Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “production monitoring”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 649 records · Page 36

Rapid Analytical Methodology for Chloride Molten Salt Reactor Safeguards and Process Monitoring

Technologies that enable near real-time isotopic analysis of advanced molten salt reactor (MSR) fuels are critically needed to safeguard these reactors, increase their operational efficiency, and enable their widespread deployment with confidence. We present a systematic approach to developing near real-time dissolution and chemical isolation of U, Pu, and major fission products from highly radioactive chloride molten salt samples. Chemical yields greater than 95% were observed for both uranium and the lanthanides. Interference reduction enabled the detection and quantification of key diagnostic isotopes (including 112Ag, 147Nd, and 153Sm) that were previously undetectable in the original sample. The results from this initial scoping study lay the foundation for the development of future automated systems that can enable cost-efficient, near-real time chemical separation and analysis of extremely highly radioactive molten salt samples.

38 - RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCL↗

Downhole laser system with an improved laser output production and data collection

One or more embodiments relates to a method of growing ultrasmooth and high quantum efficiency CsTe photocathodes. The method includes exposing a substrate of Cs using an alkali source such as an effusion cell; and controlling co-evaporating growth and co-deposition forming a CsTe growth. The method further includes monitoring a stoichiometry of the CsTe growth.

Mcintyre, Dustin↗

Downhole laser system with an improved laser output production and data collection

One or more embodiments relates to a method of growing ultrasmooth and high quantum efficiency CsTe photocathodes. The method includes exposing a substrate of Cs using an alkali source such as an effusion cell; and controlling co-evaporating growth and co-deposition forming a CsTe growth. The method further includes monitoring a stoichiometry of the CsTe growth.

McIntyre, Dustin↗

Assessing the Effectiveness of Large-Scale Environmental Restoration: Challenges and Opportunities

A recent National Academies consensus report addresses monitoring and assessment of cumulative effects of large-scale and multiple restoration projects within the context of long-term environmental change. Fines and penalties from the Deepwater Horizon oil spill in the Gulf of Mexico (GoM) have supported hundreds of restoration projects at spatial scales not often possible in the past. Here, in this paper, the report committee members and staff provide personal reflections from our time working on the study. We found that gaps in data collection, issues with data accessibility, and a lack of synthesis and analysis are hindering the ability to answer a basic question: What are the impacts of these many restoration efforts on improving ecosystem health and productivity in the GoM at the regional and Gulf wide scale? Restoration efforts are occurring in environments where many trends are changing and exhibiting higher variability than in the past, suggesting that previously successful restoration practices may no longer be adequate to compensate for the effects of environmental changes and variability. Our proposed approach to these challenges includes employing emerging monitoring technologies; using conceptual models; devising an adaptive management framework; rethinking restoration outcome goals; assessing cumulative effects; and undertaking rigorous synthesis and analysis of existing information on long-term environmental trends and restoration efforts. Restoration scientists and practitioners working in the GoM have an unprecedented opportunity to demonstrate large-scale environmental recovery if advances in monitoring, synthesis, assessment, and action are taken quickly. We are cautiously optimistic that, with mid-course adjustments, continued progress toward large-scale environmental recovery is possible.

