicago and lowest LCCP value at Seattle. In contrast, the heat pump has the highest LCEC at Seattle and the lowest LCEC at Miami. As a future work, a more comprehensive carbon emission and cost analysis of heat pump systems will be conducted through all major cities around the world.

Shen, Bo↗
DOE OSTI2023

Cooling systems having an integrated ionic liquid salt dehumidification system

A cooling system utilizes an organic ionic salt composition for dehumidification of an airflow. The organic ionic salt composition absorbs moisture from an inlet airflow to produce an outlet airflow with a reduce moisture from that of the inlet airflow. The organic ionic salt composition may be regenerated, wherein the absorbed moisture is expelled by heating with a heating device. The heating device may be an electrochemical heating device, such as a fuel cell, an electrochemical metal hydride heating device, an electrochemical heat pump or compressor, or a condenser of a refrigerant cycle, which may utilize an electrochemical pump or compressor. The efficiency of the cooling system may be increased by utilization of the waste heat the cooling system. The organic ionic salt composition may circulate back and forth or in a loop between a conditioner, where it absorbs moisture, to a regenerator, where moisture is desorbed by heating.

Bahar, Bamdad↗