54 ENVIRONMENTAL SCIENCES↗

The value of adding black carbon to community monitoring of particulate matter

Low-cost particulate matter (PM) sensors are increasingly used by researchers, public health agencies, and the public to measure spatial and temporal variations in air pollution, which can inform strategies for community air pollution reduction. While low-cost PM sensors provide a valuable measure of harmful fine particulate matter (PM 2.5 ), a significant portion of ambient PM 2.5 is typically the secondary product of air pollution emitted by varied sources outside of community boundaries. In contrast, concentrations of black carbon (BC), a component of PM 2.5 , are directly emitted by a few specific sources, such as diesel engines within communities. Motivated by community organizations seeking to understand persistent sources of local pollution, this study deployed a suite of custom-built BC sensors alongside a network of low-cost PM sensors for four weeks in two seasons at 50 stationary locations in the adjacent cities of Richmond, North Richmond, and San Pablo, California, east of the San Francisco Bay. Concentrations of BC varied more than PM 2.5 both temporally and spatially. Monthly network-average BC was 3×higher in winter than late spring, while PM 2.5 was only 10% lower. In both seasons, average PM 2.5 concentrations at two-thirds of sites were within ±10% of the network average, whereas two-thirds of sites had BC levels outside of ±10% of the network-average concentration. The most and least polluted locations were more persistent across seasons for BC than PM 2.5 , and the temporal dynamics of BC at these sites were similar, signifying that they are impacted by the same emission sources. Together, these spatiotemporal trends show that BC is a better indicator of the proximity and activity of local pollution sources than PM 2.5 . Thus, including BC in addition to PM 2.5 in community monitoring networks can provide additional insights about local sources of air pollution.

54 ENVIRONMENTAL SCIENCES↗

The Potential and Cost of Carbon Dioxide Removal Using Direct Air Capture with Land-Based Wind and Utility-Scale Photovoltaics

The rapid deployment of direct air capture and storage (DACS) is critical for achieving emission targets, necessitating precise evaluation of the scale and cost of carbon dioxide removal. This study examines the availability of land, electricity generation, and geologic CO 2 storage within the United States, estimating a technical potential for low-temperature, adsorbent-based DACS to remove approximately 9 gigatonnes of CO 2 annually. By 2050, a substantial portion of this removal could be achieved at net-removed costs below $\$$300/tonneCO 2 , though costs are highly variable depending on factors such as facility scale, construction expenses, climate-dependent productivity and heating efficiency, and geologic storage conditions. In the short term, DACS deployment will help identify key research priorities for advancing technology and reducing removal costs. Concurrently, there is an urgent need for scientifically robust and standardized frameworks for monitoring, reporting, and verifying DACS performance across both established and emerging technologies and energy sources.

Carbon capture↗

Prediction of Solution Behavior via Calorimetric Measurements Allows for Detailed Elucidation of Polyoxometalate Transformation

The solution behavior of a polyoxometalate cluster, LiNa-U 24 Pp 12 (Li 24 Na 24 [(UO 2 O 2 ) 24 (P 2 O 7 ) 12 ]) that consists of 24 uranyl ions, peroxide groups, and 12 pyrophosphate linkers, was successfully predicted based on new thermodynamic results using a calorimetric method recently described for uranyl peroxide nanoclusters (UPCs), molybdenum blues, and molybdenum browns. The breakdown of LiNa-U 24 Pp 12 and formation of U 24 (Li 24 [UO 2 O 2 OH] 24 ) was monitored in situ via Raman spectroscopy using a custom heating apparatus. A combination of analytical techniques confirmed the simultaneous existence of U 24 Pp 12 and U 24 midway through the conversion process and U 24 as the single end product. The application of a molecular weight filter resulted in a complete and successful separation of UPCs from solution and, in conjunction with DOSY results, confirmed the presence of large intermediate cluster building blocks.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Opportunities, Challenges, and Research Needs for Remote Microreactor Operations

As the nuclear industry develops new advanced reactor technologies, many companies are embracing this advancement by pursuing the development of microreactors. The term microreactor generally refers to a nuclear reactor with an operating power of 20 MW(thermal) or less. The power range of microreactors makes them appealing for many use cases, such as powering remote communities, mining sites, and military bases. Most of the microreactor designs being pursued are expected to incorporate remote facility operations into the final product. However, no framework has yet been developed to determine what remote operations systems require for reliable, resilient, and secure operation of a microreactor. Here, this work identifies the research needs for challenges that are unique to remote operations and monitoring for microreactors, specifically regarding instrumentation and control, communication methods, regulatory requirements, and operational policies. The types of commands and sensor measurements that must be transmitted between the facilities, as well as methods for verifying the trustworthiness of these signals, are assessed. This work evaluates the security, reliability, and performance requirements that must be met when considering the selection of communication hardware and protocols for use in remote operations. Also, an assessment was performed to study how remote operations fit within current regulatory requirements and what may need to be updated in regulatory policy to allow for remote operation. Finally, the operational contingencies unique to remote operations that must be in place for responses to abnormal events are identified. This paper identifies the challenges and research opportunities within the areas of importance for the design of remote operation systems.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Demonstration of Novel Monitoring Techniques for a North Dakota Carbon Capture and Storage Project

Conference paper presented at 16th International Conference on Greenhouse Gas Control Technologies (GHGT-16), Lyon, France, October 23–27, 2022. We present an overview and initial results of the novel and sustainable monitoring techniques developed by the Energy & Environmental Research Center (EERC) and its commercial partners associated with the Red Trail Energy (RTE) carbon capture and storage (CCS) project. RTE is an investor-owned 64-million-gallon dry mill ethanol production plant in Richardton, North Dakota, USA. Currently in operation as of June 2022, the RTE facility will capture 180,000 tonnes of carbon dioxide (CO 2 ) annually (>99% CO 2 ) that is otherwise emitted during the ethanol production process and inject it into the Broom Creek Formation, a deep saline aquifer, for permanent on-site geologic storage.

01 COAL, LIGNITE, AND PEAT↗

Role of chemical production and depositional losses on formaldehyde in the Community Regional Atmospheric Chemistry Multiphase Mechanism (CRACMM)

Abstract. Formaldehyde (HCHO) is an important air pollutant with direct cancer risk and ozone-forming potential. HCHO sources are complex because HCHO is both directly emitted and produced from oxidation of most gas-phase reactive organic carbon. We update the secondary production of HCHO in the Community Regional Atmospheric Chemistry Multiphase Mechanism (CRACMM) in the Community Multiscale Air Quality (CMAQ) model. Production of HCHO from isoprene and monoterpenes is increased, correcting an underestimate in the current version. Simulated June–August surface HCHO during peak photochemical production (11:00–15:00 LT, local time) increased by 0.6 ppb (32 %) over the southeastern USA and by 0.2 ppb (13 %) over the contiguous USA. The increased HCHO compares more favorably with satellite-based observations from the TROPOspheric Monitoring Instrument (TROPOMI) and from aircraft-based observations. Evaluation against hourly surface observations indicates a missing nighttime sink that can be improved by increased nighttime deposition, which reduces June–August nocturnal (20:00–04:00 LT) surface HCHO by 1.1 ppb (36 %) over the southeastern USA and 0.5 ppb (29 %) over the contiguous USA. The ability of CRACMM to capture peak levels of HCHO at midday is improved, particularly at sites in the northeastern USA, while peak levels at sites in the southeastern USA are improved, although still lower than observed. Using established risk assessment methods, lifetime exposure of the population in the contiguous USA (∼ 320 million) to ambient HCHO levels predicted here may result in 6200 lifetime cancer cases, with 40 % from controllable anthropogenic emissions of nitrogen oxides and reactive organic compounds. Chemistry updates will be available in CRACMM version 2 (CRACMM2) in CMAQv5.5.

Skipper, T. Nash↗

Analysis of measurements from an array of radioxenon samplers near to Hartlepool Nuclear Power Station

As part of a scientific research and development project, the radionuclide fingerprint of an operating advanced gas-cooled reactor 25 (AGR) has been studied across several facets (Goodwin et al., 2024). One part of this project was to deploy an array of 26 radioxenon samplers to the region for a period of around 1 year, to measure any radioxenon emissions from the reactors of the 27 Hartlepool nuclear power station at a range of tens of kilometres away. The array of 3 sensors was operational for around 12 28 months from March 2022 and detected many occurrences of isotopes of radioxenon. Here we provide a detailed analysis and 29 interpretation of the data and where possible, attribution of detections to a source or region. Whilst a key part of this work is to 30 measure any emissions of radioxenon from Hartlepool, this work presents one of the most comprehensive efforts to determine the 31 source of a great number of (mostly) 133Xe detections. A combination of different types of atmospheric dispersion modelling 32 techniques, including the use of stack monitoring data from nearby civil radioxenon-emitting nuclear facilities has enabled the 33 majority of detections to be attributed to one or more possible sources. Whilst emissions from Hartlepool have been detected on 34 the systems, the majority of detections are associated with a medical isotope production facility in Fleurus, Belgium (IRE).

Advanced gas-cooled reactor↗

Characterizing Plug Load Energy Use and Savings Potential in Army Buildings

The Assistant Secretary of the Army (Installations, Energy and Environment) tasked the Pacific Northwest National Laboratory to examine plug loads in typical Army buildings. Plug loads (also known as miscellaneous electric loads (MELs)) represent the electricity used by appliances and devices that are plugged in or hardwired and serve functions outside of a building’s core end uses. Common plug loads include computers, printers, copiers, networking devices, refrigerators, and vending machines. They also include personal electronic devices such as televisions, smart phones, tablets, and gaming systems. Examples of hardwired MELs include elevators, air compressors, and fire and security systems. The findings from this study confirm that significant energy is consumed within Army buildings by plug load devices and hardwired MEL equipment. A number of opportunities are identified for reducing unnecessary energy use that could save the Army over $5 million per year when broadly applied. Army regulations clearly spell out expectations for the purchase and operation of information technology equipment (computers, laptops, monitors, printers, and multi-function devices). However, the policies regarding the shutdown or activation of sleep and other lower power modes after 30 minutes of inactivity (15 minutes for monitors) do not appear to be consistently followed. There are many effective approaches and pathways for impacting change as it relates to improving awareness, implementing measures, and adjusting behaviors to identify and reduce plug load energy use. The Army should prioritize and consider deploying all of these to better understand and manage plug load equipment to save energy and enhance resilience across their facilities. Engaging the building occupants who use these devices daily via outreach and education should be a strong component of the strategy. The focus should be on reducing waste without sacrificing productivity or the benefits that many of these devices provide. Continued evaluation of plug loads beyond that performed here is important to gather lessons from additional building and equipment types, and to stay aware of evolving device technology and management options. This will highlight additional needs for policies, best practices, control technologies, and education of personnel to achieve real reductions in energy waste from plug load equipment. It is recommended that this study may serve as the foundation for a broader and sustained focus on plug loads and MELs, towards simultaneously enhancing the productivity, readiness, and resilience of the Army while reducing energy use and demand, and freeing up resources to better support the mission.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Performance of the Pair Spectrometer in Hall D at Jefferson Lab

This article describes the performance of the pair spectrometer installed in experimental Hall D at Jefferson Lab and its successfully operation in multiple experiments with the GlueX detector. The primary purpose of the pair spectrometer is the precise determination of the flux of beam photons incident on the GlueX target, a critical input for physics analyses such as absolute cross-section measurements. The photon energy spectrum is determined by reconstructing electron–positron pairs produced in a thin converter inserted into the photon beam. The spectrometer is integrated into the GlueX trigger system, whose electronics enable continuous real-time monitoring of the photon flux and the recording of e+e- pair candidates for offline analysis. In addition, the pair spectrometer provides a versatile test facility for evaluating calorimeter prototypes using leptons with well-defined energies produced via electromagnetic pair production.

Somov, Alexander [Jefferson Lab]↗

Decoupling electrode kinetics to elucidate reaction mechanisms in alkaline water electrolysis

Alkaline water electrolysis (AWE) presents key advantages, including reduced material costs, enhanced operational stability, and compatibility with non-precious metal catalysts, positioning it as a scalable route for hydrogen production. In this study, we introduce a minimally invasive single-cell configuration incorporating a reference electrode via diaphragm extension to form an internal ion channel. This setup, combined with an interfaced potentiostat and auxiliary electrometer, enables real-time, independent monitoring of anode and cathode behavior, offering high-resolution electrochemical diagnostics. While it is well established that the hydrogen evolution reaction (HER) exhibits sluggish kinetics in alkaline media, our study reveals that this limitation persists even in practical AWE systems where nickel-based substrates are used as electrodes. This observation is supported by both experimental data and voltage breakdown modeling. Arrhenius-type analysis reveals that localized electric fields induced by catalysts shift the reaction kinetics from classical Butler–Volmer behavior toward a Marcus-like regime, where interfacial molecular dynamics and bimolecular charge transfer dominate. We propose a semi-empirical model and a surficial reaction mechanism to describe these dynamics. This work underscores the critical need for cathode innovation and provides a rational framework for designing advanced catalysts and electrode architectures to optimize AWE performance.

08 HYDROGEN↗

Real-Time Inventory Change Detection for the Protactinium Decay Inventory of the Molten Salt Breeder Reactor

This work presents a novel monitoring method for detecting material loss from the decay inventory of the molten salt breeder reactor (MSBR) by monitoring for changes to the system dynamics using an isotopic ratio. Here the isotopic masses in the decay inventory of a MSBR were simulated under several material loss scenarios. In each case, the ratio of 231 Pa to 233 Pa served as a sensitive and lasting indicator of material loss. This isotope ratio quickly decreased outside the normal range after a material loss, and the ratio remained depressed for several years after the loss. The dynamics of this ratio were driven by the periodic batch discard from the decay inventory every 220 days, which was specified in the MSBR design to periodically remove fission product buildup. For this method, isotopic ratios were found to be rapid and enduring indicators of inventory change if they comprise a pair with a short half-life (e.g., 233 Pa) and a long half-life (e.g., 231 Pa) relative to the effective half-life induced by the driving system process (e.g., the batch discard cycle). Using such an isotope pair enabled a method to monitor for changes to the effective half-life of the system and by extension changes to the system inputs and outputs.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Indoor Occupant Counting by RF Backscattering

Building HVAC (heating, ventilation and air conditioning) consumes approximately 13% of all energy consumption in USA. Motion detectors, cameras and user programmable thermostats have been shown to be ineffective for HVAC controls to save energy, mostly due to the user concerns of comfort, reliability and privacy. A new HVAC control system based on real-time occupant counting that is fully automated, highly accurate, economically sensible and preserving privacy and aesthetics can thus bring forth a disruptive impact to this large energy sector. Our indoor occupant monitoring technology is based on the radio-frequency identification system (RFID), deployed in the room, not on the occupants. One reader with four antennas can be deployed on the ceiling or behind the ceiling panels for every thousand square feet in home, office and assisted living, with or without room partitions. The sticker-like passive tag, 10 cents each and maintenance-free, are profusely hidden on the wall or inside the furniture at arbitrary position, preserving privacy and aesthetics. The large number of tags can realize diverse observation points to accommodate arbitrary room layouts, which is impractical by other active units of camera, infrared, radar or lidar. With 20 tags, the system can reliably detect the number of occupants. For 100 tags, occupant posture and location can be known. The technology has been verified in the research labs and test buildings with very high accuracy. When the real-time occupant number can be accurately known without assuming devices on occupants or occupant motion, the building HVAC system can be automated to achieve building energy saving without sacrificing occupant comfort. According to our limited testing in a few types of building models and the simplified cost calculation, the RFID system has low overall cost in production, deployment, operation and maintenance. The signal processing algorithm based on machine learning requires very small number of training cases as most learning is transferrable for various layouts, and very low computational needs during operation, according to our testing in four different room sizes and layouts. In our preliminary estimate from HVAC saving alone, the RFID system can potentially pay for itself within 1.5 years, in addition to the other enhancement in building automation systems (BAS). Our commercialization strategy and business pitch deck focus on venturing this Cornell occupant monitoring technology into BAS and energy management markets. We have identified three broad BAS market segments of senior living, residential buildings, and office buildings. We have put together the minimum viable product characteristics for these identified segments, including analyses on total cost and competing technologies, as well as the fit and technical gaps for these market segments. We intend to bring the technology to market by licensing or partnering with existing BAS vendors. A list of potential collaborators and licensing partner candidates was assembled for different aspects of integrating our technology into a potential product that can be used with BAS.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Model and remote-sensing-guided experimental design and hypothesis generation for monitoring snow-soil–plant interactions

In this study, we develop a machine-learning (ML)-enabled strategy for selecting hillslope-scale ecohydrological monitoring sites within snow-dominated mountainous watersheds, with a particular focus on snow-soil–plant interactions. Data layers rely on spatial data layers from both remote sensing and hydrological model simulations. Specifically, a Landsat-based foresummer drought sensitivity index is used to define the dependency of the annual peak plant productivity on the Palmer drought severity index in the early growing season. Hydrological simulations provide the spatiotemporal dynamics of near-surface soil moisture and snow depth. In this framework, a regression analysis identifies the key hydrological variables relevant to the spatial heterogeneity of drought sensitivity. We then apply unsupervised clustering to these key variables, using the Gaussian mixture model, to group hillslopes into several zones that have divergent relationships regarding soil moisture, snow dynamics, and drought sensitivity. Using the datasets collected in the East River Watershed (Crested Butte, Colorado, United States), results show that drought sensitivity is significantly correlated with model-derived soil moisture and snow-free timing over space and time. The relationship is, however, non-linear, such that the correlation decreases above a threshold elevation and in a heavy snow year due to large snowpacks, lateral flow, and soil storage limitations. Clustering is then able to define the zones that have high or low sensitivity to drought, as well as the mid-elevation regions where sensitivity is associated with the topographic aspect and net potential radiation. In addition, the algorithm identifies the most representative hillslopes with road/trail access within each zone for installing monitoring sites. Our method also aims to significantly increase the use of ML and model-simulation results to guide critical zone and watershed monitoring activities.

54 ENVIRONMENTAL SCIENCES↗

Cement sensors with acoustic bandgaps using carbon nanotubes

Cement is widely used in wellbores to stabilize the steel casing used in wellbore operations for oil and gas production, enhanced geothermal systems and carbon sequestration, and to limit fluid movement between sub-surface strata. Flaws such as microcracks in wellbore cement can lead to leakage along the wellbore compromising wellbore integrity. There is an increasing need for methods to monitor cement crack propagation in wellbore environments. In this study, we develop and report the first cementitious sensors capable of exhibiting high frequency acoustic bandgaps (ABGs) using carbon nanotubes (CNTs). Computational simulations of a sensor unit cell are used to design cement-multi walled carbon nanotubes (MWCNTs) sensors that show a wide bandgap. When the cement-MWCNTs sensors is embedded in cement specimens, bandgaps were measured experimentally under 300 kHz and under 600 kHz, consistent with the computationally predicted bandgaps in the range of 290–360 kHz, 410–460 kHz and 515–585 kHz. These bandgap features were absent in homogeneous cement specimens. X-ray tomographic reconstructions showed microscopic debonding at cement-MWCNTs sensor interface. Frequency response analysis of a three-dimensional computational model indicated a shift of frequency of minimum transmission due to the interface debonding, but no perturbation of bandgap response was observed. Here, the cement-MWCNTs sensors developed in this study show the potential of a packed CNT inclusion material in cementitious matrix to create ABGs in a cement matrix.

36 MATERIALS SCIENCE↗